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公开(公告)号：US20190185964A1
公开(公告)日：2019-06-20
申请号：US16327359
申请日：2017-08-21
CPC分类号： C22B59/00 , B01D11/04 , C22B3/44 , Y02P10/234
摘要： Provided is a method for efficiently purifying scandium by separating scandium and impurities from an acidic solution which contains scandium and impurities that include iron. A method for purifying scandium according to the present invention subjects an acidic solution, which contains an element component including at least ion, while containing scandium, to solvent extraction by means of a mixed extractant containing a phosphoric acid-based extractant and a neutral extractant, thereby extracting scandium from the acidic solution. It is preferable that the phosphoric acid-based extractant is contained in the mixed extractant at a mixing molar ratio within the range of from 5% to 50% (inclusive). It is also preferable that the pH of the acidic solution is adjusted to a value within the range of from 0.0 to 2.0 (inclusive) before the solvent extraction.
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公开(公告)号：US09863018B2
公开(公告)日：2018-01-09
申请号：US15321286
申请日：2015-06-26
发明人： Masahiro Goto , Fukiko Kubota
CPC分类号： C22B3/42 , B01J20/22 , B01J45/00 , B01J47/12 , C22B3/001 , C22B3/0024 , C22B3/0098 , C22B3/06 , C22B3/24 , C22B7/007 , C22B23/0415 , C22B59/00 , Y02P10/234
摘要： Provided is a system for efficiently recovering trace metal from a large amount of a raw material, such as when trace metal is recovered from nickel oxide ore. This ion exchange resin has, on a carrier, an amide derivative represented by the following general formula. In the formula, R1 and R2 represent the same or different alkyl groups, R3 represents a hydrogen atom or an alkyl group, and R4 represents a hydrogen atom or an arbitrary group, other than an amino group, bonded to α carbon as an amino acid. The amide derivative is preferably a glycinamide derivative. The carrier preferably includes a primary amine and/or a secondary amine.
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公开(公告)号：US20170166995A1
公开(公告)日：2017-06-15
申请号：US15321286
申请日：2015-06-26
发明人： Masahiro Goto , Fukiko Kubota
CPC分类号： C22B3/42 , B01J20/22 , B01J45/00 , B01J47/12 , C22B3/001 , C22B3/0024 , C22B3/0098 , C22B3/06 , C22B3/24 , C22B7/007 , C22B23/0415 , C22B59/00 , Y02P10/234
摘要： Provided is a system for efficiently recovering trace metal from a large amount of a raw material, such as when trace metal is recovered from nickel oxide ore. This ion exchange resin has, on a carrier, an amide derivative represented by the following general formula. In the formula, R1 and R2 represent the same or different alkyl groups, R3 represents a hydrogen atom or an alkyl group, and R4 represents a hydrogen atom or an arbitrary group, other than an amino group, bonded to α carbon as an amino acid. The amide derivative is preferably a glycineamide derivative. The carrier preferably includes a primary amine and/or a secondary amine.
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公开(公告)号：US09376734B2
公开(公告)日：2016-06-28
申请号：US14423093
申请日：2013-04-26
发明人： Masahiro Goto , Fukiko Kubota , Yuzo Baba
IPC分类号： C22B58/00 , C22B3/00 , C07D233/64 , C07D237/06 , B01D11/04 , C07C237/06 , C22B3/26 , C22B3/32 , C22B3/38
CPC分类号： C22B58/00 , B01D11/0492 , C07C237/06 , C07D233/64 , C22B3/0024 , C22B3/0032 , C22B3/005 , Y02P10/234 , Y02P20/582
摘要： Provided are an extraction agent and extraction method that selectively extract and, at a low cost, recover indium from an acidic solution containing indium and zinc. The indium extraction agent comprises an amide derivative represented by general formula (I). In the formula, R1 and R2 each indicate the same or different alkyl group, R3 indicates a hydrogen atom or an alkyl group, and R4 indicates a hydrogen atom or any given group, other than an amino group, bound to the α-carbon as an amino acid. The general formula preferably has a glycine unit, a histidine unit, a lysine unit, an aspartic acid unit, or an N-methylglycine unit. By extracting indium from an acidic solution containing indium and zinc by means of solvent extraction using the extraction agent, it is possible to selectively extract indium.
