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公开(公告)号：US08449849B2
公开(公告)日：2013-05-28
申请号：US13242616
申请日：2011-09-23
申请人： Sagar B. Gadewar , Michael D. Wyrsta , Philip Grosso , Aihua Zhang , Eric W. McFarland , Zachary J. A. Komon , Jeffrey H. Sherman
发明人： Sagar B. Gadewar , Michael D. Wyrsta , Philip Grosso , Aihua Zhang , Eric W. McFarland , Zachary J. A. Komon , Jeffrey H. Sherman
CPC分类号： C07C15/02 , C07C1/26 , C07C11/04 , C07C11/06 , C07C17/10 , C07C17/37 , C07C2527/053 , C07C2529/40 , C07C2529/44 , C07C2529/46 , C07C2529/48 , C07C2529/83 , C07C2529/85 , C07C2529/89 , Y02P20/52 , Y10S585/943 , C07C15/04 , C07C19/075
摘要： A method comprising providing a halogen stream; providing a first alkane stream; reacting at least a portion of the halogen stream with at least a portion of the first alkane stream to form a halogenated stream, wherein the halogenated stream comprises alkyl monohalides, alkyl polyhalides, and a hydrogen halide; providing a second alkane stream; and reacting at least a portion of the second alkane stream with at least a portion of the alkyl polyhalides to create at least some additional alkyl monohalides.
摘要翻译： 一种包括提供卤素流的方法; 提供第一烷烃流; 使卤素物流的至少一部分与至少一部分第一烷烃物流反应以形成卤化物流，其中卤代物流包含烷基一卤化物，烷基多卤化物和卤化氢; 提供第二烷烃流; 并使第二烷烃物流的至少一部分与至少一部分烷基多卤化物反应以产生至少一些另外的烷基一卤化物。
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公开(公告)号：US07579510B2
公开(公告)日：2009-08-25
申请号：US11703358
申请日：2007-02-05
申请人： Sagar B. Gadewar , Michael D. Wyrsta , Philip Grosso , Aihua Zhang , Eric W. McFarland , Zachary J. A. Komon , Jeffrey H. Sherman
发明人： Sagar B. Gadewar , Michael D. Wyrsta , Philip Grosso , Aihua Zhang , Eric W. McFarland , Zachary J. A. Komon , Jeffrey H. Sherman
CPC分类号： C07C15/02 , C07C1/26 , C07C11/04 , C07C11/06 , C07C17/10 , C07C17/37 , C07C2527/053 , C07C2529/40 , C07C2529/44 , C07C2529/46 , C07C2529/48 , C07C2529/83 , C07C2529/85 , C07C2529/89 , Y02P20/52 , Y10S585/943 , C07C15/04 , C07C19/075
摘要： An improved continuous process for converting methane, natural gas, or other hydrocarbon feedstocks into one or more higher hydrocarbons or olefins by continuously cycling through the steps of alkane halogenation, product formation (carbon-carbon coupling), product separation, and regeneration of halogen is provided. Preferably, the halogen is continually recovered by reacting hydrobromic acid with air or oxygen. The invention provides an efficient route to aromatic compounds, aliphatic compounds, mixtures of aliphatic and aromatic compounds, olefins, gasoline grade materials, and other useful products.
摘要翻译： 通过连续循环通过烷烃卤化，产物形成（碳 - 碳偶联），产物分离和卤素再生的步骤将甲烷，天然气或其它烃原料转化成一种或多种高级烃或烯烃的改进的连续方法是 提供。 优选地，通过使氢溴酸与空气或氧反应来连续地回收卤素。 本发明提供了芳香化合物，脂肪族化合物，脂族和芳族化合物的混合物，烯烃，汽油级材料和其它有用产物的有效途径。
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公开(公告)号：US08053616B2
公开(公告)日：2011-11-08
申请号：US12496348
申请日：2009-07-01
申请人： Sagar B. Gadewar , Michael D. Wyrsta , Philip Grosso , Aihua Zhang , Eric W. McFarland , Zachary J. A. Komon , Jeffrey H. Sherman
发明人： Sagar B. Gadewar , Michael D. Wyrsta , Philip Grosso , Aihua Zhang , Eric W. McFarland , Zachary J. A. Komon , Jeffrey H. Sherman
IPC分类号： C07C17/00
CPC分类号： C07C15/02 , C07C1/26 , C07C11/04 , C07C11/06 , C07C17/10 , C07C17/37 , C07C2527/053 , C07C2529/40 , C07C2529/44 , C07C2529/46 , C07C2529/48 , C07C2529/83 , C07C2529/85 , C07C2529/89 , Y02P20/52 , Y10S585/943 , C07C15/04 , C07C19/075
摘要： A method comprising providing a halogen stream; providing a first alkane stream; reacting at least a portion of the halogen stream with at least a portion of the first alkane stream to form a halogenated stream, wherein the halogenated stream comprises alkyl monohalides, alkyl polyhalides, and a hydrogen halide; providing a second alkane stream; and reacting at least a portion of the second alkane stream with at least a portion of the alkyl polyhalides to create at least some additional alkyl monohalides.
