公开(公告)号：US5310800A

公开(公告)日：1994-05-10

申请号：US860192

申请日：1992-03-26

申请人： Shizuo Shimizu ,  Akira Uchiyama ,  Kunihide Hiraoka ,  Katsuo Okamoto ,  Yasuhiko Otawa

发明人： Shizuo Shimizu ,  Akira Uchiyama ,  Kunihide Hiraoka ,  Katsuo Okamoto ,  Yasuhiko Otawa

IPC分类号： C08F255/00 ,  C08K5/14 ,  C08L23/16 ,  C08L23/26

CPC分类号： C08K5/14 ,  C08F255/00 ,  C08L23/10 ,  C08L23/16 ,  C08L2312/02

摘要： A partially crosslinked thermoplastic elastomer composition having an excellent heat-bondability is obtained by dynamically heat-treating a peroxide-crosslinking olefin copolymer rubber with an .alpha.,.beta.-unsaturated carboxylic acid or a derivative thereof in the presence of an organic peroxide.

摘要翻译： 通过在有机过氧化物的存在下用α，β-不饱和羧酸或其衍生物动态热处理过氧化物交联的烯烃共聚物橡胶，获得具有优异的热粘合性的部分交联的热塑性弹性体组合物。

公开(公告)号：US5061572A

公开(公告)日：1991-10-29

申请号：US412625

申请日：1989-09-26

申请人： Shunichi Hamada ,  Akira Uchiyama ,  Katsuo Okamoto

发明人： Shunichi Hamada ,  Akira Uchiyama ,  Katsuo Okamoto

IPC分类号： B32B25/10 ,  B32B25/14 ,  B32B27/12 ,  C08J7/04 ,  D06N3/00 ,  D06N3/04 ,  D06N3/10 ,  D06N3/18

CPC分类号： D06N3/10 ,  B32B27/12 ,  D06N3/045 ,  D06N3/183 ,  Y10S428/904 ,  Y10T428/31913 ,  Y10T442/3886 ,  Y10T442/678

摘要： A thermoplastic elastomer laminate comprising: a base fabric, a polyolefin intermediate layer formed on said fabric comprising a polyolefin, at least a part of which is modified by grafting with at least one monomer selected from unsaturated carboxylic acids and derivatives thereof, and a thermoplastic elastomer surface layer formed on said intermediate layer comprising a thermoplastic elastomer. The surface layer is comprised of a composition comprising: a polyolefin resin and an ethylene/alpha-olefin copolymer rubber, in which only said copolymer rubber is, or both said copolymer rubber and at least a part of said polyolefin resin are partially crosslinked. The product is attractive as an artificial leather.

公开(公告)号：US4889762A

公开(公告)日：1989-12-26

申请号：US137054

申请日：1987-12-23

申请人： Akira Uchiyama ,  Katsuo Okamoto

发明人： Akira Uchiyama ,  Katsuo Okamoto

IPC分类号： C08J7/04 ,  D06N7/02

CPC分类号： C08J7/042 ,  C08J2323/16 ,  Y10S428/901 ,  Y10T428/24802 ,  Y10T428/24975 ,  Y10T428/259 ,  Y10T428/31565 ,  Y10T428/31587 ,  Y10T428/31797 ,  Y10T428/31913

摘要： Molded articles of thermoplastic elastomer obtained in accordance with the present invention comprise a molded product prepared from a thermoplastic elastomer containing a partially cross-linked product of ethylene/.alpha.-olefin copolymer rubber and a polyolefin resin, a primer layer containing at least one compound selected from the group of saturated polyesters and chlorinated polyolefins and formed on the surface of said molded article, and a topcoat layer containing at least one compound selected from the group of saturated polyesters, acrylic ester resins, polyvinyl chloride and polyisocyanate (provided that the topcoat layer contains at least the acrylic ester resin when the primer layer consists only of the saturated polyester) and formed on said primer layer. The molded articles of the invention mentioned above have such excellent surface characteristics that the surface thereof is hard to get a scratch, excellent in appearance as well as in touch and, moreover, is hard to subject to attack by hydrocarbon solvents.

