公开(公告)号：US08846560B2

公开(公告)日：2014-09-30

申请号：US13331274

申请日：2011-12-20

申请人： Shuwu Yang ,  Bruce Edward Reynolds ,  Julie Chabot ,  Bo Kou

发明人： Shuwu Yang ,  Bruce Edward Reynolds ,  Julie Chabot ,  Bo Kou

IPC分类号： B01J23/00 ,  B01J23/40 ,  B01J23/42 ,  B01J23/44 ,  B01J23/70 ,  B01J23/74 ,  B01J27/02 ,  B01J27/043 ,  B01J27/045 ,  B01J27/24 ,  B01J31/00 ,  B01J23/883 ,  B01J27/051 ,  B01J23/85 ,  B01J37/20 ,  B01J23/887 ,  C10G49/04 ,  B01J23/24 ,  B01J35/00 ,  B01J35/10

CPC分类号： B01J23/883 ,  B01J23/24 ,  B01J23/85 ,  B01J23/8872 ,  B01J23/8873 ,  B01J27/051 ,  B01J27/0515 ,  B01J35/0073 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1095 ,  B01J37/20 ,  C10G49/04 ,  C10G49/06 ,  C10G49/12 ,  C10G2300/107 ,  C10G2300/1077 ,  C10G2300/205 ,  C10G2300/301 ,  C10G2300/701 ,  C10G2300/703 ,  C10G2300/802

摘要： A process for preparing a slurry catalyst is provided. The slurry catalyst is prepared from at least a Group VIB metal precursor and optionally at least a Promoter metal precursor selected from Group VIII, Group IIB, Group IIA, Group IVA metals and combinations thereof. The slurry catalyst comprises a plurality of dispersed particles in a hydrocarbon medium having an average particle size ranging from 1 to 300 μm. The slurry catalyst is then mixed with a hydrogen feed at a pressure from 1435 psig (10 MPa) to 3610 psig (25 MPa) and a temperature from 200-800° F. at 500 to 15,000 scf hydrogen per bbl of slurry catalyst for a minute to 20 hours, for the slurry catalyst to be saturated with hydrogen providing an increase of k-values in terms of HDS, HDN, and HDMCR of at least 15% compared to a slurry catalyst that is not saturated with hydrogen.

摘要翻译： 提供了一种制备浆料催化剂的方法。 浆料催化剂由至少VIB族金属前体和任选的至少一种选自VIII族，IIB族，IIA族，IVA族金属及其组合的促进剂金属前体制备。 浆料催化剂在平均粒度为1〜300μm的烃介质中含有多个分散粒子。 然后将浆料催化剂与氢气进料混合，压力为1435psig（10MPa）至3610psig（25MPa），温度为200-800°F，每桶浆料催化剂为500至15,000scf氢气 分钟至20小时，浆液催化剂用氢饱和，与不饱和氢气的浆料催化剂相比，HDS，HDN和HDMCR的k值提高至少15％。

公开(公告)号：US09068132B2

公开(公告)日：2015-06-30

申请号：US13233477

申请日：2011-09-15

申请人： Shuwu Yang ,  Julie Chabot ,  Bruce Edward Reynolds ,  Bo Kou

发明人： Shuwu Yang ,  Julie Chabot ,  Bruce Edward Reynolds ,  Bo Kou

IPC分类号： C10G47/26 ,  C10G47/32 ,  C10G47/36 ,  C10G65/00 ,  C10G65/10 ,  C10G65/18 ,  C10G47/00 ,  C10G47/02

CPC分类号： C10G47/02 ,  C10G47/26 ,  C10G47/32 ,  C10G47/36 ,  C10G65/00 ,  C10G65/10 ,  C10G65/18 ,  C10G2300/205 ,  C10G2300/4075 ,  C10G2300/701 ,  C10G2300/802

摘要： A method to reduce metal deposit in the hydroprocessing or upgrade of heavy oil feedstock is provided. The method comprises feeding an improved catalyst feed to the system, with the improved catalyst feed comprising a fresh slurry catalyst and a deoiled spent catalyst, with the deoiled spent catalyst being present in an amount of at least 10% the catalyst feed for the heavy oil upgrade system to have at least a 5% reduction in metal contaminant build-up compared to heavy oil upgrade system without the deoiled spent catalyst in the feed.