摘要翻译： 提供一种提取剂和提取方法，其选择性地提取并且以低成本从含有铟和锌的酸性溶液中回收铟。 铟提取剂包含由通式（I）表示的酰胺衍生物。 在该式中，R 1和R 2各自表示相同或不同的烷基，R 3表示氢原子或烷基，R 4表示氢原子或与α-碳结合的除氨基以外的任何给定基团 氨基酸。 通式优选具有甘氨酸单元，组氨酸单元，赖氨酸单元，天冬氨酸单元或N-甲基甘氨酸单元。 通过使用萃取剂通过溶剂萃取从含有铟和锌的酸性溶液中提取铟，可以选择性地提取铟。
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公开(公告)号：US20150376734A1
公开(公告)日：2015-12-31
申请号：US14765272
申请日：2014-03-12
发明人： Masahiro Goto , Fukiko kubota , Yuzo Baba
CPC分类号： C22B3/0004 , C22B3/0005 , C22B13/04 , C22B15/0063 , C22B15/0089 , Y02P10/234 , Y02P10/236 , Y02W30/84
摘要： In order to selectively extract copper and/or lead from an acidic solution containing high concentrations of manganese, etc., the valuable-metal extracting agent of the present invention is expressed by general formula (1). In the formula, R1 and R2 each represent the same or different alkyl groups, R3 represents a hydrogen atom or an alkyl group, and R4 represents a hydrogen atom or a given group, other than an amino group, that bonds with an α carbon as an amino acid. In general formula (1), the inclusion of a glycine unit, a histidine unit, a lysine unit, an asparagine acid unit, or a normal methylglycine unit is preferred. When using the extracting agent to extract copper/and lead, it is preferable that the pH of the acidic solution be adjusted to 1.0-5.5 inclusive.
摘要翻译： 为了从含有高浓度锰等的酸性溶液中选择性地提取铜和/或铅，本发明的有价值金属提取剂由通式（1）表示。 在该式中，R 1和R 2各自表示相同或不同的烷基，R 3表示氢原子或烷基，R 4表示与α碳键合的氢原子或除了氨基以外的给定基团 氨基酸。 在通式（1）中，优选包含甘氨酸单元，组氨酸单元，赖氨酸单元，天冬酰胺酸单元或正常的甲基甘氨酸单元。 当使用提取剂萃取铜和铅时，优选将酸性溶液的pH调节至1.0-5.5（含）。
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公开(公告)号：US20150211093A1
公开(公告)日：2015-07-30
申请号：US14423061
申请日：2013-04-26
发明人： Masahiro Goto , Fukiko Kubota , Yuzo Baba
IPC分类号： C22B58/00 , C22B3/44 , C22B3/08 , C07C237/06 , C07D233/64
CPC分类号： C22B58/00 , B01D11/0492 , C07C237/06 , C07D233/64 , C22B3/0005 , C22B3/0032 , C22B3/08 , C22B3/44 , Y02P10/234 , Y02P20/582
摘要： Provided are an extraction agent and extraction method that selectively extract and, at a low cost, recover gallium from an acidic solution containing gallium and zinc. The gallium extraction agent comprises an amide derivative represented by general formula (1). In the formula, R and R2 each indicate the same or different alkyl group, R3 indicates a hydrogen atom or an alkyl group, and R4 indicates a hydrogen atom or any given group, other than an amino group, bonded to the α-carbon as an amino acid. The general formula preferably has a glycine unit, a histidine unit, a lysine unit, an aspartic acid unit, or an N-methylglycine unit. By extracting gallium from an acidic solution containing gallium and zinc by means of solvent extraction using the extraction agent, it is possible to selectively extract gallium.
摘要翻译： 提供一种提取剂和提取方法，其选择性地提取并且以低成本从含有镓和锌的酸性溶液中回收镓。 镓提取剂包含由通式（1）表示的酰胺衍生物。 在该式中，R和R 2各自表示相同或不同的烷基，R 3表示氢原子或烷基，R 4表示氢原子或与α-碳结合的除氨基以外的任何给定基团， 氨基酸。 通式优选具有甘氨酸单元，组氨酸单元，赖氨酸单元，天冬氨酸单元或N-甲基甘氨酸单元。 通过使用提取剂通过溶剂萃取从含有镓和锌的酸性溶液中提取镓，可以选择性地提取镓。
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7.发明授权Valuable metal extraction agent and valuable metal extraction method using said extraction agent 有权有价值的金属提取剂和有价值的金属提取方法使用所述提取剂公开(公告)号：US08951486B2
公开(公告)日：2015-02-10
申请号：US14001832
申请日：2012-11-02
发明人： Masahiro Goto , Fukiko Kubota , Yuzo Baba
IPC分类号： C01F17/00 , C07C237/06 , C22B3/26 , C22B59/00 , C22B23/00 , C22B3/00 , C07D233/26 , H01M8/00
CPC分类号： C22B23/0461 , B01D11/00 , C01F17/0006 , C07C237/06 , C07D233/26 , C22B3/0005 , C22B3/0032 , C22B23/00 , C22B23/0453 , C22B59/00 , H01M8/008 , H01M10/54 , Y02P10/234 , Y02W30/84 , Y02W30/86
摘要： The objective of the present invention is to selectively extract light rare earth metals, and by extension, europium, from an acidic solution containing a plurality of types of rare earth metal. This valuable metal extraction agent is represented by the general formula. In the formula: R1 and R2 each indicate the same or different alkyl group; R3 indicates a hydrogen atom or an alkyl group; and R4 indicates a hydrogen atom or any given group other than an amino group bonded to the α carbon as an amino acid. Preferably, the general formula has a glycine unit, a histidine unit, a lysine unit, an aspartic acid unit, or an N-methylglycine unit. Preferably, when extracting europium using the extraction agent, the pH is adjusted into the range of 2.0-3.0 inclusive, and when selectively extracting light rare earth metals, the pH is adjusted to 1.7-2.7 inclusive.
