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公开(公告)号:US09620820B2
公开(公告)日:2017-04-11
申请号:US15167300
申请日:2016-05-27
发明人: Toru Itakura , Kyosuke Ito , Jun Ishikawa , Rie Yokoi
IPC分类号: H01M10/0569 , H01M4/133 , H01M4/587 , H01M10/0525 , H01M4/58 , H01G11/06 , H01G11/62 , H01M2/16 , H01M4/136 , H01M4/66 , H01M10/0568 , H01M10/0585 , H01M4/62 , H01M4/04 , H01M4/1397 , H01M4/02
CPC分类号: H01M10/0569 , H01G11/06 , H01G11/32 , H01G11/50 , H01G11/60 , H01G11/62 , H01G11/84 , H01M2/162 , H01M2/1653 , H01M4/0404 , H01M4/043 , H01M4/0471 , H01M4/133 , H01M4/136 , H01M4/1397 , H01M4/5825 , H01M4/587 , H01M4/621 , H01M4/623 , H01M4/625 , H01M4/661 , H01M10/0525 , H01M10/0568 , H01M10/0585 , H01M2004/021 , H01M2004/027 , H01M2004/028 , H01M2220/20 , H01M2220/30 , H01M2300/0034 , H01M2300/0045 , Y02E60/122 , Y02E60/13 , Y02T10/7011 , Y02T10/7022
摘要: A power storage device with reduced initial irreversible capacity is provided. The power storage device includes a positive electrode including a positive electrode current collector and a positive electrode active material layer, a negative electrode including a negative electrode current collector and a negative electrode active material layer, and an electrolyte solution. In the negative electrode active material layer, the content percentage of a carbon material with an R value of 1.1 or more is less than 2 wt %. The R value refers to a ratio of a peak intensity I1360 to a peak intensity I1580 (I1360/I1580). The peak intensity I1360 and the peak intensity I1580 are observed by Raman spectrometry at a Raman shift of 1360 cm−1 and a Raman shift of 1580 cm−1, respectively. The electrolyte solution contains a lithium ion and an ionic liquid composed of an organic cation and an anion.
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公开(公告)号:US09362564B2
公开(公告)日:2016-06-07
申请号:US14046104
申请日:2013-10-04
发明人: Toru Itakura , Kyosuke Ito , Jun Ishikawa , Rie Yokoi
IPC分类号: H01M4/587 , H01M10/0525 , H01M10/0569 , H01G11/06 , H01G11/62 , H01M4/58 , H01M4/62
CPC分类号: H01M10/0569 , H01G11/06 , H01G11/32 , H01G11/50 , H01G11/60 , H01G11/62 , H01G11/84 , H01M2/162 , H01M2/1653 , H01M4/0404 , H01M4/043 , H01M4/0471 , H01M4/133 , H01M4/136 , H01M4/1397 , H01M4/5825 , H01M4/587 , H01M4/621 , H01M4/623 , H01M4/625 , H01M4/661 , H01M10/0525 , H01M10/0568 , H01M10/0585 , H01M2004/021 , H01M2004/027 , H01M2004/028 , H01M2220/20 , H01M2220/30 , H01M2300/0034 , H01M2300/0045 , Y02E60/122 , Y02E60/13 , Y02T10/7011 , Y02T10/7022
摘要: A power storage device with reduced initial irreversible capacity is provided. The power storage device includes a positive electrode including a positive electrode current collector and a positive electrode active material layer, a negative electrode including a negative electrode current collector and a negative electrode active material layer, and an electrolyte solution. In the negative electrode active material layer, the content percentage of a carbon material with an R value of 1.1 or more is less than 2 wt %. The R value refers to a ratio of a peak intensity I1360 to a peak intensity I1580 (I1360/I1580). The peak intensity I1360 and the peak intensity I1580 are observed by Raman spectrometry at a Raman shift of 1360 cm−1 and a Raman shift of 1580 cm−1, respectively. The electrolyte solution contains a lithium ion and an ionic liquid composed of an organic cation and an anion.