摘要翻译： 提供了一种在重油原料的加氢处理或升级中减少金属沉积的方法。 该方法包括将改进的催化剂进料进料给系统，改进的催化剂进料包含新鲜的浆料催化剂和脱油的废催化剂，脱油的废催化剂的存在量为重油的催化剂进料的至少10％ 升级系统与重油升级系统相比，金属污染物累积量减少至少5％，而在进料中没有脱油废催化剂。

公开(公告)号：US20120172201A1

公开(公告)日：2012-07-05

申请号：US13331274

申请日：2011-12-20

申请人： Shuwu Yang ,  Bruce Edward Reynolds ,  Julie Chabot ,  Bo Kou

发明人： Shuwu Yang ,  Bruce Edward Reynolds ,  Julie Chabot ,  Bo Kou

IPC分类号： B01J37/18 ,  B01J27/043 ,  B01J37/20 ,  B01J27/047

CPC分类号： B01J23/883 ,  B01J23/24 ,  B01J23/85 ,  B01J23/8872 ,  B01J23/8873 ,  B01J27/051 ,  B01J27/0515 ,  B01J35/0073 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1095 ,  B01J37/20 ,  C10G49/04 ,  C10G49/06 ,  C10G49/12 ,  C10G2300/107 ,  C10G2300/1077 ,  C10G2300/205 ,  C10G2300/301 ,  C10G2300/701 ,  C10G2300/703 ,  C10G2300/802

摘要： A process for preparing a slurry catalyst is provided. The slurry catalyst is prepared from at least a Group VIB metal precursor and optionally at least a Promoter metal precursor selected from Group VIII, Group IIB, Group IIA, Group IVA metals and combinations thereof. The slurry catalyst comprises a plurality of dispersed particles in a hydrocarbon medium having an average particle size ranging from 1 to 300 nm. The slurry catalyst is then mixed with a hydrogen feed at a pressure from 1435 psig (10 MPa) to 3610 psig (25 MPa) and a temperature from 200-800° F. at 500 to 15,000 scf hydrogen per bbl of slurry catalyst for a minute to 20 hours, for the slurry catalyst to be saturated with hydrogen providing an increase of k-values in terms of HDS, HDN, and HDMCR of at least 15% compared to a slurry catalyst that is not saturated with hydrogen.

摘要翻译： 提供了一种制备浆料催化剂的方法。 浆料催化剂由至少VIB族金属前体和任选的至少一种选自VIII族，IIB族，IIA族，IVA族金属及其组合的促进剂金属前体制备。 浆料催化剂在平均粒径为1〜300nm的烃介质中含有多个分散粒子。 然后将浆料催化剂与氢气进料混合，压力为1435psig（10MPa）至3610psig（25MPa），温度为200-800°F，每桶浆料催化剂为500至15,000scf氢气 分钟至20小时，浆液催化剂用氢饱和，与不饱和氢气的浆料催化剂相比，HDS，HDN和HDMCR的k值提高至少15％。

公开(公告)号：US20120000821A1

公开(公告)日：2012-01-05

申请号：US13233477

申请日：2011-09-15

申请人： Shuwu Yang ,  Julie Chabot ,  Bruce Edward Reynolds ,  Bo Kou

发明人： Shuwu Yang ,  Julie Chabot ,  Bruce Edward Reynolds ,  Bo Kou

IPC分类号： C10G65/10

CPC分类号： C10G47/02 ,  C10G47/26 ,  C10G47/32 ,  C10G47/36 ,  C10G65/00 ,  C10G65/10 ,  C10G65/18 ,  C10G2300/205 ,  C10G2300/4075 ,  C10G2300/701 ,  C10G2300/802

摘要： A method to reduce metal deposit in the hydroprocessing or upgrade of heavy oil feedstock is provided. The method comprises feeding an improved catalyst feed to the system, with the improved catalyst feed comprising a fresh slurry catalyst and a deoiled spent catalyst, with the deoiled spent catalyst being present in an amount of at least 10% the catalyst feed for the heavy oil upgrade system to have at least a 5% reduction in metal contaminant build-up compared to heavy oil upgrade system without the deoiled spent catalyst in the feed.

