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公开(公告)号：US08722311B2
公开(公告)日：2014-05-13
申请号：US13574938
申请日：2011-01-19
申请人： Shojiro Yukawa , Shinya Arase , Toshiaki Takeyama , Yuki Endo , Takeo Moro
发明人： Shojiro Yukawa , Shinya Arase , Toshiaki Takeyama , Yuki Endo , Takeo Moro
CPC分类号： G02B3/0012 , C07D405/06 , C07D405/14 , G03F7/0226 , G03F7/0233
摘要： There is provided a resist composition suitable for forming a microlens which is excellent in transparency, heat resistance, and sensitivity characteristics, excellent in solubility in a developer, and as the result thereof has high resolution. A positive resist composition comprising; a component (A): an alkali-soluble polymer; a component (B): a compound having an organic group to be photolyzed to generate an alkali-soluble group; a component (C): a crosslinkable compound of Formula (1): [where R1, R2, and, R3 are independently a C1-6 alkylene group or oxyalkylene group which are optionally branched; and E1, E2, and E3 are independently a group containing a structure of Formula (2) or Formula (3): (where R4 is a hydrogen atom or a methyl group)]; and a component (D): a solvent.
摘要翻译： 提供了适于形成透明性，耐热性和灵敏度特性优异，显影剂中溶解性优异的微透镜的抗蚀剂组合物，其结果是具有高分辨率。 正型抗蚀剂组合物，其包含： 组分（A）：碱溶性聚合物; 成分（B）：具有被光解以产生碱溶性基团的有机基团的化合物; 组分（C）：式（1）的可交联化合物：[其中R 1，R 2和R 3独立地为任选支化的C 1-6亚烷基或氧化烯基; E1，E2和E3独立地为含有式（2）或式（3）结构的基团：（其中R 4是氢原子或甲基）]; 和组分（D）：溶剂。
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公开(公告)号：US20120292487A1
公开(公告)日：2012-11-22
申请号：US13574938
申请日：2011-01-19
申请人： Shojiro Yukawa , Shinya Arase , Toshiaki Takeyama , Yuki Endo , Takeo Moro
发明人： Shojiro Yukawa , Shinya Arase , Toshiaki Takeyama , Yuki Endo , Takeo Moro
IPC分类号： G03F7/004 , H01L27/146 , G03F7/20
CPC分类号： G02B3/0012 , C07D405/06 , C07D405/14 , G03F7/0226 , G03F7/0233
摘要： There is provided a resist composition suitable for forming a microlens which is excellent in transparency, heat resistance, and sensitivity characteristics, excellent in solubility in a developer, and as the result thereof has high resolution. A positive resist composition comprising; a component (A): an alkali-soluble polymer; a component (B): a compound having an organic group to be photolyzed to generate an alkali-soluble group; a component (C): a crosslinkable compound of Formula (1): [where R1, R2, and, R3 are independently a C1-6 alkylene group or oxyalkylene group which are optionally branched; and E1, E2, and E3 are independently a group containing a structure of Formula (2) or Formula (3): (where R4 is a hydrogen atom or a methyl group)]; and a component (D): a solvent.
摘要翻译： 提供了适于形成透明性，耐热性和灵敏度特性优异，显影剂中溶解性优异的微透镜的抗蚀剂组合物，其结果是具有高分辨率。 正型抗蚀剂组合物，其包含： 组分（A）：碱溶性聚合物; 成分（B）：具有被光解以产生碱溶性基团的有机基团的化合物; 组分（C）：式（1）的可交联化合物：[其中R 1，R 2和R 3独立地为任选支化的C 1-6亚烷基或氧化烯基; E1，E2和E3独立地为含有式（2）或式（3）结构的基团：（其中R 4是氢原子或甲基）]; 和组分（D）：溶剂。
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公开(公告)号：US08778597B2
公开(公告)日：2014-07-15
申请号：US13521876
申请日：2011-01-24
申请人： Toshiaki Takeyama , Yuki Endo , Takeo Moro , Kentaro Ohmori
发明人： Toshiaki Takeyama , Yuki Endo , Takeo Moro , Kentaro Ohmori
CPC分类号： C08G59/3236 , C08G59/38 , C08L63/00 , G03F7/038
摘要： A curable composition that maintains good handleability in the liquid form and that can be photo- or heat-cured to form a cured product having physical properties including both high transparency and high flexural strength. A curable composition includes, an epoxy compound of (1): [where each of E1, E2, and E3 is independently an organic group of Formula (2) or Formula (3); and each of R1, R2, and R3 is independently an optionally branched alkylene group or oxyalkylene group: (where R4 is a hydrogen atom or a methyl group)]; and an acid generator.
