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公开(公告)号：US3278566A
公开(公告)日：1966-10-11
申请号：US42792265
申请日：1965-01-25
Applicant: SHELL OIL CO
Inventor： CALHOUN GEORGE M
IPC: C07C317/00
CPC classification number: C10M1/08 , C07C317/00 , C07C323/00 , C10M2203/06 , C10M2203/10 , C10M2203/102 , C10M2205/00 , C10M2205/14 , C10M2205/16 , C10M2205/17 , C10M2207/021 , C10M2207/022 , C10M2207/023 , C10M2207/024 , C10M2207/04 , C10M2207/046 , C10M2207/125 , C10M2207/129 , C10M2207/282 , C10M2207/34 , C10M2207/40 , C10M2207/402 , C10M2207/404 , C10M2209/084 , C10M2209/103 , C10M2209/104 , C10M2209/105 , C10M2209/107 , C10M2209/108 , C10M2219/04 , C10M2219/085 , C10M2221/04 , C10M2221/043 , C10M2223/06 , C10M2223/061 , C10M2223/063 , C10M2223/065 , C10M2229/02 , C10M2229/05 , C10N2220/02 , C10N2230/08 , C10N2240/02 , C10N2240/04 , C10N2240/042 , C10N2240/044 , C10N2240/046 , C10N2240/12 , C10N2240/121 , C10N2240/14
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公开(公告)号：US3156649A
公开(公告)日：1964-11-10
申请号：US2420660
申请日：1960-04-25
Applicant: SHELL OIL CO
Inventor： HEWETT WILLIAM A , CALHOUN GEORGE M
IPC: C08C19/20 , C08F8/34 , C08F210/00 , C08F236/04 , C10M151/00
CPC classification number: C10M151/00 , C08C19/20 , C08F8/34 , C08F210/00 , C08F236/04 , C08F2800/10 , C10M2203/06 , C10M2203/10 , C10M2205/00 , C10M2207/021 , C10M2207/023 , C10M2207/125 , C10M2207/129 , C10M2207/281 , C10M2207/282 , C10M2207/283 , C10M2207/286 , C10M2207/289 , C10M2207/34 , C10M2207/40 , C10M2207/402 , C10M2207/404 , C10M2209/084 , C10M2209/103 , C10M2209/107 , C10M2219/06 , C10M2219/082 , C10M2221/04 , C10M2221/041 , C10M2229/02 , C10M2229/05 , C10N2240/08 , C10N2250/10 , C08F210/14
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公开(公告)号：US3309428A
公开(公告)日：1967-03-14
申请号：US47266365
申请日：1965-07-16
Applicant: SHELL OIL CO
Inventor： CALHOUN GEORGE M , HYMAN DIAMOND
IPC: A01N57/18 , C07C43/295 , C07C391/02 , C07F9/38 , C07F9/40 , C10L1/26 , C10M137/14 , C10M141/10 , C10M169/00
CPC classification number: C10M141/10 , A01N57/18 , C07C43/295 , C07C391/02 , C07F9/3808 , C07F9/4006 , C10L1/2608 , C10L1/2616 , C10L1/2625 , C10M3/00 , C10M137/14 , C10M2201/102 , C10M2203/06 , C10M2203/10 , C10M2203/102 , C10M2203/104 , C10M2203/106 , C10M2203/108 , C10M2205/00 , C10M2205/026 , C10M2205/14 , C10M2205/16 , C10M2205/17 , C10M2205/18 , C10M2205/22 , C10M2207/023 , C10M2207/024 , C10M2207/04 , C10M2207/046 , C10M2207/123 , C10M2207/125 , C10M2207/129 , C10M2207/22 , C10M2207/282 , C10M2207/289 , C10M2207/34 , C10M2207/40 , C10M2207/402 , C10M2207/404 , C10M2209/084 , C10M2209/103 , C10M2209/104 , C10M2209/105 , C10M2209/107 , C10M2209/108 , C10M2209/109 , C10M2211/08 , C10M2215/062 , C10M2217/028 , C10M2217/06 , C10M2219/044 , C10M2219/046 , C10M2219/082 , C10M2219/083 , C10M2219/084 , C10M2219/087 , C10M2219/088 , C10M2219/089 , C10M2223/00 , C10M2223/04 , C10M2223/041 , C10M2223/042 , C10M2223/047 , C10M2223/063 , C10M2223/065 , C10M2223/08 , C10M2223/12 , C10M2223/121 , C10M2225/04 , C10M2227/082 , C10M2229/02 , C10M2229/05 , C10M2290/02 , C10N2210/02 , C10N2210/03 , C10N2210/04 , C10N2210/08 , C10N2220/02 , C10N2230/08 , C10N2230/12 , C10N2240/02 , C10N2240/04 , C10N2240/042 , C10N2240/044 , C10N2240/046 , C10N2240/08 , C10N2240/10 , C10N2240/101 , C10N2240/104 , C10N2240/106 , C10N2240/12 , C10N2240/121 , C10N2240/14 , C10N2240/201 , C10N2240/202 , C10N2240/40 , C10N2240/401 , C10N2240/402 , C10N2240/403 , C10N2240/404 , C10N2240/405 , C10N2240/406 , C10N2240/407 , C10N2240/408 , C10N2240/409 , C10N2240/62 , C10N2250/10
Abstract: A lubricant or fuel composition comprises a major proportion of a lubricant or fuel and a minor proportion of a compound of formula wherein R is a hydrocarbon radical having at least 6 carbon atoms, the R1's (same or different) are hydrogen, hydrocarbyl or a metallic or nonmetallic cationic radical, and the X's (same or different) are oxygen or sulphur. Specified cationic radicals include alkaline earth metals, Zn, Sn, Pb, Cd, Al and organic amine radicals. The additives may be used in amounts of about 0,1 to 25%, preferably about 0,5 to 5,0% by weight of the total composition. The lubricating oil may be mineral or synthetic. A phenolic anti-oxidant, specifically p, p1-methylene bisphenol may be present.ALSO:The invention comprises compounds of formula where R is an alkyl or cycloalkyl radical having at least 6 carbon atoms, the R1's (same or different) are hydrogen, hydrocarbyl or metallic or non-metallic cationic radicals, e.g. organic ammonium radicals, and the X's (same or different) are oxygen or sulphur. Specified metals are alkaline earth metals, Zn, Pb, Sn, Cd and Al. They may be prepared by reacting an alkyl or cycloalkyl mercaptan or mercaptide with a halomethylphosphono compound Hal-CH2-P(X)(XR1)2 and if desired interconverting the resulting salts, free acids or esters. In addition to compounds falling within the above general formula the Specification specifically refers to compounds in which R is phenyl and benzyl. All these compounds are used as additives for lubricants or fuels (see Group III).
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公开(公告)号：US3235628A
公开(公告)日：1966-02-15
申请号：US38123364
申请日：1964-07-08
Applicant: SHELL OIL CO
Inventor： CALHOUN GEORGE M
CPC classification number: C10M1/08 , C07F9/3808 , C07F9/4006 , C10L1/2616 , C10M2203/06 , C10M2203/10 , C10M2205/00 , C10M2205/14 , C10M2205/16 , C10M2205/17 , C10M2205/18 , C10M2207/023 , C10M2207/024 , C10M2207/125 , C10M2207/129 , C10M2207/282 , C10M2207/34 , C10M2207/40 , C10M2207/402 , C10M2207/404 , C10M2209/084 , C10M2209/103 , C10M2209/107 , C10M2209/108 , C10M2209/109 , C10M2223/063 , C10M2223/065 , C10M2227/082 , C10M2229/02 , C10M2229/05 , C10N2220/02 , C10N2230/08 , C10N2230/12 , C10N2240/02 , C10N2240/08 , C10N2240/12 , C10N2240/121 , C10N2240/201 , C10N2240/202 , C10N2240/40 , C10N2240/401 , C10N2240/402 , C10N2240/403 , C10N2240/404 , C10N2240/405 , C10N2240/406 , C10N2240/407 , C10N2240/408 , C10N2240/409 , C10N2240/62 , C10N2250/10
