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公开(公告)号:US20190115525A1
公开(公告)日:2019-04-18
申请号:US16217455
申请日:2018-12-12
发明人: Fumimasa HORIKIRI , Kenji SHIBATA , Kazutoshi WATANABE , Kazufumi SUENAGA , Masaki NOGUCHI , Kenji KUROIWA
IPC分类号: H01L41/316 , H01L41/187 , H01L41/332 , H01L21/308 , H01L41/113 , C23C14/08 , C23C14/34
摘要: This method for manufacturing a lead-free niobate-system ferroelectric thin film device includes: a lower electrode film formation step of forming a lower electrode film on a substrate; a ferroelectric thin film formation step of forming a niobate-system ferroelectric thin film on the lower electrode film; an etch mask pattern formation step of forming an etch mask in a desired pattern on the niobate-system ferroelectric thin film; and a ferroelectric thin film etching step of shaping the niobate-system ferroelectric thin film into a desired fine pattern by wet etching using an etchant comprising: a predetermined chelating agent including at least one selected from EDTMP, NTMP, CyDTA, HEDP, GBMP, DTPMP, and citric acid; an aqueous alkaline solution containing an aqueous ammonia solution; and an aqueous hydrogen peroxide solution.
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公开(公告)号:US20180026176A1
公开(公告)日:2018-01-25
申请号:US15548543
申请日:2016-01-19
发明人: Fumimasa HORIKIRI , Kenji SHIBATA , Kazutoshi WATANABE , Kazufumi SUENAGA , Masaki NOGUCHI , Kenji KUROIWA
IPC分类号: H01L41/316 , C23C14/34 , H01L41/113 , H01L41/332 , H01L41/187
CPC分类号: H01L41/316 , C23C14/08 , C23C14/34 , H01L21/308 , H01L41/113 , H01L41/187 , H01L41/1873 , H01L41/332
摘要: This method for manufacturing a lead-free niobate-system ferroelectric thin film device includes: a lower electrode film formation step of forming a lower electrode film on a substrate; a ferroelectric thin film formation step of forming a niobate-system ferroelectric thin film on the lower electrode film; an etch mask pattern formation step of forming an etch mask in a desired pattern on the niobate-system ferroelectric thin film; and a ferroelectric thin film etching step of shaping the niobate-system ferroelectric thin film into a desired fine pattern by wet etching using an etchant comprising: a predetermined chelating agent including at least one selected from EDTMP, NTMP, CyDTA, HEDP, GBMP, DTPMP, and citric acid; an aqueous alkaline solution containing an aqueous ammonia solution; and an aqueous hydrogen peroxide solution.
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公开(公告)号:US20220270887A1
公开(公告)日:2022-08-25
申请号:US17629157
申请日:2020-07-06
发明人: Fumimasa HORIKIRI , Noboru FUKUHARA
IPC分类号: H01L21/3063 , H01L21/306
摘要: There is provided a method for manufacturing a structure, including:
applying a first etching to a surface of a member, at least the surface being composed of Group III nitride; and applying a second etching to the surface to which the first etching has been applied, wherein in applying the first etching, a flat portion and a protruding portion are formed, the flat portion being newly appeared on the surface by etching, and the protruding portion being raised with respect to the flat portion, which is caused by being less likely to be etched than the flat portion, and in applying the second etching, the protruding portion is lowered by etching the protruding portion.-
公开(公告)号:US20220148883A1
公开(公告)日:2022-05-12
申请号:US17605834
申请日:2020-03-13
发明人: Fumimasa HORIKIRI , Noboru RUKUHARA
IPC分类号: H01L21/306 , H01L21/308 , H01L21/3213 , H01L29/20
摘要: A structure manufacturing method including: preparing a treatment object that includes an etching target having a surface to be etched comprising a conductive group III nitride and a region to be etched, a conductive member in contact with at least a portion of a surface of a conductive region of the etching target that is electrically connected to the region to be etched, and a mask formed on the surface to be etched and comprising a non-conductive material; and etching the group III nitride by immersing the treatment object in an alkaline or acidic etching solution containing peroxodisulfate ions as an oxidizing agent that accepts electrons, and irradiating the surface to be etched with light through the etching solution, wherein an edge that defines the region to be etched is constituted by an edge of the mask without including an edge of the conductive member.