摘要翻译： 一种包括提供卤素流的方法; 提供第一烷烃流; 使卤素物流的至少一部分与至少一部分第一烷烃物流反应以形成卤化物流，其中卤代物流包含烷基一卤化物，烷基多卤化物和卤化氢; 提供第二烷烃流; 并使第二烷烃物流的至少一部分与至少一部分烷基多卤化物反应以产生至少一些另外的烷基一卤化物。
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公开(公告)号：US20120009090A1
公开(公告)日：2012-01-12
申请号：US13242616
申请日：2011-09-23
申请人： Sagar B. Gadewar , Michael D. Wyrsta , Philip Grosso , Aihua Zhang , Eric W. McFarland , Zachary J.A. Komon , Jeffrey H. Sherman
发明人： Sagar B. Gadewar , Michael D. Wyrsta , Philip Grosso , Aihua Zhang , Eric W. McFarland , Zachary J.A. Komon , Jeffrey H. Sherman
CPC分类号： C07C15/02 , C07C1/26 , C07C11/04 , C07C11/06 , C07C17/10 , C07C17/37 , C07C2527/053 , C07C2529/40 , C07C2529/44 , C07C2529/46 , C07C2529/48 , C07C2529/83 , C07C2529/85 , C07C2529/89 , Y02P20/52 , Y10S585/943 , C07C15/04 , C07C19/075
摘要： A method comprising providing a halogen stream; providing a first alkane stream; reacting at least a portion of the halogen stream with at least a portion of the first alkane stream to form a halogenated stream, wherein the halogenated stream comprises alkyl monohalides, alkyl polyhalides, and a hydrogen halide; providing a second alkane stream; and reacting at least a portion of the second alkane stream with at least a portion of the alkyl polyhalides to create at least some additional alkyl monohalides.
摘要翻译： 一种包括提供卤素流的方法; 提供第一烷烃流; 使卤素物流的至少一部分与至少一部分第一烷烃物流反应以形成卤化物流，其中卤代物流包含烷基一卤化物，烷基多卤化物和卤化氢; 提供第二烷烃流; 并使第二烷烃物流的至少一部分与至少一部分烷基多卤化物反应以产生至少一些另外的烷基一卤化物。
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公开(公告)号：US20100099928A1
公开(公告)日：2010-04-22
申请号：US12496348
申请日：2009-07-01
申请人： Sagar B. Gadewar , Michael D. Wyrsta , Philip Grosso , Aihua Zhang , Eric W. McFarland , Zachary J.A. Komon , Jeffrey H. Sherman
发明人： Sagar B. Gadewar , Michael D. Wyrsta , Philip Grosso , Aihua Zhang , Eric W. McFarland , Zachary J.A. Komon , Jeffrey H. Sherman
CPC分类号： C07C15/02 , C07C1/26 , C07C11/04 , C07C11/06 , C07C17/10 , C07C17/37 , C07C2527/053 , C07C2529/40 , C07C2529/44 , C07C2529/46 , C07C2529/48 , C07C2529/83 , C07C2529/85 , C07C2529/89 , Y02P20/52 , Y10S585/943 , C07C15/04 , C07C19/075
摘要： A method comprising providing a halogen stream; providing a first alkane stream; reacting at least a portion of the halogen stream with at least a portion of the first alkane stream to form a halogenated stream, wherein the halogenated stream comprises alkyl monohalides, alkyl polyhalides, and a hydrogen halide; providing a second alkane stream; and reacting at least a portion of the second alkane stream with at least a portion of the alkyl polyhalides to create at least some additional alkyl monohalides.