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公开(公告)号：US3114710A
公开(公告)日：1963-12-17
申请号：US778160
申请日：1960-02-10
Applicant: SHELL OIL CO
Inventor： CALHOUN GEORGE M
CPC classification number: C10M5/00 , C07F9/3808 , C10M2223/065 , C10N2210/01 , C10N2210/02 , C10N2210/03 , C10N2210/04 , C10N2210/08 , C10N2230/12 , C10N2240/08 , C10N2240/40 , C10N2240/402 , C10N2240/403 , C10N2240/404 , C10N2240/405 , C10N2240/406 , C10N2240/407 , C10N2240/408 , C10N2240/409 , C10N2240/62 , C10N2250/10
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Patent Agency Ranking
公开(公告)号：US3041284A
公开(公告)日：1962-06-26
申请号：US75388258
申请日：1958-08-08
Applicant: SHELL OIL CO
Inventor： CALHOUN GEORGE M , HEWETT WILLIAM A
CPC classification number: C10M1/08 , C10M2203/06 , C10M2203/10 , C10M2205/00 , C10M2205/14 , C10M2205/16 , C10M2205/17 , C10M2207/021 , C10M2207/022 , C10M2207/023 , C10M2207/027 , C10M2207/04 , C10M2207/123 , C10M2207/125 , C10M2207/128 , C10M2207/129 , C10M2207/22 , C10M2207/281 , C10M2207/282 , C10M2207/283 , C10M2207/286 , C10M2207/287 , C10M2207/289 , C10M2207/34 , C10M2207/40 , C10M2207/402 , C10M2207/404 , C10M2209/00 , C10M2209/02 , C10M2209/084 , C10M2209/10 , C10M2209/103 , C10M2209/104 , C10M2209/107 , C10M2209/108 , C10M2219/082 , C10M2219/084 , C10M2219/085 , C10M2229/02 , C10M2229/05 , C10N2220/02 , C10N2230/08 , C10N2240/12 , C10N2240/121
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公开(公告)号：US3400139A
公开(公告)日：1968-09-03
申请号：US43019765
申请日：1965-02-03
Applicant: SHELL OIL CO
Inventor： CALHOUN GEORGE M
IPC: C07F9/40
CPC classification number: C10M1/08 , C07C323/00 , C07F9/4006 , C10M2203/06 , C10M2203/10 , C10M2203/102 , C10M2205/00 , C10M2205/14 , C10M2205/16 , C10M2205/17 , C10M2207/021 , C10M2207/022 , C10M2207/023 , C10M2207/024 , C10M2207/04 , C10M2207/046 , C10M2207/125 , C10M2207/129 , C10M2207/282 , C10M2207/34 , C10M2207/40 , C10M2207/402 , C10M2207/404 , C10M2209/084 , C10M2209/103 , C10M2209/104 , C10M2209/105 , C10M2209/107 , C10M2209/108 , C10M2219/04 , C10M2219/085 , C10M2221/04 , C10M2221/043 , C10M2223/06 , C10M2223/061 , C10M2223/063 , C10M2223/065 , C10M2229/02 , C10M2229/05 , C10N2220/02 , C10N2230/08 , C10N2240/02 , C10N2240/04 , C10N2240/042 , C10N2240/044 , C10N2240/046 , C10N2240/12 , C10N2240/121 , C10N2240/14
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公开(公告)号：US3316332A
公开(公告)日：1967-04-25
申请号：US31232963
申请日：1963-09-30
Applicant: SHELL OIL CO
Inventor： CALHOUN GEORGE M , HYMAN DIAMOND
IPC: A01N57/18 , C07C43/295 , C07C391/02 , C07F9/38 , C07F9/40 , C10L1/26 , C10M137/14 , C10M141/10 , C10M169/00
