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    Magnesium compound, olefin polymerization catalyst, and method for producing olefin polymer
    1.
    发明授权
    Magnesium compound, olefin polymerization catalyst, and method for producing olefin polymer 有权
    镁化合物，烯烃聚合催化剂和烯烃聚合物的制造方法

    公开(公告)号：US07220694B2

    公开(公告)日：2007-05-22

    申请号：US10831327

    申请日：2004-04-26

    申请人： Shohjiroh Tanase ,  Takehiro Tsuda ,  Tsuyoshi Ota ,  Hideo Funabashi

    发明人： Shohjiroh Tanase ,  Takehiro Tsuda ,  Tsuyoshi Ota ,  Hideo Funabashi

    IPC分类号： B01J31/00

    CPC分类号： C08F110/06 ,  C08F4/6565 ,  C08F2500/18 ,  C08F2500/24

    摘要： The invention relates to a magnesium compound effective in producing olefin polymers having an increased bulk density and a narrowed particle size distribution, not lowering the stereospecificity of the polymers produced and not lowering the polymerization activity in producing the polymers, to an olefin polymerization catalyst comprising the compound, and to a method for producing such olefin polymers. The olefin polymerization catalyst comprises (A) a solid catalyst component prepared by contacting a magnesium compound having a specific particle size distribution index (P), a titanium compound and an electron donor compound with each other, (B) an organometallic compound, and (C) an electron donor. The olefin polymerization method comprises polymerizing an olefin in the presence of the catalyst to give olefin polymers.

    摘要翻译： 本发明涉及一种有效地生产烯烃聚合物的镁化合物，该烯烃聚合物具有增加的堆积密度和较窄的粒度分布，不降低所生产的聚合物的立体定向性，并且不降低制备聚合物时的聚合活性， 化合物，以及这种烯烃聚合物的制造方法。 烯烃聚合催化剂包括（A）通过使具有特定粒度分布指数（P）的镁化合物，钛化合物和电子给体化合物彼此接触而制备的固体催化剂组分，（B）有机金属化合物和（ C）电子给体。 烯烃聚合方法包括在催化剂存在下使烯烃聚合，得到烯烃聚合物。

    Catalyst for bulk polymerization, catalyst for vapor phase polymerization, method of polymerization using these, and olefin polymer obtained with these
    9.
    发明授权
    Catalyst for bulk polymerization, catalyst for vapor phase polymerization, method of polymerization using these, and olefin polymer obtained with these 失效
    用于本体聚合的催化剂，用于气相聚合的催化剂，使用它们的聚合方法以及用它们获得的烯烃聚合物

    公开(公告)号：US06689849B1

    公开(公告)日：2004-02-10

    申请号：US10018478

    申请日：2001-12-19

    申请人： Takanori Sadashima ,  Masami Kanamaru ,  Tsuyoshi Ota ,  Hideo Funabashi

    发明人： Takanori Sadashima ,  Masami Kanamaru ,  Tsuyoshi Ota ,  Hideo Funabashi

    IPC分类号： C08F442

    CPC分类号： C08F110/06 ,  Y10S526/901 ,  Y10S526/902 ,  C08F4/6565 ,  C08F4/6465 ,  C08F2500/12 ,  C08F2500/17

    摘要： The present invention provides a catalyst for bulk or vapor-phase polymerization having high polymerization activity during bulk or vapor-phase polymerization and providing an olefin polymer having excellent properties in melt flow rate and stereoregularity by adding a small amount of hydrogen. The catalyst for bulk or vapor-phase polymerization of an &agr;-olefin compound under a presence of hydrogen, the catalyst is made by contacting the following ingredients (A) to (C). (A) a solid catalyst ingredient, comprising: (a) a magnesium compound, (b) titanium tetrachloride, and (c) dialkyl phthalate (Each of the alkyl group denotes a straight-chain or branched-chain hydrocarbon group having a carbon number of 3 to 20.); (B) an organoaluminum compound; and (C) an organosilicon compound, which is expressed by the following general chemical formula (1). (R1)(R2CH2)Si(OR3)(OR4)  (1)

    摘要翻译： 本发明提供一种用于本体或气相聚合时具有高聚合活性的本体或气相聚合催化剂，并通过加入少量氢提供具有优异的熔体流动速率和立构规整性的烯烃聚合物。本体催化剂 或在氢气存在下气相聚合α-烯烃化合物，催化剂是通过使以下成分（A）与（C）接触来制备的。（A）固体催化剂成分，其包含：（a）镁化合物 ，（b）四氯化钛和（c）邻苯二甲酸二烷基酯（每个烷基表示碳数为3〜20的直链或支链烃基）;（B）有机铝化合物; 和（C）由以下通式（1）表示的有机硅化合物。