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    Heat-developable light-sensitive material comprising a sensitizing dye
    1.
    发明授权
    Heat-developable light-sensitive material comprising a sensitizing dye 失效
    包含感光染料的可热显影的感光材料

    公开(公告)号：US4965181A

    公开(公告)日：1990-10-23

    申请号：US492266

    申请日：1990-02-28

    申请人： Seiiti Kubodera ,  Akihiko Ikegawa ,  Masaki Okazaki

    发明人： Seiiti Kubodera ,  Akihiko Ikegawa ,  Masaki Okazaki

    IPC分类号： G03C1/18 ,  G03C1/498 ,  G03C8/40

    CPC分类号： G03C1/18 ,  G03C1/49854

    摘要： A heat-developable light-sensitive material comprising a support having provided thereon a light-sensitive layer comprising a silver halide which is spectrally sensitized with at least one dye represented by formula (I): ##STR1## wherein R.sub.0 and R.sub.1, which may be the same or different, each represents a hydrogen atom, an alkyl group, an aryl group, an alkoxy group, an aryloxy group, a halogen atom, an alkoxycarbonyl group, an acylamino group, an acyl group, a cyano group, a carbamoyl group, a sulfamoyl group, a carboxyl group, or an acyloxy group; provided that at least one of R.sub.0 and R.sub.1 represents a group other than a hydrogen atom; R.sub.2 represents a hydrogen atom, an alkyl group, or an aryl group; R.sub.3 represents an alkyl group, an aryl group, an alkoxy group, an aryloxy group, an acyl group, an acyloxy group, an alkoxycarbonyl group, or an acylamino group; provided that when R.sub.3 represents an aryl group, R.sub.0 and R.sub.1 each represents a group other than an aryl group; the group represented by R.sub.3 has a value of S of 544 or less wherein S is represented by formula (Z):S=3.536L-2.661B+535.4 (Z)wherein L represents the length of the group R.sub.3 along the axis of the bond between the group R.sub.3 and the center of the benzene nucleus to which the group R.sub.3 is connected, and B represents the smaller value of B.sub.1 +B.sub.4 and B.sub.2 +B.sub.3 wherein B.sub.1, B.sub.2, B.sub.3, and B.sub.4 each represents the width of the group R.sub.3 which are measured at their maximum points and perpendicular to said axis and each other, provided that B.sub.1 is the smallest value and B.sub.2, B.sub.3, and B.sub.4 are successively larger; R.sub.4 and R.sub.5, which may be the same or different, each represents an alkyl group; X represents an anion; and n is 0 or 1, as required to satisfy charge balance.

    摘要翻译： 一种可热显影的感光材料，其包括在其上设置有感光层的支撑体，所述感光层包含用至少一种由式（I）表示的染料进行光谱增感的卤化银：其中R 0和R 1， 可以相同或不同，分别表示氢原子，烷基，芳基，烷氧基，芳氧基，卤素原子，烷氧基羰基，酰基氨基，酰基，氰基， 氨基甲酰基，氨磺酰基，羧基或酰氧基; 条件是R 0和R 1中的至少一个表示除氢原子以外的基团; R2表示氢原子，烷基或芳基; R3表示烷基，芳基，烷氧基，芳氧基，酰基，酰氧基，烷氧基羰基或酰氨基; 条件是当R 3表示芳基时，R 0和R 1各自表示除芳基以外的基团; 由R3表示的基团的S值为544以下，其中S由式（Z）表示：S = 3.536L-2.661B + 535.4（Z）其中L表示基团R3沿着 组R3与基团R3所连接的苯环的中心之间的键，B表示B1 + B4和B2 + B3的较小值，其中B1，B2，B3和B4各自表示基团的宽度 R3，其最大点和垂直于所述轴线彼此测量，条件是B1是最小值，B2，B3和B4相继较大; R 4和R 5可以相同或不同，各自表示烷基; X表示阴离子; n为0或1，满足电荷平衡的要求。

    Optical wavelength conversion device
    2.
    发明授权
    Optical wavelength conversion device 失效
    光波长转换装置

