Catalytic hydrofinishing of petroleum distillates in the lubricating oil boiling range
    3.
    发明授权
    Catalytic hydrofinishing of petroleum distillates in the lubricating oil boiling range 失效
    石油馏分在润滑油锅炉范围内的催化氢化

    公开(公告)号:US3619414A

    公开(公告)日:1971-11-09

    申请号:US3619414D

    申请日:1969-02-19

    Applicant: SUN OIL CO

    CPC classification number: C10M171/002 C10G2400/10

    Abstract: A process for the catalytic hydrofinishing of petroleum distillate in the lubricating oil boiling range (e.g., to produce lube oils, rubber oils, refrigerator oils, transformer oils, cable oils ATF and friction drive transmission fluids, etc.) comprises contacting a lubricating oil distillate stock with hydrogen, in the presence of a catalyst comprising a hydrogenating component selected from the group consisting of sulfides and oxides of (a) a combination of molybdenum and at least one iron group metal (e.g., Co, Ni, Fe, W) and (b) a combination of nickel and tungsten. Preferably, the hydrogenating component is composited with an inorganic oxide support (preferably refractory), and the contacting carried out at an average catalyst temperature of about 650-765* F. and with at least from 500 p.s.i. of hydrogen (preferably 800-3000 p.s.i.). The combination of conditions is so selected as to effect appreciable hydrogen consumption but no substantial cracking. Clay finishing of the catalytically hydrofinished product can be advantageous where it is desired to have such additional improvement as better electrical properties or lighter color.

    Light-colored highly aromatic oil and process of preparation
    9.
    发明授权
    Light-colored highly aromatic oil and process of preparation 失效
    浅色高芳烃油及其制备方法

    公开(公告)号:US3706653A

    公开(公告)日:1972-12-19

    申请号:US3706653D

    申请日:1969-10-27

    Applicant: SUN OIL CO

    CPC classification number: C10G45/68 C10G2400/10 Y10S208/02

    Abstract: A NOVEL LIGHT-STABLE RUBBER PROCESS OIL CONTAINING 45-85 PERCENT OF AROMATIC HYDROCARBONS IS OBTAINED IN HIGH YIELD FROM A 40-10,000 SUS (AT 100*F.) NAPHTHENIC DISTILLATE BY A TWO STEP AROMATIZATION PROCESS. IN THE FIRST STEP, WITH A SULFACTIVE CATALYST, THE SULFUR AND NITROGEN IN THE OIL ARE GREATLY REDUCED AND THE AROMATIC CONTENT INCREASES. IN THE SECOND STEP, WITH NI OR NOBLE METAL CATALYST, THE AROMATIC CONTENT IS FURTHER INCREASED AND THE PRODUCT OIL HAS GOOD COLOR STABILITY WHEN AGED IN THE PRESENCE OF ULTRAVIOLET LIGHT. OILS PRODUCED BY THE PROCESS ARE ESPECIALLY USEFUL WHEN COMPOUNDED WITH NATURAL RUBBERS AND SYNTHETIC ELASTOMERIC POLYMERS (E.G., NEOPRENE, GRS) WHICH EXHIBIT IMPROVED PROCESSABILITY AND PHYSICAL PROPERTIES WHEN COMPOUNDED WITH OILS OF HIGH AROMATICITY.

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