公开(公告)号：US5084426A

公开(公告)日：1992-01-28

申请号：US379420

申请日：1989-07-13

申请人： Shoichi Iwaya ,  Hitoshi Masumura ,  Haruo Taguchi ,  Munemitsu Hamada ,  Tomohiro Sogabe ,  Shigeya Takahashi ,  Hiroyuki Satoh

发明人： Shoichi Iwaya ,  Hitoshi Masumura ,  Haruo Taguchi ,  Munemitsu Hamada ,  Tomohiro Sogabe ,  Shigeya Takahashi ,  Hiroyuki Satoh

IPC分类号： C04B35/46 ,  C04B35/47 ,  C04B35/472 ,  H01C7/02 ,  H01C7/04

CPC分类号： C04B35/47 ,  C04B35/472

摘要： A semiconductive ceramic composition capable of permitting its resistance-temperature characteristics and resistance to be controlled as desired and a firing temperature of the composition to be lowered to a degree sufficient to facilitate the mass-production at a low cost. The composition contains a main component consisting of SrO, PbO and TiO.sub.2 and is subjected to firing in an oxidizing atmosphere. The composition may contain at least one of SiO.sub.2 and M as a minor component. A variation in amount of the main and minor components permits characteristics and properties of the composition to be varied as desired.

公开(公告)号：US06172453B2

公开(公告)日：2001-01-09

申请号：US08341617

申请日：1994-11-17

申请人： Munemitsu Hamada ,  Masaru Fukuda ,  Haruo Taguchi ,  Shoichi Iwaya ,  Hiroaki Abe

发明人： Munemitsu Hamada ,  Masaru Fukuda ,  Haruo Taguchi ,  Shoichi Iwaya ,  Hiroaki Abe

IPC分类号： H01J102

CPC分类号： H01J61/067 ,  C04B35/465 ,  C04B35/486 ,  H01J9/022 ,  H01J61/0675 ,  H01J61/09 ,  H01J61/24 ,  H01J61/70 ,  H01J61/72 ,  H01J61/78

摘要： The present invention provides an electrode for a ceramic electrode fluorescent discharge lamp; an electrode material for a discharge lamp, which has high electron flow density, high thermal shock resistance, and reduced deterioration due to sputtering; and also a method for manufacturing the same. The invention makes it possible to reduce the tube diameter of the ceramic electrode fluorescent discharge lamp. An electrode material for a discharge lamp is obtained from a first component of 0.5 to 1.5 mols of BaO, CaO or SrO, a second component of 0.05 to less than 0.3 mols or more than 0.7 to 0.95 mols of ZrO2 or TiO2, and a third component of 0.025 to less than 0.3 mols of V2O5, Nb2O5, Ta2O5, Sc2O3, Y2O3, La2O3, Dy2O3, or Ho2O3, or 0.05 to less than 0.15 mols or more than 0.35 to 0.95 mols of HfO2, CrO3, MoO3 or WO3. This electrode material is granulated and is turned into a massive, granular, or porous electrode material. This is placed in a cylindrical semiconductor ceramic container with a closed bottom and is reduced and fired to prepare an electrode. A mercury dispenser of the ceramic electrode fluorescent discharge lamp is disposed in series between the cylindrical semiconductor ceramic container with a closed bottom and a lead-in portion of the lead wire.

摘要翻译： 本发明提供一种陶瓷电极荧光放电灯用电极， 用于放电灯的电极材料，其电子密度高，耐热冲击性高，并且由于溅射而导致的劣化降低; 以及其制造方法。 本发明可以减小陶瓷电极荧光放电灯的管径。 用于放电灯的电极材料由0.5至1.5摩尔的BaO，CaO或SrO的第一组分，0.05至小于0.3摩尔或大于0.7至0.95摩尔的ZrO 2或TiO 2的第二组分和第三组分 0.025至小于0.3摩尔的V 2 O 5，Nb 2 O 5，Ta 2 O 5，Sc 2 O 3，Y 2 O 3，La 2 O 3，Dy 2 O 3或Ho 2 O 3，或0.05至小于0.15摩尔或大于0.35至0.95摩尔的HfO 2，CrO 3，MoO 3或WO 3。 将该电极材料造粒并变成块状，粒状或多孔的电极材料。 将其放置在具有封闭底部的圆筒形半导体陶瓷容器中并且被还原和烧制以制备电极。 陶瓷电极荧光放电灯的水银分配器串联设置在具有封闭底部的圆筒形半导体陶瓷容器和引线的引入部分之间。

