摘要:
The present invention relates to a catalyst composition for the synthesis of thin multi-walled carbon nanotube (MWCNT) and a method for manufacturing a catalyst composition. More particularly, this invention relates to a multi-component metal catalyst composition comprising i) main catalyst of Fe and Al, ii) inactive support of Mg and iii) optional co-catalyst at least one selected from Co, Ni, Cr, Mn, Mo, W, V, Sn, or Cu. Further, the present invention affords thin multi-walled carbon nanotube having 5˜20 nm of diameter and 100˜10,000 of aspect ratio in a high yield.
摘要:
The present invention relates to a catalyst for preparing a carbon nanotube having desired apparent density by controlling the adding amount of co-precipitating agent in the process of preparing a catalyst in order to obtain a catalyst having a minimized particle size. More specifically, this invention relates to a catalyst for preparing carbon nanotube having desired apparent density based upon the reverse-correlation between the amount of co-precipitating agent added in the process of preparing catalyst and the apparent density of catalyst. The carbon nanotube prepared by the catalyst having low apparent density shows excellent electrical conductivity and highly uniformed dispersion in the polymer/carbon nanotube composite.
摘要:
The present invention relates to a catalyst composition for preparing carbon nanotube containing multi-component support materials of amorphous Si, Mg and Al as well as a bulk scale preparation process for preparing carbon nanotube using said catalyst composition. More specifically, this invention relates to a process for preparing carbon nanotube using the catalyst composition comprising a transition metal catalyst and support materials of amorphous Si, Mg and Al.
摘要:
The present invention relates to a process for preparing catalyst composition for the synthesis of carbon nanotube with high yields using the spray pyrolysis method. More particularly, this invention relates to a process for preparing catalyst composition for the synthesis of carbon nanotube comprising the steps of i) dissolving multi-component metal precursors of catalyst composition in de-ionized water; ii) spraying obtained catalytic metal precursor solution into the high temperature reactor by gas atomization method; iii) forming the catalyst composition powder by pyrolysis of gas atomized material; and iv) obtaining the catalyst composition powder, wherein said catalyst composition comprises i) main catalyst selected from Fe or Co, ii) Al, iii) optional co-catalyst at least one selected from Ni, Cu, Sn, Mo, Cr, Mn, V, W, Ti, Si, Zr or Y, iv) inactive support of Mg. Further, the catalyst composition prepared by this invention has a very low apparent density of 0.01˜0.50 g/ml as well as the catalyst composition affords high production yield (1,000˜1,800%) of carbon nanotube.
摘要:
The present invention relates to a process for preparing catalyst composition for the synthesis of carbon nanotube with high yields using the spray pyrolysis method. More particularly, this invention relates to a process for preparing catalyst composition for the synthesis of carbon nanotube comprising the steps of i) dissolving multi-component metal precursors of catalyst composition in de-ionized water; ii) spraying obtained catalytic metal precursor solution into the high temperature reactor by gas atomization method; iii) forming the catalyst composition powder by pyrolysis of gas atomized material; and iv) obtaining the catalyst composition powder, wherein said catalyst composition comprises i) main catalyst selected from Fe or Co, ii) Al, iii) optional co-catalyst at least one selected from Ni, Cu, Sn, Mo, Cr, Mn, V, W, Ti, Si, Zr or Y, iv) inactive support of Mg. Further, the catalyst composition prepared by this invention has a very low apparent density of 0.01˜0.50 g/ml as well as the catalyst composition affords high production yield (1,000˜1,800%) of carbon nanotube.
摘要:
The present invention relates to a catalyst composition for the synthesis of thin multi-walled carbon nanotube (MWCNT) and a method for manufacturing a catalyst composition. More particularly, this invention relates to a multi-component metal catalyst composition comprising i) main catalyst of Fe and Al, ii) inactive support of Mg and iii) optional co-catalyst at least one selected from Co, Ni, Cr, Mn, Mo, W, V, Sn, or Cu. Further, the present invention affords thin multi-walled carbon nanotube having 5˜20 nm of diameter and 100˜10,000 of aspect ratio in a high yield.
摘要:
The present invention is to provide anode active material hybridized with carbon nano fibers for lithium secondary battery prepared by following steps comprising, i) dispersing the nano size metal catalyst to the surface of anode material selected from graphite, amorphous silicon or the complex of graphite and amorphous silicon; and ii) growing the carbon nano fiber by chemical vapor deposition method, wherein carbon nano fibers are grown in a vine form and surround the surface of anode active material.
摘要:
The present invention relates to a catalyst composition for preparing carbon nanotube and a process for preparing carbon nanotube using the same. More particularly, this invention relates to a process for preparing carbon nanotube by the chemical vapor deposition method through the decomposition of lower saturated or unsaturated hydrocarbons using a multi-component metal catalyst composition containing active metal catalyst from Co, V, Al and inactive porous support. Further, the present invention affords the carbon nanotube having 5˜30 nm of diameter and 100˜10,000 of aspect ratio in a high catalytic yield.
摘要:
The present invention relates to a catalyst composition for preparing carbon nanotube and a process for preparing carbon nanotube using the same. More particularly, this invention relates to a process for preparing carbon nanotube by the chemical vapor deposition method through the decomposition of lower saturated or unsaturated hydrocarbons using a multi-component metal catalyst composition containing active metal catalyst from Co, V, Al and inactive porous support. Further, the present invention affords the carbon nanotube having 5˜30 nm of diameter and 100˜10,000 of aspect ratio in a high catalytic yield.
摘要:
The present invention provides a composite silicon anode material hybridizing carbon nanofiber for lithium secondary battery prepared by the steps comprising: i) preparing a support made by amorphous silicon alloy after processing amorphous silicon and metal; ii) dispersing the catalyst selected from Fe, Co, Ni, Cu, Mg, Mn, Ti, Sn, Si, Zr, Zn, Ge, Pb or In on the surface of said support made by amorphous silicon alloy; and iii) growing the carbon nanofiber using a carbon source selected from carbon monoxide, methane, acetylene or ethylene on said support by a chemical vapor deposition method, wherein the amount of grown carbon nanofiber is 1˜110 wt % of the amount of said support.