摘要翻译： 一种包括提供卤素流的方法; 提供第一烷烃流; 使卤素物流的至少一部分与至少一部分第一烷烃物流反应以形成卤化物流，其中卤代物流包含烷基一卤化物，烷基多卤化物和卤化氢; 提供第二烷烃流; 并使第二烷烃物流的至少一部分与至少一部分烷基多卤化物反应以产生至少一些另外的烷基一卤化物。
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公开(公告)号：US07883568B2
公开(公告)日：2011-02-08
申请号：US11703277
申请日：2007-02-05
申请人： Sagar B. Gadewar , Peter K. Stoimenov , Philip Grosso , Eric W. McFarland , Ashley W. Breed , Michael J. Weiss , Michael D. Wyrsta
发明人： Sagar B. Gadewar , Peter K. Stoimenov , Philip Grosso , Eric W. McFarland , Ashley W. Breed , Michael J. Weiss , Michael D. Wyrsta
IPC分类号： B01D53/02
CPC分类号： B01D3/10 , B01D1/16 , B01D53/685 , B01D53/75 , B01D2251/60 , B01D2257/2022 , B01D2257/2025 , C01B7/0743 , C01B7/096 , C01B21/0433 , C01B21/045 , C01B2210/0009 , C01B2210/0015
摘要： A process is provided for separating one or more light gases from bromine or chlorine using one or more physical separations and contact with a chemical scrubber to recover additional halogen. In one aspect, the process comprises (a) providing a feed of halogen containing one or more light gases to a distillation column or flash vaporizer; (b) operating the distillation column or flash vaporizer to separate the feed into (i) a first liquid containing a major amount of halogen and no more than a minor amount of light gas(es), and (ii) a first vapor containing a major amount of light gas(es) and no more than a minor amount of halogen; and (c) providing the vapor to a chemical scrubber to recover halogen from the vapor.
摘要翻译： 提供了一种使用一种或多种物理分离从溴或氯中分离一种或多种轻质气体的方法，并与化学洗涤器接触以回收额外的卤素。 一方面，该方法包括（a）向蒸馏塔或闪蒸器提供含有一种或多种轻质气体的卤素进料; （b）操作蒸馏塔或闪蒸器以将进料分离成（i）含有主要量的卤素和不多于少量轻质气体的第一液体，和（ii）含有 主要量的轻质气体，不超过少量的卤素; 和（c）将蒸汽提供给化学洗涤器以从蒸气中回收卤素。
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公开(公告)号：US20120088848A1
公开(公告)日：2012-04-12
申请号：US13076953
申请日：2011-03-31
申请人： Timothy J. Deming , Miaoer Yu , Scott A. Curtin , Jungyeon Hwang , Michael D. Wyrsta , Andrew Nowak , Scott W. Seidel
发明人： Timothy J. Deming , Miaoer Yu , Scott A. Curtin , Jungyeon Hwang , Michael D. Wyrsta , Andrew Nowak , Scott W. Seidel
IPC分类号： A61K47/34 , C08B37/00 , C07H21/00 , C08J3/205 , C07F15/00 , C08G69/48 , B29C67/24 , C07F15/04 , C07K2/00
CPC分类号： C07F15/065 , C07F15/025 , C07F15/045 , C07K1/02 , C08G69/48
摘要： Methods and compositions for the generation of polypeptides having varied material properties are disclosed herein. Methods include means for initiating the polymerization of aminoacid-N-carboxyanhydride (NCA) monomer by combining the monomer with an amido-containing metallacycle, for making self assembling amphiphilic block copolypeptides and related protocols for adding oligo(ethyleneglycol) functionalized aminoacid-N-carboxyanhydrides (NCAs) to polyaminoacid chains. Additional methods include means of adding an end group to the carboxy terminus of a polyaminoacid chain by reacting an alloc-protected amino acid amide with a transition metal-donor ligand complex to forming an amido-amidate metallacycle for use in further polymerization reactions. Novel compositions for use in peptide synthesis and design including five and six membered amido-containing metallacycles and block copolypeptides are also disclosed.
