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    Contact lens material
    3.
    发明授权
    Contact lens material 失效
    隐形眼镜材料

    公开(公告)号：US5605942A

    公开(公告)日：1997-02-25

    申请号：US583746

    申请日：1996-01-17

    申请人： Haruyuki Hiratani ,  Kazuhiko Nakada ,  Shoji Ichinohe ,  Toshio Yamazaki ,  Hideto Kato

    发明人： Haruyuki Hiratani ,  Kazuhiko Nakada ,  Shoji Ichinohe ,  Toshio Yamazaki ,  Hideto Kato

    IPC分类号： C08G73/10 ,  G02B1/04 ,  A61F2/16

    CPC分类号： C08G73/106 ,  C08G73/1039 ,  G02B1/043

    摘要： A contact lens material comprising a condensation polymer having a recurring unit represented by the formula (I): ##STR1## wherein R.sup.1 is --C(CF.sub.3).sub.2 -- or ##STR2## R.sup.2 is a group represented by the formula: ##STR3## in which l is an integer of 1 to 3, m is an integer of 1 to 15 and n is an integer of 1 to 3, ##STR4## in which u is an integer of 1 to 3 and v is an integer of 1 to 3, a group represented by the formula (II): ##STR5## wherein R.sup.3, R.sup.4, R.sup.5 and R.sup.6 are the same or different and each is hydrogen atom or an alkyl group having 1 to 5 carbon atoms, or a group represented by the formula (III): ##STR6## wherein R.sup.7 is --C(CF.sub.3).sub.2 --, ##STR7## or a direct bond, and R.sup.8 and R.sup.9 are the same or different and each is an alkyl group having 1 to 3 carbon atoms, a fluoroalkyl group having 1 to 3 carbon atoms, hydrogen atom, hydroxyl group or carboxyl group. The contact lens material is excellent in transparency, having high oxygen permeability and moreover, excellent in heat resistance, ultraviolet-ray absorbing property and forming and processing property.

    摘要翻译： 包含具有由式（I）表示的重复单元的缩聚物的隐形眼镜材料：其中R 1是-C（CF 3）2 - 或R 2是由下式表示的基团： IMAGE>其中l为1〜3的整数，m为1〜15的整数，n为1〜3的整数，＆lt; IMAGE＆gt;中，u为1〜3的整数，v为 1〜3，式（II）表示的基团：其中R 3，R 4，R 5和R 6相同或不同，各自为氢原子或碳原子数1〜5的烷基， 由式（III）表示的基团：其中R 7是-C（CF 3）2 - ， - 或直接键，其中R 8和R 9相同或不同，并且各自为烷基 具有1至3个碳原子，具有1至3个碳原子的氟代烷基，氢原子，羟基或羧基。 隐形眼镜材料的透明度优异，透氧性高，耐热性，紫外线吸收性，成型加工性优异。

    Water-absorptive soft contact lens material and contact lens made thereof
    5.
    发明授权
    Water-absorptive soft contact lens material and contact lens made thereof 失效
    吸水软性隐形眼镜材料及其隐形眼镜

    公开(公告)号：US5786434A

    公开(公告)日：1998-07-28

    申请号：US709691

    申请日：1996-09-10

    申请人： Ichiro Ando ,  Toru Kawaguchi ,  Shoji Ichinohe ,  Toshio Yamazaki

    发明人： Ichiro Ando ,  Toru Kawaguchi ,  Shoji Ichinohe ,  Toshio Yamazaki

    IPC分类号： G02C7/04 ,  C08F20/52 ,  C08F30/08 ,  C08F220/56 ,  C08F226/06 ,  C08F230/08 ,  G02B1/04 ,  C08F220/18

    CPC分类号： C08F230/08 ,  G02B1/043

    摘要： A water-absorptive soft contact lens material having a high transparency, an excellent flexibility, a high oxygen permeability independent of water content, a high mechanical strength and an adequate hardness, which comprises a copolymer prepared by the polymerization of a monomer mixture comprising an N,N-dialkyl acrylamide or methacrylamide, an N-vinyllactam and a bis(silicon-containing alkyl) fumarate in a specific ratio, and which provides water-absorptive soft contact lenses having excellent properties such as high transparency and high oxygen permeability.

