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1.发明申请METHOD AND SYSTEM FOR PRODUCING A SYNTHESIS GAS IN AN OXYGEN TRANSPORT MEMBRANE BASED REFORMING SYSTEM WITH RECYCLING OF THE PRODUCED SYNTHESIS GAS 有权在生产合成气回收的基于氧气输送膜的改造系统中生产合成气的方法和系统公开(公告)号：US20140319427A1
公开(公告)日：2014-10-30
申请号：US14098731
申请日：2013-12-06
IPC分类号： C01B3/38
CPC分类号： C01B3/382 , C01B3/384 , C01B13/0251 , C01B2203/0233 , C01B2203/0283 , C01B2203/043 , C01B2203/0822 , C01B2203/0827 , C01B2203/142 , Y02P20/128
摘要： A method and system for producing a synthesis gas in an oxygen transport membrane based reforming system that utilizes a combined feed stream having a steam to carbon ratio between about 1.6 and 3.0 and a temperature between about 500° C. and 750° C. The combined feed stream is comprised a pre-reformed hydrocarbon feed, superheated steam, and a reaction product stream created by the reaction of a hydrogen containing stream reacted with the permeated oxygen at the permeate side of the oxygen transport membrane elements and wherein the hydrogen containing stream is a recycled portion of the synthesis gas.
摘要翻译： 一种用于在基于氧传输膜的重整系统中生产合成气的方法和系统，其利用蒸汽与碳之比在约1.6和3.0之间以及在约500℃和750℃之间的温度的组合进料流。 进料流包括预重整的烃进料，过热蒸汽和通过在氧输送膜元件的渗透侧与与渗透氧反应的含氢流反应产生的反应产物流，其中含氢流是 合成气的再循环部分。
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2.发明授权Method and system for producing a synthesis gas in an oxygen transport membrane based reforming system with recycling of the produced synthesis gas 有权用于在氧传输膜基重整系统中生产合成气的方法和系统，其中回收所生产的合成气公开(公告)号：US09365422B2
公开(公告)日：2016-06-14
申请号：US14098731
申请日：2013-12-06
CPC分类号： C01B3/382 , C01B3/384 , C01B13/0251 , C01B2203/0233 , C01B2203/0283 , C01B2203/043 , C01B2203/0822 , C01B2203/0827 , C01B2203/142 , Y02P20/128
摘要： A method and system for producing a synthesis gas in an oxygen transport membrane based reforming system that utilizes a combined feed stream having a steam to carbon ratio between about 1.6 and 3.0 and a temperature between about 500° C. and 750° C. The combined feed stream is comprised a pre-reformed hydrocarbon feed, superheated steam, and a reaction product stream created by the reaction of a hydrogen containing stream reacted with the permeated oxygen at the permeate side of the oxygen transport membrane elements and wherein the hydrogen containing stream is a recycled portion of the synthesis gas.
摘要翻译： 一种用于在基于氧传输膜的重整系统中生产合成气的方法和系统，其利用蒸汽与碳之比在约1.6和3.0之间以及在约500℃和750℃之间的温度的组合进料流。 进料流包括预重整的烃进料，过热蒸汽和通过在氧输送膜元件的渗透侧与与渗透氧反应的含氢流反应产生的反应产物流，其中含氢流是 合成气的再循环部分。
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3.发明申请METHOD AND SYSTEM FOR PRODUCING METHANOL USING AN OXYGEN TRANSPORT MEMBRANE BASED REFORMING SYSTEM 有权使用基于氧运输膜的改造系统生产甲醇的方法和系统公开(公告)号：US20140323599A1
公开(公告)日：2014-10-30
申请号：US14081403
申请日：2013-11-15
申请人： Shrikar Chakravarti , Minish M. Shah , Raymond Francis Drnevich , Wladimir Y. Sarmiento-Darkin , Brian R. Kromer , Sean M. Kelly
发明人： Shrikar Chakravarti , Minish M. Shah , Raymond Francis Drnevich , Wladimir Y. Sarmiento-Darkin , Brian R. Kromer , Sean M. Kelly
IPC分类号： C07C29/151
CPC分类号： C07C29/1518 , C01B3/38 , C01B3/382 , C01B13/0251 , C01B2203/0233 , C01B2203/0244 , C01B2203/0261 , C01B2203/061 , C01B2203/0833 , C01B2203/141 , C01B2203/148 , C07C31/04
摘要： A method and system for producing methanol that employs both an oxygen transport membrane (OTM) based reforming system together with a more traditional steam methane reforming (SMR) and/or autothermal (ATR) synthesis gas production system is disclosed. The dual mode system and method for producing the synthesis gas in a methanol production process optimizes the efficiency and productivity of the methanol plant by using the OTM based reforming system as an independent source of synthesis gas. The disclosed methods and systems are configurable either as a retrofit to existing methanol production facilities or as an integrated package into newly constructed methanol production facilities.
