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1.发明授权Method of reducing the content of residual monomers in aqueous polymer dispersions 失效降低水性聚合物分散体中残留单体含量的方法公开(公告)号：US06444760B1
公开(公告)日：2002-09-03
申请号：US09508104
申请日：2000-03-17
IPC分类号： C08F600
CPC分类号： C08F6/006
摘要： A process is described for effectively reducing the residual monomer content of an aqueous polymer dispersion by aftertreatment at atmospheric pressure or above with an initiator system comprising a) a hydroperoxide, hydrogen peroxide or a peracid, and b) an &agr;-hydroxy carboxylic acid, such as tartaric acid, or with a salt thereof.
摘要翻译： 描述了一种方法，用于通过包括a）氢过氧化物，过氧化氢或过酸的引发剂体系，和b）α-羟基羧酸，在大气压或以上的后处理有效降低聚合物水分散体的残留单体含量， 作为酒石酸，或其盐。
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2.发明授权Method for reducing residual monomers in liquid systems by adding an oxidation-reduction initiator system 有权通过添加氧化还原引发剂体系来减少液体体系中残留单体的方法公开(公告)号：US06462138B1
公开(公告)日：2002-10-08
申请号：US09508089
申请日：2000-03-15
申请人： Robert Rupaner , Sven Lawrenz , Johannes Dobbelaar , Gerhard Bauer , Franz-Josef Mueseler , Werner Kirchner , Bradley Ronald Morrison , Jürgen Nahstoll , Martin Meister , Reinhard Bächer , Wolfgang Hübinger , Gerhard Schumacher
发明人： Robert Rupaner , Sven Lawrenz , Johannes Dobbelaar , Gerhard Bauer , Franz-Josef Mueseler , Werner Kirchner , Bradley Ronald Morrison , Jürgen Nahstoll , Martin Meister , Reinhard Bächer , Wolfgang Hübinger , Gerhard Schumacher
IPC分类号： C08F600
CPC分类号： C08F6/003 , C08F6/006 , Y10S526/919
摘要： A process is described for reducing the residual monomer content in a liquid solution, mixture, melt, suspension or dispersion of a polymer by postpolymerization with addition of a redox initiator system at a reaction temperature appropriate to it and with an extremely short mixing time of the liquid system in the production reactor by metering—gradually, in portions or continuously—at least one of the redox initiator components required to initiate polymerization of the residual monomers over a period (metering time) which is from about 10 to 250 times the mixing time of the liquid system in said reactor.
摘要翻译： 描述了一种方法，用于通过在适合于它的反应温度下加入氧化还原引发剂体系并以极短的混合时间减少聚合物的液体溶液，混合物，熔体，悬浮液或分散体中的残余单体含量， 液体系统在生产反应器中逐渐，部分或连续地至少一种氧化还原引发剂组分在一段时间（计量时间）内引发聚合残留单体所需的量，其为混合时间的约10至250倍 的液体系统。
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公开(公告)号：US06086723A
公开(公告)日：2000-07-11
申请号：US134926
申请日：1998-08-17
申请人： Wolfgang Hubinger , Rainer Wunder , Gerhard Bauer , Johannes Dobbelaar , Sven Lawrenz , Franz-Josef Mueseler , Jurgen Nahstoll , Robert Rupaner , Christian-Ulrich Schmidt
发明人： Wolfgang Hubinger , Rainer Wunder , Gerhard Bauer , Johannes Dobbelaar , Sven Lawrenz , Franz-Josef Mueseler , Jurgen Nahstoll , Robert Rupaner , Christian-Ulrich Schmidt
CPC分类号： B01J19/2465 , B01J19/0013 , C08F6/003 , B01J2219/00103 , B01J2219/00108 , B01J2219/0011 , B01J2219/00123 , B01J2219/0025 , Y10S203/90
摘要： A process for deodorizing and subsequently cooling dispersions or liquids comprisinga) passing steam through the dispersion or liquid to be cooled and held in a vessel (1), said dispersion or liquid being caused to foam up as a result,b) discharging the foam from the top section of the vessel via a nozzle (5) into an evacuated separation vessel (4), the foam being broken in the process,c) condensing the water vapor formed from the foam in a heat exchanger (8) and removing volatile organic components at the same time, andd) returning the broken foam to the vessel (1),in which the steps a) to d) are performed until the dispersion or liquid has been deodorized to the desired extent, wherein, after completion of the deodorization (in accordance with steps a) to d)), the hot dispersion or liquid is discharged from the bottom section of the vessel (1) through the nozzle (5) into the evacuated separation vessel (4), so that the dispersion or the liquid is cooled, the nozzle (5) and the evacuated separation vessel (4) also being used beforehand for performing step b), wherein the water vapor held in the separation vessel (4) is condensed at the heat exchanger (8) which was also employed beforehand in step c), and wherein the cooled dispersion or liquid is discharged from the bottom of the separation vessel (4).
