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公开(公告)号：US07235612B2
公开(公告)日：2007-06-26
申请号：US10766487
申请日：2004-01-29
申请人： Sadayuki Kobayashi , Jiro Kumaki , Akira Hirai , Toru Nishimura
发明人： Sadayuki Kobayashi , Jiro Kumaki , Akira Hirai , Toru Nishimura
CPC分类号： C08L67/02 , C08J3/005 , C08L69/00 , C08L81/02 , C08L2666/18
摘要： This invention is a method for manufacturing a polymer alloy, by making at least two resins used as components miscible, and inducing the spinodal decomposition for causing phase separation, for forming a co-continuous structure with a wavelength of concentration fluctuation of 0.001 to 1 μm or a dispersed structure with a distance between particles of 0.001 to 1 μm. This invention is also a polymer alloy manufactured by the method. The polymer alloy of this invention can provide a molded article, film, fibers and the like respectively with excellent mechanical properties at high productivity.
摘要翻译： 本发明是一种制造聚合物合金的方法，通过使至少两种树脂用作可混溶的组分，并引起旋节分解引起相分离，形成波长为0.001至1μm的共连续结构 或具有0.001至1μm的颗粒之间的距离的分散结构。 本发明也是通过该方法制造的聚合物合金。 本发明的聚合物合金可以分别以高生产率提供优异的机械性能的模塑制品，薄膜，纤维等。
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公开(公告)号：US07462672B2
公开(公告)日：2008-12-09
申请号：US11802762
申请日：2007-05-24
申请人： Sadayuki Kobayashi , Jiro Kumaki
发明人： Sadayuki Kobayashi , Jiro Kumaki
CPC分类号： C08L67/02 , C08J3/005 , C08L69/00 , C08L81/02 , C08L2666/18
摘要： A polymer alloy of polyphenylene sulfide resin and a polyester resin with polyethylene terephthalate as a main component, and forming a co-continuous structure with a wavelength of concentration fluctuation of 0.001 to 1 μm or a dispersed structure with a distance between particles of to 1 μm. The co-continuous structure or dispersed structure of the polymer alloy is formed by the phase separation caused by spinodal decomposition. The polymer alloy is miscible when the shear rate is kept in a range from 100 to 10000 sec−1, and is separated into phases under no shear flow. The polymer alloy of this invention can provide a molded article, film, fibers and the like respectively with excellent mechanical properties at high productivity.
摘要翻译： 聚苯硫醚树脂和聚对苯二甲酸乙二醇酯作为主要成分的聚酯树脂的聚合物合金，形成浓度波动为0.001〜1μm的共连续结构体或粒径为1μm的分散结构体 。 聚合物合金的共连续结构或分散结构通过由旋节分解引起的相分离形成。 当剪切速率保持在100至10000秒-1的范围内时，聚合物合金是可混溶的，并且在无剪切流动下分离成相。 本发明的聚合物合金可以分别以高生产率提供优异的机械性能的模塑制品，薄膜，纤维等。
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公开(公告)号：US20070225450A1
公开(公告)日：2007-09-27
申请号：US11802762
申请日：2007-05-24
申请人： Sadayuki Kobayashi , Jiro Kumaki
发明人： Sadayuki Kobayashi , Jiro Kumaki
IPC分类号： C08L67/00
CPC分类号： C08L67/02 , C08J3/005 , C08L69/00 , C08L81/02 , C08L2666/18
摘要： This invention is a method for manufacturing a polymer alloy, by making at least two resins used as components miscible, and inducing the spinodal decomposition for causing phase separation, for forming a co-continuous structure with a wavelength of concentration fluctuation of 0.001 to 1 μm or a dispersed structure with a distance between particles of 0.001 to 1 μm. This invention is also a polymer alloy manufactured by the method. The polymer alloy of this invention can provide a molded article, film, fibers and the like respectively with excellent mechanical properties at high productivity.