    公开(公告)号：US4830447A

    公开(公告)日：1989-05-16

    申请号：US154709

    申请日：1988-02-11

    申请人： Kozi Kamiyama ,  Yoji Okazaki ,  Masaki Okazaki ,  Seiiti Kubodera ,  Syozo Takeuchi

    发明人： Kozi Kamiyama ,  Yoji Okazaki ,  Masaki Okazaki ,  Seiiti Kubodera ,  Syozo Takeuchi

    IPC分类号： G02F1/377 ,  G02F1/383

    CPC分类号： G02F1/377 ,  G02F1/383

    摘要： An optical wavelength conversion device is composed of an organic nonlinear optical material, and a cladding layer having a refractive index lower than the refractive index of the organic nonlinear optical material and covering the organic nonlinear optical material, thereby to convert a fundamental wave entering the optical wavelength conversion device to a second harmonic, and to radiate the second harmonic. At least one of device edge faces including edge faces of the organic nonlinear optical material is provided with a shielding layer for shielding the device edge face from ambient atmosphere, thereby to prevent the organic nonlinear optical material from sublimation and deterioration.

    摘要翻译： 光波长转换装置由有机非线性光学材料和折射率低于有机非线性光学材料的折射率并覆盖有机非线性光学材料的包覆层组成，从而转换进入光学的基波 波长转换装置到二次谐波，并且辐射二次谐波。 包括有机非线性光学材料的边缘面的器件边缘面中的至少一个设置有用于屏蔽器件边缘面与环境大气的屏蔽层，从而防止有机非线性光学材料升华和劣化。

    Heat developable light-sensitive material containing polymethine
    3.
    发明授权
    Heat developable light-sensitive material containing polymethine 失效
    含有多聚甲醛的热显影光敏材料

    公开(公告)号：US4740455A

    公开(公告)日：1988-04-26

    申请号：US893851

    申请日：1986-08-06

    申请人： Seiiti Kubodera ,  Masaki Okazaki

    发明人： Seiiti Kubodera ,  Masaki Okazaki

    IPC分类号： G03C1/12 ,  G03C1/498 ,  G03C7/00 ,  G03C8/40

    CPC分类号： G03C1/12 ,  G03C1/49854

    摘要： A novel heat developable light-sensitive material is provided comprising a silver halide spectrally sensitized by a polymethine containing at least one basic nucleus wherein the dye contains, as a group for substituting nitrogen atoms in said basic nucleus, at least one of the groups represented by general formulae (A) and (B): ##STR1##--(CH.sub.2 --.sub.2 NHSO.sub.2 Rwherein m represents an integer of 1 or 2; Y represents an atomic group necessary for the formation of a cyclic imide group; and R represents a C.sub.1-4 alkyl group.In a preferred embodiment, the atomic group represented by Y is selected from the group consisting of a succinic acid imido group, a phthalic acid imido group, an orthobenzosulfimido group, and a maleimido group. The atomic group may be optionally substituted by a halogen atom, a nitro group, a carboxyl group, an acylamino group such as an acetylamino group, or an alkoxycarbonyl amino group such as an ethoxycarbonyl group.

    摘要翻译： 提供了一种新型的可热显影的感光材料，其包括通过含有至少一个碱性核的聚甲基化物对其进行光谱增感的卤化银，其中染料含有作为用于取代所述碱性核中的氮原子的基团，至少一个由 （A）和（B）：其中m表示1或2的整数; Y表示形成环状酰亚胺基所需的原子团; R表示 在优选的实施方案中，由Y表示的原子团选自琥珀酸亚氨基，邻苯二甲酰亚氨基，邻苯甲酰亚氨基和马来酰亚胺基，原子团可以是 任选地被卤素原子，硝基，羧基，酰氨基如乙酰氨基或烷氧基羰基氨基如乙氧基羰基取代。

    Laser light source
    4.
    发明授权
    Laser light source 失效
    激光光源

    公开(公告)号：US4981613A

    公开(公告)日：1991-01-01

    申请号：US116923

    申请日：1987-11-04

    申请人： Masaki Okazaki ,  Seiiti Kubodera

    发明人： Masaki Okazaki ,  Seiiti Kubodera

    IPC分类号： G02F1/361

    CPC分类号： G02F1/3612

    摘要： A light source composed of a semiconductor laser and a nonlinear optical element which converts a laser beam emitted from the semiconductor laser to a laser beam having a shorter wavelength, disposed in the path of a laser beam produced by the laser, the nonlinear optical element containing a compound represented by formula (I): ##STR1## wherein Z.sup.1, Z.sup.2, X and n are as defined in the specification, of formula (II) ##STR2## wherein Z.sup.3 and Z.sup.4 are defined in the specification, or an acid adduct therefore. the nonlinear optical element exhibits high transmittances to blue light and generates a laser beam having a shorter wavelength than that of the laser applied.

