公开(公告)号：US08962135B2

公开(公告)日：2015-02-24

申请号：US12255440

申请日：2008-10-21

申请人： Shinichi Inoue ,  Yuusuke Toyama ,  Mizue Nagata ,  Toshitsugu Hosokawa ,  Yutaka Moroishi ,  Fumiko Nakano

发明人： Shinichi Inoue ,  Yuusuke Toyama ,  Mizue Nagata ,  Toshitsugu Hosokawa ,  Yutaka Moroishi ,  Fumiko Nakano

IPC分类号： B32B7/12 ,  C09J7/02 ,  C09J133/14

CPC分类号： C09J7/0217 ,  C09J7/385 ,  C09J133/14 ,  G02F2202/28 ,  Y10T428/2891 ,  Y10T428/2896 ,  Y10T428/31551

摘要： A pressure-sensitive adhesive composition for an optical film of the present invention comprises 100 parts by weight of a (meth)acrylic polymer comprising 45 to 99.99% by weight of an alkyl (meth)acrylate monomer unit and 0.01 to 2% by weight of a tertiary amino group-containing monomer unit; and 0.01 to 2 parts by weight of a peroxide as a crosslinking agent. The pressure-sensitive adhesive composition can form an pressure-sensitive adhesive layer that has satisfactory reworkability such that optical films can be easily peeled from liquid crystal panels with no adhesive residue and also has satisfactory processability such that it can be worked without pressure-sensitive adhesive fouling or dropout.

摘要翻译： 本发明的光学膜用粘合剂组合物包含100重量份由（甲基）丙烯酸烷基酯单体单元组成的45-99.99重量％的（甲基）丙烯酸系聚合物和0.01〜2重量％ 含叔氨基的单体单元; 和0.01〜2重量份作为交联剂的过氧化物。 压敏粘合剂组合物可以形成具有良好的再加工性的压敏粘合剂层，使得光学膜可以容易地从液晶面板剥离而没有粘合残留物，并且还具有令人满意的加工性，使得其可以在没有压敏粘合剂的情况下加工 结垢或辍学

公开(公告)号：US07923120B2

公开(公告)日：2011-04-12

申请号：US12203447

申请日：2008-09-03

申请人： Yuusuke Toyama ,  Masayuki Satake ,  Akiko Ogasawara ,  Yutaka Moroishi ,  Fumiko Nakano

发明人： Yuusuke Toyama ,  Masayuki Satake ,  Akiko Ogasawara ,  Yutaka Moroishi ,  Fumiko Nakano

IPC分类号： B32B27/08 ,  B32B27/30 ,  B32B27/34 ,  B32B27/36 ,  C08L33/14 ,  C09J133/14 ,  C09K19/38

CPC分类号： C09J175/04 ,  C08G18/289 ,  C08G18/6229 ,  C08G18/8022 ,  C08G2170/40 ,  C09J7/22 ,  C09J7/38 ,  C09J7/385 ,  C09J2433/00 ,  Y10T428/1059 ,  Y10T428/24438 ,  Y10T428/28 ,  Y10T428/2826 ,  Y10T428/2887 ,  Y10T428/3175 ,  Y10T428/31797 ,  Y10T428/31909 ,  Y10T428/31913 ,  Y10T428/3192 ,  Y10T442/2738

摘要： Provided herein is a pressure sensitive adhesive for an optical film comprising: 100 parts by weight of a (meth)acrylic-based polymer (A) including an alkyl (meth)acrylate (a1) and a (meth)acrylic-based monomer containing a hydroxyl group (a2), as a copolymerizable component, in content in the range of from 0.01 to 5 parts by weight relative to 100 parts by weight of the alkyl (meth)acrylate (a1); 0.02 to 2 parts by weight of a peroxide (B); and 0.001 to 2 parts by weight of an isocyanate-based compound (C), the contents of the peroxide (B) and the isocyanate-based compound (C) being values relative to 100 parts by weight of the (meth)acrylic-based polymer (A).