公开(公告)号：US4404029A

公开(公告)日：1983-09-13

申请号：US350379

申请日：1982-02-19

申请人： Shoichi Iwaya ,  Hitoshi Masumura ,  Yoshifumi Midori ,  Yasunobu Oikawa ,  Hisao Abe

发明人： Shoichi Iwaya ,  Hitoshi Masumura ,  Yoshifumi Midori ,  Yasunobu Oikawa ,  Hisao Abe

IPC分类号： H05B41/18 ,  C04B35/46 ,  C04B35/468 ,  H01B3/12 ,  H01G7/06 ,  H03K12/00 ,  C04B35/00

CPC分类号： C04B35/4682

摘要： A D-E hysteresis loop of ferroelectrics known in the art has a square shape when the ferroelectrics are a BaTiO.sub.3 single crystal. Such ferroelectrics are used as a non-linear dielectric element of, for example a pulse generating device. The non-linear dielectric element according to the present invention consists of a polycrystal mainly composed of Ba(Ti.sub.0.90-0.98 Sn.sub.0.02-1.00)O.sub.3 and having an average grain diameter of from 10 to 60 .mu.m. The non-linearity is excellent and the temperature dependence of the non-linearity is considerably low.

摘要翻译： 当铁电体是BaTiO 3单晶时，本领域已知的铁电体的D-E磁滞回线具有正方形形状。 这种铁电体用作例如脉冲发生装置的非线性介电元件。 根据本发明的非线性电介质元件由主要由Ba（Ti0.90-0.98Sn0.02-1.00）O3组成的平均粒径为10至60μm的多晶体组成。 非线性非常好，非线性的温度依赖性相当低。

公开(公告)号：US20100075219A1

公开(公告)日：2010-03-25

申请号：US12527430

申请日：2007-02-16

申请人： Shoichi Iwaya ,  Hitoshi Masumura ,  Noriyuki Sakai ,  Takayuki Fujita ,  Hiroshi Sasagawa ,  Hiroshi Sato ,  Hisao Fukumori

发明人： Shoichi Iwaya ,  Hitoshi Masumura ,  Noriyuki Sakai ,  Takayuki Fujita ,  Hiroshi Sasagawa ,  Hiroshi Sato ,  Hisao Fukumori

IPC分类号： H01M10/05 ,  H01M4/70 ,  H01M4/58 ,  H01M4/50 ,  H01M4/00 ,  H01M4/62 ,  H01M10/04 ,  H01M10/38

CPC分类号： H01M2/14 ,  H01M4/0471 ,  H01M4/13 ,  H01M4/139 ,  H01M4/485 ,  H01M4/505 ,  H01M4/525 ,  H01M4/58 ,  H01M4/624 ,  H01M4/661 ,  H01M10/0525 ,  H01M10/38

摘要： In multilayer wholly solid lithium ion secondary batteries, a laminate having a collector layer of material with high conductivity superimposed on an active material layer has been disposed so as to attain a lowering of battery impedance. Consequently, in the fabrication of each of positive electrode layer and negative electrode layer, stacking of three layers consisting of an active material layer, a collector layer and an active material layer has been needed, thereby posing the problem of complex processing and high production cost. In the invention, a positive electrode layer and a negative electrode layer are fabricated from paste consisting of active material mixed with conductive substance in a given mixing ratio, and no collector layer is disposed. This realizes process simplification and manufacturing cost reduction without deterioration of battery performance and has also been effective in enhancing of battery performance, such as improvement to cycle characteristics.