摘要翻译： 一种固化组合物，其在液体形式中保持良好的操作性，并且可以进行光固化或热固化以形成具有包括高透明度和高弯曲强度的物理性质的固化产物。 可固化组合物包括（1）：[其中E1，E2和E3各自独立地为式（2）或式（3）的有机基团的环氧化合物; R 1，R 2和R 3各自独立地为任选支链的亚烷基或氧化烯基（其中R 4为氢原子或甲基）]; 和酸发生剂。
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公开(公告)号：US20120295199A1
公开(公告)日：2012-11-22
申请号：US13521876
申请日：2011-01-24
申请人： Toshiaki Takeyama , Yuki Endo , Takeo Moro , Kentaro Ohmori
发明人： Toshiaki Takeyama , Yuki Endo , Takeo Moro , Kentaro Ohmori
CPC分类号： C08G59/3236 , C08G59/38 , C08L63/00 , G03F7/038
摘要： A curable composition that maintains good handleability in the liquid form and that can be photo- or heat-cured to form a cured product having physical properties including both high transparency and high flexural strength. A curable composition includes, an epoxy compound of (1): [where each of E1, E2, and E3 is independently an organic group of Formula (2) or Formula (3); and each of R1, R2, and R3 is independently an optionally branched alkylene group or oxyalkylene group: (where R4 is a hydrogen atom or a methyl group)]; and an acid generator.
摘要翻译： 一种固化组合物，其在液体形式中保持良好的操作性，并且可以进行光固化或热固化以形成具有包括高透明度和高弯曲强度的物理性质的固化产物。 可固化组合物包括（1）：[其中E1，E2和E3各自独立地为式（2）或式（3）的有机基团的环氧化合物; R 1，R 2和R 3各自独立地为任选支链的亚烷基或氧化烯基（其中R 4为氢原子或甲基）]; 和酸发生剂。
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公开(公告)号：US20130274433A1
公开(公告)日：2013-10-17
申请号：US13885298
申请日：2011-11-14
申请人： Yuki Endo , Toshiaki Takeyama , Sayoko Yanagisawa
发明人： Yuki Endo , Toshiaki Takeyama , Sayoko Yanagisawa
IPC分类号： C08G59/02
CPC分类号： C08G59/02 , C07D303/16 , C07D303/44 , C08G59/027 , C08G59/32 , C08G59/3218 , H01L23/293 , H01L2924/0002 , H05K3/285 , H05K3/287 , H05K3/4676 , H01L2924/00
摘要： There is provided an epoxy resin composition having low viscosity and a high cationic curing property. An epoxy compound of Formula (1): (in Formula (1), A is an (n4)-valent C4-20 linear hydrocarbon group optionally containing an epoxy group, an (n4)-valent C4-20 cyclic hydrocarbon group optionally containing an epoxy group, or an (n4)-valent group of a combination of the linear hydrocarbon group and the cyclic hydrocarbon group; R1 and R2 are each independently a hydrogen atom or a C1-10 alkyl group; n1 is an integer of 2 to 6; n2 is an integer of 2; n3 is an integer of 1; and n4 is an integer of 3 to 8). For example, A is an (n4)-valent organic group formed by removing (n4) hydrogen atoms from butane, pentane, or hexane, or an (n4)-valent organic group formed by removing (n4) hydrogen atoms from cyclobutane, cyclopentane, cyclohexane, epoxycyclohexane, alkyl-substituted epoxycyclohexane, bicycloheptene, or bicyclooctene.
