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公开(公告)号:US20240250237A1
公开(公告)日:2024-07-25
申请号:US18625418
申请日:2024-04-03
Applicant: SEMICONDUCTOR ENERGY LABORATORY CO., LTD.
Inventor: Tatsuya IKENUMA , Yumiko YONEDA
IPC: H01M4/133 , C01B32/184 , H01M4/04 , H01M4/1393 , H01M4/587 , H01M4/62
CPC classification number: H01M4/133 , C01B32/184 , H01M4/0416 , H01M4/049 , H01M4/1393 , H01M4/587 , H01M4/625 , Y02E60/10 , Y02E60/13
Abstract: To provide graphene oxide that has high dispersibility and is easily reduced. To provide graphene with high electron conductivity. To provide a storage battery electrode including an active material layer with high electric conductivity and a manufacturing method thereof. To provide a storage battery with increased discharge capacity. A method for manufacturing a storage battery electrode that is to be provided includes a step of dispersing graphene oxide into a solution containing alcohol or acid, a step of heating the graphene oxide dispersed into the solution, and a step or reducing the graphene oxide.
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公开(公告)号:US20230331556A1
公开(公告)日:2023-10-19
申请号:US18043102
申请日:2021-08-20
Applicant: SEMICONDUCTOR ENERGY LABORATORY CO., LTD.
Inventor: Shunpei YAMAZAKI , Tetsuya KAKEHATA , Yumiko YONEDA , Kazutaka KURIKI
IPC: C01B25/45
CPC classification number: C01B25/45 , C01P2006/80 , C01P2006/40 , C01P2004/04 , C01P2002/70
Abstract: A method for manufacturing a highly purified positive electrode active material is provided. Alternatively, a method for manufacturing a positive electrode active material whose crystal structure is not easily broken even when charge and discharge are repeated is provided. The method for manufacturing a positive electrode active material containing lithium and a transition metal includes a first step of preparing a lithium compound, a phosphorus compound, and water; a second step of forming a first mixture by mixing the lithium compound, the phosphorus compound, and the water; a third step of forming a second mixture by adding a first aqueous solution to the first mixture to adjust a pH; a fourth step of forming a third mixture by mixing an iron(II) compound with the second mixture; a fifth step of forming a fourth mixture by heating the third mixture; and a sixth step of obtaining a positive electrode active material by filtering, washing, and drying the fourth mixture. High-purity materials are used as the lithium compound, the phosphorus compound, the water, and the iron(II) compound.
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公开(公告)号:US20220293923A1
公开(公告)日:2022-09-15
申请号:US17632358
申请日:2020-07-29
Applicant: SEMICONDUCTOR ENERGY LABORATORY CO., LTD.
Inventor: Kazutaka KURIKI , Yumiko YONEDA , Hiroshi KADOMA , Kaori OGITA , Shunpei YAMAZAKI
IPC: H01M4/38 , H01M4/36 , H01M10/0525
Abstract: A highly reliable solid-state secondary battery with improved cycle performance, reliability, or safety is provided. A negative electrode includes, over a negative electrode current collector, n negative electrode active material layers (n is an integer greater than or equal to 2) and n−1 separation layers. The negative electrode active material layers and the separation layers are alternately stacked. The thickness of the negative electrode active material is greater than or equal to 20 nm and less than or equal to 100 nm. The separation layers each include titanium. The separation layer preferably includes titanium (Ti), titanium nitride (TiN), or titanium oxynitride (TiOxNy, 0
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公开(公告)号:US20220255076A1
公开(公告)日:2022-08-11
申请号:US17729170
申请日:2022-04-26
Applicant: SEMICONDUCTOR ENERGY LABORATORY CO., LTD.
Inventor: Mayumi MIKAMI , Aya UCHIDA , Yumiko YONEDA , Yohei MOMMA , Masahiro TAKAHASHI , Teruaki OCHIAI
IPC: H01M4/525 , C01G53/00 , H01M4/131 , H01M4/133 , H01M4/134 , H01M4/139 , H01M4/36 , H01M4/505 , H01M10/0525 , H01M6/16
Abstract: A positive electrode active material having high capacity and excellent cycle performance is provided. The positive electrode active material has a small difference in a crystal structure between the charged state and the discharged state. For example, the crystal structure and volume of the positive electrode active material, which has a layered rock-salt crystal structure in the discharged state and a pseudo-spinel crystal structure in the charged state at a high voltage of approximately 4.6 V, are less likely to be changed by charge and discharge as compared with those of a known positive electrode active material.
