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公开(公告)号：US06448438B1
公开(公告)日：2002-09-10
申请号：US09493011
申请日：2000-01-28
IPC分类号： C07C5121
摘要： A method for purifying acrylic acid, which comprises carrying out dehydration distillation of an aqueous solution of acrylic acid by means of a dehydration column, wherein a distillation column having a theoretical plate number of at least 3 plates is used as the dehydration column, and the operational temperature of a site corresponding to the second theoretical plate is adjusted to be from 50 to 78° C.
摘要翻译： 一种纯化丙烯酸的方法，其包括用脱水塔对丙烯酸水溶液进行脱水蒸馏，其中使用具有至少3个板的理论塔板数的蒸馏塔作为脱水塔， 将与第二理论塔板相对应的部位的工作温度调整为50〜78℃。
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2.发明申请Apparatus For (Meth) Acrylic Acid Production And Process For Producing (Meth) Acrylic Acid 审中-公开（甲基）丙烯酸生产装置和（甲基）丙烯酸生产方法公开(公告)号：US20080021238A1
公开(公告)日：2008-01-24
申请号：US11569578
申请日：2004-09-07
申请人： Masahiko Yamagishi , Shuhei Yada , Kimikatsu Jinno
发明人： Masahiko Yamagishi , Shuhei Yada , Kimikatsu Jinno
CPC分类号： B01J8/067 , B01J2208/00053 , B01J2208/00061 , B01J2208/00212 , B01J2208/00221 , B01J2208/00256 , C07C51/215 , Y02P20/124 , Y02P20/51 , C07C57/04
摘要： (Meth)acrylic acid is produced using a reactor (1) through a vapor-phase catalytic oxidation reaction of propane or the like in a raw material gas, and the obtained reaction gas is distributed to a heat exchanger (20) and an absorption tower (30). Heat energy is recovered from the reaction gas supplied to the heat exchanger (20), and the reaction gas cooled in the heat exchanger (20) and the reaction gas distributed to the absorption tower (30) are supplied to the absorption tower (30). (Meth) acrylic acid is recovered from the reaction gas in an absorbing liquid, to thereby produce (meth) acrylic acid. The reaction gas is distributed to the heat exchanger (20) and the absorption tower (30) according to a pressure of the raw material gas at an inlet of the reactor (1). The present invention allows heat recovery from the reaction gas and a stable and continuous operation even when the heat exchanger for heat recovery is clogged.
摘要翻译： （甲基）丙烯酸通过原料气体中丙烷等的气相催化氧化反应使用反应器（1）制备，并将所得反应气体分配到热交换器（20）和吸收塔 （30）。 从供给到热交换器（20）的反应气体回收热能，在热交换器（20）中冷却的反应气体和分配到吸收塔（30）的反应气体供给到吸收塔30， 。 （甲基）丙烯酸从吸收液体中的反应气体中回收，由此生成（甲基）丙烯酸。 反应气体根据反应器（1）入口处的原料气体的压力而分配到热交换器（20）和吸收塔（30）。 即使在热回收用热交换器堵塞的情况下，本发明也能够从反应气体进行热回收和稳定连续的运转。
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公开(公告)号：US5910607A
公开(公告)日：1999-06-08
申请号：US508697
申请日：1995-07-28
IPC分类号： C07C51/46 , C07C57/07 , C07C51/21 , C07C51/235
CPC分类号： C07C51/46
摘要： In a process for producing acrylic acid, wherein propylene and/or acrolein is catalytically oxidized with molecular oxygen in a vapor phase and the gas resulting from the oxidation is cooled and/or absorbed in water to form a crude aqueous acrylic acid, followed by azeotropic distillation to remove the water with an entrainer of a boiling point of no higher than 130.degree. C. on the crude aqueous acrylic acid which may have, upon necessity, undergone removal of aldehydes contained therein to produce acrylic acid purified in that the crude aqueous acrylic acid is substantially dehydrated, the improvement which comprises conducting the azeotropic distillation under such conditions that concentrations of the entrainer and water in the bottom product of the azeotropic distillation are from 5% to 30% by weight and no higher than 0.5% by weight, respectively, where the theoretical number of plates in the azeotropic distillation column for dehydration used and that in the distillation column for separating acetic acid used are preferably from 5 to 20. Highly-purified acrylic acid can thus be obtained from the crude aqueous acrylic acid without causing unfavorable polymerization of acrylic acid.