摘要翻译： 一种用于除臭和随后冷却分散体或液体的方法，包括a）使蒸汽通过待冷却的分散体或液体并保持在容器（1）中，使所述分散体或液体发泡，结果b）排出泡沫 从容器的顶部经由喷嘴（5）到抽空的分离容器（4）中，泡沫在该过程中被破坏，c）将由泡沫形成的水蒸汽在热交换器（8）中冷凝并除去挥发性 有机成分，d）将破碎的泡沫返回到容器（1），其中进行步骤a）至d），直到分散体或液体已经被除臭至所需程度，其中在完成 除臭（根据步骤a）至d）），热分散体或液体通过喷嘴（5）从容器（1）的底部排出到抽空的分离容器（4）中，使得分散体 或液体被冷却，喷嘴（5）和e 真空分离容器（4）也预先用于进行步骤b），其中保持在分离容器（4）中的水蒸汽在步骤c）中预先使用的热交换器（8）冷凝，其中 冷却的分散体或液体从分离容器（4）的底部排出。
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公开(公告)号：US06252018B1
公开(公告)日：2001-06-26
申请号：US09039189
申请日：1998-03-16
申请人： Robert Rupaner , Sven Lawrenz , Gerhard Bauer , Johannes Dobbelaar , Jürgen Nahstoll , Franz-Josef Mueseler , Axel Ferber , Jürgen Hartmann , Peter Keller , Martin Meister , Josef Neutzner , Gerd Rehmer
发明人： Robert Rupaner , Sven Lawrenz , Gerhard Bauer , Johannes Dobbelaar , Jürgen Nahstoll , Franz-Josef Mueseler , Axel Ferber , Jürgen Hartmann , Peter Keller , Martin Meister , Josef Neutzner , Gerd Rehmer
IPC分类号： C08F201
CPC分类号： C08F6/006 , B01F7/00433 , B01J19/18 , B01J19/20 , B01J2219/00094 , B01J2219/00177 , B01J2219/00189 , B01J2219/185
摘要： At least one single-stage or multistage stirrer which produces not only a tangential flow component but also an axial flow field is used in a stirred-vessel reactor in connection with the preparation of polymers by liquid phase polymerization.
摘要翻译： 在通过液相聚合制备聚合物的搅拌釜反应器中使用至少一个单级或多级搅拌器，其不仅产生切向流分量而且产生轴向流场。
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5.发明授权公开(公告)号：US06303726B1
公开(公告)日：2001-10-16
申请号：US09147659
申请日：1999-02-09
申请人： Bernhard Schuler , Gerhard Auchter , Johannes Türk , Rik Noordijk , Johannes Dobbelaar , Reinhard Bächer , Wolfgang Hümmer
发明人： Bernhard Schuler , Gerhard Auchter , Johannes Türk , Rik Noordijk , Johannes Dobbelaar , Reinhard Bächer , Wolfgang Hümmer
IPC分类号： C08F11802
CPC分类号： C09J133/064 , C08F220/12 , C09J2201/606 , Y10T428/2826
摘要： A polymer which contains from 50 to 99.98% by weight of a C1-C12 alkyl (meth)acrylate a), from 0.02 to 10% by weight of a vinylaromatic compound b), from 0 to 10% by weight of an ethylenically unsaturated acid or of an ethylenically unsaturated acid anhydride c), and from 0 to 40% by weight of further monomers d), the percentages by weight being based on the polymer and the polymer being obtainable by polymerizing the monomers a) to d) in at least two stages which differ in their content of vinylaromatic compounds in such a way that the content of vinylaromatic compounds in the vinylaromatics-rich stage is at least 5 times as great as in the low-vinylaromatics stage.
摘要翻译： 含有50〜99.98重量％的（甲基）丙烯酸C 1 -C 12烷基酯a），0.02〜10重量％的乙烯基芳族化合物b），0〜10重量％的烯键式不饱和酸或 的烯属不饱和酸酐c）和0至40重量％的另外的单体d），所述重量百分比基于聚合物和聚合物，其可通过将单体a）至d）聚合至少两个阶段 其中乙烯基芳族化合物的含量不同，使得在富含乙烯基芳烃的阶段中的乙烯基芳族化合物的含量是低乙烯基芳烃化合物阶段的至少5倍。
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6.发明授权Method for reducing the quantity of residual monomers in aqueous polymeric dispersions 失效降低水性聚合物分散体中残余单体量的方法公开(公告)号：US06433132B1
公开(公告)日：2002-08-13
申请号：US09784452
申请日：2001-08-17
IPC分类号： C08F600
CPC分类号： C08F6/006
摘要： A process for reducing the amount of residual monomer in aqueous polymer dispersions operates by aftertreatment with an initiator system essentially comprising a) from 0.001 to 5% by weight, based on the total monomer amount used to prepare the polymer dispersion, a1) of an oxidizing agent R1OOH, where R1 is hydrogen or a C1-C8-alkyl or a C6-C12-aryl group, and/or a2) of a compound which in aqueous medium releases hydrogen peroxide, and b) from 0.005 to 5% by weight, based on the total monomer amount used to prepare the polymer dispersion, of a reducing agent prepared from b1) an aldehyde R2CH═O, where R2 is a C1-C12-alkyl group which may contain functional groups and/or may be olefinically unsaturated, and b2) an inorganic dithionite, and c) catalytic amounts of a polyvalent metal ion which is able to exist in a plurality of valence states.