CPC classification number: C10M141/10 , A01N57/18 , C07C43/295 , C07C391/02 , C07F9/3808 , C07F9/4006 , C10L1/2608 , C10L1/2616 , C10L1/2625 , C10M3/00 , C10M137/14 , C10M2201/102 , C10M2203/06 , C10M2203/10 , C10M2203/102 , C10M2203/104 , C10M2203/106 , C10M2203/108 , C10M2205/00 , C10M2205/026 , C10M2205/14 , C10M2205/16 , C10M2205/17 , C10M2205/18 , C10M2205/22 , C10M2207/023 , C10M2207/024 , C10M2207/04 , C10M2207/046 , C10M2207/123 , C10M2207/125 , C10M2207/129 , C10M2207/22 , C10M2207/282 , C10M2207/289 , C10M2207/34 , C10M2207/40 , C10M2207/402 , C10M2207/404 , C10M2209/084 , C10M2209/103 , C10M2209/104 , C10M2209/105 , C10M2209/107 , C10M2209/108 , C10M2209/109 , C10M2211/08 , C10M2215/062 , C10M2217/028 , C10M2217/06 , C10M2219/044 , C10M2219/046 , C10M2219/082 , C10M2219/083 , C10M2219/084 , C10M2219/087 , C10M2219/088 , C10M2219/089 , C10M2223/00 , C10M2223/04 , C10M2223/041 , C10M2223/042 , C10M2223/047 , C10M2223/063 , C10M2223/065 , C10M2223/08 , C10M2223/12 , C10M2223/121 , C10M2225/04 , C10M2227/082 , C10M2229/02 , C10M2229/05 , C10M2290/02 , C10N2210/02 , C10N2210/03 , C10N2210/04 , C10N2210/08 , C10N2220/02 , C10N2230/08 , C10N2230/12 , C10N2240/02 , C10N2240/04 , C10N2240/042 , C10N2240/044 , C10N2240/046 , C10N2240/08 , C10N2240/10 , C10N2240/101 , C10N2240/104 , C10N2240/106 , C10N2240/12 , C10N2240/121 , C10N2240/14 , C10N2240/201 , C10N2240/202 , C10N2240/40 , C10N2240/401 , C10N2240/402 , C10N2240/403 , C10N2240/404 , C10N2240/405 , C10N2240/406 , C10N2240/407 , C10N2240/408 , C10N2240/409 , C10N2240/62 , C10N2250/10
Abstract: A lubricant or fuel composition comprises a major proportion of a lubricant or fuel and a minor proportion of a compound of formula wherein R is a hydrocarbon radical having at least 6 carbon atoms, the R1's (same or different) are hydrogen, hydrocarbyl or a metallic or nonmetallic cationic radical, and the X's (same or different) are oxygen or sulphur. Specified cationic radicals include alkaline earth metals, Zn, Sn, Pb, Cd, Al and organic amine radicals. The additives may be used in amounts of about 0,1 to 25%, preferably about 0,5 to 5,0% by weight of the total composition. The lubricating oil may be mineral or synthetic. A phenolic anti-oxidant, specifically p, p1-methylene bisphenol may be present.ALSO:The invention comprises compounds of formula where R is an alkyl or cycloalkyl radical having at least 6 carbon atoms, the R1's (same or different) are hydrogen, hydrocarbyl or metallic or non-metallic cationic radicals, e.g. organic ammonium radicals, and the X's (same or different) are oxygen or sulphur. Specified metals are alkaline earth metals, Zn, Pb, Sn, Cd and Al. They may be prepared by reacting an alkyl or cycloalkyl mercaptan or mercaptide with a halomethylphosphono compound Hal-CH2-P(X)(XR1)2 and if desired interconverting the resulting salts, free acids or esters. In addition to compounds falling within the above general formula the Specification specifically refers to compounds in which R is phenyl and benzyl. All these compounds are used as additives for lubricants or fuels (see Group III).