摘要翻译： 在制备丙烯酸的方法中，其中丙烯和/或丙烯醛在气相中用分子氧催化氧化，并且由氧化产生的气体在水中冷却和/或吸收以形成粗水性丙烯酸，然后共沸 蒸馏以除去水，其中沸点不高于130℃的夹带剂在粗水性丙烯酸上，根据需要，可以将其除去其中所含的醛以产生纯化的丙烯酸，因为粗水性丙烯酸 酸基本脱水，其改进包括在共沸蒸馏的底部产物中的夹带剂和水的浓度分别为5重量％至30重量％且不高于0.5重量％的条件下进行共沸蒸馏 ，其中用于脱水的共沸蒸馏塔中的理论塔板数和蒸馏塔中的板的理论数量 所使用的分离乙酸优选为5〜20。因此，可以从粗水性丙烯酸获得高度纯化的丙烯酸，而不会引起丙烯酸的不利聚合。
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公开(公告)号：US5935534A
公开(公告)日：1999-08-10
申请号：US758502
申请日：1996-12-02
申请人： Hiroshi Umino , Hiromitsu Shibuya , Nobuyasu Chikamatsu , Kazuo Kikuchi , Masahiko Yamagishi , Kiyoshi Takahashi
发明人： Hiroshi Umino , Hiromitsu Shibuya , Nobuyasu Chikamatsu , Kazuo Kikuchi , Masahiko Yamagishi , Kiyoshi Takahashi
摘要： In a crystallization method, a liquid mixture containing a crystallizable component is cooled so as to form and separate crystals of the crystallizable component. Then, a purified melt having purity substantially equal to that of the separated crystals, to which a polymerization inhibitor is added and which is heated to a temperature higher than a freezing point of the separated crystals, is circulated to flow contacting the crystals so as to accelerate melting. Then, the melted crystals are recovered along with the purified melt containing the polymerization inhibitor.
摘要翻译： 在结晶方法中，将含有可结晶组分的液体混合物冷却以形成和分离可结晶组分的晶体。 然后，将纯度基本上等于分离的结晶的纯化熔体循环到与晶体接触的流动中，向其中加入聚合抑制剂并将其加热到高于分离晶体的凝固点的温度，从而 加速融化 然后，将熔融的晶体与含有聚合抑制剂的纯化熔体一起回收。
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5.发明授权System for reforming heavy oil, method therefor, and combined cycle power system 有权重油改造系统，方法和联合循环动力系统公开(公告)号：US07658078B2
公开(公告)日：2010-02-09
申请号：US11192059
申请日：2005-07-29
申请人： Koji Nishida , Nobuyuki Hokari , Shin-ichi Inage , Osami Yokota , Hirokazu Takahashi , Masahiko Yamagishi , Akinori Hayashi
发明人： Koji Nishida , Nobuyuki Hokari , Shin-ichi Inage , Osami Yokota , Hirokazu Takahashi , Masahiko Yamagishi , Akinori Hayashi
IPC分类号： F02C6/18
CPC分类号： C10G31/06 , B01J19/2425 , B01J19/243 , B01J2219/00006 , B01J2219/00085 , B01J2219/00094 , C10G31/08 , F01K23/10 , F02C6/18 , Y02E20/16
摘要： A heavy oil reforming system includes a reforming preheater raising the temperature of a mixed fluid comprising a high pressure heavy oil and high pressure steam up to a temperature for reforming reaction. The mixed fluid having been heated up to the temperature for reforming reaction is introduced into a reformer kept at the temperature for reforming reaction and thereby the heavy oil is reformed. This reforming system allows the attainment of a residence time of 1 to 10 min necessary for reforming in a uniform or nearly uniform temperature field, thereby implementing the manufacturing of reformed fuels from a large volume of heavy oil.