摘要翻译： 本发明提供一种用于光学膜的压敏粘合剂，其包括：100重量份包含（甲基）丙烯酸烷基酯（a1）的（甲基）丙烯酸类聚合物（A）和（甲基）丙烯酸系单体，其包含 相对于100重量份的（甲基）丙烯酸烷基酯（a1），作为可共聚成分的羟基（a2）的含量范围为0.01〜5重量份。 0.02〜2重量份过氧化物（B）; 和0.001〜2重量份的异氰酸酯系化合物（C），过氧化物（B）和异氰酸酯系化合物（C）的含量相对于（甲基）丙烯酸系化合物（C）的100重量份 聚合物（A）。

公开(公告)号：US08685204B2

公开(公告)日：2014-04-01

申请号：US12864047

申请日：2009-01-20

申请人： Fumiko Nakano ,  Yutaka Moroishi ,  Aimi Matsuura ,  Toshitsugu Hosokawa ,  Akiko Tanaka

发明人： Fumiko Nakano ,  Yutaka Moroishi ,  Aimi Matsuura ,  Toshitsugu Hosokawa ,  Akiko Tanaka

IPC分类号： B32B38/10

CPC分类号： C09J5/06 ,  C08F2220/1825 ,  C08K5/14 ,  C08L33/08 ,  C09J7/385 ,  C09J133/08 ,  C09J2201/606 ,  C09J2205/302 ,  G02F1/1335 ,  G02F2202/28 ,  Y10T156/1126 ,  Y10T156/1153 ,  Y10T156/1911 ,  Y10T428/28 ,  C08F220/06 ,  C08F2220/281

摘要： An object of the invention is to provide a pressure-sensitive adhesive optical film-peeling method capable of easily detaching the pressure-sensitive adhesive optical film from a glass substrate with no damage to the glass substrate or no adhesive deposit on the glass substrate, and to provide a pressure-sensitive adhesive optical film suitable for use in such a peeling method. The invention is directed to a method for peeling a pressure-sensitive adhesive optical film from an optical film-carrying glass substrate including a glass substrate and the pressure-sensitive adhesive optical film bonded thereto, which includes: exposing the optical film-carrying glass substrate to an environment at a temperature of 40 to 98° C. and a relative humidity of 60 to 99% for three minutes or more; and then peeling the pressure-sensitive adhesive optical film from the glass substrate under the environment.

摘要翻译： 本发明的目的是提供一种能够容易地从玻璃基板上分离玻璃基板的粘合型光学膜剥离方法，而不会损伤玻璃基板，也可以不在玻璃基板上粘合， 以提供适合用于这种剥离方法的压敏粘合剂光学膜。 本发明涉及一种剥离由粘合有玻璃基板和粘合型光学膜的玻璃基板的带光学薄膜玻璃基板的粘合型光学薄膜的方法，该方法包括：将带光学薄膜的玻璃基板 温度为40〜98℃，相对湿度为60〜99％的环境3分钟以上; 然后在环境下从玻璃基板剥离压敏粘合剂光学膜。

公开(公告)号：US20100304134A1

公开(公告)日：2010-12-02

申请号：US12864047

申请日：2009-01-20

申请人： Fumiko Nakano ,  Yutaka Moroishi ,  Aimi Matsuura ,  Toshitsugu Hosokawa ,  Akiko Tanaka

发明人： Fumiko Nakano ,  Yutaka Moroishi ,  Aimi Matsuura ,  Toshitsugu Hosokawa ,  Akiko Tanaka

IPC分类号： B32B17/04 ,  B32B38/10

CPC分类号： C09J5/06 ,  C08F2220/1825 ,  C08K5/14 ,  C08L33/08 ,  C09J7/385 ,  C09J133/08 ,  C09J2201/606 ,  C09J2205/302 ,  G02F1/1335 ,  G02F2202/28 ,  Y10T156/1126 ,  Y10T156/1153 ,  Y10T156/1911 ,  Y10T428/28 ,  C08F220/06 ,  C08F2220/281

摘要： An object of the invention is to provide a pressure-sensitive adhesive optical film-peeling method capable of easily detaching the pressure-sensitive adhesive optical film from a glass substrate with no damage to the glass substrate or no adhesive deposit on the glass substrate, and to provide a pressure-sensitive adhesive optical film suitable for use in such a peeling method. The invention is directed to a method for peeling a pressure-sensitive adhesive optical film from an optical film-carrying glass substrate including a glass substrate and the pressure-sensitive adhesive optical film bonded thereto, which includes: exposing the optical film-carrying glass substrate to an environment at a temperature of 40 to 98° C. and a relative humidity of 60 to 99% for three minutes or more; and then peeling the pressure-sensitive adhesive optical film from the glass substrate under the environment.