    摘要翻译： 由半导体激光器和非线性光学元件组成的光源，其将从半导体激光器发射的激光束转换为具有较短波长的激光束，设置在由激光器产生的激光束的路径中，所述非线性光学元件包含 式（I）表示的化合物：其中Z 1，Z 2，X和n如说明书中定义的式（II）其中Z 3和Z 4在说明书中定义的式（I） ，或酸加合物。 非线性光学元件对蓝色光表现出高的透射率，并且产生具有比所施加激光的波长短的波长的激光束。

    Image forming process
    5.
    发明授权
    Image forming process 失效
    图像形成过程

    公开(公告)号：US4690883A

    公开(公告)日：1987-09-01

    申请号：US808719

    申请日：1985-12-13

    申请人： Seiiti Kubodera ,  Masaki Okazaki

    发明人： Seiiti Kubodera ,  Masaki Okazaki

    IPC分类号： G03C1/14 ,  G03C1/12 ,  G03C7/00 ,  G03C8/40 ,  G03C5/54 ,  G03C1/10 ,  G03C1/19

    CPC分类号： G03C1/12 ,  G03C8/404

    摘要： A process for forming an image is provided, comprising imagewise exposing a photosensitive material comprising on a support a photosensitive silver halide, a sensitizing dye having general formula (I) and/or (II), and a compound which forms or releases a mobile dye in proportion or counter-proportion to the reduction of the photosensitive silver halide into silver by heating, and transferring the resulting mobile dye to a dye-fixing element in the presence of a hydrophilic solvent,wherein formulas (I) and (II) are: ##STR1## wherein Z.sup.1 and Z.sup.2 represent a group of non-metallic atoms necessary to form a 5- or 6-membered heterocyclic ring; R.sup.1 and R.sup.2 represent a substituted or unsubstituted alkyl group; L.sup.1, L.sup.2, and L.sup.3 represent a substituted or unsubstituted methine group; p and q are equal to 0 or 1; m is equal to 0, 1, 2, or 3; X1.sup..crclbar. represents an anion; k is equal to 0 or 1, with the proviso that the number of organic acid groups contained in the molecule except X1.sup..crclbar. is up to 1, andZ.sup.3 has the same meaning as Z.sup.1 and Z.sup.2 ; R.sup.3 has the same meaning as R.sup.1 and R.sup.2 except an alkyl group having an acid group; L.sup.4 and L.sup.5 have the same meaning as L.sup.1, L.sup.2, and L.sup.3 ; Z.sup.4 represents a group of non-metallic atoms necessary to form a 5- or 6-membered heterocyclic ring; R.sup.4 represents a hydrogen atom, or a substituted or unsubstituted alkyl, aryl or heterocyclic group; r has the same meaning as p and q; and n has the same meaning as m.

    摘要翻译： 提供了一种用于形成图像的方法，包括将包含在支持体上的感光性卤化银感光材料，具有通式（I）和/或（II）的增感染料，以及形成或释放移动染料的化合物成像曝光 与通过加热将感光卤化银还原成银而成比例或成比例的，并且在亲水性溶剂的存在下将所得的可移动染料转移到染料固定元件上，其中式（I）和（II）是： （Ⅰ）其中Z1和Z2代表形成5-或6-元杂环所必需的一组非金属原子; R1和R2表示取代或未取代的烷基; L1，L2和L3代表取代或未取代的次甲基; p和q等于0或1; m等于0,1,2或3; X1（ - ）表示阴离子; k等于0或1，条件是除了X1（ - ）以外的分子中含有的有机酸基团数为1，Z3与Z1和Z2具有相同的含义。 R3具有与R1和R2相同的含义，除了具有酸基的烷基; L4和L5具有与L1，L2和L3相同的含义; Z4表示形成5-或6-元杂环所必需的一组非金属原子; R4表示氢原子或取代或未取代的烷基，芳基或杂环基; r与p和q具有相同的含义; n与m具有相同的含义。