摘要翻译： 公开了一种用于生产甲醇的方法和系统，其采用基于氧传输膜（OTM）的重整系统与更传统的蒸汽甲烷重整（SMR）和/或自热（ATR）合成气生产系统。 在甲醇生产过程中生产合成气的双模系统和方法通过使用基于OTM的重整系统作为独立的合成气源来优化甲醇装置的效率和生产率。 公开的方法和系统可以作为对现有甲醇生产设施的改造或作为新建甲醇生产设备的综合包装进行配置。
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4.发明授权Method and system for producing methanol using an oxygen transport membrane based reforming system 有权使用基于氧传输膜的重整系统生产甲醇的方法和系统公开(公告)号：US09115045B2
公开(公告)日：2015-08-25
申请号：US14081403
申请日：2013-11-15
申请人： Shrikar Chakravarti , Minish M. Shah , Raymond Francis Drnevich , Wladimir Y. Sarmiento-Darkin , Brian R. Kromer , Sean M. Kelly
发明人： Shrikar Chakravarti , Minish M. Shah , Raymond Francis Drnevich , Wladimir Y. Sarmiento-Darkin , Brian R. Kromer , Sean M. Kelly
IPC分类号： C07C29/151 , C01B3/38 , C01B13/02
CPC分类号： C07C29/1518 , C01B3/38 , C01B3/382 , C01B13/0251 , C01B2203/0233 , C01B2203/0244 , C01B2203/0261 , C01B2203/061 , C01B2203/0833 , C01B2203/141 , C01B2203/148 , C07C31/04
摘要： A method and system for producing methanol that employs both an oxygen transport membrane (OTM) based reforming system together with a more traditional steam methane reforming (SMR) and/or autothermal (ATR) synthesis gas production system is disclosed. The dual mode system and method for producing the synthesis gas in a methanol production process optimizes the efficiency and productivity of the methanol plant by using the OTM based reforming system as an independent source of synthesis gas. The disclosed methods and systems are configurable either as a retrofit to existing methanol production facilities or as an integrated package into newly constructed methanol production facilities.