摘要翻译： 提供了一种在重油原料的加氢处理或升级中减少金属沉积的方法。 该方法包括将改进的催化剂进料进料给系统，改进的催化剂进料包含新鲜的浆料催化剂和脱油的废催化剂，脱油的废催化剂的存在量为重油的催化剂进料的至少10％ 升级系统与重油升级系统相比，金属污染物累积量减少至少5％，而在进料中没有脱油废催化剂。

公开(公告)号：US08759242B2

公开(公告)日：2014-06-24

申请号：US13233455

申请日：2011-09-15

申请人： Shuwu Yang ,  Julie Chabot ,  Bruce Edward Reynolds

发明人： Shuwu Yang ,  Julie Chabot ,  Bruce Edward Reynolds

IPC分类号： B01J31/02 ,  C10G65/10 ,  C10G65/00 ,  C10G47/02 ,  C10G47/32 ,  C10G65/18 ,  C10G47/26

CPC分类号： C10G47/02 ,  C10G47/26 ,  C10G47/32 ,  C10G65/00 ,  C10G65/10 ,  C10G65/18 ,  C10G2300/701 ,  C10G2300/802

摘要： An improved slurry catalyst feed system for heavy oil upgraded is provided. The catalyst feed system comprises a fresh slurry catalyst and a deoiled spent catalyst, with the deoiled spent catalyst being present in an amount of at least 10% the catalyst feed system. The deoiled spent catalyst is a slurry catalyst that has been used in a hydroprocessing operation resulting in than 80% but more than 10% of original catalytic activity, and containing less than 10 wt. % soluble hydrocarbons as unconverted heavy oil feed. The deoiled spent catalyst is slurried in a hydrocarbon medium as dispersed particles prior to being fed to the heavy oil upgrade system.

摘要翻译： 提供了一种用于重油升级的改进的浆料催化剂进料系统。 催化剂进料系统包括新鲜的浆料催化剂和脱油的废催化剂，脱油的废催化剂的存在量为催化剂进料体系的至少10％。 脱油的废催化剂是在加氢操作中使用的浆料催化剂，其导致比原始催化活性高80％但大于10％，并且含有少于10wt。 ％可溶性烃作为未转化的重油进料。 脱油废催化剂在烃介质中作为分散颗粒在进料到重油升级系统之前浆化。

公开(公告)号：US20120172204A1

公开(公告)日：2012-07-05

申请号：US13331479

申请日：2011-12-20

申请人： Ling Jiao ,  Julie Chabot ,  Joseph V. Nguyen ,  Christopher Paul Dunckley ,  Shuwu Yang ,  Erin P. Maris ,  Oleg Mironov ,  Bruce Edward Reynolds ,  Alexander E. Kuperman

发明人： Ling Jiao ,  Julie Chabot ,  Joseph V. Nguyen ,  Christopher Paul Dunckley ,  Shuwu Yang ,  Erin P. Maris ,  Oleg Mironov ,  Bruce Edward Reynolds ,  Alexander E. Kuperman

IPC分类号： B01J35/10 ,  B01J31/02

CPC分类号： B01J23/883 ,  B01J23/24 ,  B01J23/85 ,  B01J23/8872 ,  B01J23/8873 ,  B01J27/051 ,  B01J27/0515 ,  B01J35/0073 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1095 ,  B01J37/20 ,  C10G49/04 ,  C10G49/06 ,  C10G49/12 ,  C10G2300/107 ,  C10G2300/1077 ,  C10G2300/205 ,  C10G2300/301 ,  C10G2300/701 ,  C10G2300/703 ,  C10G2300/802

摘要： An improved hydroprocessing slurry catalyst is provided for the upgrade of heavy oil feedstock. The catalyst comprises dispersed particles in a hydrocarbon medium with the dispersed particles have an average particle size ranging from 1 to 300 μm. The catalyst has a total pore volume of at least 0.5 cc/g and a polymodal pore distribution with at least 80% of pore sizes in the range of 5 to 2,000 Angstroms in diameter. The catalyst is prepared from sulfiding and dispersing a metal precursor solution in a hydrocarbon diluent, the metal precursor comprising at least a Primary metal precursor and optionally a Promoter metal precursor, the metal precursor solution having a pH of at least 4 and a concentration of less than 10 wt. % of Primary metal in solution.