公开(公告)号：US5188882A

公开(公告)日：1993-02-23

申请号：US804591

申请日：1991-12-10

申请人： Akira Uchiyama ,  Naoaki Jimbo ,  Shizuo Shimizu

发明人： Akira Uchiyama ,  Naoaki Jimbo ,  Shizuo Shimizu

IPC分类号： B29C45/14 ,  B32B27/08

CPC分类号： B29C45/14811 ,  B32B27/08 ,  B29C2045/14844 ,  B29C45/1418 ,  Y10T428/24504 ,  Y10T428/249981 ,  Y10T428/249992 ,  Y10T428/249993 ,  Y10T428/31913

摘要： A multilayered molding is disclosed, which has a base molding outer layer mainly composed of a partial crosslinking type substance A obtained from polyolefin resin and ethylene-.alpha.-olefin copolymer rubber or a mixture B of polyolefin resin and ethylene-.alpha.-olefin copolymer rubber or both. The outermost layer is in direct contact with and forms a lamination with an inner intermediate layer or a base molding composed of a polyethylene resin, for instance, and is firmly bonded to the outermost layer. A method of manufacturing such multilayered molding is also disclosed, in which a composite sheet of the thermoplastic elastomer with or without the intermediate layer is preliminarily heated, followed by being suction held in close contact with a mold cavity inner surface, thus forming a surface layer. The mold is then clamped, and fluidized and plasticized polyolefin resin is injected to produce the molding. The polyolefin resin may also be injected prior to the clamping.

摘要翻译： 公开了一种多层成型体，其具有主要由聚烯烃树脂和乙烯-α-烯烃共聚物橡胶得到的部分交联型物质A或聚烯烃树脂和乙烯-α-烯烃共聚物橡胶的混合物B的基础成型外层，或 都。 最外层例如与内部中间层或由聚乙烯树脂构成的基底模塑件直接接触并形成层压，并且牢固地结合到最外层。 还公开了制造这种多层成型体的方法，其中预先加热具有或不具有中间层的热塑性弹性体的复合片材，然后与模具腔内表面紧密接触地吸附，从而形成表面层 。 然后将模具夹紧，并注入流化和增塑的聚烯烃树脂以制备模制品。 聚烯烃树脂也可以在夹紧之前被注入。

公开(公告)号：US5609703A

公开(公告)日：1997-03-11

申请号：US412515

申请日：1995-03-27

申请人： Shun-ichi Hamada ,  Akira Uchiyama ,  Shizuo Shimizu

发明人： Shun-ichi Hamada ,  Akira Uchiyama ,  Shizuo Shimizu

IPC分类号： B32B5/18 ,  B29C44/04 ,  B29C44/06 ,  B29C67/24 ,  B32B5/20 ,  B32B25/08 ,  B32B27/08 ,  B32B27/32 ,  B32B37/06 ,  B60C9/28

CPC分类号： B29C44/321 ,  B29K2021/00 ,  B29K2023/00 ,  Y10T156/1031 ,  Y10T156/1044 ,  Y10T428/249988

摘要： In accordance with the present invention, there is provided a process for preparing thermoplastic elastomer laminates which comprises placing a thermoplastic elastomer foamable sheet in an unexpanded state containing a polyolefin resin, an ethylene/.alpha.-olefin copolymer rubber and a foaming agent onto the back of a thermoplastic elastomer sheet containing a polyolefin resin and an ethylene/.alpha.-olefin copolymer rubber, heat fusion bonding both sheets to each other, and heating the resulting laminated sheet to expand the thermoplastic elastomer sheet containing the foaming agent.

摘要翻译： 根据本发明，提供一种制备热塑性弹性体层压材料的方法，该方法包括将含有聚烯烃树脂，乙烯/α-烯烃共聚物橡胶和发泡剂的未发泡状态的热塑性弹性体可发泡片材放置在 含有聚烯烃树脂和乙烯/α-烯烃共聚物橡胶的热塑性弹性体片，将两片热熔接合，并加热得到的层压片，使包含发泡剂的热塑性弹性体片膨胀。