    摘要翻译： 一种具有高透明度，优异的柔韧性，与水含量无关的高透氧性，高机械强度和足够硬度的吸水软性隐形眼镜材料，其包含通过将包含N的单体混合物聚合制备的共聚物 ，N-二烷基丙烯酰胺或甲基丙烯酰胺，N-乙烯基内酰胺和具有比例的双（含硅烷基）富马酸酯，并且提供具有优异性能例如高透明度和高透氧性的吸水软性隐形眼镜。

    Modification of resins with isocyanatosiloxanes
    7.
    发明授权
    Modification of resins with isocyanatosiloxanes 失效
    用异氰酸酯硅氧烷改性树脂

    公开(公告)号：US5703159A

    公开(公告)日：1997-12-30

    申请号：US570387

    申请日：1995-12-11

    申请人： Shoji Ichinohe ,  Toshio Yamazaki ,  Akira Yamamoto

    发明人： Shoji Ichinohe ,  Toshio Yamazaki ,  Akira Yamamoto

    IPC分类号： C08G18/42 ,  C08G18/62 ,  C08G18/71 ,  C08G18/77 ,  C08G77/388 ,  C08G77/50 ,  C08G77/26

    CPC分类号： C08G18/6229 ,  C08G18/4238 ,  C08G18/6212 ,  C08G18/718 ,  C08G18/778 ,  C08G77/388 ,  C08G77/50

    摘要： Resins having a group reactive with an isocyanate group on a side chain are modified with isocyanatosiloxanes. In one form, the isocyanatosiloxane is a single end isocyanatosiloxane obtained by effecting addition reaction between a single end hydrogenosiloxane and an isocyanate group-containing organic silicon compound having one isocyanate group and at least one aliphatic unsaturated hydrocarbon group. A single end isocyanatosiloxane obtained by introducing an isocyanate group into a single end primary aminosiloxane is also useful. In another form, the isocyanatosiloxane is a polyfunctional isocyanatosiloxane which is obtained by effecting addition reaction between a hydrogenosiloxane having at least two SiH groups and an isocyanate group-containing organic silicon compound having one isocyanate group and one aliphatic unsaturated hydrocarbon group.

    摘要翻译： 具有与侧链上的异氰酸酯基反应的基团的树脂用异氰酸酯硅氧烷改性。 在一种形式中，异氰酸酯基硅氧烷是通过在单端氢硅氧烷和具有一个异氰酸酯基和至少一个脂肪族不饱和烃基的含异氰酸酯基的有机硅化合物之间进行加成反应获得的单端异氰酸酯硅氧烷。 通过将异氰酸酯基引入单末端伯氨基硅氧烷而获得的单末端异氰酸酯硅氧烷也是有用的。 在另一种形式中，异氰酸基硅氧烷是通过在具有至少两个SiH基的氢硅氧烷与具有一个异氰酸酯基和一个脂肪族不饱和烃基的含异氰酸酯基的有机硅化合物之间进行加成反应获得的多官能异氰酸酯基硅氧烷。

    Ocular lens material
    9.
    发明授权
    Ocular lens material 失效
    眼镜材料

    公开(公告)号：US5556929A

    公开(公告)日：1996-09-17

    申请号：US582023

    申请日：1996-01-02

    申请人： Yasuhiro Yokoyama ,  Yuriko Watanabe ,  Akinori Okumura ,  Shoji Ichinohe ,  Toshio Yamazaki

    发明人： Yasuhiro Yokoyama ,  Yuriko Watanabe ,  Akinori Okumura ,  Shoji Ichinohe ,  Toshio Yamazaki

    IPC分类号： G02C7/04 ,  A61L27/00 ,  C08F20/34 ,  C08F30/08 ,  C08F220/36 ,  C08F220/54 ,  C08F226/06 ,  C08F230/08 ,  C08F290/00 ,  C08F290/06 ,  G02B1/04 ,  C08F26/00