摘要翻译： 提供改进的加氢处理浆料催化剂用于重油原料的升级。 该催化剂包含在烃介质中的分散颗粒，其中分散的颗粒的平均粒度范围为1至300μm。 催化剂具有至少0.5cc / g的总孔体积和直径为5至2,000埃范围内具有至少80％的孔径的多模式孔分布。 催化剂是通过将金属前体溶液硫化并分散在烃稀释剂中制备的，金属前体包含至少一种金属前体和任选的助催化剂金属前体，该金属前体溶液的pH值至少为4，浓度较低 超过10重量％ 溶液中初级金属的％。

公开(公告)号：US08809222B2

公开(公告)日：2014-08-19

申请号：US13331372

申请日：2011-12-20

申请人： Oleg Mironov ,  Alexander E. Kuperman ,  Julie Chabot ,  Shuwu Yang ,  Joseph V. Nguyen ,  Ling Jiao ,  Bruce Edward Reynolds ,  Axel Brait ,  Kenneth Kwik ,  Modinat Kotun

发明人： Oleg Mironov ,  Alexander E. Kuperman ,  Julie Chabot ,  Shuwu Yang ,  Joseph V. Nguyen ,  Ling Jiao ,  Bruce Edward Reynolds ,  Axel Brait ,  Kenneth Kwik ,  Modinat Kotun

IPC分类号： B01J27/02 ,  B01J27/047 ,  B01J27/049 ,  B01J27/043 ,  B01J27/045 ,  B01J23/00 ,  B01J23/40 ,  B01J23/42 ,  B01J23/44 ,  B01J23/58 ,  B01J23/70 ,  B01J23/74 ,  B01J23/85 ,  B01J23/883 ,  B01J23/887 ,  B01J27/051 ,  B01J23/24 ,  B01J35/00 ,  B01J37/20 ,  C10G49/04 ,  B01J35/10

CPC分类号： B01J23/883 ,  B01J23/24 ,  B01J23/85 ,  B01J23/8872 ,  B01J23/8873 ,  B01J27/051 ,  B01J27/0515 ,  B01J35/0073 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1095 ,  B01J37/20 ,  C10G49/04 ,  C10G49/06 ,  C10G49/12 ,  C10G2300/107 ,  C10G2300/1077 ,  C10G2300/205 ,  C10G2300/301 ,  C10G2300/701 ,  C10G2300/703 ,  C10G2300/802

摘要： An improved process for preparing a slurry catalyst for the upgrade of heavy oil feedstock is provided. In the process, high shear mixing is employed to generate an emulsion containing droplets of metal precursor in oil with droplet sizes ranging from 0.1 to 300 μm. The emulsion is subsequently sulfided with a sulfiding agent, or in-situ in a heavy oil feedstock to form a slurry catalyst. The in-situ sulfidation in heavy oil is under sufficient condition for the heavy oil feedstock to generate the sulfiding source needed for the sulfidation.