摘要翻译： 本发明的目的是从含有多种类型的稀土金属的酸性溶液中选择性地提取轻稀土金属，并延伸铕。 这种有价值的金属提取剂由通式表示。 式中R1和R2各自表示相同或不同的烷基; R3表示氢原子或烷基; R 4表示氢原子或与作为氨基酸的α碳键合的氨基以外的任意给定基团。 优选地，通式为甘氨酸单元，组氨酸单元，赖氨酸单元，天冬氨酸单元或N-甲基甘氨酸单元。 优选地，当使用提取剂提取铕时，将pH调节到2.0-3.0的范围内，并且当选择性提取轻稀土金属时，将pH调节至1.7-2.7（含）。
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公开(公告)号：US09493857B2
公开(公告)日：2016-11-15
申请号：US14765272
申请日：2014-03-12
发明人： Masahiro Goto , Fukiko Kubota , Yuzo Baba
CPC分类号： C22B3/0004 , C22B3/0005 , C22B13/04 , C22B15/0063 , C22B15/0089 , Y02P10/234 , Y02P10/236 , Y02W30/84
摘要： In order to selectively extract copper and/or lead from an acidic solution containing high concentrations of manganese, etc., the valuable-metal extracting agent of the present invention is expressed by general formula (1). In the formula, R1 and R2 each represent the same or different alkyl groups, R3 represents a hydrogen atom or an alkyl group, and R4 represents a hydrogen atom or a given group, other than an amino group, that bonds with an α carbon as an amino acid. In general formula (1), the inclusion of a glycine unit, a histidine unit, a lysine unit, an asparagine acid unit, or a normal methylglycine unit is preferred. When using the extracting agent to extract copper/and lead, it is preferable that the pH of the acidic solution be adjusted to 1.0-5.5 inclusive.
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公开(公告)号：US09481638B2
公开(公告)日：2016-11-01
申请号：US14130283
申请日：2013-02-21
发明人： Masahiro Goto , Fukiko Kubota , Yuzo Baba
CPC分类号： C07C237/06 , C22B3/0005 , C22B3/001 , C22B3/0024 , C22B3/0032 , C22B59/00 , Y02P10/234
摘要： Provided is a method for selectively extracting and inexpensively recovering scandium from an acidic solution containing calcium, magnesium, and scandium. The scandium extraction method according to the present invention involves subjecting an acidic solution containing calcium, magnesium, and scandium to solvent extraction using an extraction agent consisting of an amide derivative represented by the general formula below. In the formula, R1 and R2 represent the same or different alkyl groups, and R3 is a hydrogen atom or alkyl group. The amide derivative preferably consisting of one or more derivatives selected from glycine amide derivatives, histidine amide derivatives, lysine amide derivatives, and aspartic acid amide derivatives. The pH of the acidic solution is preferably pre-adjusted to between 1 and 4.
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10.发明授权Method for separating impurities from an acidic solution containing nickel and cobalt and/or scandium 有权从含有镍和钴和/或钪的酸性溶液中分离杂质的方法公开(公告)号：US09458526B2
公开(公告)日：2016-10-04
申请号：US14765307
申请日：2014-03-17
发明人： Masahiro Goto , Fukiko Kubota , Yuzo Baba , Yoshitomo Ozaki , Jiro Hayata , Tatsuya Higaki , Toshihiko Nagakura , Shinya Matsumoto
CPC分类号： C22B59/00 , C22B3/005 , C22B3/44 , C22B23/0453 , C22B23/0461 , Y02P10/234
摘要： Provided is a method for efficiently separating nickel, cobalt and/or scandium, and impurities from an acidic solution containing impurities such as manganese, iron, zinc, and aluminum. A valuable-metal extracting agent of the present invention is expressed by general formula (1). In the formula, R1 and R2 each represent the same or different alkyl groups, R3 represents a hydrogen atom or an alkyl group, and R4 represents a hydrogen atom or a given group, other than an amino group, that bonds with an α carbon as an amino acid. In general formula (1), the inclusion of a glycine unit, a histidine unit, a lysine unit, an asparagine acid unit, or a normal methylglycine unit is preferred.
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