    CPC分类号： C08F220/54 ,  C08F226/06 ,  C08F290/068 ,  G02B1/043

    摘要： An ocular lens material made of a copolymer obtained by polymerizing copolymerizable components comprising (A) a fluorine-containing di(meth)acrylate having urethane bonds, of the formula (I): ##STR1## wherein each of R.sup.1 and R.sup.2 independently represents a hydrogen atom or a methyl group, each of R.sup.3 and R.sup.4 independently represents a C.sub.5-15 alkylene group, R.sup.5 represents a C.sub.1-20 alkylene group containing from 1 to 20 fluorine atoms, each of m and n independently represents an integer of from 1 to 5, and each of x and y independently represents 0 or 1, (B) a silicone-containing di(meth)acrylate having urethane bonds, of the formula (II): ##STR2## wherein each of R.sup.6 and R.sup.7 independently represents a hydrogen atom or a methyl group, each of R.sup.8 and R.sup.9 independently represents a C.sub.1-10 alkylene group or a C.sub.2-10 ether group, R.sup.10 represents a siloxane structure of the formula (III): ##STR3## wherein r is an integer of from 1 to 50, and each of p and q independently represents an integer of from 1 to 5, and (C) a monomer having an unsaturated double bond, copolymerizable with the fluorine-containing di(meth)acrylate (A) and the silicone-containing di(meth)acrylate (B).

    摘要翻译： 1.一种由通过使包含（A）具有氨基甲酸酯键的含氟二（甲基）丙烯酸酯，式（I）：其中R 1和R 2各自独立地表示的可共聚组分 表示氢原子或甲基，R3和R4各自独立地表示C5-15亚烷基，R5表示含有1〜20个氟原子的C1-20亚烷基，m和n分别独立地表示 1〜5，x和y各自独立地表示0或1，（B）具有氨基甲酸酯键的含硅氧烷的二（甲基）丙烯酸酯，式（II）表示：氢原子或甲基，各自表示氢原子或甲基 的R 8和R 9独立地表示C 1-10亚烷基或C 2-10醚基，R 10表示式（III）的硅氧烷结构：1〜50，p和q各自独立地表示1〜 5，和（C）具有不饱和双键的单体，可与th共聚 （甲基）丙烯酸酯（A）和含硅氧烷的二（甲基）丙烯酸酯（B）。

    Organopolysiloxanes having a silanol group and process of making them
    10.
    发明授权
    Organopolysiloxanes having a silanol group and process of making them 失效
    具有硅烷醇基团的有机聚硅氧烷及其制备方法

    公开(公告)号：US5508369A

    公开(公告)日：1996-04-16

    申请号：US291066

    申请日：1994-08-17

    申请人： Toshio Yamazaki ,  Nobuyuki Suzuki ,  Shinichi Morioka ,  Shoji Ichinohe

    发明人： Toshio Yamazaki ,  Nobuyuki Suzuki ,  Shinichi Morioka ,  Shoji Ichinohe

    IPC分类号： C07F7/08 ,  C08G77/16 ,  C08G77/22

    CPC分类号： C07F7/0859

    摘要： Novel organopolysiloxanes having one silanol group within a molecule and the method for manufacturing them at high purity and high yield. The organopolysiloxanes having a silanol group are expressed by the formula (1) below: ##STR1## wherein R.sup.1 is a monovalent hydrocarbon group with 1 to 8 carbon atoms, each of R.sup.2, R.sup.3 and R.sup.4 is a monovalent hydrocarbon group with 1 to 8 carbon atoms or a siloxyl group expressed by --OSiR.sup.5 R.sup.7, wherein R.sup.5, R.sup.6 and R.sup.7 are monovalent hydrocarbon groups with 1 to 8 carbon atoms, Y is either a hydrogen atom, a halogen atom, or a monovalent hydrocarbon group with 1 to 12 carbon atoms, n is an integer of from 0 to 12, and a is either 0 or 1, with the proviso that the grouping Y--(CH.sub.2).sub.n --Si does not includes H--Si, CH.sub.3 --Si or a hydrolyzable silyl group.

    摘要翻译： 在分子内具有一个硅烷醇基团的新型有机聚硅氧烷及其以高纯度和高收率制造的方法。 具有硅烷醇基的有机聚硅氧烷由下式（1）表示：其中R1是具有1至8个碳原子的一价烃基，R2，R3和R4各自是1价烃基， 至8个碳原子或由-OSiR 5 R 7表示的硅氧烷基，其中R 5，R 6和R 7为具有1至8个碳原子的一价烃基，Y为氢原子，卤原子或含1至12个碳原子的单价烃基 碳原子，n为0〜12的整数，a为0或1，条件是Y-（CH2）n-Si分子不包括H-Si，CH3-Si或可水解甲硅烷基 。