摘要翻译： 本发明的目的是提供一种能够容易地从玻璃基板上分离玻璃基板的粘合型光学膜剥离方法，而不会损伤玻璃基板，也可以不在玻璃基板上粘合， 以提供适合用于这种剥离方法的压敏粘合剂光学膜。 本发明涉及一种剥离由粘合有玻璃基板和粘合型光学膜的玻璃基板的带光学薄膜玻璃基板的粘合型光学薄膜的方法，该方法包括：将带光学薄膜的玻璃基板 温度为40〜98℃，相对湿度为60〜99％的环境3分钟以上; 然后在环境下从玻璃基板剥离压敏粘合剂光学膜。

公开(公告)号：US07435779B2

公开(公告)日：2008-10-14

申请号：US11290165

申请日：2005-11-30

申请人： Yuusuke Toyama ,  Masayuki Satake ,  Akiko Ogasawara ,  Yutaka Moroishi ,  Fumiko Nakano

发明人： Yuusuke Toyama ,  Masayuki Satake ,  Akiko Ogasawara ,  Yutaka Moroishi ,  Fumiko Nakano

IPC分类号： C08L33/14 ,  C09J133/14 ,  C09K19/38

CPC分类号： C09J175/04 ,  C08G18/289 ,  C08G18/6229 ,  C08G18/8022 ,  C08G2170/40 ,  C09J7/22 ,  C09J7/38 ,  C09J7/385 ,  C09J2433/00 ,  Y10T428/1059 ,  Y10T428/24438 ,  Y10T428/28 ,  Y10T428/2826 ,  Y10T428/2887 ,  Y10T428/3175 ,  Y10T428/31797 ,  Y10T428/31909 ,  Y10T428/31913 ,  Y10T428/3192 ,  Y10T442/2738

摘要： It is an object of the invention to provide a pressure sensitive adhesive for an optical film with which a pressure sensitive adhesive type optical film capable of suppressing bowing and light leakage caused by a stress accompanying a dimensional change of members such as an optical film, high in durability, excellent in handling ability in an aspect of a fabrication process thereof and good in quality can be obtained. There is provided a pressure sensitive adhesive for an optical film comprising: 100 parts by weight of a (meth)acrylic-based polymer (A) including an alkyl (meth)acrylate (a1) and a (meth)acrylic-based monomer containing a hydroxyl group (a2), as a copolymerizable component, in content in the range of from 0.01 to 5 parts by weight relative to 100 parts by weight of the alkyl (meth)acrylate (a1); 0.02 to 2 parts by weight of a peroxide (B); and 0.001 to 2 parts by weight of an isocyanate-based compound (C), the contents of the peroxide (B) and the isocyanate-based compound (C) being values relative to 100 parts by weight of the (meth)acrylic-based polymer (A).

摘要翻译： 本发明的目的是提供一种用于光学膜的压敏粘合剂，通过该压敏粘合剂型光学膜能够抑制伴随诸如光学膜的部件的尺寸变化的应力引起的弯曲和漏光 在耐久性方面，可以获得在其制造方法方面的良好的处理能力和良好的质量。 提供一种用于光学膜的压敏粘合剂，其包括：100重量份的包含（甲基）丙烯酸烷基酯（a1）的（甲基）丙烯酸类聚合物（A）和（甲基）丙烯酸类单体，其包含 相对于100重量份的（甲基）丙烯酸烷基酯（a1），作为可共聚成分的羟基（a2）的含量范围为0.01〜5重量份。 0.02〜2重量份过氧化物（B）; 和0.001〜2重量份的异氰酸酯系化合物（C），过氧化物（B）和异氰酸酯系化合物（C）的含量相对于（甲基）丙烯酸系化合物（C）的100重量份 聚合物（A）。

公开(公告)号：US20090022988A1

公开(公告)日：2009-01-22

申请号：US12203447

申请日：2008-09-03

申请人： Yuusuke Toyama ,  Masayuki Satake ,  Akiko Ogasawara ,  Yutaka Moroishi ,  Fumiko Nakano

发明人： Yuusuke Toyama ,  Masayuki Satake ,  Akiko Ogasawara ,  Yutaka Moroishi ,  Fumiko Nakano