摘要翻译: 提供了具有降低的初始不可逆容量的蓄电装置。 蓄电装置具备包括正极集电体和正极活性物质层的正极,负极集电体和负极活性物质层的负极以及电解液。 在负极活性物质层中,R值为1.1以上的碳材料的含有率小于2重量%。 R值是指峰强度I1360与峰值强度I1580(I1360 / I1580)的比。 通过拉曼光谱测定,在1360cm -1的拉曼位移和1580cm -1的拉曼位移分别观察峰强度I1360和峰强度I1580。 电解质溶液含有锂离子和由有机阳离子和阴离子组成的离子液体。
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公开(公告)号:US20130164610A1
公开(公告)日:2013-06-27
申请号:US13719542
申请日:2012-12-19
发明人: Toru ITAKURA , Kyosuke Ito , Rie Yokoi (Matsubara) , Jun Ishikawa
IPC分类号: H01M10/0569 , H01M10/052
CPC分类号: H01M10/0569 , H01M10/052 , H01M10/0568 , H01M2300/0045 , Y02E60/122
摘要: A nonaqueous electrolyte of the present invention includes an ionic liquid including a first alicyclic quaternary ammonium cation having one or more substituents, a second alicyclic quaternary ammonium cation having an alicyclic skeleton that is the same as an alicyclic skeleton of the first alicyclic quaternary ammonium cation, and a counter anion to the first alicyclic quaternary ammonium cation and the second alicyclic quaternary ammonium cation and an alkali metal salt. In the second alicyclic quaternary ammonium cation, one of substituents bonded to a nitrogen atom in the alicyclic skeleton is a substituent including a halogen element. In the ionic liquid, the amount of a salt including the second alicyclic quaternary ammonium cation is less than or equal to 1 wt % per unit weight of the ionic liquid, or is less than or equal to 0.8 wt % per unit weight of the nonaqueous electrolyte.
摘要翻译: 本发明的非水电解质包括具有一个以上取代基的第一脂环季铵阳离子的离子液体,具有与第一脂环族季铵阳离子的脂环族骨架相同的脂环族骨架的第二脂环族季铵阳离子, 和第一脂环季铵阳离子和第二脂环族季铵阳离子的抗衡阴离子和碱金属盐。 在第二脂环季铵阳离子中,与脂环族骨架中的氮原子结合的取代基之一是包含卤素元素的取代基。 在离子液体中,包含第二脂环族季铵阳离子的盐的量为每单位离子液体重量的1重量%以下,或小于等于0.8重量%,每单位重量的非水性 电解液
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公开(公告)号:US09997806B2
公开(公告)日:2018-06-12
申请号:US15440964
申请日:2017-02-23
发明人: Kyosuke Ito , Toru Itakura
IPC分类号: H01M10/0569 , H01G11/06 , H01G11/52 , H01G11/60 , H01G11/62 , H01M10/0525 , C07D207/06 , C07C311/48
CPC分类号: H01M10/0569 , C07C309/06 , C07C311/48 , C07D207/06 , H01G11/04 , H01G11/06 , H01G11/52 , H01G11/60 , H01G11/62 , H01M10/052 , H01M10/0525 , H01M2220/20 , H01M2220/30 , H01M2300/0017 , H01M2300/0028 , H01M2300/0045 , Y02E60/122 , Y02E60/13 , Y02T10/7011 , Y02T10/7022
摘要: An ionic liquid having high electrochemical stability and a low melting point. An ionic liquid represented by the following general formula (G0) is provided. In the general formula (G0), R0 to R5 are individually any of an alkyl group having 1 to 20 carbon atoms, a methoxy group, a methoxymethyl group, a methoxyethyl group, and a hydrogen atom, and A− is a univalent imide-based anion, a univalent methide-based anion, a perfluoroalkyl sulfonic acid anion, tetrafluoroborate, or hexafluorophosphate.
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公开(公告)号:US09847555B2
公开(公告)日:2017-12-19
申请号:US15477670
申请日:2017-04-03
发明人: Toru Itakura , Kyosuke Ito , Jun Ishikawa , Rie Yokoi
IPC分类号: H01M10/0569 , H01M4/587 , H01M10/0525 , H01M4/58 , H01G11/06 , H01G11/62 , H01M2/16 , H01M4/133 , H01M4/136 , H01M4/66 , H01M10/0568 , H01M10/0585 , H01G11/32 , H01G11/50 , H01G11/60 , H01G11/84 , H01M4/62 , H01M4/04 , H01M4/1397 , H01M4/02
CPC分类号: H01M10/0569 , H01G11/06 , H01G11/32 , H01G11/50 , H01G11/60 , H01G11/62 , H01G11/84 , H01M2/162 , H01M2/1653 , H01M4/0404 , H01M4/043 , H01M4/0471 , H01M4/133 , H01M4/136 , H01M4/1397 , H01M4/5825 , H01M4/587 , H01M4/621 , H01M4/623 , H01M4/625 , H01M4/661 , H01M10/0525 , H01M10/0568 , H01M10/0585 , H01M2004/021 , H01M2004/027 , H01M2004/028 , H01M2220/20 , H01M2220/30 , H01M2300/0034 , H01M2300/0045 , Y02E60/122 , Y02E60/13 , Y02T10/7011 , Y02T10/7022
摘要: A power storage device with reduced initial irreversible capacity is provided. The power storage device includes a positive electrode including a positive electrode current collector and a positive electrode active material layer, a negative electrode including a negative electrode current collector and a negative electrode active material layer, and an electrolyte solution. In the negative electrode active material layer, the content percentage of a carbon material with an R value of 1.1 or more is less than 2 wt %. The R value refers to a ratio of a peak intensity I1360 to a peak intensity I1580 (I1360/I1580). The peak intensity I1360 and the peak intensity I1580 are observed by Raman spectrometry at a Raman shift of 1360 cm−1 and a Raman shift of 1580 cm−1, respectively. The electrolyte solution contains a lithium ion and an ionic liquid composed of an organic cation and an anion.