摘要翻译： 公开了一种用于生产甲醇的方法和系统，其采用基于氧传输膜（OTM）的重整系统与更传统的蒸汽甲烷重整（SMR）和/或自热（ATR）合成气生产系统。 在甲醇生产过程中生产合成气的双模系统和方法通过使用基于OTM的重整系统作为独立的合成气源来优化甲醇装置的效率和生产率。 公开的方法和系统可以作为对现有甲醇生产设施的改造或作为新建甲醇生产设备的综合包装进行配置。
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5.发明授权公开(公告)号：US09562472B2
公开(公告)日：2017-02-07
申请号：US14619260
申请日：2015-02-11
申请人： Sean M. Kelly , Shrikar Chakravarti , Juan Li
发明人： Sean M. Kelly , Shrikar Chakravarti , Juan Li
IPC分类号： B01D53/22 , F02C3/22 , H02K7/18 , C10J3/48 , F02C7/22 , C10J3/20 , F01D15/10 , F02C3/28 , C01B3/38 , C01B3/48 , C01B13/02 , F01K13/00 , F01K23/06
CPC分类号： F02C3/22 , B01D53/228 , C01B3/382 , C01B3/48 , C01B13/0251 , C01B2203/0244 , C01B2203/0283 , C01B2203/0415 , C01B2203/06 , C01B2203/1241 , C01B2203/127 , C01B2203/84 , C01B2203/86 , C10J2300/093 , C10J2300/0959 , C10J2300/0976 , C10J2300/1678 , F01D15/10 , F01K13/00 , F01K23/068 , F02C3/28 , F02C7/22 , H02K7/1823 , Y02E20/16 , Y02E20/18 , Y02E20/185 , Y02E20/326 , Y02E20/344 , Y02P20/129 , Y02P20/13 , Y02P30/30
摘要： A carbon capture enabled system and method for generating electric power and/or fuel from methane containing sources using oxygen transport membranes by first converting the methane containing feed gas into a high pressure synthesis gas. Then, in one configuration the synthesis gas is combusted in oxy-combustion mode in oxygen transport membranes based boiler reactor operating at a pressure at least twice that of ambient pressure and the heat generated heats steam in thermally coupled steam generation tubes within the boiler reactor; the steam is expanded in steam turbine to generate power; and the carbon dioxide rich effluent leaving the boiler reactor is processed to isolate carbon. In another configuration the synthesis gas is further treated in a gas conditioning system configured for carbon capture in a pre-combustion mode using water gas shift reactors and acid gas removal units to produce hydrogen or hydrogen-rich fuel gas that fuels an integrated gas turbine and steam turbine system to generate power. The disclosed method and system can also be adapted to integrate with coal gasification systems to produce power from both coal and methane containing sources with greater than 90% carbon isolation.
摘要翻译： 一种采用碳捕获的系统和方法，用于通过首先将含甲烷的进料气体转化为高压合成气体，使用氧气输送膜从含甲烷的源产生电能和/或燃料。 然后，在一种配置中，合成气在氧气传输膜的锅炉反应器中以氧气燃烧模式燃烧，其工作压力至少为环境压力的两倍，并且产生的热量在锅炉反应器内的热耦合蒸汽发生管中加热蒸汽; 蒸汽在蒸汽轮机中膨胀以发电; 并且离开锅炉反应器的富含二氧化碳的流出物被处理以分离碳。 在另一种配置中，合成气在配置成以预燃燃烧模式进行碳捕集的气体调节系统中进一步处理，其中使用水煤气变换反应器和酸性气体去除单元来产生用于燃烧集成燃气轮机的氢或富氢燃料气体， 蒸汽轮机系统发电。 所公开的方法和系统还可以适应于与煤气化系统集成以从具有大于90％碳隔离的含煤和含甲烷的源产生电力。
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6.发明申请公开(公告)号：US20150226118A1
公开(公告)日：2015-08-13
申请号：US14619260
申请日：2015-02-11
申请人： Sean M. Kelly , Shrikar Chakravarti , Juan Li
发明人： Sean M. Kelly , Shrikar Chakravarti , Juan Li
CPC分类号： F02C3/22 , B01D53/228 , C01B3/382 , C01B3/48 , C01B13/0251 , C01B2203/0244 , C01B2203/0283 , C01B2203/0415 , C01B2203/06 , C01B2203/1241 , C01B2203/127 , C01B2203/84 , C01B2203/86 , C10J2300/093 , C10J2300/0959 , C10J2300/0976 , C10J2300/1678 , F01D15/10 , F01K13/00 , F01K23/068 , F02C3/28 , F02C7/22 , H02K7/1823 , Y02E20/16 , Y02E20/18 , Y02E20/185 , Y02E20/326 , Y02E20/344 , Y02P20/129 , Y02P20/13 , Y02P30/30
摘要： A carbon capture enabled system and method for generating electric power and/or fuel from methane containing sources using oxygen transport membranes by first converting the methane containing feed gas into a high pressure synthesis gas. Then, in one configuration the synthesis gas is combusted in oxy-combustion mode in oxygen transport membranes based boiler reactor operating at a pressure at least twice that of ambient pressure and the heat generated heats steam in thermally coupled steam generation tubes within the boiler reactor; the steam is expanded in steam turbine to generate power; and the carbon dioxide rich effluent leaving the boiler reactor is processed to isolate carbon. In another configuration the synthesis gas is further treated in a gas conditioning system configured for carbon capture in a pre-combustion mode using water gas shift reactors and acid gas removal units to produce hydrogen or hydrogen-rich fuel gas that fuels an integrated gas turbine and steam turbine system to generate power. The disclosed method and system can also be adapted to integrate with coal gasification systems to produce power from both coal and methane containing sources with greater than 90% carbon isolation.