IPC分类号： B32B7/12

CPC分类号： C09J175/04 ,  C08G18/289 ,  C08G18/6229 ,  C08G18/8022 ,  C08G2170/40 ,  C09J7/22 ,  C09J7/38 ,  C09J7/385 ,  C09J2433/00 ,  Y10T428/1059 ,  Y10T428/24438 ,  Y10T428/28 ,  Y10T428/2826 ,  Y10T428/2887 ,  Y10T428/3175 ,  Y10T428/31797 ,  Y10T428/31909 ,  Y10T428/31913 ,  Y10T428/3192 ,  Y10T442/2738

摘要： Provided herein is a pressure sensitive adhesive for an optical film comprising: 100 parts by weight of a (meth)acrylic-based polymer (A) including an alkyl (meth)acrylate (a1) and a (meth)acrylic-based monomer containing a hydroxyl group (a2), as a copolymerizable component, in content in the range of from 0.01 to 5 parts by weight relative to 100 parts by weight of the alkyl (meth)acrylate (a1); 0.02 to 2 parts by weight of a peroxide (B); and 0.001 to 2 parts by weight of an isocyanate-based compound (C), the contents of the peroxide (B) and the isocyanate-based compound (C) being values relative to 100 parts by weight of the (meth)acrylic-based polymer (A).

摘要翻译： 本发明提供一种用于光学膜的压敏粘合剂，其包括：100重量份包含（甲基）丙烯酸烷基酯（a1）的（甲基）丙烯酸类聚合物（A）和（甲基）丙烯酸系单体，其包含 相对于100重量份的（甲基）丙烯酸烷基酯（a1），作为可共聚成分的羟基（a2）的含量范围为0.01〜5重量份。 0.02〜2重量份过氧化物（B）; 和0.001〜2重量份的异氰酸酯系化合物（C），过氧化物（B）和异氰酸酯系化合物（C）的含量相对于（甲基）丙烯酸系化合物（C）的100重量份 聚合物（A）。

公开(公告)号：US20090233102A1

公开(公告)日：2009-09-17

申请号：US11720688

申请日：2005-11-17

申请人： Yuusuke Toyama ,  Masayuki Satake ,  Akiko Ogasawara ,  Yutaka Moroishi ,  Fumiko Nakano

发明人： Yuusuke Toyama ,  Masayuki Satake ,  Akiko Ogasawara ,  Yutaka Moroishi ,  Fumiko Nakano

IPC分类号： B32B27/40 ,  C08K3/18 ,  B05D3/00

CPC分类号： C09J175/04 ,  C08G18/7642 ,  C08G2170/40 ,  C09J133/04 ,  G02B5/30 ,  Y10T428/31551

摘要： The invention relates to a pressure-sensitive adhesive for an optical film, comprising 0.02 to 2 parts by weight of a peroxide (B) and 0.01 to 5 parts by weight of an isocyanate-based compound (C) contained in 100 parts by weight of a (meth)acrylic polymer (A) consisting primarily of an alkyl(meth)acrylate and not containing a functional group reactive with an isocyanate group. By using the invented pressure-sensitive adhesive for an optical film, there can be obtained a pressure sensitive adhesion type optical film that can suppress warping and light leakage caused by a stress accompanying a dimensional change of members such as an optical film, has high durability, is excellent in handling ability in the manufacturing process and is excellent in quality.

摘要翻译： 本发明涉及一种用于光学膜的压敏粘合剂，其包含0.02至2重量份的过氧化物（B）和0.01至5重量份的异氰酸酯基化合物（C），其包含在100重量份的 主要由（甲基）丙烯酸烷基酯组成的不含与异氰酸酯基反应的官能团的（甲基）丙烯酸聚合物（A）。 通过使用本发明的光学膜用粘合剂，可以获得能够抑制伴随光学膜等构件的尺寸变化的应力引起的翘曲和漏光的压敏粘合型光学膜，具有高耐久性 ，在制造工序中的处理能力优异，质量优异。

公开(公告)号：US20060121273A1

公开(公告)日：2006-06-08

申请号：US11290165

申请日：2005-11-30

申请人： Yuusuke Toyama ,  Masayuki Satake ,  Akiko Ogasawara ,  Yutaka Moroishi ,  Fumiko Nakano

发明人： Yuusuke Toyama ,  Masayuki Satake ,  Akiko Ogasawara ,  Yutaka Moroishi ,  Fumiko Nakano