摘要翻译： 提供了一种用于制备用于重油原料升级的浆料催化剂的改进方法。 在此过程中，使用高剪切混合产生含有液滴尺寸范围为0.1至300μm的油中金属前体的液滴的乳液。 然后将乳液用硫化剂硫化，或在重油原料中原位形成浆料催化剂。 重油中的原位硫化在足够的条件下使重油原料产生硫化所需的硫化源。

公开(公告)号：US20120172206A1

公开(公告)日：2012-07-05

申请号：US13331630

申请日：2011-12-20

申请人： Joseph V. Nguyen ,  Julie Chabot ,  Ling Jiao ,  Christopher Paul Dunckley ,  Shuwu Yang ,  Erin P. Maris ,  Oleg Mironov ,  Bruce Edward Reynolds ,  Alexander E. Kuperman

发明人： Joseph V. Nguyen ,  Julie Chabot ,  Ling Jiao ,  Christopher Paul Dunckley ,  Shuwu Yang ,  Erin P. Maris ,  Oleg Mironov ,  Bruce Edward Reynolds ,  Alexander E. Kuperman

IPC分类号： B01J31/02

CPC分类号： B01J23/883 ,  B01J23/24 ,  B01J23/85 ,  B01J23/8872 ,  B01J23/8873 ,  B01J27/051 ,  B01J27/0515 ,  B01J35/0073 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1095 ,  B01J37/20 ,  C10G49/04 ,  C10G49/06 ,  C10G49/12 ,  C10G2300/107 ,  C10G2300/1077 ,  C10G2300/205 ,  C10G2300/301 ,  C10G2300/701 ,  C10G2300/703 ,  C10G2300/802

摘要： A method for preparing an improved slurry catalyst for the upgrade of heavy oil feedstock is provided. In one embodiment, the process comprises: sulfiding at least a metal precursor solution with at least a sulfiding agent forming a sulfided Group VIB catalyst precursor, the metal precursor solution having a pH of at least 4 and a concentration of less than 10 wt. % of Primary metal in solution; and mixing the catalyst precursor with a hydrocarbon diluent to form the slurry catalyst composition. The slurry catalyst prepared therefrom has a BET total surface area of at least 100 m2/g, a total pore volume of at least 0.5 cc/g and a polymodal pore distribution with at least 80% of pore sizes in the range of 5 to 2,000 Angstroms in diameter.

摘要翻译： 提供了一种制备用于提高重油原料的改进的浆料催化剂的方法。 在一个实施方案中，该方法包括：至少硫化金属前体溶液与至少一种形成硫化VIB族催化剂前体的硫化剂，金属前体溶液的pH值至少为4，浓度小于10wt。 溶液中一次金属的含量％ 并将催化剂前体与烃稀释剂混合以形成淤浆催化剂组合物。 由其制备的浆料催化剂具有至少100m 2 / g的BET总表面积，至少0.5cc / g的总孔体积和至少80％孔径在5至2,000范围内的多孔分布 直径埃。

公开(公告)号：US20120172205A1

公开(公告)日：2012-07-05

申请号：US13331528

申请日：2011-12-20

申请人： Julie Chabot ,  Ling Jiao ,  Joseph V. Nguyen ,  Christopher Paul Dunckley ,  Shuwu Yang ,  Erin P. Maris ,  Oleg Mironov ,  Bruce Edward Reynolds ,  Alexander E. Kuperman

发明人： Julie Chabot ,  Ling Jiao ,  Joseph V. Nguyen ,  Christopher Paul Dunckley ,  Shuwu Yang ,  Erin P. Maris ,  Oleg Mironov ,  Bruce Edward Reynolds ,  Alexander E. Kuperman

IPC分类号： B01J31/02

CPC分类号： B01J23/883 ,  B01J23/24 ,  B01J23/85 ,  B01J23/8872 ,  B01J23/8873 ,  B01J27/051 ,  B01J27/0515 ,  B01J35/0073 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1095 ,  B01J37/20 ,  C10G49/04 ,  C10G49/06 ,  C10G49/12 ,  C10G2300/107 ,  C10G2300/1077 ,  C10G2300/205 ,  C10G2300/301 ,  C10G2300/701 ,  C10G2300/703 ,  C10G2300/802

摘要： An improved hydroprocessing slurry catalyst is provided for the upgrade of heavy oil feedstock. The slurry catalyst is prepared from at least a Group VIB metal precursor compound and optionally at least a Promoter metal precursor compound. The catalyst comprises dispersed particles in a hydrocarbon medium with the dispersed particles have an average particle size ranging from 1 to 300 μm. The catalyst has a total surface area of at least 100 m2/g. The catalyst is prepared from sulfiding and dispersing a metal precursor solution in a hydrocarbon diluent, the metal precursor comprising at least a Primary metal precursor and optionally a Promoter metal precursor, the metal precursor solution having a pH of at least 4 and a concentration of less than 10 wt. % of Primary metal in solution.