摘要翻译： 本文公开了用于产生具有不同材料性质的多肽的方法和组合物。 方法包括通过将单体与含酰胺的金属环组合来引发氨基酸-N-羧酸酐（NCA）单体的聚合的手段，用于制备自组装两亲嵌段共聚肽和用于加入低聚（乙二醇）官能化的氨基酸-N-羧酸酐的相关方案 （NCAs）转化为聚氨基酸链。 另外的方法包括通过使分配保护的氨基酸酰胺与过渡金属给体配体络合物反应形成酰氨基脒化物金属环用于进一步聚合反应而将端基加入到聚氨基酸链的羧基末端的方法。 还公开了用于肽合成和设计的新型组合物，包括含有五元和六元的含酰胺的金属螯合物和嵌段共聚肽。
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公开(公告)号：US07968519B2
公开(公告)日：2011-06-28
申请号：US12006440
申请日：2008-01-02
申请人： Timothy J. Deming , Miaoer Yu , Scott A. Curtin , Jungyeon Hwang , Michael D. Wyrsta , Andrew Nowak , Scott W. Seidel
发明人： Timothy J. Deming , Miaoer Yu , Scott A. Curtin , Jungyeon Hwang , Michael D. Wyrsta , Andrew Nowak , Scott W. Seidel
IPC分类号： C07K2/00
摘要： Methods and compositions for the generation of polypeptides having varied material properties are disclosed herein. Methods include means for initiating the polymerization of aminoacid-N-carboxyanhydride (NCA) monomer by combining the monomer with an amido-containing metallacycle, for making self assembling amphiphilic block copolypeptides and related protocols for adding oligo(ethyleneglycol) functionalized aminoacid-N-carboxyanhydrides (NCAs) to polyaminoacid chains. Additional methods include means of adding an end group to the carboxy terminus of a polyaminoacid chain by reacting an alloc-protected amino acid amide with a transition metal-donor ligand complex to forming an amido-amidate metallacycle for use in further polymerization reactions. Novel compositions for use in peptide synthesis and design including five and six membered amido-containing metallacycles and block copolypeptides are also disclosed.
摘要翻译： 本文公开了用于产生具有不同材料性质的多肽的方法和组合物。 方法包括通过将单体与含酰胺的金属环组合来引发氨基酸-N-羧酸酐（NCA）单体的聚合的手段，用于制备自组装两亲嵌段共聚肽和用于加入低聚（乙二醇）官能化的氨基酸-N-羧酸酐的相关方案 （NCAs）转化为聚氨基酸链。 另外的方法包括通过使分配保护的氨基酸酰胺与过渡金属给体配体络合物反应形成酰氨基脒化物金属环用于进一步聚合反应而将端基加入到聚氨基酸链的羧基末端的方法。 还公开了用于肽合成和设计的新型组合物，包括含有五元和六元的含酰胺的金属螯合物和嵌段共聚肽。
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公开(公告)号：US20080277319A1
公开(公告)日：2008-11-13
申请号：US11749741
申请日：2007-05-16
申请人： Michael D. Wyrsta
发明人： Michael D. Wyrsta
CPC分类号： B01D53/62 , B01D2251/40 , B01D2257/504 , C01B32/60 , C01F5/24 , C01F11/18 , C04B2/005 , C04B14/28 , C04B18/12 , Y02C10/04 , Y02P20/152 , Y02W30/93 , C04B20/02
摘要： An energy efficient method and system for producing micron-sized particles and transforming and sequestering carbon dioxide into mineral carbonates is described, along with uses for the mineral carbonates produced in the process.
摘要翻译： 描述了用于生产微米级颗粒并将二氧化碳转化和螯合成矿物碳酸盐的能量效率方法和系统，以及在该方法中生产的碳酸钙矿物的用途。
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公开(公告)号：US20080032575A1
公开(公告)日：2008-02-07
申请号：US11462753
申请日：2006-08-07
IPC分类号： A63C5/03
CPC分类号： B63B35/7909
摘要： Waterboards such as surfboards are described that are formed of a combination of a resilient foam core with an outer shell of polycarbonate or polyurethane. Such waterboards may further include fibrous material bonded to or embedded in the outer shell for additional strength.
摘要翻译： 描述了诸如冲浪板的水板，其由弹性泡沫芯与聚碳酸酯或聚氨酯的外壳的组合形成。 这种水板还可以包括结合到外壳或嵌入外壳中的纤维材料，以增加强度。
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