公开(公告)号：US12030037B2

公开(公告)日：2024-07-09

申请号：US17295931

申请日：2019-12-04

申请人： SABIC Global Technologies B.V.

发明人： Wugeng Liang ,  David West ,  Hector Perez ,  Sagar Sarsani ,  Luanyi Elizabeth Li

IPC分类号： B01J21/08 ,  B01J23/02 ,  B01J23/10 ,  B01J23/30 ,  B01J23/78 ,  B01J23/83 ,  B01J23/888 ,  C07C2/84

CPC分类号： B01J23/30 ,  B01J21/08 ,  C07C2/84 ,  C07C2521/08 ,  C07C2523/30

摘要： A catalyst composition, suitable for producing ethylene and other C2+ hydrocarbons, from methane. The composition comprises a blended product of two distinct catalyst components, blended at such synergistic proportions that results in a catalyst having high ethylene selectivity while maintaining low ethyne selectivity and sufficient catalytic activity rate. The invention further provides a method for preparing such a catalyst composition and a process for producing ethylene and other C2+ hydrocarbons, using such a catalyst composition.

公开(公告)号：US11154841B2

公开(公告)日：2021-10-26

申请号：US17252828

申请日：2019-08-07

申请人： Wugeng Liang ,  Luanyi Li ,  Vidya Sagar Reddy Sarsani ,  Hector Perez ,  David West ,  Sabic Global Technologies, B.V.

发明人： Wugeng Liang ,  Luanyi Li ,  Vidya Sagar Reddy Sarsani ,  Hector Perez ,  David West

IPC分类号： B01J23/10 ,  B01J23/04 ,  B01J35/10 ,  B01J37/08 ,  C01B3/38 ,  C07C2/84 ,  C07C11/04 ,  B82Y30/00 ,  B82Y40/00

摘要： An OCM nanoplate catalyst comprising ≥25 wt. % nanoplates; wherein a nanoplate is a three-dimensional object defined in accordance with ISO/TS 80004-2:2015; wherein a nanoplate is characterized by a first external dimension (thickness (t)≤100 nm), a second external dimension (length (l)>t), and a third external dimension (width (w)>t); wherein l and w can be the same or different; and wherein l≥5 t, w≥5 t, or l≥5 t and w≥5 t; and wherein the OCM nanoplate catalyst has general formula AaZbEcDdOx; wherein A=alkaline earth metal; Z=first rare earth element; E=second rare earth element; D=redox agent/third rare earth element; wherein the first, second, and third rare earth element are not the same; wherein a=1.0; wherein b=1.0 to 3.0; wherein c=0 to 1.5; wherein d=0 to 1.5; wherein (b>(c+d)); and wherein x balances the oxidation states.

公开(公告)号：US11439984B2

公开(公告)日：2022-09-13

申请号：US16821409

申请日：2020-03-17

申请人： Sabic Global Technologies, B.V.

发明人： Wugeng Liang ,  Luanyi Li ,  Hector Perez ,  Jae Hyung Kim ,  Pankaj Gautam ,  Vidya Sagar Reddy Sarsani ,  David West

IPC分类号： B01J23/10 ,  B01J35/00 ,  B01J35/10 ,  B01J37/02 ,  C07C2/84 ,  B01J21/12

摘要： A supported oxidative coupling of methane (OCM) catalyst comprising a support and an OCM catalytic composition characterized by the general formula AaZbEcDdOx; wherein A is an alkaline earth metal; wherein Z is a first rare earth element; wherein E is a second rare earth element; wherein D is a redox agent or a third rare earth element; wherein the first rare earth element, the second rare earth element, and the third rare earth element, when present, are not the same; wherein a is 1.0; wherein b is from about 0.1 to about 10.0; wherein c is from about 0.1 to about 10.0; wherein d is from about 0 to about 10.0; and wherein x balances the oxidation states.

公开(公告)号：US11090633B2

公开(公告)日：2021-08-17

申请号：US16743714

申请日：2020-01-15

申请人： SABIC Global Technologies B.V.

发明人： Wugeng Liang ,  David West ,  Hector Perez ,  Sagar Sarsani ,  Luanyi Elizabeth Li ,  Pankaj Gautam

IPC分类号： B01J23/30 ,  C07C11/04 ,  C07C2/84 ,  B01J23/10 ,  B01J21/08 ,  B01J37/04

摘要： A catalyst composition, suitable for producing ethylene and other C2+ hydrocarbons from methane. The composition includes a blended product of two distinct catalyst components, blended at such synergistic proportions, that results in a catalyst having high C2+ hydrocarbon selectivity while maintaining an overall sufficient catalyst activity and low ethyne selectivity. Methods for preparing such a catalyst composition and a process for producing C2+ hydrocarbons using such a catalyst composition are provided.