摘要翻译： 在多层全固体锂离子二次电池中，已经布置了具有叠加在活性物质层上的具有高导电性的材料的集电体层的层压体，以便获得电池阻抗的降低。 因此，在正极层和负极层的制造中，需要层叠由活性物质层，集电体层和活性物质层构成的3层，因此存在复杂的加工和高生产成本的问题 。 在本发明中，正极层和负极层由以与给定混合比例的与导电物质混合的活性物质组成的糊料制成，没有设置集电体层。 这实现了过程简化和制造成本的降低，而不会降低电池性能，并且还有效地提高电池性能，例如改善循环特性。

公开(公告)号：US4896436A

公开(公告)日：1990-01-30

申请号：US182604

申请日：1988-04-18

申请人： Shoichi Iwaya ,  Hitoshi Masumura ,  Hiroki Takahashi ,  Masaaki Ohkawara ,  Katsumi Kobayashi ,  Takashi Ito

发明人： Shoichi Iwaya ,  Hitoshi Masumura ,  Hiroki Takahashi ,  Masaaki Ohkawara ,  Katsumi Kobayashi ,  Takashi Ito

IPC分类号： B01D1/18

CPC分类号： B01D1/18 ,  Y10S159/02 ,  Y10S159/28

摘要： The spray drying process and the apparatus therefor, of the present invention use a spray drying chamber formed by a heat-resistant porous membrane. Said porous membrane enables rapid separation of a discharge gas and a produced powder and accordingly total recovery of the produced powder from the spray drying chamber. Therefore, there occurs no nonuniformity in product composition; cleaning and blowing-off of adhered fine powder can be conducted rapidly and easily even in frequent product changes inevitable with a less grade larger quantity production system; as a result, a fine powder of higher quality and higher purity can be produced.

公开(公告)号：US4484251A

公开(公告)日：1984-11-20

申请号：US425076

申请日：1982-09-20

申请人： Sho Masujima ,  Yoshishige Towatari ,  Shoichi Iwaya ,  Hitoshi Masumura ,  Hisao Abe ,  Norimasa Sakamoto

发明人： Sho Masujima ,  Yoshishige Towatari ,  Shoichi Iwaya ,  Hitoshi Masumura ,  Hisao Abe ,  Norimasa Sakamoto

IPC分类号： H01C7/115 ,  H01G7/06 ,  H01G4/10 ,  H01L29/12

CPC分类号： H01G7/06 ,  H01C7/115

摘要： A current restriction device for alternate circuit with small size, low producing cost and low power loss has been found by using a ferro-electric body with rectangular hysterisis characteristics. Said device is used for instance as a ballast for restricting current in a fluorescent lamp. Said ferro-electric body has main component of B.sub.a T.sub.i O.sub.3, additive of S.sub.r or P.sub.b for substitution of part of B.sub.a and Z.sub.n or S.sub.n for substitution of part of T.sub.i, and a mineralizer of M.sub.n o or C.sub.r2 O.sub.3. The voltage-current characteristics of said ferro-electric body show non-linearity that the impedance ratio (Z.sub.2 /Z.sub.1) of the impedance Z.sub.2 measured with alternate field of 500 volts/mm to the impedance Z.sub.1 measured with alternate field of 5 volts/mm is less than 1/10.

摘要翻译： PCT No.PCT / JP82 / 00047 Sec。 371日期1982年9月20日 102（e）1982年9月20日PCT提交1982年2月20日PCT公布。 出版物WO83 / 0302800 日期：1983年9月1日。通过使用具有矩形滞后特性的铁电体，发现了具有体积小，生产成本低，功率损耗小的交流电路限流装置。 所述装置例如用作限制荧光灯中的电流的镇流器。 所述铁电体具有BaTiO3的主要成分，Sr或Pb的添加剂，用于取代一部分Ba和Zn或Sn以取代部分Ti，以及MnO或Cr2O3的矿化剂。 所述铁电体的电压 - 电流特性显示出以500伏/毫米的交变场测量的阻抗Z2的阻抗比（Z2 / Z1）与以5伏/毫米的交变场测量的阻抗Z1的阻抗比（Z2 / Z1）非线性 小于1/10。

公开(公告)号：US08883347B2

公开(公告)日：2014-11-11

申请号：US12302250

申请日：2007-02-13

申请人： Mamoru Baba ,  Shoichi Iwaya ,  Hitoshi Masumura ,  Hiroshi Sato ,  Hiroshi Sasagawa ,  Noriyuki Sakai ,  Takayuki Fujita

发明人： Mamoru Baba ,  Shoichi Iwaya ,  Hitoshi Masumura ,  Hiroshi Sato ,  Hiroshi Sasagawa ,  Noriyuki Sakai ,  Takayuki Fujita

