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公开(公告)号:US06548447B1
公开(公告)日:2003-04-15
申请号:US09253265
申请日:1999-02-19
IPC分类号: B01J2362
CPC分类号: B01J23/8926 , B01J23/626 , B01J35/04 , C07C5/48 , C07C2521/04 , C07C2521/06 , C07C2523/14 , C07C2523/42 , C07C2523/62 , C07C2523/72 , C07C2523/89 , C07C11/02
摘要: A process for the production of a mono-olefin from a gaseous paraffinic hydrocarbon having at least two carbon atoms or mixtures thereof comprising reacting the hydrocarbons and molecular oxygen in the presence of a platinum catalyst. The catalyst consists essentially of platinum modified with Sn or Cu and supported on a ceramic monolith.
摘要翻译: 一种从具有至少两个碳原子的气态链烷烃或其混合物生产单烯烃的方法,包括在铂催化剂存在下使烃和分子氧反应。 催化剂基本上由用Sn或Cu改性并负载在陶瓷整料上的铂组成。
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公开(公告)号:US5905180A
公开(公告)日:1999-05-18
申请号:US720562
申请日:1996-09-30
IPC分类号: B01J23/62 , B01J23/89 , B01J35/04 , C07B61/00 , C07C5/327 , C07C5/48 , C07C11/02 , C07C5/333
CPC分类号: B01J23/8926 , B01J23/626 , C07C5/48 , B01J35/04 , C07C2521/04 , C07C2521/06 , C07C2523/14 , C07C2523/42 , C07C2523/62 , C07C2523/72 , C07C2523/89
摘要: A process for the production of a mono-olefin from a gaseous paraffinic hydrocarbon having at least two carbon atoms or mixtures thereof comprising reacting said hydrocarbons and molecular oxygen in the presence of a platinum catalyst. The catalyst consists essentially of platinum modified with Sn or Cu and supported on a ceramic monolith.
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公开(公告)号:US5639929A
公开(公告)日:1997-06-17
申请号:US422787
申请日:1995-04-17
CPC分类号: C07C5/48 , C07C2521/04 , C07C2521/06 , C07C2523/42 , C07C2523/46 , C07C2523/52 , C07C2523/755
摘要: A process for the oxidative dehydrogenation of hydrocarbons is disclosed in which C.sub.2 -C.sub.6 alkanes are contacted with an oxygen containing gas in a fluidized catalyst bed of platinum, rhodium, nickel or platinum-gold supported on .alpha.-alumina or zirconia. Ethane is dehydrogenated to ethylene and higher alkanes are dehydrogenated to ethylene, propylene and iso-butylene.
摘要翻译: 公开了一种烃的氧化脱氢方法,其中在负载在α-氧化铝或氧化锆上的铂,铑,镍或铂金的流化催化剂床中,C2-C6烷烃与含氧气体接触。 乙烷脱氢为乙烯,高级烷烃脱氢为乙烯,丙烯和异丁烯。
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公开(公告)号:US06846773B1
公开(公告)日:2005-01-25
申请号:US08821384
申请日:1997-03-20
IPC分类号: B01J23/62 , B01J23/89 , B01J35/04 , C07B61/00 , C07C5/327 , C07C5/48 , C07C11/02 , B01J23/42
CPC分类号: B01J23/8926 , B01J23/626 , B01J35/04 , C07C5/48 , C07C2521/04 , C07C2521/06 , C07C2523/14 , C07C2523/42 , C07C2523/62 , C07C2523/72 , C07C2523/89 , C07C11/02
摘要: A process for the production of a mono-olefin from a gaseous paraffinic hydrocarbon having at least two carbon atoms or mixtures thereof comprising reacting said hydrocarbons and molecular oxygen in the presence of a platinum catalyst. The catalyst consists essentially of platinum modified with Sn or Cu and supported on a ceramic monolith.