公开(公告)号：US5096652A

公开(公告)日：1992-03-17

申请号：US593499

申请日：1990-10-04

申请人： Akira Uchiyama ,  Naoaki Jimbo ,  Shizuo Shimizu

发明人： Akira Uchiyama ,  Naoaki Jimbo ,  Shizuo Shimizu

IPC分类号： B29C45/14 ,  B32B27/08

CPC分类号： B29C45/14811 ,  B32B27/08 ,  B29C2045/14844 ,  B29C45/1418

摘要： A multilayered molding is disclosed, which has a base molding outer layer mainly composed of a partial crosslinking type substance A obtained from polyolefin resin and ethylene-.alpha.-olefin copolymer rubber or a mixture B of polyolefin resin and ethylene-.alpha.-olefin copolymer rubber or both. The outermost layer is in direct contact with and forms a lamination with an inner intermediate layer or a base molding composed of a polyethylene resin, for instance, and is firmly bonded to the outermost layer. A method of manufacturing such multilayered molding is also disclosed, in which a composite sheet of the thermoplastic elastomer with or without the intermediate layer is preliminarily heated, followed by being suction held in close contact with a mold cavity inner surface, thus forming a surface layer. The mold is then clamped, and fluidized and plasticized polyolein resin is injected to produce the molding. The polyolefin resin may also be injected prior to the clamping.

公开(公告)号：US20090127649A1

公开(公告)日：2009-05-21

申请号：US12292452

申请日：2008-11-19

申请人： Akira Uchiyama

发明人： Akira Uchiyama

IPC分类号： H01L21/762 ,  H01L29/06

CPC分类号： H01L21/76264 ,  H01L21/28123 ,  H01L29/66772 ,  H01L29/78654

摘要： According to the present invention, a semiconductor device includes a semiconductor layer; a device-isolation region formed in the semiconductor layer; an active region surrounded by the device isolation region; and a gap, formed at boundary between the device isolation region and the active region. The gap is not formed under the active region. The gap is formed on a side wall portion of the active region, which extends in a depth direction.

摘要翻译： 根据本发明，半导体器件包括半导体层; 形成在所述半导体层中的器件隔离区; 被器件隔离区包围的有源区; 以及形成在器件隔离区域和有源区域之间的边界处的间隙。 在活性区域之下不形成间隙。 间隙形成在有源区域的沿深度方向延伸的侧壁部分上。

公开(公告)号：US07049356B2

公开(公告)日：2006-05-23

申请号：US09779558

申请日：2001-02-09

申请人： Yuichi Itoh ,  Kunihiko Mizumoto ,  Hiroyasu Yamaoka ,  Akira Uchiyama

发明人： Yuichi Itoh ,  Kunihiko Mizumoto ,  Hiroyasu Yamaoka ,  Akira Uchiyama

IPC分类号： C08L91/00 ,  C08L9/00 ,  C08J3/24

CPC分类号： C08L23/04 ,  C08L23/0815 ,  C08L23/10 ,  C08L23/16 ,  C08L2207/04 ,  C08L2312/00 ,  C08L2666/04

摘要： This invention relates to a perfectly or partially crosslinked olefinic thermoplastic elastomer composition which comprises 10 to 90 parts by weight of a crystalline polyolefin (a), 90 to 10 parts by weight of an olefin-based copolymer rubber (b) (the total amount of the components (a) and (b) being 100 parts by weight) and 3 to 100 parts by weight of a paraffinic mineral oil softening agent (c) having an evaporation loss of 0.4% by weight or less at a condition of 200° C., atmospheric pressure and 1 hour and having a kinetic viscosity (40° C.) of 50 to 250 cSt; an olefinic thermoplastic elastomer composition which is obtainable by subjecting a mixture including 40 to 85 parts by weight of an ethylene-based copolymer rubber (A), 60 to 15 parts by weight of an olefinic resin (B) and 45 parts by weight or less of a softening agent (C) [the total amount of the components (A), (B) and (C) being 100 parts by weight] to dynamic heat treatment in the presence of a crossliking agent and which has a gloss value of 80% or more and a haze value of 10% or less on glass plate when subjected to the fogging test at a condition of 100° C. and 3 hours according to the prescription of A method of DIN 75201; and a manufacturing method and use of the compositions.