摘要翻译： 本发明是一种制造聚合物合金的方法，通过使至少两种树脂用作可混溶的组分，并引起旋节分解以引起相分离，形成波长为0.001至1μm的共连续结构 或具有0.001至1μm的颗粒之间的距离的分散结构。 本发明也是通过该方法制造的聚合物合金。 本发明的聚合物合金可以分别以高生产率提供优异的机械性能的模塑制品，薄膜，纤维等。
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4.发明申请公开(公告)号：US20070032577A1
公开(公告)日：2007-02-08
申请号：US10550666
申请日：2004-02-10
IPC分类号： C09D101/18
CPC分类号： C08L67/04 , C08J5/18 , C08J2367/04 , C08L1/10 , C08L25/18 , C08L33/08 , C08L33/10 , C08L2666/26 , C08L2666/06 , C08L2666/04
摘要： The invention provides a resin composition containing poly(lactic acid) and a cellulosic ester, which are biomass type materials; a resin composition excellent in transparency, mechanical properties, and thermostability; a biaxially drawn film containing poly(lactic acid) and at least one compound selected from cellulosic esters, poly(meth)acrylates, and polyvinyl compounds having a glass transition temperature of 60° C. or higher; and a biaxially drawn film excellent in transparency, mechanical properties, and thermostability. The aims of the invention can be achieved by a resin composition obtained by melt-kneading a poly(lactic acid) polymer with a weight average molecular weight of 50,000 or higher and a cellulosic ester; a resin composition excellent in transparency and having luminous transmittance of 40% or higher for visible light with 400 nm; its production method; a molded article and a film made of the resin composition; a poly(lactic acid) biaxially drawn film containing a poly(lactic acid) polymer with a weight average molecular weight of 50,000 or higher and at least one compound selected from cellulosic esters, poly(meth)acrylates, and polyvinyl compounds having a glass transition temperature of 60° C. or higher; a poly(lactic acid) biaxially drawn film excellent in transparency and having film haze of 10% or lower; and a molded article made of the film.
摘要翻译： 本发明提供含有聚（乳酸）和纤维素酯的树脂组合物，其为生物质型材料; 透明性，机械性能和热稳定性优异的树脂组合物; 含有聚（乳酸）和至少一种选自纤维素酯，聚（甲基）丙烯酸酯和玻璃化转变温度为60℃以上的聚乙烯基化合物的化合物的双轴拉伸膜; 以及透明性，机械性能和热稳定性优异的双轴拉伸膜。 本发明的目的可以通过将重均分子量为50,000以上的聚（乳酸）聚合物和纤维素酯熔融捏合得到的树脂组合物实现， 对于400nm的可见光，透明性优异，透光率为40％以上的树脂组合物; 其生产方式; 模塑制品和由该树脂组合物制成的薄膜; 含有重均分子量为50,000以上的聚（乳酸）聚合物的聚（乳酸）双轴拉伸膜和至少一种选自纤维素酯，聚（甲基）丙烯酸酯和具有玻璃化转变的聚乙烯基化合物的化合物 温度为60℃以上; 具有透明性优异且膜雾度为10％以下的聚（乳酸）双轴拉伸膜; 和由该膜制成的模制品。
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公开(公告)号：US08338547B2
公开(公告)日：2012-12-25
申请号：US12680436
申请日：2008-09-18
IPC分类号： C08G75/14 , C08L81/04 , B29K67/00 , B29K101/12 , B29K81/00
CPC分类号： C08J3/005 , C08J3/28 , C08L77/00 , C08L79/08 , Y10T428/31786
摘要： To provide a structure material having excellent mechanical characteristics and a functional material having excellent regularity, provided are a polymer alloy which is composed of at least two components of thermoplastic resins and of which the structure can be controlled finely and evenly dispersed and a production method of the polymer alloy. With respect to a polymer alloy composed of at least two or more components of thermoplastic resins, a precursor (A) of at least one thermoplastic resin among the thermoplastic resin components composing the polymer alloy is chemically reacted in the co-presence of the remaining thermoplastic resin component (B1) and/or a precursor (B2) of the thermoplastic resin component to induce spinodal decomposition, so that it is made possible to obtain a polymer alloy having excellent regularity and of which the structure is finely controllable and the structure is evenly dispersed.