摘要翻译: 一种由具有至少两个碳原子的气态链烷烃或其混合物生产单烯烃的方法,包括在铂催化剂存在下使所述烃和分子氧反应。 催化剂基本上由用Sn或Cu改性并负载在陶瓷整料上的铂组成。
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公开(公告)号:US6072097A
公开(公告)日:2000-06-06
申请号:US146409
申请日:1998-09-03
CPC分类号: B01J23/8926 , B01J23/626 , C07C5/48 , B01J35/04 , C07C2521/04 , C07C2521/06 , C07C2523/14 , C07C2523/42 , C07C2523/62 , C07C2523/72 , C07C2523/89
摘要: A process for the production of a mono-olefin from a gaseous paraffinic hydrocarbon having at least two carbon atoms or mixtures thereof comprising reacting said hydrocarbons and molecular oxygen in the presence of a platinum catalyst. The catalyst consists essentially of platinum modified with Sn or Cu and supported on a ceramic monolith.
摘要翻译: 一种由具有至少两个碳原子的气态链烷烃或其混合物生产单烯烃的方法,包括在铂催化剂存在下使所述烃和分子氧反应。 催化剂基本上由用Sn或Cu改性并负载在陶瓷整料上的铂组成。
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公开(公告)号:US08790546B2
公开(公告)日:2014-07-29
申请号:US12528416
申请日:2008-03-05
申请人: Lanny D. Schmidt , Paul J. Dauenhauer , Nick J. Degenstein , Bradon J. Dreyer , Joshua L. Colby
发明人: Lanny D. Schmidt , Paul J. Dauenhauer , Nick J. Degenstein , Bradon J. Dreyer , Joshua L. Colby
CPC分类号: C10L5/44 , B01J23/63 , B01J35/04 , B01J37/0201 , C01B3/12 , C10J3/26 , C10J2200/158 , C10J2300/0916 , C10J2300/0946 , C10J2300/0959 , C10J2300/0986 , C10J2300/1846 , C10L5/363 , Y02E50/10 , Y02E50/30 , Y02P20/145 , Y02P20/52
摘要: A method comprising contacting a carbon and hydrogen-containing solid fuel and a metal-based catalyst in the presence of oxygen to produce hydrogen gas and carbon monoxide gas, wherein the contacting occurs at a temperature sufficiently high to prevent char formation in an amount capable of stopping production of the hydrogen gas and the carbon monoxide gas is provided. In one embodiment, the metal-based catalyst comprises a rhodium-cerium catalyst. Embodiments further include a system for producing syngas. The systems and methods described herein provide shorter residence time and high selectivity for hydrogen and carbon monoxide.
摘要翻译: 一种方法,包括在氧存在下使碳和氢的固体燃料和金属基催化剂接触以产生氢气和一氧化碳气体,其中所述接触在足够高的温度下发生,以防止能够形成 提供氢气和一氧化碳气体的停止生产。 在一个实施方案中,金属基催化剂包含铑 - 铈催化剂。 实施例还包括用于生产合成气的系统。 本文所述的系统和方法提供较短的停留时间和对氢气和一氧化碳的高选择性。
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公开(公告)号:US20080237542A1
公开(公告)日:2008-10-02
申请号:US12043030
申请日:2008-03-05
IPC分类号: C01B3/40
CPC分类号: C01B3/342 , B01J23/42 , B01J23/63 , B01J35/04 , B01J37/0201 , B01J37/0242 , C01B3/26 , C01B3/326 , C01B3/382 , C01B3/386 , C01B3/40 , C01B2203/0244 , C01B2203/0261 , C01B2203/0277 , C01B2203/06 , C01B2203/061 , C01B2203/062 , C01B2203/0861 , C01B2203/1005 , C01B2203/1023 , C01B2203/1029 , C01B2203/1041 , C01B2203/1047 , C01B2203/1058 , C01B2203/1064 , C01B2203/107 , C01B2203/1076 , C01B2203/1082 , C01B2203/1217 , C01B2203/1235 , C01B2203/1288 , C01B2203/1619 , Y02P20/52
摘要: The invention provides methods for the production of synthesis gas. More particularly, various embodiments of the invention relate to systems and methods for volatilizing fluid fuel to produce synthesis gas by using a metal catalyst on a solid support matrix.