摘要翻译： 提供了一种具有低粘度和高阳离子固化性能的环氧树脂组合物。 式（1）的环氧化合物：（式（1）中，A是任选含有环氧基的（n4）价的C4-20直链烃基，（n4）价的C4-20环烃基， 环状基团或直链烃基和环状烃基的（n4）价基团; R1和R2各自独立地为氢原子或C1-10烷基; n1为2〜 6; n2为2的整数; n3为1的整数，n4为3〜8的整数）。 例如，A是通过从丁烷，戊烷或己烷除去（n4）氢原子或通过从环丁烷除去（n4））氢原子形成的（n4）价有机基团而形成的（n4）有机基团，环戊烷 环己烷，环氧环己烷，烷基取代环氧环己烷，双环庚烯或双环辛烯。
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公开(公告)号：US08765835B2
公开(公告)日：2014-07-01
申请号：US13814090
申请日：2011-07-27
申请人： Toshiaki Takeyama , Yuki Endo , Sayoko Yanagisawa
发明人： Toshiaki Takeyama , Yuki Endo , Sayoko Yanagisawa
IPC分类号： C08G59/24 , C08L63/00 , C07D301/14 , G03F7/004
CPC分类号： G03F7/004 , C08G59/24 , C08G59/3218 , C08G59/68 , G03F7/038
摘要： There is provided a curable composition having a low viscosity and high cationic curability. A curable composition including an epoxy compound of Formula (1): [in Formula (1), A is a monocyclic aliphatic hydrocarbon group optionally containing an epoxy group; R1, R2, R3 and R4 are independently a hydrogen atom or a C1-10 alkyl group; n1 and n2 are independently an integer of 2 to 6; n3 and n4 are individually an integer of 2; and n5 and n6 are individually an integer of 1], and an acid generator.
摘要翻译： 提供了具有低粘度和高阳离子固化性的可固化组合物。 一种包含式（1）的环氧化合物的可固化组合物：[在式（1）中，A是任选含有环氧基的单环脂族烃基; R1，R2，R3和R4独立地为氢原子或C1-10烷基; n1和n2独立地为2〜6的整数。 n3和n4分别为2的整数; n5和n6分别为1的整数]和酸发生剂。
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公开(公告)号：US20130172525A1
公开(公告)日：2013-07-04
申请号：US13814015
申请日：2011-07-27
申请人： Toshiaki Takeyama , Yuki Endo , Sayoko Yanagisawa
发明人： Toshiaki Takeyama , Yuki Endo , Sayoko Yanagisawa
IPC分类号： C07D405/14 , C08G73/06
CPC分类号： C07D405/14 , C08G59/027 , C08G59/3245 , C08G73/0644
摘要： There is provided an epoxy compound that provides properties of cured products combining high transparency with high flexural strength by being thermally cured while maintaining advantageous handling properties in a liquid state thereof; and a method for producing a composition by using the epoxy compound. A method for producing an epoxy compound of Formula (1): (in Formula (1), n1, n2, and n3 are individually any one of integers of 2 to 6; n4, n5, and n6 are individually an integer of 2; n7, n8, and n9 are individually an integer of 1; and R1, R2, R3, R4, R5, and R6 are independently a hydrogen atom or a C1-10 alkyl group), including: reacting cyanuric chloride with a C4-8 alkenol and reacting the obtained compound having an unsaturated bond with a peroxide.
摘要翻译： 提供一种环氧化合物，其通过热固化而提供高透明度和高抗弯强度的固化产物的性质，同时保持其液体状态下的有利处理性能; 以及使用该环氧化合物制造组合物的方法。 式（1）的环氧化合物的制造方法（式（1）中，n1，n2和n3分别是2〜6的整数中的任一个，n4，n5和n6分别为2的整数。 n7，n8和n9分别为1的整数; R1，R2，R3，R4，R5和R6独立地为氢原子或C1-10烷基），包括：将氰尿酰氯与C4-8 将所得到的具有不饱和键的化合物与过氧化物反应。
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公开(公告)号：US09102663B2
公开(公告)日：2015-08-11
申请号：US13814015
申请日：2011-07-27
申请人： Toshiaki Takeyama , Yuki Endo , Sayoko Yanagisawa
发明人： Toshiaki Takeyama , Yuki Endo , Sayoko Yanagisawa
CPC分类号： C07D405/14 , C08G59/027 , C08G59/3245 , C08G73/0644
摘要： There is provided an epoxy compound that provides properties of cured products combining high transparency with high flexural strength by being thermally cured while maintaining advantageous handling properties in a liquid state thereof; and a method for producing a composition by using the epoxy compound. A method for producing an epoxy compound of Formula (1): (in Formula (1), n1, n2, and n3 are individually any one of integers of 2 to 6; n4, n5, and n6 are individually an integer of 2; n7, n8, and n9 are individually an integer of 1; and R1, R2, R3, R4, R5, and R6 are independently a hydrogen atom or a C1-10 alkyl group), including: reacting cyanuric chloride with a C4-8 alkenol and reacting the obtained compound having an unsaturated bond with a peroxide.