公开(公告)号：US11633721B2

公开(公告)日：2023-04-25

申请号：US17769879

申请日：2020-09-21

申请人： SABIC Global Technologies B.V.

发明人： Wugeng Liang ,  Luanyi Li ,  Hector Perez ,  Pankaj Gautam ,  David West

IPC分类号： B01J23/10 ,  B01J23/02 ,  B01J37/02 ,  B01J37/08 ,  C07C2/84 ,  B01J35/10 ,  B01J35/00 ,  C07C11/04

摘要： A multilayer supported oxidative coupling of methane (OCM) catalyst composition (support, first single oxide layer, one or more mixed oxide layers, optional second single oxide layer) characterized by formula AaZbEcDdOx/support; A is alkaline earth metal; Z is first rare earth element; E is second rare earth element; D is redox agent/third rare earth element; the first, second, third rare earth element are not the same; a=1.0; b=0.1-10.0; c=0.1-10.0; d=0-10.0; x balances oxidation states; first single oxide layer (Zb1Ox1, b1=0.1-10.0; x1 balances oxidation states) contacts support and one or more mixed oxide layers; one or more mixed oxide layers (Aa2Zb2Ec2Dd2Ox2, a2=1.0; b2=0.1-10.0; c2=0.1-10.0; d2=0-10.0; x2 balances oxidation states; AaZbEcDdOx and Aa2Zb2Ec2Dd2Ox2 are different) contacts first single oxide layer and optionally second single oxide layer, and second single oxide layer (AO), when present, contacts one or more mixed oxide layers and optionally first single oxide layer.

公开(公告)号：US11541375B2

公开(公告)日：2023-01-03

申请号：US17623042

申请日：2020-07-27

申请人： SABIC Global Technologies B.V. ,  Wugeng Liang ,  David West ,  Hector Perez ,  Vidya Sagar Reddy Sarsani ,  Luanyi Elizabeth Li

发明人： Wugeng Liang ,  David West ,  Hector Perez ,  Vidya Sagar Reddy Sarsani ,  Luanyi Elizabeth Li

IPC分类号： B01J23/30 ,  C01F17/32 ,  B01J23/00 ,  B01J23/10 ,  B01J37/04 ,  B01J37/08 ,  C01G41/00 ,  C07C2/84

摘要： The invention relates to a composition containing a catalyst suitable for producing ethylene and other C2+ hydrocarbons at high selectivity while improving both methane conversion and product yield. Particularly, the catalyst contains mixed metal oxides having at least one alkali earth metal and at least one rare earth metal along with an alkali metal promoter in the form of an alkali metal or in the form of an alkali metal tungstate. The invention further provides a method for preparing such a composition, using a calcination process to calcine the alkali metal promoters together with mixed metal oxides. Additionally, the invention further describes a process for producing C2+ hydrocarbons, using such a composition.

公开(公告)号：US20220380275A1

公开(公告)日：2022-12-01

申请号：US17769884

申请日：2020-09-21

申请人： Wugeng Liang ,  Azim Ali ,  Hector Perez ,  Jae Hyung Kim ,  Pankaj Gautam ,  David West ,  SABIC Global Technologies B.V.

发明人： Wugeng Liang ,  Azim Ali ,  Hector Perez ,  Jae Hyung Kim ,  Pankaj Gautam ,  David West

IPC分类号： C07C2/84 ,  B01J23/00 ,  B01J23/10 ,  B01J23/02 ,  B01J35/10 ,  B01J37/02 ,  B01J35/00

摘要： A multilayer supported oxidative coupling of methane (OCM) catalyst composition (alpha-Al2O3 support, first single oxide layer, one or more mixed oxide layers, optional second single oxide layer) characterized by formula AaZbEcDdOx/alpha-Al2O3; A is alkaline earth metal; Z is first rare earth element; E is second rare earth element; D is redox agent/third rare earth element; the first, second, third rare earth element are not the same; a=1.0; b=0.1-10.0; c=0.1-10.0; d=0-10.0; x balances oxidation states; first single oxide layer (Zb1Ox1, b1=0.1-10.0; x1 balances oxidation states) contacts alpha-Al2O3 support and one or more mixed oxide layers; one or more mixed oxide layers (Aa2Zb2Ec2Dd2Ox2, a2=1.0; b2=0.1-10.0; c2=0.1-10.0; d2=0-10.0; x2 balances oxidation states; AaZbEcDdOx and Aa2Zb2Ec2Dd2Ox2 are different) contacts first single oxide layer and optionally second single oxide layer, and second single oxide layer (AO), when present, contacts one or more mixed oxide layers and optionally first single oxide layer.

