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    Methods for restoring the heat transfer coefficient of an oligomerization reactor
    5.
    发明授权
    Methods for restoring the heat transfer coefficient of an oligomerization reactor 有权
    恢复低聚反应器传热系数的方法

    公开(公告)号：US06380451B1

    公开(公告)日：2002-04-30

    申请号：US09474306

    申请日：1999-12-29

    申请人： Bruce E. Kreischer ,  Warren M. Ewert ,  Ronald D. Knudsen

    发明人： Bruce E. Kreischer ,  Warren M. Ewert ,  Ronald D. Knudsen

    IPC分类号： C07C208

    CPC分类号： B08B9/08 ,  B01J19/002 ,  B01J2219/00252 ,  C07C2/08 ,  Y02P20/52 ,  Y02P20/582 ,  Y10S585/95

    摘要： The specification discloses a method for cleaning an oligomerization reactor after making a higher olefin in the reactor. An olefin is reacted in the presence of a catalyst comprising an aluminum alkyl to form an olefin reaction product. For example, ethylene can be trimerized in the reaction to produce 1-hexene. The reaction also causes a co-product residue of the catalyst to form on the interior surface of the reactor. The interior surface of the reactor is then contacted with an alcohol under conditions effective to remove at least a substantial amount of the catalyst residue from the interior surface of the reactor. The catalyst-removing step can be carried out by combining an alcohol with the process medium used in the reactor. The combined medium can be used to remove both the accumulated polymer co-product and the accumulated catalyst residue from the reactor.

    摘要翻译： 该说明书公开了在反应器中制备高级烯烃之后清洗低聚反应器的方法。 烯烃在包含烷基铝的催化剂的存在下反应以形成烯烃反应产物。 例如，乙烯可以在反应中进行三聚，以产生1-己烯。 该反应还导致催化剂的副产物残余物在反应器的内表面上形成。 然后在有效地从反应器的内表面除去至少大量催化剂残余物的条件下，将反应器的内表面与醇接触。 催化剂除去步骤可以通过将醇与反应器中使用的加工介质结合来进行。 组合的介质可用于从反应器中除去累积的聚合物共同产物和累积的催化剂残余物。

    Methods of Preparation of an Olefin Oligomerization Catalyst
    6.
    发明申请
    Methods of Preparation of an Olefin Oligomerization Catalyst 有权
    烯烃低聚催化剂的制备方法

    公开(公告)号：US20080177122A1

    公开(公告)日：2008-07-24

    申请号：US12057853

    申请日：2008-03-28

    申请人： Ronald D. Knudsen ,  Bruce E. Kreischer ,  Ronald G. Abbott ,  Steven D. Bridges

    发明人： Ronald D. Knudsen ,  Bruce E. Kreischer ,  Ronald G. Abbott ,  Steven D. Bridges

    IPC分类号： C07C2/08

    CPC分类号： B01J31/143 ,  B01J31/0244 ,  B01J31/2226 ,  B01J2231/20 ,  B01J2531/62 ,  C07C2/32 ,  C07C11/02

    摘要： A method of making a catalyst for use in oligomerizing an olefin, comprising a chromium-containing compound, a pyrrole-containing compound, a metal alkyl, a halide-containing compound, and optionally a solvent, the method comprising abating all or a portion of water, acidic protons, or both from a composition comprising the chromium-containing compound, a composition comprising the pyrrole-containing compound, a composition comprising a non-metal halide-containing compound, a composition comprising the solvent, or combinations thereof prior to contact thereof with a composition comprising a metal halide-containing compound.

    摘要翻译： 一种制备用于低聚烯烃的催化剂的方法，包括含铬化合物，含吡咯的化合物，金属烷基，含卤化合物和任选的溶剂，所述方法包括减少全部或部分 包含含铬化合物的组合物，包含含吡咯的化合物的组合物，包含非金属卤化物的化合物的组合物，包含溶剂的组合物或其接触前的组合的组合物，水，酸性质子或两者 其包含含有金属卤化物的化合物的组合物。

    Methods of preparation of an olefin oligomerization catalyst
    7.
    发明授权
    Methods of preparation of an olefin oligomerization catalyst 有权
    制备烯烃低聚催化剂的方法