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公开(公告)号:US20200303739A1
公开(公告)日:2020-09-24
申请号:US16893726
申请日:2020-06-05
Applicant: SEMICONDUCTOR ENERGY LABORATORY CO., LTD.
Inventor: Takuya MIWA , Yumiko YONEDA , Teppei OGUNI
Abstract: A composite oxide with high diffusion rate of lithium is provided. Alternatively, a lithium-containing complex phosphate with high diffusion rate of lithium is provided. Alternatively, a positive electrode active material with high diffusion rate of lithium is provided. Alternatively, a lithium ion battery with high output is provided. Alternatively, a lithium ion battery that can be manufactured at low cost is provided. A positive electrode active material is formed through a first step of mixing a lithium compound, a phosphorus compound, and water, a second step of adjusting pH by adding a first aqueous solution to a first mixed solution formed in the first step, a third step of mixing an iron compound with a second mixed solution formed in the second step, a fourth step of performing heat treatment under a pressure more than or equal to 0.1 MPa and less than or equal to 2 MPa at a highest temperature more than 100° C. and less than or equal to 119 ° C. on a third mixed solution formed in the third step with a pH of more than or equal to 3.5 and less than or equal to 5.0.
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公开(公告)号:US20170338489A1
公开(公告)日:2017-11-23
申请号:US15586341
申请日:2017-05-04
Applicant: SEMICONDUCTOR ENERGY LABORATORY CO., LTD.
Inventor: Takuya MIWA , Yumiko YONEDA , Teppei OGUNI
IPC: H01M4/58 , C01B25/45 , H01M10/0525 , H01M4/02
CPC classification number: H01M4/5825 , C01B25/45 , C01P2002/72 , C01P2004/03 , C01P2004/62 , C01P2004/64 , C01P2006/40 , H01M10/0525 , H01M2004/028
Abstract: A composite oxide with high diffusion rate of lithium is provided. Alternatively, a lithium-containing complex phosphate with high diffusion rate of lithium is provided. Alternatively, a positive electrode active material with high diffusion rate of lithium is provided. Alternatively, a lithium ion battery with high output is provided. Alternatively, a lithium ion battery that can be manufactured at low cost is provided. A positive electrode active material is formed through a first step of mixing a lithium compound, a phosphorus compound, and water, a second step of adjusting pH by adding a first aqueous solution to a first mixed solution formed in the first step, a third step of mixing an iron compound with a second mixed solution formed in the second step, a fourth step of performing heat treatment under a pressure more than or equal to 0.1 MPa and less than or equal to 2 MPa at a highest temperature more than 100° C. and less than or equal to 119° C. on a third mixed solution formed in the third step with a pH of more than or equal to 3.5 and less than or equal to 5.0.
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公开(公告)号:US20170187040A1
公开(公告)日:2017-06-29
申请号:US15381152
申请日:2016-12-16
Applicant: SEMICONDUCTOR ENERGY LABORATORY CO., LTD.
Inventor: Yumiko YONEDA , Teppei OGUNI , Takuya MIWA , Masaki YAMAKAJI , Ayae TSURUTA
IPC: H01M4/587 , H01M2/16 , H01M10/0587 , H01M4/1393 , H01M4/04 , H01M10/0525 , H01M4/36 , H01M2/14
CPC classification number: H01M4/587 , C01B32/225 , C01B32/23 , C01P2006/40 , H01M2/145 , H01M2/1626 , H01M2/1653 , H01M2/1673 , H01M4/0404 , H01M4/133 , H01M4/1393 , H01M4/364 , H01M4/625 , H01M10/052 , H01M10/0525 , H01M10/0587 , H01M2004/027 , H01M2220/20
Abstract: To provide a manufacturing method of graphene oxide that allows mass production through a relatively simple process, at low costs, and with safety and efficiency. A hydrogen peroxide solution, sulfuric acid, and flake graphite are put in a reaction container, and the mixture is stirred to obtain expansion graphite. The synthesized expansion graphite is washed not with pure water but with a saturated aqueous solution of magnesium sulfate (MgSO4) or an organic solvent, whereby a large amount of sulfuric acid is contained between graphite layers. The expansion graphite is subjected to heat treatment or microwave irradiation to form expanded graphite, and a graphite layer is peeled by ultrasonic treatment and then oxidized to form a graphene compound.
