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公开(公告)号：US10759881B2
公开(公告)日：2020-09-01
申请号：US16153122
申请日：2018-10-05
发明人： Yu Han , Qiwei Tian , Xinglong Dong , Zhaohui Liu , Jean-Marie Basset , Youssef Saih , Miao Sun , Sohel Shaikh , Wei Xu
IPC分类号： C08F8/30 , C01B39/04 , B01J29/40 , B01J29/89 , B01J29/08 , B01J29/70 , B01J29/80 , B01J37/00 , B01J37/02 , C08F226/04 , C08F230/02 , B01J29/44 , B01J29/03 , B01J35/00 , B01J35/10 , C08F8/44 , C10G3/00 , B01J35/08 , B01J29/00 , C08F8/32 , C08F8/40 , B01J29/06
摘要： According to one or more embodiments, a mesoporous zeolite may included a microporous framework that includes a plurality of micropores having diameters of less than or equal to 2 nm, and a plurality of mesopores having diameters of greater than 2 nm and less than or equal to 50 nm. The mesoporous zeolite may included an aluminosilicate material, a titanosilicate material, or a pure silicate material. The mesoporous zeolite may included a surface area of greater than 350 m2/g and a pore volume of greater than 0.3 cm3/g.
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2.发明授权Tethered transition metals promoted photocatalytic system for efficient hydrogen evolutions 有权连接的过渡金属促进了光催化体系的高效氢化演化公开(公告)号：US09579639B2
公开(公告)日：2017-02-28
申请号：US14477414
申请日：2014-09-04
发明人： Kazuhiro Takanabe , Tayirjan Isimjan , Weili Yu , Silvano Del Gobbo , Wei Xu
IPC分类号： B01J31/22 , C01B3/06 , B01J37/03 , B01J37/04 , B01J23/06 , B01J23/755 , B01J27/043 , B01J35/00
CPC分类号： B01J31/226 , B01J23/06 , B01J23/755 , B01J27/043 , B01J31/2273 , B01J31/2278 , B01J35/004 , B01J37/038 , B01J37/04 , B01J2531/847 , C01B3/065 , Y02E60/36 , Y02E60/364
摘要： The present invention is directed, at least in part, to a process for improving the efficiency of a photocatalyst (a semiconductor photocatalyst) by tethering (depositing) a metal (e.g., metal ions of a late transition metal, such as nickel) to the semiconductor (photocatalyst) surface through the use of an organic ligand. More specifically, 1,2-ethanedithiol (EDT) functions as an excellent molecular linker (organic ligand) to attach a transition metal complex (e.g., nickel (Ni2+ ions)) to the semiconductor surface, which can be in the form of a cadmium sulfide surface. The photocatalyst has particular utility in generating hydrogen from H2S.
摘要翻译： 本发明至少部分地涉及通过将金属（例如后过渡金属如镍的金属离子）束缚（沉积）（例如镍）来提高光催化剂（半导体光催化剂）的效率的方法， 半导体（光催化剂）表面通过使用有机配体。 更具体地，1,2-乙二硫醇（EDT）作为将过渡金属络合物（例如镍（Ni 2+离子））附着到半导体表面上的优异的分子接头（有机配体）起作用，其可以是镉的形式 硫化物表面。 该光催化剂特别适用于从H2S产生氢气。
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公开(公告)号：US11965133B2
公开(公告)日：2024-04-23
申请号：US18059761
申请日：2022-11-29
发明人： Khalid Ali Almajnouni , Shatha Ali Alabbad , Abdulelah Alghadeer , Ola Ali , Isidoro Morales Osorio , Abdennour Bourane , Wei Xu , Jorge Gascon Sabate , Jullian Vittenet , Mohammed Alabdullah , Alberto Rodriguez-Gomez , Marcus John Killingworth
CPC分类号： C10G11/187 , C10G69/06 , C10G2300/1033 , C10G2300/807
摘要： A hydrocarbon feed stream may be processed by a method that may include catalytically cracking a hydrocarbon feed stream in a counter-current reactor to produce a first effluent stream, and processing a portion or all of the first effluent stream by at least one or more separations. The at least one or more separations may form at least a second effluent stream including at least 95 wt. % C4-C6 hydrocarbons, and a third effluent stream including at least 95 wt. % of ethane, propane, or a combination thereof. In some embodiments, the method may further include catalytically cracking a portion or all of the second effluent stream in a second reactor to form a second reactor effluent stream, combining a portion of all of the second reactor effluent stream with the first effluent stream, steam cracking a portion or all of the third effluent stream to form a steam cracked effluent stream, and combining a portion or all of the steam cracked effluent stream with the first effluent. In other embodiments, the method may further include passing a portion or all of the second effluent stream to the counter-current reactor, steam cracking a portion or all of the third effluent stream to form a steam cracked effluent stream, and combining a portion or all of the steam cracked effluent stream with the first effluent stream.