摘要翻译： 提供改进的加氢处理浆料催化剂用于重油原料的升级。 浆料催化剂由至少VIB族金属前体化合物和任选的至少一种助催化剂金属前体化合物制备。 该催化剂包含在烃介质中的分散颗粒，其中分散的颗粒的平均粒度范围为1至300μm。 催化剂的总表面积至少为100m 2 / g。 催化剂是通过将金属前体溶液硫化并分散在烃稀释剂中制备的，金属前体包含至少一种金属前体和任选的助催化剂金属前体，该金属前体溶液的pH值至少为4，浓度较低 超过10重量％ 溶液中初级金属的％。

公开(公告)号：US09040446B2

公开(公告)日：2015-05-26

申请号：US13331630

申请日：2011-12-20

申请人： Joseph V. Nguyen ,  Julie Chabot ,  Ling Jiao ,  Christopher Paul Dunckley ,  Shuwu Yang ,  Erin P. Maris ,  Oleg Mironov ,  Bruce Edward Reynolds ,  Alexander E. Kuperman

发明人： Joseph V. Nguyen ,  Julie Chabot ,  Ling Jiao ,  Christopher Paul Dunckley ,  Shuwu Yang ,  Erin P. Maris ,  Oleg Mironov ,  Bruce Edward Reynolds ,  Alexander E. Kuperman

IPC分类号： B01J27/04 ,  B01J27/043 ,  B01J27/045 ,  B01J37/00 ,  B01J37/04 ,  B01J31/00 ,  B01J27/24 ,  B01J27/02 ,  B01J23/00 ,  B01J23/40 ,  B01J23/42 ,  B01J23/44 ,  B01J23/58 ,  B01J23/883 ,  B01J23/24 ,  B01J23/85 ,  B01J23/887 ,  B01J27/051 ,  B01J35/00 ,  B01J37/20 ,  C10G49/04 ,  C10G49/06 ,  C10G49/12 ,  B01J35/10

CPC分类号： B01J23/883 ,  B01J23/24 ,  B01J23/85 ,  B01J23/8872 ,  B01J23/8873 ,  B01J27/051 ,  B01J27/0515 ,  B01J35/0073 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1095 ,  B01J37/20 ,  C10G49/04 ,  C10G49/06 ,  C10G49/12 ,  C10G2300/107 ,  C10G2300/1077 ,  C10G2300/205 ,  C10G2300/301 ,  C10G2300/701 ,  C10G2300/703 ,  C10G2300/802

摘要： A method for preparing an improved slurry catalyst for the upgrade of heavy oil feedstock is provided. In one embodiment, the process comprises: sulfiding at least a metal precursor solution with at least a sulfiding agent forming a sulfided Group VIB catalyst precursor, the metal precursor solution having a pH of at least 4 and a concentration of less than 10 wt. % of Primary metal in solution; and mixing the catalyst precursor with a hydrocarbon diluent to form the slurry catalyst composition. The slurry catalyst prepared therefrom has a BET total surface area of at least 100 m2/g, a total pore volume of at least 0.5 cc/g and a polymodal pore distribution with at least 80% of pore sizes in the range of 5 to 2,000 Angstroms in diameter.

摘要翻译： 提供了一种制备用于提高重油原料的改进的浆料催化剂的方法。 在一个实施方案中，该方法包括：至少硫化金属前体溶液与至少一种形成硫化VIB族催化剂前体的硫化剂，金属前体溶液的pH值至少为4，浓度小于10wt。 溶液中一次金属的含量％ 并将催化剂前体与烃稀释剂混合以形成淤浆催化剂组合物。 由其制备的浆料催化剂具有至少100m 2 / g的BET总表面积，至少0.5cc / g的总孔体积和至少80％孔径在5至2,000范围内的多孔分布 直径埃。