摘要翻译： 本发明涉及一种完全或部分交联的烯烃热​​塑性弹性体组合物，其包含10至90重量份的结晶聚烯烃（a），90至10重量份的烯烃基共聚物橡胶（b）（总计 组分（a）和（b）为100重量份）和3至100重量份在200℃条件下蒸发损失为0.4重量％以下的石蜡矿物油软化剂（c） 大气压和1小时，动力粘度（40℃）为50〜250cSt; 烯烃类热塑性弹性体组合物，其通过使含有乙烯系共聚物橡胶（A）40〜85重量份，烯烃系树脂（B）60〜15重量份和45重量份以下的混合物 的软化剂（C）[组分（A），（B）和（C）的总量为100重量份]在光泽剂存在下进行动态热处理，其光泽值为80 ％以上，雾度值为10％以下时，在100℃，3小时的条件下进行雾化试验时，根据DIN75201A法的处方， 以及组合物的制造方法和用途。

公开(公告)号：US06723794B2

公开(公告)日：2004-04-20

申请号：US10066575

申请日：2002-02-06

申请人： Masaaki Kawasaki ,  Keiji Okada ,  Tetsuo Tojo ,  Kyoko Kobayashi ,  Yuichi Itoh ,  Akira Uchiyama ,  Toshiyuki Tsutsui ,  Toshihiro Sagane

发明人： Masaaki Kawasaki ,  Keiji Okada ,  Tetsuo Tojo ,  Kyoko Kobayashi ,  Yuichi Itoh ,  Akira Uchiyama ,  Toshiyuki Tsutsui ,  Toshihiro Sagane

IPC分类号： C08L2302

CPC分类号： C08L23/02 ,  A61J1/03 ,  B65D23/003 ,  B65D51/28 ,  C08K5/14 ,  C08L23/0815 ,  C08L23/10 ,  C08L23/142 ,  C08L23/16 ,  C08L23/22 ,  C08L91/00 ,  C08L2205/03 ,  C08L2207/04 ,  C08L2312/00 ,  C08L2666/04

摘要： An olefin thermoplastic elastomer composition comprises a crystalline polyolefin resin (A) and an ethylene/&agr;-olefin/nonconjugated polyene copolymer rubber (B), and optionally a softener (C) and/or an inorganic filler (D), in a specific ratio. The copolymer rubber (B) is prepared by the use of a metallocene catalyst and comprises ethylene, an &agr;-olefin of 3 to 20 carbon atoms and a nonconjugated polyene. This composition ca provide molded products of more excellent tensile strength, elongation at break, elastomeric properties (elongation set, permanent compression set, etc.), heat resistance and low-temperature properties than the conventional non-crosslinked olefin thermoplastic elastomers, even if the composition is in the non-crosslinked form. The composition in the partially or completely crosslinked form can provided molded products of more excellent low-temperature properties, tensile strength, elongation at break and elastomeric properties than the conventional vulcanized rubbers.

摘要翻译： 烯烃热塑性弹性体组合物包含结晶聚烯烃树脂（A）和乙烯/α-烯烃/非共轭多烯共聚物橡胶（B）和任选的软化剂（C）和/或无机填料（D） 。 共聚物橡胶（B）通过使用茂金属催化剂制备，包括乙烯，3-20个碳原子的α-烯烃和非共轭多烯。 该组合物提供比常规非交联烯烃热塑性弹性体更优异的拉伸强度，断裂伸长率，弹性体性能（伸长率设定，永久压缩变形等），耐热性和低温性能的成型产品，即使 组合物为非交联形式。 部分或完全交联形式的组合物可以提供比常规硫化橡胶更优异的低温性能，拉伸强度，断裂伸长率和弹性体性能的成型产品。

公开(公告)号：US06599981B2

公开(公告)日：2003-07-29

申请号：US09988058

申请日：2001-11-16

申请人： Yuichi Itoh ,  Akira Uchiyama

发明人： Yuichi Itoh ,  Akira Uchiyama

IPC分类号： C08L2704

CPC分类号： B29C47/60 ,  B29C47/0009 ,  B29C47/38 ,  B29C47/402

摘要： This invention relates to a method for manufacturing an olefinic thermoplastic elastomer composition, characterized by disposing specific kneading segment at least at one place of the screw on the occasion of manufacturing an olefinic thermoplastic elastomer composition comprising a polyolefin resin and a crosslinked rubber by dynamic crosslinking with a twin screw extruder.

摘要翻译： 烯烃类热塑性弹性体组合物的制造方法技术领域本发明涉及烯烃类热塑性弹性体组合物的制造方法，其特征在于，在制造含有聚烯烃树脂和交联橡胶的烯烃类热塑性弹性体组合物的情况下，至少在螺杆的一个位置配置特定的混炼段， 双螺杆挤出机。