Abstract translation: 润滑剂或燃料组合物包含主要比例的润滑剂或燃料和较小比例的式（FORM：0904968 / III / 1）化合物，其中R是具有至少6个碳原子的烃基，R 1（相同或 不同的）是氢，烃基或金属或非金属阳离子基团，X（相同或不同）是氧或硫。 指定的阳离子自由基包括碱土金属，Zn，Sn，Pb，Cd，Al和有机胺基。 添加剂的用量可以占组合物总重量的约0.1至25重量％，优选约0.5至5.0重量％。 润滑油可以是矿物或合成的。 可以存在酚类抗氧化剂，特别是p，p1-亚甲基双酚。还有：本发明包括具有至少6个碳原子的式[FormM：0904968 / IV（b）/ 1）的化合物，其中R是烷基或环烷基 原子，R 1（相同或不同）是氢，烃基或金属或非金属阳离子自由基，例如 有机铵基，X（相同或不同）是氧或硫。 规定的金属是碱土金属，Zn，Pb，Sn，Cd和Al。 它们可以通过使烷基或环烷基硫醇或硫醇与卤代甲基膦酰基化合物Hal-CH2-P（X）（XR1）2反应并且如果需要将所得盐，游离酸或酯相互转化来制备。 除了上述通式中的化合物外，本说明书具体指其中R为苯基和苄基的化合物。 所有这些化合物都用作润滑剂或燃料的添加剂（见第III组）。
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9.发明授权
公开(公告)号：US3238131A
公开(公告)日：1966-03-01
申请号：US7781760
申请日：1960-12-23
Applicant: SHELL OIL CO
Inventor： CALHOUN GEORGE M , HYMAN DIAMOND
IPC: C07C43/295 , C07C391/02 , C07F9/38 , C10L1/26 , C10M137/14
CPC classification number: C10M137/14 , C07C43/295 , C07C391/02 , C07F9/3808 , C10L1/2608 , C10L1/2616 , C10L1/2625 , C10M3/00 , C10M2201/102 , C10M2203/06 , C10M2203/10 , C10M2203/102 , C10M2203/104 , C10M2203/106 , C10M2203/108 , C10M2205/00 , C10M2205/026 , C10M2205/14 , C10M2205/16 , C10M2205/17 , C10M2205/18 , C10M2205/22 , C10M2207/023 , C10M2207/024 , C10M2207/04 , C10M2207/046 , C10M2207/123 , C10M2207/125 , C10M2207/129 , C10M2207/22 , C10M2207/282 , C10M2207/289 , C10M2207/34 , C10M2207/40 , C10M2207/402 , C10M2207/404 , C10M2209/084 , C10M2209/103 , C10M2209/104 , C10M2209/105 , C10M2209/107 , C10M2209/108 , C10M2209/109 , C10M2211/08 , C10M2215/062 , C10M2217/028 , C10M2217/06 , C10M2219/044 , C10M2219/046 , C10M2219/082 , C10M2219/083 , C10M2219/084 , C10M2219/087 , C10M2219/088 , C10M2219/089 , C10M2223/00 , C10M2223/04 , C10M2223/041 , C10M2223/042 , C10M2223/047 , C10M2223/063 , C10M2223/065 , C10M2223/08 , C10M2223/12 , C10M2223/121 , C10M2225/04 , C10M2227/082 , C10M2229/02 , C10M2229/05 , C10M2290/02 , C10N2210/02 , C10N2210/03 , C10N2210/04 , C10N2210/08 , C10N2220/02 , C10N2230/08 , C10N2230/12 , C10N2240/02 , C10N2240/04 , C10N2240/042 , C10N2240/044 , C10N2240/046 , C10N2240/08 , C10N2240/10 , C10N2240/101 , C10N2240/104 , C10N2240/106 , C10N2240/12 , C10N2240/121 , C10N2240/14 , C10N2240/201 , C10N2240/202 , C10N2240/40 , C10N2240/401 , C10N2240/402 , C10N2240/403 , C10N2240/404 , C10N2240/405 , C10N2240/406 , C10N2240/407 , C10N2240/408 , C10N2240/409 , C10N2240/62 , C10N2250/10
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公开(公告)号：US3189547A
公开(公告)日：1965-06-15
申请号：US82479659
申请日：1959-07-03
Applicant: SHELL OIL CO
Inventor： CALHOUN GEORGE M
IPC: C07F9/40
CPC classification number: C10M1/08 , C07C323/00 , C07F9/4006 , C10M2203/06 , C10M2203/10 , C10M2203/102 , C10M2205/00 , C10M2205/14 , C10M2205/16 , C10M2205/17 , C10M2207/021 , C10M2207/022 , C10M2207/023 , C10M2207/024 , C10M2207/04 , C10M2207/046 , C10M2207/125 , C10M2207/129 , C10M2207/282 , C10M2207/34 , C10M2207/40 , C10M2207/402 , C10M2207/404 , C10M2209/084 , C10M2209/103 , C10M2209/104 , C10M2209/105 , C10M2209/107 , C10M2209/108 , C10M2219/04 , C10M2219/085 , C10M2221/04 , C10M2221/043 , C10M2223/06 , C10M2223/061 , C10M2223/063 , C10M2223/065 , C10M2229/02 , C10M2229/05 , C10N2220/02 , C10N2230/08 , C10N2240/02 , C10N2240/04 , C10N2240/042 , C10N2240/044 , C10N2240/046 , C10N2240/12 , C10N2240/121 , C10N2240/14
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