摘要翻译： 一种采用碳捕获的系统和方法，用于通过首先将含甲烷的进料气体转化为高压合成气体，使用氧气输送膜从含甲烷的源产生电力和/或燃料。 然后，在一种配置中，合成气在氧气传输膜的锅炉反应器中以氧气燃烧模式燃烧，其工作压力至少为环境压力的两倍，并且产生的热量在锅炉反应器内的热耦合蒸汽发生管中加热蒸汽; 蒸汽在蒸汽轮机中膨胀以发电; 并且离开锅炉反应器的富含二氧化碳的流出物被处理以分离碳。 在另一种配置中，合成气在配置成以预燃燃烧模式进行碳捕集的气体调节系统中进一步处理，其中使用水煤气变换反应器和酸性气体去除单元来产生用于燃烧集成燃气轮机的氢或富氢燃料气体， 蒸汽轮机系统发电。 所公开的方法和系统还可以适应于与煤气化系统集成以从具有大于90％碳隔离的含煤和含甲烷的源产生电力。
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7.发明申请METHOD AND SYSTEM FOR ADJUSTING SYNTHESIS GAS MODULE IN AN OXYGEN TRANSPORT MEMBRANE BASED REFORMING SYSTEM 有权基于氧气运输膜的改造系统调整合成气模块的方法与系统公开(公告)号：US20160272493A1
公开(公告)日：2016-09-22
申请号：US15166735
申请日：2016-05-27
CPC分类号： C01B3/386 , B01J8/009 , B01J8/0457 , B01J8/0496 , B01J2208/0053 , B01J2219/00006 , B01J2219/00495 , B01J2219/00745 , C01B3/26 , C01B3/382 , C01B3/384 , C01B13/0251 , C01B2203/0233 , C01B2203/0244 , C01B2203/0261 , C01B2203/04 , C01B2203/0495 , C01B2203/0833 , C01B2203/0838 , C01B2203/0883 , C01B2203/1205 , C01B2203/1235 , C01B2203/127 , C01B2203/142 , C01B2203/80
摘要： A method and system for producing a synthesis gas in an oxygen transport membrane based reforming system is disclosed that carries out an air heated pre-reforming process, a primary reforming process, a secondary reforming process.
摘要翻译： 公开了一种在氧传输膜基重整系统中生产合成气的方法和系统，其进行空气加热预重整工艺，初级重整工艺，二次重整工艺。
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公开(公告)号：US09290422B2
公开(公告)日：2016-03-22
申请号：US13686328
申请日：2012-11-27
IPC分类号： C07C27/00 , C07C1/12 , C07C29/151 , C10K3/06 , C10G2/00 , C10K1/00 , C01B3/38 , C10J3/72 , C10K3/04
CPC分类号： C07C1/12 , C01B3/382 , C01B2203/0233 , C01B2203/0244 , C01B2203/0283 , C01B2203/043 , C01B2203/0475 , C01B2203/062 , C01B2203/0811 , C01B2203/1241 , C01B2203/1258 , C01B2203/142 , C01B2203/148 , C07C29/1518 , C10G2/30 , C10J3/721 , C10J2300/1659 , C10J2300/1665 , C10J2300/1678 , C10J2300/1815 , C10J2300/1838 , C10K1/003 , C10K1/005 , C10K3/04 , C10K3/06 , C07C31/04
摘要： A hybrid plant and method for producing liquid fuel product from hydrogen and carbon monoxide containing streams produced by gasifying solid carbonaceous feedstock and steam reforming of light fossil fuels. When a gasification unit in the hybrid plant is operating at reduced capacity or is not operational, oxygen that would have been used in the gasification unit is diverted to a light fossil fuel conversion unit containing an autothermal reformer to increase H2-rich syngas flow to a liquid fuel production unit and maintain liquid fuel production at near nameplate capacity.
