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    Indeno-fused photochromic naphthopyrans, naphthols and photochromic articles
    4.
    发明授权
    Indeno-fused photochromic naphthopyrans, naphthols and photochromic articles 有权
    茚并稠合的光致变色萘并吡喃，萘酚和光致变色制品

    公开(公告)号：US07262295B2

    公开(公告)日：2007-08-28

    申请号：US10393177

    申请日：2003-03-20

    申请人： Robert W. Walters ,  Anil Kumar ,  Clara E. Nelson ,  Anu Chopra

    发明人： Robert W. Walters ,  Anil Kumar ,  Clara E. Nelson ,  Anu Chopra

    IPC分类号： C07D265/30 ,  C07D493/00

    CPC分类号： C07D405/04 ,  C07D491/04 ,  Y10T428/31504 ,  Y10T428/31551 ,  Y10T442/259

    摘要： Described are photochromic materials of indeno [2′,3′:3,4]naphtho[1,2-b]pyran structure, characterized in that they have a nitrogen or sulfur containing substituent at the 11-position ring atom, are substantially free of spiro-substituents at the 13-position and have been adapted to provide an increase in the sensitivity, visible lambda max or a combination thereof as measured in the Indenonaphthopyran Photochromic Performance Test. Optional substituents can be present at the other positions of the indeno [2′,3′:3,4]naphtho [1,2-b]pyran structure. Also described are naphthols used to produce the photochromic materials and photochromic articles that contain or that have coatings containing at least one of the novel photochromic materials or combinations thereof with other photochromic materials.

    摘要翻译： 描述茚并[2'，3'：3,4]萘并[1,2-b]吡喃结构的光致变色材料，其特征在于它们在11位环原子上具有含氮或硫的取代基， 的螺取代基在13位，并且已经适于提供灵敏度，可见λmax或其组合的增加，如在茚氢萘酚光致变色性能测试中所测量的。 茚并[2'，3'：3,4]萘并[1,2-b]吡喃结构的其它位置可以存在任选的取代基。 还描述了用于生产光致变色材料和光致变色制品的萘酚，其含有或具有包含至少一种新型光致变色材料或其与其它光致变色材料的组合的涂层。

    Photochromic naphthopyrans
    7.
    发明授权
    Photochromic naphthopyrans 有权
    光致变色萘并吡喃

    公开(公告)号：US06348604B1

    公开(公告)日：2002-02-19

    申请号：US09656509

    申请日：2000-09-06

    申请人： Clara M. Nelson ,  Anu Chopra ,  David B. Knowles ,  Barry Van Gemert ,  Anil Kumar

    发明人： Clara M. Nelson ,  Anu Chopra ,  David B. Knowles ,  Barry Van Gemert ,  Anil Kumar

    IPC分类号： G02B523

    CPC分类号： C07D311/92 ,  C07D493/04 ,  G02B5/23

    摘要： Described are novel photochromic 2H-naphtho[1,2-b]pyran compounds essentially characterized by having two adjacent moderate to strong electron donor substituents at the 8 and 9 positions or a fused heterocyclic group formed by the substituents coming together, weak to moderate electron donors at the 2 position and a rating of at least 80 in the Relative &Dgr;OD at Saturation Test. The compounds also have certain substituents at the 5 position and optionally at the 6 position of the naphtho portion of the compound. These compounds may be represented by the following graphic formula: Also described are polymeric organic host materials that contain or that are coated with such compounds. Optically clear articles such as ophthalmic lenses or adjacent plastic transparencies that incorporate the novel naphthopyran compounds or combinations thereof with complementary photochromic compounds, e.g., certain other naphthopyrans, benzopyrans, and spiro(indoline)type compounds, are also described.

    摘要翻译： 描述了新颖的光致变色2H-萘并[1,2-b]吡喃化合物，其基本上特征在于在8和9位具有两个相邻的中等至强电子给体取代基或由取代基组成的稠合杂环基团，弱至中等电子 捐助者在2位置，并且在饱和度测试的相对DELTAOD中评级至少为80。 化合物在化合物的萘酚部分的5位和任选地位置上也具有某些取代基。 这些化合物可以由以下图解表示：还描述了含有这些化合物或被这些化合物包被的聚合物有机主体材料。 还描述了光学透明的物品，例如将眼用透镜或相邻的塑料透明胶片结合到新的萘并吡喃化合物或其组合与互补光致变色化合物，例如某些其它萘并吡喃，苯并吡喃和螺（二氢吲哚）型化合物。

    Indeno-fused photochromic naphthopyrans
    8.
    发明授权
    Indeno-fused photochromic naphthopyrans 有权
    印度融合的光致变色萘并吡喃

    公开(公告)号：US06296785B1

    公开(公告)日：2001-10-02

    申请号：US09656510

    申请日：2000-09-06

    申请人： Clara M. Nelson ,  Anu Chopra ,  Olga G. Petrovskaia ,  David B. Knowles ,  Barry Van Gemert ,  Anil Kumar

    发明人： Clara M. Nelson ,  Anu Chopra ,  Olga G. Petrovskaia ,  David B. Knowles ,  Barry Van Gemert ,  Anil Kumar