摘要翻译： 为了提供具有优异机械特性的结构材料和具有优异规则性的功能材料，提供了由热塑性树脂的至少两种组分组成并且其结构可以精细均匀分散的聚合物合金和制备方法 聚合物合金。 对于由至少两种以上的热塑性树脂成分构成的聚合物合金，构成聚合物合金的热塑性树脂成分中的至少一种热塑性树脂的前体（A）在剩余的热塑性树脂的共存下进行化学反应 树脂成分（B1）和/或热塑性树脂成分的前体（B2）引起旋节状分解，使得可以获得具有优异规则性并且其结构精细可控且结构均匀的聚合物合金 分散
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公开(公告)号：US20110269907A1
公开(公告)日：2011-11-03
申请号：US13180031
申请日：2011-07-11
IPC分类号： C08L51/04 , C08L69/00 , C08L27/06 , C08L33/12 , C08L23/12 , C08L23/06 , C08L67/04 , C08L25/04
CPC分类号： C08L51/006 , C08K5/092 , C08L23/0853 , C08L25/12 , C08L33/06 , C08L33/12 , C08L35/06 , C08L51/04 , C08L53/00 , C08L55/02 , C08L67/04 , C08L2666/02 , C08L2666/04 , C08L2666/24 , C08L2666/14
摘要： A resin composition is described that is excellent in strength, impact resistance, heat resistance and moldability, while further allowing for a reduction in the amount of CO2 needed for its production. The resin composition includes a styrene-based resin (A), an aliphatic polyester (B) and at least one species selected from a compatibilizer (C) and a dicarboxylic anhydride (D), wherein the compatibilizer is preferably at least one species selected from:(C-1) a methyl methacrylate polymer; (C-2) a vinyl-based polymer to which an epoxy unit or acid anhydride unit is copolymerized; (C-3) a graft polymer in which a methyl methacrylate unit is grafted to a rubbery polymer; and (C-4) a block copolymer having a polylactide segment and a vinyl-based polymer segment.
摘要翻译： 描述了强度，耐冲击性，耐热性和成型性优异的树脂组合物，同时进一步允许其生产所需的二氧化碳的量的减少。 树脂组合物包括苯乙烯类树脂（A），脂肪族聚酯（B）和选自增容剂（C）和二羧酸酐（D）中的至少一种，其中相容剂优选为选自以下的至少一种： ：（C-1）甲基丙烯酸甲酯聚合物; （C-2）共聚有环氧单元或酸酐单元的乙烯基类聚合物; （C-3）接枝聚合物，其中甲基丙烯酸甲酯单元接枝到橡胶状聚合物上; 和（C-4）具有聚丙交酯链段和乙烯基类聚合物链段的嵌段共聚物。
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公开(公告)号：US06813827B2
公开(公告)日：2004-11-09
申请号：US10308383
申请日：2002-12-03
IPC分类号： B23P2100
CPC分类号： B23P21/004 , B63B9/00 , B63B9/06 , Y10T29/49829 , Y10T29/53365
摘要： A small planing watercraft manufacturing system includes a hull loading station, an engine mounting station, an adhesive applying station, a deck assembling station, a clamping station, a curing station and a watercraft unloading station that are disposed in a closed loop-shaped travel path in the order named with the hull loading station and the watercraft unloading station located adjacent to each other. By virtue of the closed loop-shaped travel path, the manufacturing system requires only a small space for installation thereof, can be constructed at a relatively low equipment cost and is able to produce small planing watercrafts with increased efficiencies.
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8.发明申请POLYLACTIC ACID STEREOCOMPLEX, METHOD FOR PRODUCTION THEREOF, AND NUCLEATING AGENT FOR POLYLACTIC ACID RESIN 有权聚酸酯立体异构体，其生产方法和聚氨酯树脂的核化剂公开(公告)号：US20120202944A1
公开(公告)日：2012-08-09
申请号：US13390747
申请日：2010-08-19
IPC分类号： C08L67/04
CPC分类号： C08L67/04 , B29C47/0004 , B29C47/6056 , B29C47/6087 , B29C47/92 , B29C2947/92695 , B29C2947/92704 , B29C2947/92714 , C08J3/005 , C08J2367/04 , C08K5/0008 , C08K5/0016 , C08K5/0083 , C08L2205/02 , Y10T428/2982 , C08L2666/18
摘要： A polylactic acid stereocomplex has a crystal melting peak temperature of 215° C. or more, wherein the crystal melting peak is a single peak and has a peak half width of 12° C. or less, and a crystal melting enthalpy of 60 J/g or more as measured by differential scanning calorimetry. The polylactic acid stereocomplex has a high melting point, good heat resistance, and a high level of mechanical properties and chemical resistance. The method for producing a polylactic acid stereocomplex includes chaotic mixing of 30 to 70 parts by weight of (A) poly-L-lactic acid and 30 to 70 parts by weight of (B) poly-D-lactic acid based on 100 parts by weight of the total of (A) poly-L-lactic acid and (B) poly-D-lactic acid.