    Heat-development color light-sensitive material
    6.
    发明授权
    Heat-development color light-sensitive material 失效
    热成型感光材料

    公开(公告)号：US4677051A

    公开(公告)日：1987-06-30

    申请号：US801727

    申请日：1985-11-26

    申请人： Seiiti Kubodera ,  Takanori Hioki ,  Masaki Okazaki

    发明人： Seiiti Kubodera ,  Takanori Hioki ,  Masaki Okazaki

    IPC分类号： G03C8/40 ,  C09B23/00 ,  G03C1/18 ,  G03C1/498 ,  G03C7/00 ,  G03C1/19 ,  G03C1/40

    CPC分类号： G03C1/49854

    摘要： A heat-developable color light-sensitive material is provided comprising on a support at least a light-sensitive silver halide emulsion, a binder, a compound capable of producing or releasing a mobile dye in direct or inverse proportion to the reaction of the light-sensitive silver halide being reduced into silver at elevated temperatures, and a dye having the general formula: ##STR1## wherein each of R.sup.1 and R.sup.2 is a substituted or unsubstituted alkyl or alkenyl group,R.sup.3 is a hydrogen atom, or substituted or unsubstituted alkyl, alkoxy, aryl or alkenyl group,each of X.sup.1, X.sup.2, X.sup.3, and X.sup.4 is a hydrogen atom, halogen atom, hydroxyl, carboxyl, or substituted or unsubstituted alkyl, alkoxy, alkoxycarbonyl, acyl, acyloxyl, aryl, amino, or acylamino group,X.sup.1 and X.sup.2, and X.sup.3 and X.sup.4 can be mutually combined to form a benzene ring,A.sup.- is an anion, andn is equal to 0 or 1.

    摘要翻译： 提供了一种可热显色的感光材料，其包括至少一种感光卤化银乳剂，粘合剂，能够以与发光体的反应成直接或相反比例产生或释放可移动染料的化合物， 敏感卤化银在升高的温度下还原成银，以及具有以下通式的染料：其中R1和R2各自为取代或未取代的烷基或烯基，R3为氢原子或取代或未取代的烷基， 烷氧基，芳基或烯基，X 1，X 2，X 3和X 4各自为氢原子，卤素原子，羟基，羧基或取代或未取代的烷基，烷氧基，烷氧基羰基，酰基，酰氧基，芳基，氨基或酰氨基 X1和X2，X3和X4可以相互组合形成苯环，A-是阴离子，n等于0或1。

    Heat-developable photographic materials
    9.
    发明授权
    Heat-developable photographic materials 失效
    可热成像的照相材料

    公开(公告)号：US4637975A

    公开(公告)日：1987-01-20

    申请号：US773163

    申请日：1985-09-06

    申请人： Seiiti Kubodera ,  Takanori Hioki ,  Masaki Okazaki

    发明人： Seiiti Kubodera ,  Takanori Hioki ,  Masaki Okazaki

    IPC分类号： G03C8/40 ,  C09B23/00 ,  C09B57/00 ,  G03C1/22 ,  G03C1/26 ,  G03C1/498 ,  G03C7/00 ,  G03C1/02

    CPC分类号： G03C1/49854 ,  G03C1/26

    摘要： A heat-developable photographic material having improved preservability, which comprises a support having thereon at least one heat-developable photgraphic layer, said photographic material containing a dye represented by formula (I) ##STR1## wherein R.sub.1 and R.sub.3 each represents an unsubstituted or substituted alkyl group or alkenyl group;R.sub.2 represents a hydrogen atom or an unsubstituted or substituted alkyl group, aryl group, alkenyl group, or aromatic heterocyclic group;R.sub.4 through R.sub.7 each represents a hydrogen atom or an unsubstituted or substituted alkyl group, aryl group, or alkenyl group; or R.sub.4 and R.sub.6 together form an unsubstituted or substituted alkylene group or alkenylene group;X.sub.1 represents an oxygen atom, a sulfur atom, or the group ##STR2## wherein R.sub.8 represents a hydrogen atom, an unsubstituted or substituted alkyl group, aryl group, or alkenyl group;Y.sub.1 represents an atomic group forming an unsubstituted or substituted pyridine or quinoline ring together with nitrogen and carbon atoms represented in formula (I);Y.sub.2 represents an atomic group forming an unsubstituted or substituted heterocyclic ring, together with carbon and nitrogen atoms represented in formula (I);X.sub.2 represents an anion; andn.sub.1 represents 0 or 1.