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公开(公告)号:US09577290B2
公开(公告)日:2017-02-21
申请号:US13719562
申请日:2012-12-19
发明人: Kyosuke Ito , Toru Itakura , Nobuhiro Inoue , Jun Ishikawa , Junpei Momo
IPC分类号: H01M10/0566 , H01M10/0569 , H01M10/052
CPC分类号: H01M10/0569 , H01M10/052 , H01M2300/0045 , Y02E60/122 , Y02T10/7011
摘要: A power storage device using an organic solvent as a nonaqueous solvent for a nonaqueous electrolyte, in which a CV charging period in CCCV charging can be prevented from being extended and which has high performance, can be provided. The power storage device includes a positive electrode, a negative electrode, and a nonaqueous electrolyte. The nonaqueous electrolyte includes an ionic liquid including an alicyclic quaternary ammonium cation having one or more substituents and a counter anion to the alicyclic quaternary ammonium cation, a cyclic ester, and an alkali metal salt. In particular, in the power storage device, the ionic liquid content is greater than or equal to 70 wt % and less than 100 wt % per unit weight of the ionic liquid and the cyclic ester in the nonaqueous electrolyte, or greater than or equal to 50 wt % and less than 80 wt % per unit weight of the nonaqueous electrolyte.
摘要翻译: 可以提供使用有机溶剂作为非水电解质的非水溶剂的蓄电装置,其中可以防止CCCV充电中的CV充电期延长并且具有高性能。 蓄电装置包括正极,负极和非水电解质。 非水电解质包括离子液体,其包含具有一个或多个取代基的脂环族季铵阳离子和与脂环族季铵阳离子的抗衡阴离子,环状酯和碱金属盐。 特别地,在蓄电装置中,离子液体含量大于或等于70重量%且小于100重量%,每单位重量的离子液体和非水电解质中的环状酯,或大于或等于 50重量%且小于80重量%的每单位重量的非水电解质。
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公开(公告)号:US10991984B2
公开(公告)日:2021-04-27
申请号:US15008487
申请日:2016-01-28
发明人: Toru Itakura , Kyosuke Ito , Rie Yokoi , Jun Ishikawa
IPC分类号: H01M10/0569 , H01M10/0568 , H01M10/052 , C25D3/44 , C07C275/02 , C07C275/06 , C25D3/66 , C07C233/05
摘要: A nonaqueous electrolyte of the present invention includes an ionic liquid including a first alicyclic quaternary ammonium cation having one or more substituents, a second alicyclic quaternary ammonium cation having an alicyclic skeleton that is the same as an alicyclic skeleton of the first alicyclic quaternary ammonium cation, and a counter anion to the first alicyclic quaternary ammonium cation and the second alicyclic quaternary ammonium cation and an alkali metal salt. In the second alicyclic quaternary ammonium cation, one of substituents bonded to a nitrogen atom in the alicyclic skeleton is a substituent including a halogen element. In the ionic liquid, the amount of a salt including the second alicyclic quaternary ammonium cation is less than or equal to 1 wt % per unit weight of the ionic liquid, or is less than or equal to 0.8 wt % per unit weight of the nonaqueous electrolyte.
