摘要:
A method of making a catalyst for use in oligomerizing an olefin, comprising a chromium-containing compound, a pyrrole-containing compound, a metal alkyl, a halide-containing compound, and optionally a solvent, the method comprising abating all or a portion of water, acidic protons, or both from a composition comprising the chromium-containing compound, a composition comprising the pyrrole-containing compound, a composition comprising a non-metal halide-containing compound, a composition comprising the solvent, or combinations thereof prior to contact thereof with a composition comprising a metal halide-containing compound.
摘要:
A method of making a catalyst for use in oligomerizing an olefin comprising a chromium-containing compound, a pyrrole-containing compound, a metal alkyl, a halide-containing compound, and optionally a solvent, the method comprising contacting a composition comprising the chromium-containing compound and a composition comprising the metal alkyl, wherein the composition comprising the chromium-containing compound is added to the composition comprising the metal alkyl.
摘要:
A method of making a catalyst for use in oligomerizing an olefin comprising a chromium-containing compound, a pyrrole-containing compound, a metal alkyl, a halide-containing compound, and optionally a solvent, the method comprising contacting a composition comprising the chromium-containing compound and a composition comprising the metal alkyl, wherein the composition comprising the chromium-containing compound is added to the composition comprising the metal alkyl.
摘要:
A method of making a catalyst for use in oligomerizing an olefin, comprising a chromium-containing compound, a pyrrole-containing compound, a metal alkyl, a halide-containing compound, and optionally a solvent, the method comprising abating all or a portion of water, acidic protons, or both from a composition comprising the chromium-containing compound, a composition comprising the pyrrole-containing compound, a composition comprising a non-metal halide-containing compound, a composition comprising the solvent, or combinations thereof prior to contact thereof with a composition comprising a metal halide-containing compound.
摘要:
A method of making a catalyst for use in oligomerizing an olefin comprising a chromium-containing compound, a pyrrole-containing compound, a metal alkyl, a halide-containing compound, and optionally a solvent, the method comprising contacting a composition comprising the chromium-containing compound and a composition comprising the metal alkyl, wherein the composition comprising the chromium-containing compound is added to the composition comprising the metal alkyl.
摘要:
A method of making a catalyst for use in oligomerizing an olefin comprising a chromium-containing compound, a pyrrole-containing compound, a metal alkyl, a halide-containing compound, and optionally a solvent, the method comprising contacting a composition comprising the chromium-containing compound and a composition comprising the metal alkyl, wherein the composition comprising the chromium-containing compound is added to the composition comprising the metal alkyl.
摘要:
A method of making an olefin oligomerization catalyst, comprising contacting a chromium-containing compound, a heteroatomic ligand, and a metal alkyl, wherein the chromium-containing compound comprises less than about 5 weight percent chromium oligomers. A method of making an olefin oligomerization catalyst comprising a chromium-containing compound, a nitrogen-containing compound, and a metal alkyl, the method comprising adding a composition comprising the chromium-containing compound to a composition comprising the metal alkyl. A method of making an olefin oligomerization catalyst comprising a chromium-containing compound, a nitrogen-containing compound, and a metal alkyl, the method comprising abating all or a portion of water, acidic protons, or both from a composition comprising the chromium-containing compound, a composition comprising the nitrogen-containing compound, or combinations thereof prior to or during the preparation of the catalyst. Methods of oligomerizing olefins by contacting such catalysts with an alpha olefin.
摘要:
A method of making an olefin oligomerization catalyst, comprising contacting a chromium-containing compound, a heteroatomic ligand, and a metal alkyl, wherein the chromium-containing compound comprises less than about 5 weight percent chromium oligomers. A method of making an olefin oligomerization catalyst comprising a chromium-containing compound, a nitrogen-containing compound, and a metal alkyl, the method comprising adding a composition comprising the chromium-containing compound to a composition comprising the metal alkyl. A method of making an olefin oligomerization catalyst comprising a chromium-containing compound, a nitrogen-containing compound, and a metal alkyl, the method comprising abating all or a portion of water, acidic protons, or both from a composition comprising the chromium-containing compound, a composition comprising the nitrogen-containing compound, or combinations thereof prior to or during the preparation of the catalyst. Methods of oligomerizing olefins by contacting such catalysts with an alpha olefin.
摘要:
A method of deactivate a catalyst system is described. The method may include contacting a reactor effluent comprising a catalyst system, an oligomerized olefin, and diluent with a kill agent to at least partially deactivate the catalyst system, separating the reactor effluent into one or more first streams comprising oligomerized olefin and diluent, the one or more first streams being substantially devoid of the at least partially deactivated catalyst, and a second stream comprising the deactivated catalyst; and contacting the second stream with a quench agent.
摘要:
A processes is provided to inhibit or limit the decomposition of a halide-containing olefin oligomerization catalyst system during recovery of an oligomerization product. The process includes deactivation of an olefin oligomerization catalyst system present in an olefin oligomerization reactor effluent stream by contact with an alcohol under conditions that minimize potential for deactivated catalyst system decomposition. Such conditions include minimization of the water content of the deactivation agent and concentration of the deactivation agent.