摘要翻译： 提供一种环氧化合物，其通过热固化而提供高透明度和高抗弯强度的固化产物的性质，同时保持其液体状态下的有利处理性能; 以及使用该环氧化合物制造组合物的方法。 式（1）的环氧化合物的制造方法（式（1）中，n1，n2和n3分别是2〜6的整数中的任一个，n4，n5和n6分别为2的整数。 n7，n8和n9分别为1的整数; R1，R2，R3，R4，R5和R6独立地为氢原子或C1-10烷基），包括：将氰尿酰氯与C4-8 将所得到的具有不饱和键的化合物与过氧化物反应。
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公开(公告)号：US20130177849A1
公开(公告)日：2013-07-11
申请号：US13814090
申请日：2011-07-27
申请人： Toshiaki Takeyama , Yuki Endo , Sayoko Yanagisawa
发明人： Toshiaki Takeyama , Yuki Endo , Sayoko Yanagisawa
IPC分类号： G03F7/004
CPC分类号： G03F7/004 , C08G59/24 , C08G59/3218 , C08G59/68 , G03F7/038
摘要： There is provided a curable composition having a low viscosity and high cationic curability. A curable composition including an epoxy compound of Formula (1): [in Formula (1), A is a monocyclic aliphatic hydrocarbon group optionally containing an epoxy group; R1, R2, R3 and R4 are independently a hydrogen atom or a C1-10 alkyl group; n1 and n2 are independently an integer of 2 to 6; n3 and n4 are individually an integer of 2; and n5 and n6 are individually an integer of 1], and an acid generator.
摘要翻译： 提供了具有低粘度和高阳离子固化性的可固化组合物。 一种包含式（1）的环氧化合物的可固化组合物：[在式（1）中，A是任选含有环氧基的单环脂族烃基; R1，R2，R3和R4独立地为氢原子或C1-10烷基; n1和n2独立地为2〜6的整数。 n3和n4分别为2的整数; n5和n6分别为1的整数]和酸发生剂。
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公开(公告)号：US09428606B2
公开(公告)日：2016-08-30
申请号：US13885298
申请日：2011-11-14
申请人： Yuki Endo , Toshiaki Takeyama , Sayoko Yanagisawa
发明人： Yuki Endo , Toshiaki Takeyama , Sayoko Yanagisawa
IPC分类号： C07D303/16 , C07D303/44 , C08G59/02 , C08G59/32 , H01L23/29 , H05K3/28 , H05K3/46
CPC分类号： C08G59/02 , C07D303/16 , C07D303/44 , C08G59/027 , C08G59/32 , C08G59/3218 , H01L23/293 , H01L2924/0002 , H05K3/285 , H05K3/287 , H05K3/4676 , H01L2924/00
摘要： There is provided an epoxy resin composition having low viscosity and a high cationic curing property. An epoxy compound of Formula (1): (in Formula (1), A is an (n4)-valent C4-20 linear hydrocarbon group optionally containing an epoxy group, an (n4)-valent C4-20 cyclic hydrocarbon group optionally containing an epoxy group, or an (n4)-valent group of a combination of the linear hydrocarbon group and the cyclic hydrocarbon group; R1 and R2 are each independently a hydrogen atom or a C1-10 alkyl group; n1 is an integer of 2 to 6; n2 is an integer of 2; n3 is an integer of 1; and n4 is an integer of 3 to 8). For example, A is an (n4)-valent organic group formed by removing (n4) hydrogen atoms from butane, pentane, or hexane, or an (n4)-valent organic group formed by removing (n4) hydrogen atoms from cyclobutane, cyclopentane, cyclohexane, epoxycyclohexane, alkyl-substituted epoxycyclohexane, bicycloheptene, or bicyclooctene.
摘要翻译： 提供了一种具有低粘度和高阳离子固化性能的环氧树脂组合物。 式（1）的环氧化合物：（式（1）中，A是任选含有环氧基的（n4）价的C4-20直链烃基，（n4）价的C4-20环烃基， 环状基团或直链烃基和环状烃基的（n4）价基团; R1和R2各自独立地为氢原子或C1-10烷基; n1为2〜 6; n2为2的整数; n3为1的整数，n4为3〜8的整数）。 例如，A是通过从丁烷，戊烷或己烷除去（n4）氢原子或通过从环丁烷除去（n4））氢原子形成的（n4）价有机基团而形成的（n4）有机基团，环戊烷 环己烷，环氧环己烷，烷基取代环氧环己烷，双环庚烯或双环辛烯。
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