    摘要翻译： 具有改进的保存性的可热显影的照相材料，其包括其上具有至少一个可热显影的光电图层的支持体，所述照相材料含有由式（I）表示的染料，其中R1和R3各自表示 未取代或取代的烷基或烯基; R2表示氢原子或未取代或取代的烷基，芳基，烯基或芳族杂环基; R4至R7各自表示氢原子或未取代或取代的烷基，芳基或烯基; 或R4和R6一起形成未取代或取代的亚烷基或亚烯基; X1表示氧原子，硫原子或基团，其中R8表示氢原子，未取代或取代的烷基，芳基或烯基; Y1表示与式（I）中表示的氮和碳原子一起形成未取代或取代的吡啶或喹啉环的原子团; Y2表示形成未取代或取代的杂环的原子团，以及式（I）中表示的碳和氮原子; X2表示阴离子; n1表示0或1。

    Silver halide photographic material
    10.
    发明授权
    Silver halide photographic material 失效
    卤化银照相材料

    公开(公告)号：US5422238A

    公开(公告)日：1995-06-06

    申请号：US165540

    申请日：1993-12-13

    申请人： Akihiko Ikegawa ,  Masayuki Kuramitsu ,  Masaki Okazaki

    发明人： Akihiko Ikegawa ,  Masayuki Kuramitsu ,  Masaki Okazaki

    IPC分类号： C09B23/02 ,  G03C1/14 ,  G03C1/16 ,  G03C1/18 ,  G03C1/20

    CPC分类号： G03C1/14 ,  C09B23/02

    摘要： A novel silver halide photographic material comprising at least one methine compound represented by the following general formula (I): ##STR1## wherein R.sup.1 represents --(CH.sub.2).sub.r --CONHSO.sub.2 --R.sup.3, --(CH.sub.2).sub.s --SO.sub.2 NHCO--R.sup.4, --(CH.sub.2).sub.t --CONHCO--R.sup.5 or --(CH.sub.2).sub.u --SO.sub.2 NHSO.sub.2 --R.sup.6 in which R.sup.3, R.sup.4, R.sup.5 and R.sup.6 each represents an alkyl group, alkoxy group or amino group, r, s, t and u each represents an integer 1 to 5; and R.sup.2 represents has the same meaning as R.sup.1 or represents an alkyl group; Z.sup.1 and Z.sup.2 each represents a nonmetallic atom group required to form a 5- or 6-membered heterocyclic group; p and q each represents an integer 0 or 1; L.sub.1, L.sub.2 and L.sub.3 each represents a methine group; m represents an integer 0 to 2; X represents an anion; and k represents an integer required to adjust the charge in the molecule to 0. The silver halide photographic material may comprise at least one methine compound represented by the general formula (I) and at least one water-soluble dye.

    摘要翻译： 一种新型的卤化银照相材料，其包含由以下通式（I）表示的至少一种次甲基化合物：其中R1表示 - （CH2）r-CONHSO2-R3， - （CH2）s-SO2NHCO-R4 ， - （CH2）t-CONHCO-R5或 - （CH2）u-SO2NHSO2-R6，其中R3，R4，R5和R6各自表示烷基，烷氧基或氨基，r，s，t和u各自表示 整数1〜5; 和R 2表示与R 1相同或表示烷基; Z1和Z2各自表示形成5或6元杂环基团所需的非金属原子团; p和q各自表示整数0或1; L1，L2和L3各自表示次甲基; m表示0〜2的整数。 X表示阴离子; 并且k表示将分子中的电荷调节至0所需的整数。卤化银照相材料可以包含至少一种由通式（I）表示的次甲基化合物和至少一种水溶性染料。