    IPC分类号： C07D31178

    CPC分类号： C07D311/94 ,  C07D311/96 ,  G02B5/23

    摘要： Described are novel photochromic indeno-fused naphthopyran compounds, examples of which include naphthopyran compounds having a substituted or unsubstituted indeno group, the 2,1 positions of which are fused to the naphtho portion of the naphthopyran as shown below. Also present on the naphthopyran are moderate to strong electron donor substituents at the number 6- and 7-positions and optionally at the 8-position of the pyran ring or a cyclic group fused to the h side of the naphtho portion and weak to moderate electron donor substiuents at the 3-position of the pyran ring. Certain substituents may also be present at the number 5, 8, 9, 10, 11, 12, or 13 carbon atoms of the compounds. These compounds have a rating of at least 80 in the Relative &Dgr;OD at Saturation Test and may be represented by the following graphic formula: Also described are polymeric organic host materials that contain or that are coated with such compounds. Optically clear articles such as ophthalmic lenses or other plastic transparencies that incorporate the novel naphthopyran compounds or combinations thereof with complementary photochromic compounds, e.g., certain other naphthopyrans, benzopyrans, and spiro(indoline)type compounds, are also described.

    摘要翻译： 描述了新的光致变色茚并稠合萘并吡喃化合物，其实例包括具有取代或未取代的茚并基团的萘并吡喃化合物，其2,1个位置与萘并吡喃的萘酚部分稠合，如下所示。 还存在于萘并吡喃上的是中子至强电子给体取代基，位于吡喃环的6-位和7-位，任选在8-位或稠合于萘酚部分的h侧的环状基团，弱至中等电子 在吡喃环3位的供体位。 某些取代基也可以存在于化合物的5,8,9,10,11,12或13个碳原子上。 这些化合物在饱和度测试中的相对DELTAOD中的等级至少为80，并且可以由以下图形表示：还描述了含有或涂覆有这些化合物的聚合物有机主体材料。 还描述了光学透明的物品，例如将眼用透镜或其它塑料透明胶片掺入新的萘并吡喃化合物或其组合与互补的光致变色化合物，例如某些其它萘并吡喃，苯并吡喃和螺（二氢吲哚）型化合物。

    Polymerizable polyalkoxylated naphthopyrans
    9.
    发明授权
    Polymerizable polyalkoxylated naphthopyrans 有权
    可聚合的聚烷氧基化萘并吡喃

    公开(公告)号：US6113814A

    公开(公告)日：2000-09-05

    申请号：US437982

    申请日：1999-11-10

    申请人： Barry Van Gemert ,  Anu Chopra ,  Anil Kumar

    发明人： Barry Van Gemert ,  Anu Chopra ,  Anil Kumar

    IPC分类号： G03C1/73 ,  C07D311/92 ,  C07D311/94 ,  C07D407/12 ,  C08G65/331 ,  C08G65/334 ,  C08K5/1545 ,  C08L101/00 ,  C09K9/02 ,  G02B1/04 ,  G02B5/23 ,  G05F3/02 ,  G02C7/10

    CPC分类号： C07D407/12 ,  C07D311/92 ,  C07D311/94 ,  C08G65/3315 ,  C08G65/3318 ,  C08G65/3346 ,  C08K5/1545 ,  C09B57/02 ,  C09K9/02 ,  G02B1/041 ,  G02B1/043

    摘要： Described are novel photochromic polymerizable polyalkoxylated naphthopyran compounds, examples of which are certain 2H-naphtho[1,2-b]pyrans, 3H-naphtho[2,1-b]pyrans and indeno[2,1-f]naphtho[1,2-b]pyrans each having at least one polyalkoxylated substituent of from 1 to 50 alkoxy units per substituent which is end-capped with a polymerizable group. Specific substituents are also present on the naphtho, indeno and pyrano portions of the compounds. These compounds may be represented by the following graphic formulae: ##STR1## Also described are various substrates, e.g., paper, glass, polymeric organic materials, etc., that contain or that are coated with such compounds. Optically clear articles such as contact lenses or other plastic transparencies that incorporate the novel naphthopyran compounds or combinations thereof with complementary photochromic compounds, e.g., certain other naphthopyrans, indenonaphthopyrans, benzopyrans, oxazine-type compounds, etc., are also described.

    摘要翻译： 描述了新的光致变色可聚合的聚烷氧基化萘并吡喃化合物，其实例是某些2H-萘并[1,2-b]吡喃，3H-萘并[2,1-b]吡喃和茚并[2,1-f]萘并[ 2-b]吡喃，每个具有至少一个具有1至50个烷氧基单元的聚烷氧基化取代基，每个取代基被可聚合基团封端。 具体的取代基也存在于化合物的萘并茚并吡喃部分上。 这些化合物可以由以下图解表示：还描述了含有或涂覆有这些化合物的各种基材，例如纸，玻璃，聚合有机材料等。 还描述了光学透明的物品，例如将新颖的萘并吡喃化合物或其组合与互补的光致变色化合物（例如某些其它萘并吡喃，茚并萘并吡喃，苯并吡喃，恶嗪型化合物等）结合的隐形眼镜或其它塑料透明胶片。