IPC分类号： B32B27/04 ,  D06N3/00 ,  B32B7/12

CPC分类号： C09J175/04 ,  C08G18/289 ,  C08G18/6229 ,  C08G18/8022 ,  C08G2170/40 ,  C09J7/22 ,  C09J7/38 ,  C09J7/385 ,  C09J2433/00 ,  Y10T428/1059 ,  Y10T428/24438 ,  Y10T428/28 ,  Y10T428/2826 ,  Y10T428/2887 ,  Y10T428/3175 ,  Y10T428/31797 ,  Y10T428/31909 ,  Y10T428/31913 ,  Y10T428/3192 ,  Y10T442/2738

摘要： It is an object of the invention to provide a pressure sensitive adhesive for an optical film with which a pressure sensitive adhesive type optical film capable of suppressing bowing and light leakage caused by a stress accompanying a dimensional change of members such as an optical film, high in durability, excellent in handling ability in an aspect of a fabrication process thereof and good in quality can be obtained. There is provided a pressure sensitive adhesive for an optical film comprising: 100 parts by weight of a (meth)acrylic-based polymer (A) including an alkyl (meth)acrylate (a1) and a (meth)acrylic-based monomer containing a hydroxyl group (a2), as a copolymerizable component, in content in the range of from 0.01 to 5 parts by weight relative to 100 parts by weight of the alkyl (meth)acrylate (a1); 0.02 to 2 parts by weight of a peroxide (B); and 0.001 to 2 parts by weight of an isocyanate-based compound (C), the contents of the peroxide (B) and the isocyanate-based compound (C) being values relative to 100 parts by weight of the (meth)acrylic-based polymer (A).

摘要翻译： 本发明的目的是提供一种用于光学膜的压敏粘合剂，通过该压敏粘合剂型光学膜能够抑制伴随诸如光学膜的部件的尺寸变化的应力引起的弯曲和漏光 在耐久性方面，可以获得在其制造方法方面的良好的处理能力和良好的质量。 提供一种用于光学膜的压敏粘合剂，其包括：100重量份的包含（甲基）丙烯酸烷基酯（a1）的（甲基）丙烯酸类聚合物（A）和（甲基）丙烯酸类单体，其包含 相对于100重量份的（甲基）丙烯酸烷基酯（a1），作为可共聚成分的羟基（a2）的含量范围为0.01〜5重量份。 0.02〜2重量份过氧化物（B）; 和0.001〜2重量份的异氰酸酯系化合物（C），过氧化物（B）和异氰酸酯系化合物（C）的含量相对于（甲基）丙烯酸系化合物（C）的100重量份 聚合物（A）。

公开(公告)号：US08399090B2

公开(公告)日：2013-03-19

申请号：US12090159

申请日：2006-10-17

申请人： Kohei Yano ,  Shinichi Inoue ,  Masayuki Satake ,  Yutaka Moroishi ,  Fumiko Nakano

发明人： Kohei Yano ,  Shinichi Inoue ,  Masayuki Satake ,  Yutaka Moroishi ,  Fumiko Nakano

IPC分类号： B32B7/12 ,  C08F8/32 ,  C08F2/46

CPC分类号： C09J135/02 ,  C08G18/6229 ,  C08G18/6283 ,  C08G18/7843 ,  C08G2170/40 ,  C09J133/06 ,  C09J133/24 ,  C09J175/04 ,  G02B5/3025 ,  G02B5/3083 ,  G02F2202/28 ,  Y10T428/28 ,  Y10T428/2891

摘要： This invention provides a pressure-sensitive adhesive composition that exhibits excellent pressure-sensitive adhesive properties after crosslinking treatment, does not cause lifting or lifting upon heat treatment or treatment under high-humidity conditions particularly even in the case of a pressure-sensitive adhesive layer having a reduced layer thickness, and has excellent durability. A pressure-sensitive adhesive layer formed using the pressure-sensitive adhesive composition, and a process for producing the same are also provided. Further, an optical member with pressure-sensitive adhesive comprising the pressure-sensitive adhesive layer and an image display using the same are provided. The pressure-sensitive adhesive composition is characterized by comprising 100 parts by weight of an (meth)acrylic polymer and 0.02 to 2 parts by weight of a peroxide, and 0.02 to 2 parts by weight of an isocyanate crosslinking agent, the (meth)acrylic polymer comprising as monomer units 50 to 98% by weight of an (meth)acrylic monomer represented by general formula CH2═C(R1)COOR2, wherein R1 represents hydrogen or a methyl group and R2 represents an alkyl group having 2 to 14 carbon atoms, and 0.1 to 35% by weight of a nitrogen-containing monomer.