摘要翻译: 本发明提供了生产合成气的方法。 更具体地,本发明的各种实施方案涉及通过在固体载体基质上使用金属催化剂来挥发流体燃料以产生合成气的系统和方法。
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公开(公告)号:US08349289B2
公开(公告)日:2013-01-08
申请号:US12043030
申请日:2008-03-05
IPC分类号: C01B3/24
CPC分类号: C01B3/342 , B01J23/42 , B01J23/63 , B01J35/04 , B01J37/0201 , B01J37/0242 , C01B3/26 , C01B3/326 , C01B3/382 , C01B3/386 , C01B3/40 , C01B2203/0244 , C01B2203/0261 , C01B2203/0277 , C01B2203/06 , C01B2203/061 , C01B2203/062 , C01B2203/0861 , C01B2203/1005 , C01B2203/1023 , C01B2203/1029 , C01B2203/1041 , C01B2203/1047 , C01B2203/1058 , C01B2203/1064 , C01B2203/107 , C01B2203/1076 , C01B2203/1082 , C01B2203/1217 , C01B2203/1235 , C01B2203/1288 , C01B2203/1619 , Y02P20/52
摘要: The invention provides methods for the production of synthesis gas. More particularly, various embodiments of the invention relate to systems and methods for volatilizing fluid fuel to produce synthesis gas by using a metal catalyst on a solid support matrix.
摘要翻译: 本发明提供了生产合成气的方法。 更具体地,本发明的各种实施方案涉及通过在固体载体基质上使用金属催化剂来挥发流体燃料以产生合成气的系统和方法。
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9.
公开(公告)号:US20110047864A1
公开(公告)日:2011-03-03
申请号:US12871187
申请日:2010-08-30
CPC分类号: C10L1/04 , C10G1/00 , C10G3/47 , C10G3/49 , C10G27/04 , C10G2300/1014 , C10G2300/1018 , C10G2300/1037 , Y02P30/20
摘要: Methods and reactors for producing a fuel are disclosed herein. In some embodiments, the method uses a biomass feedstock and alkane and/or alcohol feedstock, which can be contacted with a metal-containing catalyst to form products including a bio-oil. In some embodiments, oxygen-containing functional groups can be removed from a bio-oil using one or more zeolite thin films.
摘要翻译: 本文公开了用于生产燃料的方法和反应器。 在一些实施方案中,该方法使用生物质原料和烷烃和/或醇原料,其可与含金属的催化剂接触以形成包括生物油的产物。 在一些实施方案中,可以使用一种或多种沸石薄膜从生物油中除去含氧官能团。
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公开(公告)号:US06365543B1
公开(公告)日:2002-04-02
申请号:US09388218
申请日:1999-09-01
申请人: Lanny D. Schmidt , Ashish Bodke
发明人: Lanny D. Schmidt , Ashish Bodke
IPC分类号: B01J2300
CPC分类号: C10G11/02 , B01J23/40 , B01J23/42 , B01J35/06 , B01J37/0201 , B01J37/0232 , C07C5/48 , C07C2521/02 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2521/12 , C07C2523/04 , C07C2523/06 , C07C2523/08 , C07C2523/14 , C07C2523/42 , C07C2523/48 , C07C2527/224 , C10G2400/20 , Y02P20/52 , C07C11/02
摘要: A process and catalyst for the partial oxidation of paraffinic hydrocarbons, such as ethane, propane, naphtha, and natural gas condensates, to olefins, such as ethylene and propylene. The process involves contacting a paraffinic hydrocarbon with oxygen in the presence of a catalyst under autothermal process conditions. The catalyst comprises a Group 8B metal and, optionally, a promoter metal, such as tin or copper, supported on a fiber monolith support, preferably a ceramic fiber mat monolith. In another aspect, the invention is a process of oxidizing a paraffinic hydrocarbon to an olefin under autothermal conditions in the presence of a catalyst comprising a Group 8B metal and, optionally, a promoter metal, the metals being loaded onto the front face of a monolith support. An on-line method of synthesizing and regenerating catalysts for autothermal oxidation processes is also disclosed.
摘要翻译: 用于将链烷烃(例如乙烷,丙烷,石脑油和天然气)部分氧化的方法和催化剂冷凝成烯烃,例如乙烯和丙烯。 该方法包括在自热过程条件下在催化剂存在下使链烷烃与氧接触。 该催化剂包含8B族金属和任选的负载在纤维整料载体上,优选陶瓷纤维垫料整料的助催化剂金属,例如锡或铜。 在另一方面,本发明是在含有第8B族金属和任选的助催化剂金属的催化剂存在下,在自热条件下将链烷烃烃氧化成烯烃的方法,将金属加载到整料的正面上 支持。 还公开了用于自热氧化方法的催化剂的合成和再生的在线方法。
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