IPC分类号： H01M4/13 ,  H01M10/04 ,  H01M4/66 ,  H01M10/0525 ,  H01M10/0562 ,  H01M10/0585

CPC分类号： H01M4/0404 ,  H01M4/0414 ,  H01M4/0471 ,  H01M4/485 ,  H01M4/622 ,  H01M4/661 ,  H01M4/666 ,  H01M10/044 ,  H01M10/0525 ,  H01M10/0562 ,  H01M10/0585 ,  Y02E60/122 ,  Y02P70/54 ,  Y10T29/49108

摘要： This is to provide an all solid state secondary battery which can be produced by an industrially employable method capable of mass-production and has excellent secondary battery characteristics.This is an all solid state secondary battery containing a laminated material in which a positive-electrode unit and a negative-electrode unit are laminated alternately through an ion conductive inorganic-material layer, the positive-electrode unit has positive active material layers on both surfaces of a positive-electrode collector layer, the above-mentioned negative-electrode unit has negative active material layers on both surfaces of a negative-electrode collector layer, (A) at least one of the positive-electrode collector layer and the negative-electrode collector layer comprises a metal of either of Ag, Pd, Au and Pt, or an alloy containing either of Ag, Pd, Au and Pt, or a mixture containing two or more kinds selected from the metals and alloys, (B) each layer is in a sintered state, or (C) at least the starting material for the ion conductive inorganic material of the ion conductive inorganic-material layer is a calcined powder.

摘要翻译： 这是提供一种能够通过工业上可以大规模生产并且具有优异的二次电池特性的方法生产的全固态二次电池。 这是一种包含层叠材料的全固体二次电池，其中正极单元和负极单元交替地通过离子导电无机材料层层压，正极单元在两个表面上具有正的活性材料层 上述负极单元在负极集电体层的两面具有负极活性物质层，（A）正极集电体层和负极中的至少一个 集电体层包括Ag，Pd，Au和Pt中的任一种的金属，或包含Ag，Pd，Au和Pt中的任一种的合金，或包含选自金属和合金的两种或更多种的混合物，（B）每层 或（C）至少离子传导性无机材料层的离子传导性无机材料的原料为煅烧粉末。

公开(公告)号：US20090202912A1

公开(公告)日：2009-08-13

申请号：US12302250

申请日：2007-02-13

申请人： Mamoru Baba ,  Shoichi Iwaya ,  Hitoshi Masumura ,  Hiroshi Sato ,  Hiroshi Sasagawa ,  Noriyuki Sakai ,  Takayuki Fujita

发明人： Mamoru Baba ,  Shoichi Iwaya ,  Hitoshi Masumura ,  Hiroshi Sato ,  Hiroshi Sasagawa ,  Noriyuki Sakai ,  Takayuki Fujita

IPC分类号： H01M4/40 ,  H01M4/24 ,  H01M10/00

CPC分类号： H01M4/0404 ,  H01M4/0414 ,  H01M4/0471 ,  H01M4/485 ,  H01M4/622 ,  H01M4/661 ,  H01M4/666 ,  H01M10/044 ,  H01M10/0525 ,  H01M10/0562 ,  H01M10/0585 ,  Y02E60/122 ,  Y02P70/54 ,  Y10T29/49108

摘要： This is to provide an all solid state secondary battery which can be produced by an industrially employable method capable of mass-production and has excellent secondary battery characteristics.This is an all solid state secondary battery containing a laminated material in which a positive-electrode unit and a negative-electrode unit are laminated alternately through an ion conductive inorganic-material layer, the positive-electrode unit has positive active material layers on both surfaces of a positive-electrode collector layer, the above-mentioned negative-electrode unit has negative active material layers on both surfaces of a negative-electrode collector layer, (A) at least one of the positive-electrode collector layer and the negative-electrode collector layer comprises a metal of either of Ag, Pd, Au and Pt, or an alloy containing either of Ag, Pd, Au and Pt, or a mixture containing two or more kinds selected from the metals and alloys, (B) each layer is in a sintered state, or (C) at least the starting material for the ion conductive inorganic material of the ion conductive inorganic-material layer is a calcined powder.