    公开(公告)号：US07910670B2

    公开(公告)日：2011-03-22

    申请号：US12534536

    申请日：2009-08-03

    申请人： Ronald D. Knudsen ,  Ronald G. Abbott ,  Bruce E. Kreischer ,  Eduardo J. Baralt ,  Brooke L. Small

    发明人： Ronald D. Knudsen ,  Ronald G. Abbott ,  Bruce E. Kreischer ,  Eduardo J. Baralt ,  Brooke L. Small

    IPC分类号： C08F4/69

    CPC分类号： C07C2/32 ,  B01J31/04 ,  B01J31/128 ,  B01J31/143 ,  B01J31/18 ,  B01J31/181 ,  B01J31/2226 ,  B01J31/4092 ,  B01J2231/20 ,  B01J2531/62 ,  C07C2527/125 ,  C07C2531/22 ,  C08F10/00 ,  Y02P20/584 ,  C08F4/69

    摘要： A method of making an olefin oligomerization catalyst, comprising contacting a chromium-containing compound, a heteroatomic ligand, and a metal alkyl, wherein the chromium-containing compound comprises less than about 5 weight percent chromium oligomers. A method of making an olefin oligomerization catalyst comprising a chromium-containing compound, a nitrogen-containing compound, and a metal alkyl, the method comprising adding a composition comprising the chromium-containing compound to a composition comprising the metal alkyl. A method of making an olefin oligomerization catalyst comprising a chromium-containing compound, a nitrogen-containing compound, and a metal alkyl, the method comprising abating all or a portion of water, acidic protons, or both from a composition comprising the chromium-containing compound, a composition comprising the nitrogen-containing compound, or combinations thereof prior to or during the preparation of the catalyst. Methods of oligomerizing olefins by contacting such catalysts with an alpha olefin.

    摘要翻译： 一种制备烯烃低聚催化剂的方法，包括使含铬化合物，杂原子配体和金属烷基接触，其中所述含铬化合物包含小于约5重量％的铬低聚物。 一种制备包含含铬化合物，含氮化合物和金属烷基的烯烃低聚催化剂的方法，所述方法包括将含有所述含铬化合物的组合物加入到包含所述金属烷基的组合物中。 一种制备包含含铬化合物，含氮化合物和金属烷基的烯烃低聚催化剂的方法，该方法包括从包含含铬化合物的组合物中减少全部或一部分水，酸性质子或两者 化合物，包含含氮化合物的组合物或其组合在制备催化剂之前或期间。 通过使这种催化剂与α-烯烃接触来使烯烃低聚的方法。

    System and Method of Deactivating and Quenching an Oligomerization Catalyst
    8.
    发明申请
    System and Method of Deactivating and Quenching an Oligomerization Catalyst 有权
    灭活和淬灭低聚催化剂的系统和方法

    公开(公告)号：US20100113851A1

    公开(公告)日：2010-05-06

    申请号：US12609631

    申请日：2009-10-30

    申请人： Bruce E. Kreischer ,  Orson L. Sydora ,  Ronald D. Knudsen

    发明人： Bruce E. Kreischer ,  Orson L. Sydora ,  Ronald D. Knudsen

    IPC分类号： C07C2/34 ,  C07C2/08 ,  C07C7/00

    CPC分类号： B01J31/122 ,  B01J31/0237 ,  B01J31/0239 ,  B01J31/0244 ,  B01J31/143 ,  B01J2231/20 ,  B01J2531/62 ,  Y02P20/582 ,  Y10S585/903

    摘要： A method of deactivate a catalyst system is described. The method may include contacting a reactor effluent comprising a catalyst system, an oligomerized olefin, and diluent with a kill agent to at least partially deactivate the catalyst system, separating the reactor effluent into one or more first streams comprising oligomerized olefin and diluent, the one or more first streams being substantially devoid of the at least partially deactivated catalyst, and a second stream comprising the deactivated catalyst; and contacting the second stream with a quench agent.

    摘要翻译： 描述了使催化剂体系失活的方法。 该方法可以包括将包含催化剂体系，低聚烯烃和稀释剂的反应器流出物与杀灭剂接触以使催化剂体系至少部分失活，将反应器流出物分离成一个或多个包含低聚烯烃和稀释剂的第一流， 或更多的第一物流基本上不含至少部分失活的催化剂，以及包含失活的催化剂的第二物流; 并使第二流与骤冷剂接触。