摘要翻译： 本发明提供了一种在交联处理后表现出优异的压敏粘合剂性能的粘合剂组合物，即使在压敏粘合剂层的情况下，在高湿度条件下也不引起提升或提升， 降低层厚度，并且具有优异的耐久性。 还提供了使用该压敏粘合剂组合物形成的压敏粘合剂层及其制造方法。 此外，提供了包含压敏粘合剂层的压敏粘合剂的光学部件和使用其的图像显示器。 该压敏粘合剂组合物的特征在于包含100重量份的（甲基）丙烯酸类聚合物和0.02-2重量份的过氧化物，和0.02-2重量份的异氰酸酯交联剂，（甲基）丙烯酸 包含作为单体单元的聚合物50至98重量％的由通式CH 2 = C（R 1）COOR 2表示的（甲基）丙烯酸单体，其中R 1表示氢或甲基，R 2表示具有2至14个碳原子的烷基 ，和0.1〜35重量％的含氮单体。

公开(公告)号：US20090042004A1

公开(公告)日：2009-02-12

申请号：US12090159

申请日：2006-10-17

申请人： Kohei Yano ,  Shinichi Inoue ,  Masayuki Satake ,  Yutaka Moroishi ,  Fumiko Nakano

发明人： Kohei Yano ,  Shinichi Inoue ,  Masayuki Satake ,  Yutaka Moroishi ,  Fumiko Nakano

IPC分类号： B32B27/36 ,  B05D3/00 ,  B05D5/06 ,  C08F8/30

CPC分类号： C09J135/02 ,  C08G18/6229 ,  C08G18/6283 ,  C08G18/7843 ,  C08G2170/40 ,  C09J133/06 ,  C09J133/24 ,  C09J175/04 ,  G02B5/3025 ,  G02B5/3083 ,  G02F2202/28 ,  Y10T428/28 ,  Y10T428/2891

摘要： This invention provides a pressure-sensitive adhesive composition that exhibits excellent pressure-sensitive adhesive properties after crosslinking treatment, does not cause lifting or lifting upon heat treatment or treatment under high-humidity conditions particularly even in the case of a pressure-sensitive adhesive layer having a reduced layer thickness, and has excellent durability. A pressure-sensitive adhesive layer formed using the pressure-sensitive adhesive composition, and a process for producing the same are also provided. Further, an optical member with pressure-sensitive adhesive comprising the pressure-sensitive adhesive layer and an image display using the same are provided. The pressure-sensitive adhesive composition is characterized by comprising 100 parts by weight of an (meth)acrylic polymer and 0.02 to 2 parts by weight of a peroxide, and 0.02 to 2 parts by weight of an isocyanate crosslinking agent, the (meth)acrylic polymer comprising as monomer units 50 to 98% by weight of an (meth)acrylic monomer represented by general formula CH2═C(R1)COOR2, wherein R1 represents hydrogen or a methyl group and R2 represents an alkyl group having 2 to 14 carbon atoms, and 0.1 to 35% by weight of a nitrogen-containing monomer.

摘要翻译： 本发明提供了一种在交联处理后表现出优异的压敏粘合剂性能的粘合剂组合物，即使在压敏粘合剂层的情况下，在高湿度条件下也不引起提升或提升， 降低层厚度，并且具有优异的耐久性。 还提供了使用该压敏粘合剂组合物形成的压敏粘合剂层及其制造方法。 此外，提供了包含压敏粘合剂层的压敏粘合剂的光学部件和使用其的图像显示器。 该压敏粘合剂组合物的特征在于包含100重量份的（甲基）丙烯酸类聚合物和0.02-2重量份的过氧化物，和0.02-2重量份的异氰酸酯交联剂，（甲基）丙烯酸 包含作为单体单元的聚合物50至98重量％的由通式CH 2 -C（R 1）COOR 2表示的（甲基）丙烯酸单体，其中R 1表示氢或甲基，R 2表示具有2至14个碳原子的烷基 ，和0.1〜35重量％的含氮单体。