摘要翻译： 这是提供一种能够通过工业上可以大规模生产并且具有优异的二次电池特性的方法生产的全固态二次电池。 这是一种包含层叠材料的全固体二次电池，其中正极单元和负极单元交替地通过离子导电无机材料层层压，正极单元在两个表面上具有正的活性材料层 上述负极单元在负极集电体层的两面具有负极活性物质层，（A）正极集电体层和负极中的至少一个 集电体层包括Ag，Pd，Au和Pt中的任一种的金属，或包含Ag，Pd，Au和Pt中的任一种的合金，或包含选自金属和合金的两种或更多种的混合物，（B）每层 或（C）至少离子传导性无机材料层的离子传导性无机材料的原料为煅烧粉末。

公开(公告)号：US20100216032A1

公开(公告)日：2010-08-26

申请号：US12599941

申请日：2008-05-09

申请人： Mamoru Baba ,  Shoichi Iwaya ,  Hitoshi Masumura ,  Noriyuki Sakai ,  Takayuki Fujita ,  Hiroshi Sasagawa ,  Hiroshi Sato

发明人： Mamoru Baba ,  Shoichi Iwaya ,  Hitoshi Masumura ,  Noriyuki Sakai ,  Takayuki Fujita ,  Hiroshi Sasagawa ,  Hiroshi Sato

IPC分类号： H01M6/18 ,  H01M10/04

CPC分类号： B29C65/02 ,  H01M4/366 ,  H01M4/485 ,  H01M4/505 ,  H01M4/624 ,  H01M10/0525 ,  H01M10/0562 ,  Y02E60/122 ,  Y10T29/49112

摘要： Conventional ion rechargeable batteries having an electrode layer on an electrolyte layer suffer from an impurity layer formed at the interface, degrading performance. Conventional batteries with no such impurity layer have a problem of weak interface bonding. In the present invention, in a baking process step after an electrode layer is laminated on an electrolyte layer, materials for an electrode layer and an electrolyte layer are selected such that an intermediate layer formed of a reaction product contributing to charging and discharging reactions is formed at the interface of the electrode layer and the electrolyte layer. In addition, a paste that an active material is mixed with a conductive material at a predetermined mixing ratio is used to form a positive electrode layer and a negative electrode layer. Reductions in electrode resistance and interface resistance and improvement of charging and discharging cycle characteristics are made possible.

摘要翻译： 在电解质层上具有电极层的常规离子可再充电电池在界面处形成杂质层，降解性能。 没有这种杂质层的常规电池具有界面粘合弱的问题。 在本发明中，在将电极层层压在电解质层上之后的烘烤工序中，选择电极层和电解质层的材料，形成由有助于充放电反应的反应产物形成的中间层 在电极层和电解质层的界面处。 此外，使用活性物质以预定的混合比与导电材料混合的糊料形成正极层和负极层。 降低电极电阻和界面电阻以及充放电循环特性的改善成为可能。

公开(公告)号：US5015332A

公开(公告)日：1991-05-14

申请号：US306451

申请日：1989-01-25

申请人： Shoichi Iwaya ,  Hitoshi Masumura ,  Hiroki Takahashi ,  Masaaki Ohkawara ,  Katsumi Kobayashi ,  Takashi Ito

发明人： Shoichi Iwaya ,  Hitoshi Masumura ,  Hiroki Takahashi ,  Masaaki Ohkawara ,  Katsumi Kobayashi ,  Takashi Ito

IPC分类号： B01D1/18

CPC分类号： B01D1/18 ,  Y10S159/28 ,  Y10S159/41

摘要： A spray drying chamber with a head section and a heat-resistant porous membrane, the porous membrane being detachable and the head section being displaceable vertically, whereby microdrops are sprayed into a spray drying chamber together with hot air, and whereby the microdrops are dried momentarily and a fine powder is produced.

摘要翻译： PCT No.PCT / JP88 / 00670 Sec。 371日期：1989年1月25日 102（e）日期1989年1月25日PCT Filed 1988年7月5日PCT Pub。 第WO89 / 00070BC号公报 日本1989年1月12日。具有头部和耐热多孔膜的喷雾干燥室，多孔膜可拆卸，头部可垂直移位，由此微滴与热空气一起喷射到喷雾干燥室中， 从而微滴干燥，产生细粉末。