摘要翻译： 重油重整系统包括重整预热器，其将包括高压重油和高压蒸汽的混合流体的温度升高至重整反应的温度。 被加热至重整反应温度的混合流体被引入保持在重整反应温度的重整器中，由此重油被重整。 该重整系统允许在均匀或几乎均匀的温度场中实现1至10分钟的停留时间以进行重整，从而实现从大量重油制造重整燃料。
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公开(公告)号：US20070039307A1
公开(公告)日：2007-02-22
申请号：US11503934
申请日：2006-08-15
CPC分类号： F02C3/305 , F02C3/30 , F02C7/08 , F02C7/10 , F02C7/1435
摘要： Disclosed is a gas turbine power generating system capable of achieving a high output power and a high power generating efficiency under conditions with a small amount of supplied water and less change in design of a gas turbine. A fine water droplet spraying apparatus (11) is disposed in a suction air chamber (22) on the upstream side of an air compressor (2), and a moisture adding apparatus (7) for adding moisture to high pressure air supplied from the compressor (2) is disposed. A regenerator (5) for heating the air to which moisture has been added by using gas turbine exhaust gas as a heat source is also provided. With this configuration, there can be obtain an effect of reducing a power for the compressor (2) and an effect of increasing the output power due to addition of moisture to air (20) for combustion. Further, since the used amount of fuel is reduced by adopting a regenerating cycle, the power generating efficiency is improved.
摘要翻译： 公开了一种燃气轮机发电系统，其能够在少量供水的条件下和燃气轮机的设计变化较小的情况下实现高输出功率和高发电效率。 在空气压缩机（2）的上游侧的吸入空气室（22）中配置有微细的水滴喷射装置（11），以及将来自压缩机（2）供给的高压空气中的水分添加到水分添加装置 （2）。 还提供了一种用于通过使用燃气轮机废气作为热源来加热已经添加了水分的空气的再生器（5）。 通过这种结构，可以获得降低压缩机（2）的功率的效果，以及由于向空气（20）中添加水分而增加输出功率的效果，用于燃烧。 此外，由于通过采用再生循环来减少使用的燃料量，所以发电效率提高。
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公开(公告)号：US20060032211A1
公开(公告)日：2006-02-16
申请号：US11253829
申请日：2005-10-20
CPC分类号： F02C3/305 , F02C3/30 , F02C7/08 , F02C7/10 , F02C7/1435
摘要： Disclosed is a gas turbine power generating system capable of achieving a high output power and a high power generating efficiency under conditions with a small amount of supplied water and less change in design of a gas turbine. A fine water droplet spraying apparatus (11) is disposed in a suction air chamber (22) on the upstream side of an air compressor (2), and a moisture adding apparatus (7) for adding moisture to high pressure air supplied from the compressor (2) is disposed. A regenerator (5) for heating the air to which moisture has been added by using gas turbine exhaust gas a heat source is also provided. With this configuration, there can be obtain an effect of reducing a power for the compressor (2) and an effect of increasing the output power due to addition of moisture to air (20) for combustion. Further, since the used amount of fuel is reduced by adopting a regenerating cycle, the power generating efficiency is improved.
摘要翻译： 公开了一种燃气轮机发电系统，其能够在少量供水的条件下和燃气轮机的设计变化较小的情况下实现高输出功率和高发电效率。 在空气压缩机（2）的上游侧的吸入空气室（22）中配置有微细的水滴喷射装置（11），以及将来自压缩机（2）供给的高压空气中的水分添加到水分添加装置 （2）。 还提供一种用于通过使用燃气轮机废气加热加热了水分的空气的再生器（5）。 通过这种结构，可以获得降低压缩机（2）的功率的效果，以及由于向空气（20）中添加水分而增加输出功率的效果，用于燃烧。 此外，由于通过采用再生循环来减少使用的燃料量，所以发电效率提高。
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公开(公告)号：US20050040081A1
公开(公告)日：2005-02-24
申请号：US10910579
申请日：2004-08-04
申请人： Hirokazu Takahashi , Shinichi Inage , Nobuyuki Hokari , Masahiko Yamagishi , Akinori Hayashi , Osami Yokota , Youji Ishibashi
发明人： Hirokazu Takahashi , Shinichi Inage , Nobuyuki Hokari , Masahiko Yamagishi , Akinori Hayashi , Osami Yokota , Youji Ishibashi
CPC分类号： B01J4/002 , B01J3/008 , B01J2219/00006 , B01J2219/00094 , B01J2219/00166 , C10G27/04 , C10G31/06 , C10G31/08
摘要： The invention is intended to produce high-pressure light fuel gas with good combustibility by contacting and reacting high-temperature, high-pressure water and heavy oil with each other in a contact-reaction unit to extract light oil components from the heavy oil and to remove metals. The high-temperature, high-pressure water and the heavy oil are introduced to the contact-reaction unit for contact and reaction with each other therein. Heavy oil components not dissolved in the high-temperature, high-pressure water are separated by precipitation from hydrocarbon gases and light oil components which are dissolved in the high-temperature, high-pressure water. The separated heavy oil components are burnt or incinerated without any further modification.