摘要翻译： 一种用于通过气化固体碳质原料和轻化石燃料的蒸汽重整产生的氢气和一氧化碳的液体产生液体燃料产物的混合设备和方法。 当混合设备中的气化单元以降低的能力运行或不可操作时，将在气化单元中使用的氧转移到含有自热重整器的轻化石燃料转化单元，以将富H2合成气流增加到 液体燃料生产单元，并保持液体燃料生产接近铭牌能力。
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9.发明申请METHOD AND SYSTEM FOR PRODUCING A SYNTHESIS GAS USING AN OXYGEN TRANSPORT MEMBRANE BASED REFORMING SYSTEM WITH SECONDARY REFORMING 有权使用基于氧传输膜的改造系统进行二次重整的合成气体的制备方法和系统公开(公告)号：US20150190776A1
公开(公告)日：2015-07-09
申请号：US14661679
申请日：2015-03-18
CPC分类号： B01J19/2475 , B01J8/009 , B01J8/0457 , B01J8/0496 , B01J2208/0053 , B01J2219/00006 , B01J2219/00051 , B01J2219/00157 , B01J2219/24 , C01B3/26 , C01B3/382 , C01B3/384 , C01B3/386 , C01B13/0251 , C01B2203/0233 , C01B2203/0244 , C01B2203/0261 , C01B2203/04 , C01B2203/0495 , C01B2203/0838 , C01B2203/0883 , C01B2203/1205 , C01B2203/127 , C01B2203/142 , C01B2203/80
摘要： A method and system for producing a synthesis gas in an oxygen transport membrane based reforming system is disclosed that carries out a primary reforming process, a secondary reforming process.
摘要翻译： 公开了一种在氧传输膜基重整系统中生产合成气的方法和系统，其进行一次重整过程，二次重整过程。
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公开(公告)号：US20150005398A1
公开(公告)日：2015-01-01
申请号：US13927880
申请日：2013-06-26
CPC分类号： C10K1/004 , C01B3/24 , C01B3/38 , C01B2203/0233 , C01B2203/0244 , C01B2203/062 , C01B2203/0816 , C01B2203/1241 , C01B2203/141 , C01B2203/142 , C10G2/30 , C10J3/00 , C10J2300/0916 , C10J2300/093 , C10J2300/0943 , C10J2300/0959 , C10J2300/0969 , C10J2300/0976 , C10J2300/1659 , C10J2300/1678 , C10K1/005 , C10K3/06 , Y02E20/18 , Y02P20/145
摘要： A process and method for producing liquid fuel product from hydrogen and carbon monoxide containing streams produced by gasifying solid carbonaceous feedstock and steam reforming of light fossil fuels. The gasifier syngas is treated to preferentially remove at least 99% of sulfur containing impurities and less than 50% of the CO2 to produce a treated gasifier syngas and a CO2 enriched gas. The treated gasifier syngas and the light fossil fuel conversion unit product gas are combined to form a mixed syngas that is converted into a liquid fuel product. The CO2 enriched gas is used in the gasification unit.
摘要翻译： 一种用于通过气化固体碳质原料和轻化石燃料的蒸汽重整产生的含氢气和一氧化碳的液体生产液体燃料产品的方法和方法。 处理气化器合成气以优先除去至少99％的含硫杂质和少于50％的CO 2，以产生经处理的气化器合成气和富含CO 2的气体。 经处理的气化器合成气和轻化石燃料转化装置产物气体合并形成混合合成气，其被转化为液体燃料产物。 在气化单元中使用富含CO 2的气体。
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