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公开(公告)号:US20160087305A1
公开(公告)日:2016-03-24
申请号:US14854349
申请日:2015-09-15
Applicant: Semiconductor Energy Laboratory Co., Ltd.
Inventor: Yumiko YONEDA , Masaki YAMAKAJI , Ryota TAJIMA , Masaaki HIROKI
IPC: H01M10/0565 , H01M2/02
CPC classification number: H01M10/0565 , H01M2/0275 , H01M4/02 , H01M4/13 , H01M10/0436 , H01M10/052 , H01M10/0585 , H01M2300/0085 , Y02T10/7011
Abstract: A gel electrolyte and a separator are provided between the positive electrode current collector and the negative electrode current collector. The plurality of positive electrode current collectors and the plurality of negative electrode current collectors are stacked such that surfaces of negative electrodes with which active material layers are not coated or surfaces of positive electrodes with which active material layers are not coated are in contact with each other.
Abstract translation: 在正极集电体和负极集电体之间设置凝胶电解质和隔膜。 堆叠多个正极集电体和多个负极集电体,使得不涂覆有活性物质层的负极的表面或不涂覆活性物质层的正极的表面彼此接触 。
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公开(公告)号:US20150340664A1
公开(公告)日:2015-11-26
申请号:US14717615
申请日:2015-05-20
Applicant: Semiconductor Energy Laboratory Co., LTD.
Inventor: Minoru TAKAHASHI , Yuugo GOTO , Yumiko YONEDA , Takuya MIWA , Ryota TAJIMA
IPC: H01M2/02
CPC classification number: H01M2/0275 , H01M2/021 , H01M2/0287 , H01M2/30 , H01M10/0436 , H01M2220/30
Abstract: In the case where a film, which has lower strength than a metal can, is used as an exterior body of a secondary battery, a current collector provided in a region surrounded by the exterior body, an active material layer provided on a surface of the current collector, or the like might be damaged when force is externally applied to the secondary battery. A secondary battery which is resistant to external force is obtained. An opening is provided in a central portion of the secondary battery, and a terminal is formed in the opening. An outer edge of the secondary battery is fixed by thermocompression bonding. In addition, the central portion of the secondary battery is fixed by thermocompression bonding, so that the amount of bending is limited even when the outer edge portion of the secondary battery is bent.
Abstract translation: 在将具有比金属罐低的强度的膜用作二次电池的外部主体的情况下,设置在由外部主体包围的区域中的集电体,设置在外部主体的表面上的活性物质层 集电器等可能会在外部施加到二次电池上时损坏。 获得耐外力的二次电池。 在二次电池的中央部设置有开口,在开口部形成有端子。 通过热压接固定二次电池的外边缘。 此外,通过热压接固定二次电池的中心部分,使得即使当二次电池的外边缘部分弯曲时,弯曲量也受到限制。
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公开(公告)号:US20240356067A1
公开(公告)日:2024-10-24
申请号:US18395852
申请日:2023-12-26
Applicant: SEMICONDUCTOR ENERGY LABORATORY CO., LTD.
Inventor: Yumiko YONEDA , Masaki YAMAKAJI , Ryota TAJIMA , Masaaki HIROKI
IPC: H01M10/0565 , H01M4/02 , H01M4/13 , H01M10/04 , H01M10/052 , H01M10/0585 , H01M50/119 , H01M50/121 , H01M50/122 , H01M50/124
CPC classification number: H01M10/0565 , H01M4/02 , H01M4/13 , H01M10/0436 , H01M10/052 , H01M10/0585 , H01M50/119 , H01M50/121 , H01M50/122 , H01M50/124 , H01M2300/0085 , Y02T10/70
Abstract: A gel electrolyte and a separator are provided between the positive electrode current collector and the negative electrode current collector. The plurality of positive electrode current collectors and the plurality of negative electrode current collectors are stacked such that surfaces of negative electrodes with which active material layers are not coated or surfaces of positive electrodes with which active material layers are not coated are in contact with each other.
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