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公开(公告)号:US20210359195A1
公开(公告)日:2021-11-18
申请号:US17387523
申请日:2021-07-28
IPC分类号: H01L41/18 , C23C14/08 , H01L41/08 , H01L41/187 , C01G33/00 , B41J2/14 , H01L41/318 , H03H9/02
摘要: There is provided a laminated substrate with a piezoelectric thin film, comprising: a substrate; an electrode film formed on the substrate; and a piezoelectric thin film formed on the electrode film, wherein the piezoelectric thin film is made of an alkali niobium oxide represented by a composition formula of (K1-xNax)NbO3 (0
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公开(公告)号:US20210313186A1
公开(公告)日:2021-10-07
申请号:US17289199
申请日:2020-03-13
IPC分类号: H01L21/306 , H01L21/308 , H01L21/67
摘要: There is provided a structure manufacturing method, including: preparing an etching target with at least one surface comprising group III nitride; then in a state where the etching target is immersed in an etching solution containing peroxodisulfate ions, irradiating the surface of the etching target with light through the etching solution, and generating sulfate ion radicals from the peroxodisulfate ions and generating holes in the group III nitride, thereby etching the group III nitride, wherein in the etching of the group III nitride, the etching solution remains acidic during a period for etching the group III nitride by making the etching solution acidic at a start of etching the group III nitride, and the etching is performed, with a resist mask formed on the surface.
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公开(公告)号:US20200161533A1
公开(公告)日:2020-05-21
申请号:US16628524
申请日:2018-06-22
IPC分类号: H01L41/187 , H01L41/08 , H01L41/27
摘要: There is provided a laminated substrate having a piezoelectric film, including: a substrate; and a piezoelectric film provided on the substrate interposing a base film, wherein the piezoelectric film has an alkali niobium oxide based perovskite structure represented by a composition formula of (K1-xNax)NbO3 (0
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公开(公告)号:US20190198312A1
公开(公告)日:2019-06-27
申请号:US16223924
申请日:2018-12-18
CPC分类号: H01L21/0254 , H01L21/02389 , H01L21/02639 , H01L29/045 , H01L29/2003 , H01L29/32
摘要: To provide a technique of increasing a radius of curvature of (0001) plane, and narrowing an off-angle distribution, there is provided a nitride semiconductor substrate containing a group III nitride semiconductor crystal and having a main surface in which a nearest low index crystal plane is (0001) plane, wherein (0001) plane in one of a direction along axis and a direction along axis orthogonal to the axis, is curved in a concave spherical shape with respect to the main surface, and a radius of curvature of the (0001) plane in one of the direction along the axis and the direction along the axis orthogonal to the axis is different from a radius of curvature of at least a part of the (0001) plane in the other direction.
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公开(公告)号:US20220325431A1
公开(公告)日:2022-10-13
申请号:US17640003
申请日:2020-07-06
发明人: Fumimasa HORIKIRI , Noboru FUKUHARA
摘要: A method for manufacturing a structure, including photoelectrochemically etching an etching object, the photoelectrochemical etching of the etching object including: injecting an alkaline or acidic etching solution containing an oxidizing agent that receives electrons, into a rotatably held container in which an etching object at least whose surface is composed of group III nitride is held, and immersing the surface in the etching solution; irradiating the surface of the etching object held in the container with light in a stationary state of the etching object and the etching solution; and rotating the container to scatter the etching solution toward an outer peripheral side, thereby discharging the etching solution from the container, after the surface is irradiated with the light.
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公开(公告)号:US20210215621A1
公开(公告)日:2021-07-15
申请号:US17055539
申请日:2019-04-08
发明人: Fumimasa HORIKIRI
IPC分类号: G01N21/95 , H01L29/20 , G01N21/59 , G01N21/3563 , G01N21/359 , H01L21/66 , H01L21/02
摘要: There is provided a method for producing a nitride semiconductor laminate in which a thin film is homoepitaxially grown on a substrate comprising group III nitride semiconductor crystals, the method including: homoepitaxially growing a thin film on a substrate, using the substrate in which a dislocation density on its main surface is 5×106 pieces/cm2 or less, a concentration of oxygen therein is less than 1×1017 at·cm−3, and a concentration of impurities therein other than n-type impurity is less than 1×1017 at·cm−3; and inspecting a film quality of the thin film formed on the substrate, wherein in the inspection of the film quality, the film quality of the thin film is inspected by detecting a deviation of an amount of reflected light at a predetermined wavenumber determined in a range of 1,600 cm−1 or more and 1,700 cm−1 or less in a reflection spectrum obtained by irradiating the thin film on the substrate with infrared light, from an amount of reflected. light at the predetermined wavenumber determined according to a film thickness of the thin film, a carder concentration of the substrate, and a carrier concentration of the thin film.
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