摘要翻译： 聚乳酸立体络合物的结晶熔融峰温度为215℃以上，其中，结晶熔融峰为单峰，半峰宽为12℃以下，结晶熔融焓为60J / g或更高，通过差示扫描量热法测量。 聚乳酸立体络合物具有高熔点，良好的耐热性和高水平的机械性能和耐化学性。 聚乳酸立体络合物的制造方法包括：（A）聚-L-乳酸30〜70重量份，（B）聚-D-乳酸30〜70重量份混合混合，100重量份 （A）聚-L-乳酸和（B）聚-D-乳酸的总重量。
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9.发明申请THERMOPLASTIC RESIN COMPOSITION, PRODUCTION METHOD THEREOF, AND MOLDED ARTICLE 有权热塑性树脂组合物，其制造方法和模制品公开(公告)号：US20100273944A1
公开(公告)日：2010-10-28
申请号：US12293697
申请日：2007-03-22
CPC分类号： C08J3/203 , B29C47/0021 , B29C47/38 , B29C47/402 , C08L51/06 , C08L77/00 , C08L77/02 , C08L101/00 , C08L101/02 , C08L2666/24
摘要： A thermoplastic resin composition includes a thermoplastic resin (A) and a reactive functional group-containing resin (B), which has a specific structure in the morphology of the resin composition observed by transmission electron microscopy tomography, and the relaxation time T1C of each carbon nucleus by the solid NMR measurement of the thermoplastic resin composition containing a polyamide resin is kept in a specific range. The composition is excellent in the balance between contradictory properties such as impact resistance and heat resistance, remarkably exhibits a peculiar viscoelastic behavior not observed in the conventional polymeric materials, and is remarkably excellent in impact energy absorbing performance and vibration energy absorbing performance at the time of high-speed deformation.
摘要翻译： 热塑性树脂组合物包括热塑性树脂（A）和含有反应性官能团的树脂（B），其具有通过透射电子显微镜断层摄影观察到的树脂组合物的形态的特定结构，并且各碳的弛豫时间T1C 通过含有聚酰胺树脂的热塑性树脂组合物的固体NMR测定将核保持在特定范围内。 该组合物在抗冲击性和耐热性等相互矛盾的性质之间的平衡优异，显着地表现出在常规聚合物材料中未观察到的特有的粘弹性行为，并且在冲击能量吸收性能和振动能量吸收性能方面显着优异 高速变形。
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公开(公告)号：US20100216946A1
公开(公告)日：2010-08-26
申请号：US12680436
申请日：2008-09-18
CPC分类号： C08J3/005 , C08J3/28 , C08L77/00 , C08L79/08 , Y10T428/31786
摘要： To provide a structure material having excellent mechanical characteristics and a functional material having excellent regularity, provided are a polymer alloy which is composed of at least two components of thermoplastic resins and of which the structure can be controlled finely and evenly dispersed and a production method of the polymer alloy. With respect to a polymer alloy composed of at least two or more components of thermoplastic resins, a precursor (A) of at least one thermoplastic resin among the thermoplastic resin components composing the polymer alloy is chemically reacted in the co-presence of the remaining thermoplastic resin component (B1) and/or a precursor (B2) of the thermoplastic resin component to induce spinodal decomposition, so that it is made possible to obtain a polymer alloy having excellent regularity and of which the structure is finely controllable and the structure is evenly dispersed.
摘要翻译： 为了提供具有优异机械特性的结构材料和具有优异规则性的功能材料，提供了由热塑性树脂的至少两种组分组成并且其结构可以精细均匀分散的聚合物合金和制备方法 聚合物合金。 对于由至少两种以上的热塑性树脂成分构成的聚合物合金，构成聚合物合金的热塑性树脂成分中的至少一种热塑性树脂的前体（A）在剩余的热塑性树脂的共存下进行化学反应 树脂成分（B1）和/或热塑性树脂成分的前体（B2）引起旋节状分解，使得可以获得具有优异规则性并且其结构精细可控且结构均匀的聚合物合金 分散
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