摘要翻译： 用于降低聚合物水分散体中残余单体量的方法通过用引发剂体系进行后处理来操作，所述引发剂体系基本上包含a）0.001至5重量％，基于用于制备聚合物分散体的总单体量，a1）氧化剂 其中R1是氢或C1-C8烷基或C6-C12-芳基，和/或a2）在水性介质中释放过氧化氢的化合物，和b）0.005至5重量％，基于总单体 用于制备聚合物分散体的量，由b）醛，其中R2是可以含有官能团和/或可以是烯属不饱和的C1-C12-烷基，和b2）无机连二亚硫酸盐，和c）催化量 的能够以多个价态存在的多价金属离子。
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公开(公告)号：US5654361A
公开(公告)日：1997-08-05
申请号：US436529
申请日：1995-05-08
IPC分类号： C08F12/04 , C08F236/10 , C08F297/04 , C08L25/10 , C08L25/16
CPC分类号： C08F297/04 , C08F12/04 , C08F236/10 , Y10S524/923
摘要： Polymer prepared by anionic polymerization and having a number average molecular weight of from 300,000 to 10,000,000 contain, as components,from 10 to 100% by weight of an ethylenically unsaturated vinyl-aromatic a),from 0 to 90% by weight of an aliphatic diene having two conjugated double bonds b) andfrom 0 to 30% by weight of further ethylenically unsaturated monomers c).
摘要翻译： 通过阴离子聚合制备的数均分子量为300,000至10,000,000的聚合物含有10至100重量％的烯属不饱和乙烯基芳族化合物a），0至90重量％的脂族二烯 具有两个共轭双键b）和0至30重量％的其它烯属不饱和单体c）。
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公开(公告)号：US6096858A
公开(公告)日：2000-08-01
申请号：US338430
申请日：1999-06-23
IPC分类号： C08F6/00
摘要： The process of the present invention for removing residual volatiles from polymer dispersions by performing first chemical deodorization using an initiator to remove residual monomers and then physical deodorization to remove volatile constituents comprises conducting the chemical deodorization for as long as the decrease in monomers is greater than the increase in secondary components introduced into the dispersion by the initiator, to result reliably in polymer dispersions having a residual volatiles content of less than or equal to 100 ppm.
摘要翻译： 通过使用引发剂进行第一次化学除臭以除去残余单体，然后进行物理除臭除去挥发性成分，本发明从聚合物分散体中除去残留挥发物的方法包括进行化学除臭，只要单体的减少大于 通过引发剂引入到分散体中的次级组分的增加，可靠地得到残留挥发物含量小于或等于100ppm的聚合物分散体。
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9.发明授权公开(公告)号：US06583252B2
公开(公告)日：2003-06-24
申请号：US09860561
申请日：2001-05-21
申请人： Bernhard Schuler , Gerhard Auchter , Johannes Türk , Rik Noordijk , Johannes Dobbelaar , Reinhard Bächer , Wolfgang Hümmer
发明人： Bernhard Schuler , Gerhard Auchter , Johannes Türk , Rik Noordijk , Johannes Dobbelaar , Reinhard Bächer , Wolfgang Hümmer
IPC分类号： C08F11802
CPC分类号： C09J133/064 , C08F220/12 , C09J2201/606 , Y10T428/2826
摘要： A polymer composed overall of from 50 to 99.98 % by weight of C1-C12 alkyl (meth)acrylate a), from 0.02 to 10 % by weight of a vinylaromatic compound b), from 0 to 10 % by weight of an ethylenically unsaturated acid or of an ehtylenically unsaturated acid anhydride c), and from 0 to 40% by weight of further monomers d), the percentages by weight being based on the polymer and the polymer being obtainable by polymerizing the monomers a) to d) in at least two stages which differ in their content of vinylaromatic compounds in such a way that the content of vinylaromatic compounds in the vinylaromatics-rich stage is at least 5 times as great as in the low-vinylaromatics stage.
摘要翻译： 总共由0至40重量％的其它单体组成的聚合物d），其重量百分比基于聚合物和聚合物，其可通过将单体a）至d）在至少两个阶段中聚合而获得，其不同之处在于它们 乙烯基芳族化合物的含量使得乙烯基芳烃化合物在富含乙烯基芳烃的阶段中的含量是低乙烯基芳烃化合物阶段的至少5倍。
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公开(公告)号：US06566472B1
公开(公告)日：2003-05-20
申请号：US09640072
申请日：2000-08-17
IPC分类号： C08F22606
CPC分类号： C08F220/12 , C08F212/04 , C09D133/064 , E04C2/042
摘要： Binder formulations based on aqueous polymer dispersions having a minimum film-forming temperature of below 10° C. and comprising at least one binder polymer P in the form of an aqueous dispersion comprising at least one anionic emulsifier and at least one nonionic emulsifier.
摘要翻译： 基于具有低于10℃的最低成膜温度的含水聚合物分散体并包含至少一种包含至少一种阴离子乳化剂和至少一种非离子乳化剂的水性分散体形式的粘合剂聚合物P的粘合剂配方。
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