公开(公告)号：US20220258134A1

公开(公告)日：2022-08-18

申请号：US17623042

申请日：2020-07-27

申请人： Wugeng LIANG ,  David WEST ,  Vidya Sagar Reddy SARSANI ,  Hector PEREZ ,  Luanyi Elizabeth LI ,  SABIC Global Technologies B.V.

发明人： Wugeng Liang ,  David West ,  Hector Perez ,  Vidya Sagar Reddy Sarsani ,  Luanyi Elizabeth Li

IPC分类号： B01J23/30 ,  B01J23/10 ,  B01J23/00 ,  B01J37/04 ,  B01J37/08 ,  C01F17/32 ,  C01G41/00 ,  C07C2/84

摘要： The invention relates to a composition containing a catalyst suitable for producing ethylene and other C2+ hydrocarbons at high selectivity while improving both methane conversion and product yield. Particularly, the catalyst contains mixed metal oxides having at least one alkali earth metal and at least one rare earth metal along with an alkali metal promoter in the form of an alkali metal or in the form of an alkali metal tungstate. The invention further provides a method for preparing such a composition, using a calcination process to calcine the alkali metal promoters together with mixed metal oxides. Additionally, the invention further describes a process for producing C2+ hydrocarbons, using such a composition.

公开(公告)号：US11753357B2

公开(公告)日：2023-09-12

申请号：US17769884

申请日：2020-09-21

申请人： SABIC Global Technologies B.V. ,  Wugeng Liang ,  Azim Ali ,  Hector Perez ,  Jae Hyung Kim ,  Pankaj Gautam ,  David West

发明人： Wugeng Liang ,  Azim Ali ,  Hector Perez ,  Jae Hyung Kim ,  Pankaj Gautam ,  David West

IPC分类号： C07C2/84 ,  B01J23/00 ,  B01J23/02 ,  B01J23/10 ,  B01J35/00 ,  B01J35/10 ,  B01J37/02

CPC分类号： C07C2/84 ,  B01J23/002 ,  B01J23/02 ,  B01J23/10 ,  B01J35/0006 ,  B01J35/108 ,  B01J35/1009 ,  B01J35/1014 ,  B01J35/1038 ,  B01J35/1042 ,  B01J37/0236 ,  B01J2523/24 ,  B01J2523/3706 ,  C07C2523/02 ,  C07C2523/10

摘要： A multilayer supported oxidative coupling of methane (OCM) catalyst composition (alpha-Al2O3 support, first single oxide layer, one or more mixed oxide layers, optional second single oxide layer) characterized by formula AaZbEcDdOx/alpha-Al2O3; A is alkaline earth metal; Z is first rare earth element; E is second rare earth element; D is redox agent/third rare earth element; the first, second, third rare earth element are not the same; a=1.0; b=0.1-10.0; c=0.1-10.0; d=0-10.0; x balances oxidation states; first single oxide layer (Zb1Ox1, b1=0.1-10.0; x1 balances oxidation states) contacts alpha-Al2O3 support and one or more mixed oxide layers; one or more mixed oxide layers (Aa2Zb2Ec2Dd2Ox2, a2=1.0; b2=0.1-10.0; c2=0.1-10.0; d2=0-10.0; x2 balances oxidation states; AaZbEcDdOx and Aa2Zb2Ec2Dd2Ox2 are different) contacts first single oxide layer and optionally second single oxide layer, and second single oxide layer (AO), when present, contacts one or more mixed oxide layers and optionally first single oxide layer.

公开(公告)号：US11969724B2

公开(公告)日：2024-04-30

申请号：US18038547

申请日：2021-12-07

申请人： SABIC Global Technologies B.V.

发明人： Wugeng Liang ,  Hector Perez ,  Pankaj Gautam Singh ,  David West

IPC分类号： B01J8/04 ,  B01J21/04 ,  B01J23/63 ,  C07C2/84

CPC分类号： B01J8/0438 ,  B01J8/0492 ,  B01J21/04 ,  B01J23/63 ,  C07C2/84 ,  C07C2521/04 ,  C07C2523/63

摘要： The invention relates to a reactor system for oxidative coupling of methane (OCM), comprising: reactor system for oxidative coupling of methane (OCM), comprising: (a) an inlet configured to receive a reactant mixture; (b) a reaction chamber having an upstream end and a downstream end such that the reaction chamber extends from the upstream end to the downstream end, and the reaction chamber comprises a catalyst bed having a catalyst composition having at least two catalyst components: (i) a low selectivity catalyst component; and (ii) a high selectivity catalyst component; and (c) an outlet configured to recover a C2+ hydrocarbon product mixture from the reactor system; wherein the reactor system is configured such that the reactant mixture substantially contacts the high selectivity catalyst component prior to contacting the low selectivity catalyst component. The invention further describes a process for the production of C2+ hydrocarbon product mixture using the present reactor system.