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公开(公告)号:US10128541B2
公开(公告)日:2018-11-13
申请号:US15792994
申请日:2017-10-25
发明人: Toru Itakura , Kyosuke Ito , Jun Ishikawa , Rie Yokoi
IPC分类号: H01M4/587 , H01M10/0525 , H01M10/0569 , H01M4/58 , H01M4/62 , H01G11/06 , H01G11/62 , H01M2/16 , H01M4/133 , H01M4/136 , H01M4/66 , H01M10/0568 , H01M10/0585 , H01G11/32 , H01G11/50 , H01G11/60 , H01G11/84 , H01M4/04 , H01M4/1397 , H01M4/02
摘要: A power storage device with reduced initial irreversible capacity is provided. The power storage device includes a positive electrode including a positive electrode current collector and a positive electrode active material layer, a negative electrode including a negative electrode current collector and a negative electrode active material layer, and an electrolyte solution. In the negative electrode active material layer, the content percentage of a carbon material with an R value of 1.1 or more is less than 2 wt %. The R value refers to a ratio of a peak intensity I1360 to a peak intensity I1580 (I1360/I1580). The peak intensity I1360 and the peak intensity I1580 are observed by Raman spectrometry at a Raman shift of 1360 cm−1 and a Raman shift of 1580 cm−1, respectively. The electrolyte solution contains a lithium ion and an ionic liquid composed of an organic cation and an anion.
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公开(公告)号:US09583276B2
公开(公告)日:2017-02-28
申请号:US14918830
申请日:2015-10-21
发明人: Kyosuke Ito , Toru Itakura
IPC分类号: H01M6/04 , H01G11/04 , C07D207/06 , H01M10/052 , H01M10/0569 , H01G11/06 , H01G11/62 , C07C309/06 , C07C311/48 , H01G11/52 , H01G11/60 , H01M10/0525
CPC分类号: H01M10/0569 , C07C309/06 , C07C311/48 , C07D207/06 , H01G11/04 , H01G11/06 , H01G11/52 , H01G11/60 , H01G11/62 , H01M10/052 , H01M10/0525 , H01M2220/20 , H01M2220/30 , H01M2300/0017 , H01M2300/0028 , H01M2300/0045 , Y02E60/122 , Y02E60/13 , Y02T10/7011 , Y02T10/7022
摘要: An ionic liquid having high electrochemical stability and a low melting point. An ionic liquid represented by the following general formula (G0) is provided. In the general formula (G0), R0 to R5 are individually any of an alkyl group having 1 to 20 carbon atoms, a methoxy group, a methoxymethyl group, a methoxyethyl group, and a hydrogen atom, and A− is a univalent imide-based anion, a univalent methide-based anion, a perfluoroalkyl sulfonic acid anion, tetrafluoroborate, or hexafluorophosphate.
摘要翻译: 具有高电化学稳定性和低熔点的离子液体。 提供由以下通式(G0)表示的离子液体。 在通式(G0)中,R 0〜R 5分别是碳原子数1〜20的烷基,甲氧基,甲氧基甲基,甲氧基乙基和氢原子中的任一个,A-为单价酰亚胺 - 单价甲基化阴离子,全氟烷基磺酸阴离子,四氟硼酸盐或六氟磷酸盐。
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公开(公告)号:US09171677B2
公开(公告)日:2015-10-27
申请号:US14600135
申请日:2015-01-20
发明人: Kyosuke Ito , Toru Itakura
IPC分类号: H01M6/04 , H01G11/06 , C07D207/06 , H01M10/052 , H01M10/0569 , H01G11/62 , C07C309/06 , C07C311/48 , H01G11/52 , H01G11/60 , H01M10/0525
CPC分类号: H01M10/0569 , C07C309/06 , C07C311/48 , C07D207/06 , H01G11/04 , H01G11/06 , H01G11/52 , H01G11/60 , H01G11/62 , H01M10/052 , H01M10/0525 , H01M2220/20 , H01M2220/30 , H01M2300/0017 , H01M2300/0028 , H01M2300/0045 , Y02E60/122 , Y02E60/13 , Y02T10/7011 , Y02T10/7022
摘要: An ionic liquid having high electrochemical stability and a low melting point. An ionic liquid represented by the following general formula (G0) is provided. In the general formula (G0), R0 to R5 are individually any of an alkyl group having 1 to 20 carbon atoms, a methoxy group, a methoxymethyl group, a methoxyethyl group, and a hydrogen atom, and A− is a univalent imide-based anion, a univalent methide-based anion, a perfluoroalkyl sulfonic acid anion, tetrafluoroborate, or hexafluorophosphate.
摘要翻译: 具有高电化学稳定性和低熔点的离子液体。 提供由以下通式(G0)表示的离子液体。 在通式(G0)中,R 0〜R 5分别是碳原子数1〜20的烷基,甲氧基,甲氧基甲基,甲氧基乙基和氢原子中的任一个,A-为单价酰亚胺 - 单价甲基化阴离子,全氟烷基磺酸阴离子,四氟硼酸盐或六氟磷酸盐。
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