摘要翻译： 本发明旨在通过在接触反应单元中使高温，高压水和重油彼此接触和反应来生产具有良好可燃性的高压轻燃料气体，以从重油中提取轻油组分， 去除金属。 将高温高压水和重油引入到接触反应单元中以进行接触和反应。 未溶解在高温高压水中的重油成分通过溶解在高温高压水中的烃类气体和轻油成分沉淀而分离。 分离的重油组分燃烧或焚烧，无需任何进一步修改。
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公开(公告)号：US06854259B2
公开(公告)日：2005-02-15
申请号：US10670461
申请日：2003-09-26
CPC分类号： F02C3/305 , F02C3/30 , F02C7/08 , F02C7/10 , F02C7/1435
摘要： Disclosed is a gas turbine power generating system capable of achieving a high output power and a high power generating efficiency under conditions with a small amount of supplied water and less change in design of a gas turbine.A fine water droplet spraying apparatus (11) is disposed in a suction air chamber (22) on the upstream side of an air compressor (2), and a moisture adding apparatus (7) for adding moisture to high pressure air supplied from the compressor (2) is disposed. A regenerator (5) for heating the air to which moisture has been added by using gas turbine exhaust gas as a heat source is also provided. With this configuration, there can be obtain an effect of reducing a power for the compressor (2) and an effect of increasing the output power due to addition of moisture to air (20) for combustion. Further, since the used amount of fuel is reduced by adopting a regenerating cycle, the power generating efficiency is improved.
摘要翻译： 公开了一种燃气轮机发电系统，其能够在少量供水量和燃气轮机的设计变化较小的条件下实现高输出功率和高发电效率。微细水滴喷射装置（11）是 设置在空气压缩机（2）的上游侧的吸入空气室（22）中，并且设置有用于向从压缩机（2）供给的高压空气中添加水分的湿气添加装置（7）。 还提供了一种用于通过使用燃气轮机废气作为热源来加热已经添加了水分的空气的再生器（5）。 通过这种结构，可以获得降低压缩机（2）的功率的效果，以及由于向空气（20）中添加水分而增加输出功率的效果，用于燃烧。 此外，由于通过采用再生循环来减少使用的燃料量，所以发电效率提高。
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10.发明授权Waste processing system and fuel reformer used in the waste processing system 失效在废物处理系统中使用的废物处理系统和燃料重整器公开(公告)号：US06282902B1
公开(公告)日：2001-09-04
申请号：US09343273
申请日：1999-06-30
申请人： Tsutomu Okusawa , Kazuhito Koyama , Masahiko Yamagishi , Shigeo Hatamiya , Taiko Ajiro , Megumi Sunou , Yukio Ishigaki , Kenji Tokunaga
发明人： Tsutomu Okusawa , Kazuhito Koyama , Masahiko Yamagishi , Shigeo Hatamiya , Taiko Ajiro , Megumi Sunou , Yukio Ishigaki , Kenji Tokunaga
IPC分类号： F01K734
CPC分类号： B01B1/005 , C01B3/38 , F01K3/247 , F02G2254/11 , F23G5/0276 , F23G5/46 , F23G2202/106 , F23G2206/10 , F23J15/08 , Y02E20/12
摘要： A waste-to-energy incineration system, in which the amount and heat value of exhaust gas largely changes in long and short periods, comprises an incinerator for burning waste, a boiler in the incinerator for generating steam with exhaust heat generated by the incinerator, a superheater for superheating steam generated in the boiler, a steam turbine driven by steam superheated by the superheater, a generator driven by the steam turbine, a fuel reformer for reforming source fuel, and a combustor burning fuel gas reformed by the fuel reformer and at least a part of exhaust gas led from the incinerator which is able to stably decompose generated dioxin in waste incineration exhaust gas.
摘要翻译： 一种废物能量焚烧系统，其中废气的量和热值在短时间内大幅度变化，包括用于燃烧废物的焚烧炉，焚烧炉中的用于产生由焚烧炉产生的废热的蒸汽的锅炉， 用于过热锅炉中产生的蒸汽的过热器，由过热器过热的蒸汽驱动的蒸汽轮机，由蒸汽轮机驱动的发电机，用于重整源燃料的燃料重整器，以及燃烧器燃烧由燃料重整器重整的燃料气体 从焚烧炉引出的废气的至少一部分能够稳定地分解废弃焚烧废气中产生的二恶英。
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