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公开(公告)号：US20230167370A1
公开(公告)日：2023-06-01
申请号：US18059761
申请日：2022-11-29
发明人： Khalid Ali Almajnouni , Shatha Ali Alabbad , Abdulelah Alghadeer , Ola Ali , Isidoro Morales Osorio , Abdennour Bourane , Wei Xu , Jorge Gascon Sabate , Jullian Vittenet , Mohammed Alabdullah , Alberto Rodriguez-Gomez , Marcus John Killingworth
CPC分类号： C10G11/187 , C10G69/06 , C10G2300/1033 , C10G2300/807
摘要： A hydrocarbon feed stream may be processed by a method that may include catalytically cracking a hydrocarbon feed stream in a counter-current reactor to produce a first effluent stream, and processing a portion or all of the first effluent stream by at least one or more separations. The at least one or more separations may form at least a second effluent stream including at least 95 wt. % C4-C6 hydrocarbons, and a third effluent stream including at least 95 wt. % of ethane, propane, or a combination thereof. In some embodiments, the method may further include catalytically cracking a portion or all of the second effluent stream in a second reactor to form a second reactor effluent stream, combining a portion of all of the second reactor effluent stream with the first effluent stream, steam cracking a portion or all of the third effluent stream to form a steam cracked effluent stream, and combining a portion or all of the steam cracked effluent stream with the first effluent. In other embodiments, the method may further include passing a portion or all of the second effluent stream to the counter-current reactor, steam cracking a portion or all of the third effluent stream to form a steam cracked effluent stream, and combining a portion or all of the steam cracked effluent stream with the first effluent stream.
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公开(公告)号：US20220355277A1
公开(公告)日：2022-11-10
申请号：US17315841
申请日：2021-05-10
IPC分类号： B01J29/40 , B01J21/08 , B01J23/75 , B01J35/00 , B01J35/10 , B01J37/04 , B01J37/06 , B01J37/10 , B01J37/08 , B01J37/18 , B01J35/02 , C10G11/05
摘要： Embodiments of catalyst systems and methods of synthesizing catalyst systems are provided. The catalyst system may include a core comprising a zeolite; and a shell comprising a microporous fibrous silica. The shell may be in direct contact with at least a majority of an outer surface of the core. The catalyst system may have a Si/Al molar ratio greater than 5. At least a portion of the shell may have a thickness of from 50 nanometers (nm) to 600 nm.
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公开(公告)号：US11319490B2
公开(公告)日：2022-05-03
申请号：US17141963
申请日：2021-01-05
发明人： Remi Mahfouz , Ola Ali , Isidoro Morales Osorio , Wei Xu , Xinglong Dong , Yu Han
摘要： An integrated method for mesophase pitch and petrochemicals production. The method including supplying crude oil to a reactor vessel; heating the crude oil in the reactor vessel to a predetermined temperature for a predetermined amount of time; reducing asphaltene content in the crude oil by allowing polymerization reactions to occur in the reactor vessel at an elevated pressure in the absence of oxygen; producing a three-phase upgraded hydrocarbon product comprising gas, liquid, and solid hydrocarbon components, where the liquid hydrocarbon component comprises deasphalted oil and the solid hydrocarbon component comprises mesophase pitch; separating the gas, liquid, and solid hydrocarbon components; directly utilizing the liquid hydrocarbon component for petrochemicals production; and directly utilizing the solid hydrocarbon component for carbon artifact production.
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公开(公告)号：US20200347157A1
公开(公告)日：2020-11-05
申请号：US16934399
申请日：2020-07-21
发明人： Yu Han , Qiwei Tian , Xinglong Dong , Zhaohui Liu , Jean-Marie Basset , Youssef Saih , Miao Sun , Sohel Shaikh , Wei Xu
IPC分类号： C08F8/30 , C01B39/04 , B01J29/40 , B01J29/89 , B01J29/08 , B01J29/70 , B01J29/80 , B01J37/00 , B01J37/02 , C08F226/04 , C08F230/02 , B01J29/44 , B01J29/03 , B01J35/00 , B01J35/10 , C08F8/44 , C10G3/00 , B01J35/08 , B01J29/00 , C08F8/32 , C08F8/40
摘要： According to one or more embodiments, cationic polymers may be produced which include one or more monomers containing cations. Such cationic polymers may be utilized as structure directing agents to for mesoporous zeolites. The mesoporous zeolites may include micropores as well as mesopores, and may have a surface area of greater than 350 m2/g and a pore volume of greater than 0.3 cm3/g. Also described are core/shell zeolites, where at least the shell portion includes a mesoporous zeolite material.
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公开(公告)号：US20190040159A1
公开(公告)日：2019-02-07
申请号：US16153122
申请日：2018-10-05
发明人： Yu Han , Qiwei Tian , Xinglong Dong , Zhaohui Liu , Jean-Marie Basset , Youssef Saih , Miao Sun , Sohel Shaikh , Wei Xu
IPC分类号： C08F8/30 , C08F230/02 , B01J29/00 , C08F8/40 , C08F8/32 , C01B39/04 , C08F226/04 , B01J37/10 , B01J37/06 , B01J37/04 , B01J37/02 , B01J37/00 , B01J35/02 , B01J29/89 , B01J29/80 , B01J29/70 , B01J29/40 , B01J29/08 , B01J29/06
摘要： According to one or more embodiments, a mesoporous zeolite may included a microporous framework that includes a plurality of micropores having diameters of less than or equal to 2 nm, and a plurality of mesopores having diameters of greater than 2 nm and less than or equal to 50 nm. The mesoporous zeolite may included an aluminosilicate material, a titanosilicate material, or a pure silicate material. The mesoporous zeolite may included a surface area of greater than 350 m2/g and a pore volume of greater than 0.3 cm3/g.
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公开(公告)号：US11707720B2
公开(公告)日：2023-07-25
申请号：US17164137
申请日：2021-02-01
发明人： Motaz Khawaji , Ola Ali , Khalid Al-Majnouni , Wei Xu , Jorge Gascon Sabate
CPC分类号： B01J8/26 , B01J8/1872 , C10G11/182
摘要： A multi-zoned fluidized bed reactor system may include a multi-zoned fluidized bed reactor and at least one catalyst regeneration loop. The multi-zoned fluidized bed reactor comprising a housing, a fluid bed distributor plate positioned at the bottom of the housing, a fluidized catalyst bed disposed vertically above the fluid bed distributor plate and a condensation zone disposed vertically above the fluidized catalyst bed. The at least one catalyst regeneration loop may be fluidly coupled to the stripping zone and a reaction zone. The at least one catalyst regeneration loop may be operable to withdraw a portion of spent catalyst from the stripping zone, regenerate the portion of spent catalyst to produce regenerated catalyst, and return the regenerated catalyst to the reaction zone. A method of regenerating catalyst in a multi-zoned fluidized bed reactor may include passing a portion of spent catalyst from a stripping zone to a catalyst regeneration loop.
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公开(公告)号：US10196465B2
公开(公告)日：2019-02-05
申请号：US16043791
申请日：2018-07-24
发明人： Yu Han , Qiwei Tian , Xinglong Dong , Zhaohui Liu , Jean-Marie Basset , Youssef Saih , Miao Sun , Wei Xu , Sohel Shaikh
IPC分类号： C08F8/30 , C08F8/32 , C08F8/40 , B01J29/00 , B01J29/06 , B01J29/08 , B01J29/40 , B01J29/70 , B01J29/80 , B01J29/89 , B01J35/02 , B01J37/00 , B01J37/02 , B01J37/04 , B01J37/06 , B01J37/10 , C01B39/04 , C08F226/04 , C08F230/02 , C08G73/06
摘要： According to one or more embodiments, cationic polymers may be produced which include one or more monomers containing cations. Such cationic polymers may be utilized as structure directing agents to form mesoporous zeolites. The mesoporous zeolites may include micropores as well as mesopores, and may have a surface area of greater than 350 m2/g and a pore volume of greater than 0.3 cm3/g. Also described are core/shell zeolites, where at least the shell portion includes a mesoporous zeolite material.
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