利索-全球专利检索

  1. 登录
  2. 注册

搜索结果

39 条记录 (耗时 0.017 秒)

    Supported chromium oxide catalyst
    2.
    发明授权
    Supported chromium oxide catalyst 失效
    支持的氧化铬催化剂

    公开(公告)号：US5164353A

    公开(公告)日：1992-11-17

    申请号：US435681

    申请日：1989-11-14

    申请人： Siegfried Weber ,  Guido Funk

    发明人： Siegfried Weber ,  Guido Funk

    IPC分类号： C08F4/02 ,  C08F4/24 ,  C08F4/60 ,  C08F4/622 ,  C08F4/623 ,  C08F4/629 ,  C08F4/69 ,  C08F10/02

    CPC分类号： C08F10/02

    摘要： A supported catalyst for ethene polymerization by Phillips catalysis is disclosed. The supported catalyst is prepared by (1) mixing a porous silicate in an inert, organic liquid to produce a silicate suspension, (2) providing an ester of phosphoric acid or phosphorous acid, (3) mixing an organic liquid, a chromium compound, and a trialkylaluminum compound to produce a chromium compound/aluminum compound and combining the silicate suspension, the phosphorus compound and the chromium compound/aluminum compound suspension. This resulting suspension is evaporated to dryness to form a catalyst intermediate. The catalyst intermediate is heated in nitrogen, then heated in an oxygen-containing atmosphere, and then heated again in nitrogen to produce an activated catalyst. The activated catalyst is suspended in an organic liquid and treated with an alkyl boron compound to produce the desired supported catalyst.

    摘要翻译： 公开了通过菲利普斯催化剂进行乙烯聚合的负载型催化剂。 负载型催化剂的制备方法是：（1）将惰性有机液体中的多孔硅酸盐混合以制备硅酸盐悬浮液，（2）提供磷酸或亚磷酸的酯，（3）将有机液体，铬化合物， 和三烷基铝化合物，以制备铬化合物/铝化合物并将硅酸盐悬浮液，磷化合物和铬化合物/铝化合物悬浮液混合。 将所得悬浮液蒸发至干，形成催化剂中间体。 将催化剂中间体在氮气中加热，然后在含氧气氛中加热，然后在氮气中再次加热以产生活化的催化剂。 将活化的催化剂悬浮在有机液体中并用烷基硼化合物处理以产生所需的负载型催化剂。

    Phillips catalyst and its use for the preparation of ethylene/.alpha.-olefin copolymers
    4.
    发明授权
    Phillips catalyst and its use for the preparation of ethylene/.alpha.-olefin copolymers 失效
    菲利普斯催化剂及其在制备乙烯/α-烯烃共聚物中的应用

    公开(公告)号：US5557021A

    公开(公告)日：1996-09-17

    申请号：US512556

    申请日：1995-08-08

    申请人： Hans-Joachim Mueller ,  Kaspar Evertz ,  Siegfried Weber ,  Guido Funk ,  Rainer Konrad ,  Roland Saive

    发明人： Hans-Joachim Mueller ,  Kaspar Evertz ,  Siegfried Weber ,  Guido Funk ,  Rainer Konrad ,  Roland Saive

    IPC分类号： C08F2/42 ,  C08F4/00 ,  C08F4/02 ,  C08F4/06 ,  C08F4/22 ,  C08F4/24 ,  C08F10/00 ,  C08F10/02 ,  C07C2/24

    CPC分类号： C08F10/00

    摘要： A novel Phillips catalyst for the copolymerization of ethylene with .alpha.-olefins, contains, as a catalytically active component, a finely divided, aluminum silicate-supported, phosphorus-containing chromium catalyst. This can be prepared by applying at least one organic phosphorus(III), (IV) and/or (V) compound and at least one chromium(III) compound which does not react with said phosphorus compounds under the reaction conditions used, in succcession in any order or simultaneously, to a finely divided aluminum silicate hydrogel or xerogel with formation of a catalyst intermediate and activating the catalyst intermediate at elevated temperatures in an oxidizing atmosphere, with the result that the chromium catalyst is formed. The novel Phillips catalyst gives ethylene/.alpha.-olefin copolymers in which the comonomers are more uniformly distributed over the copolymer chains than is the case with ethylene/.alpha.-olefin copolymers which have been prepared with the aid of conventional Phillips catalysts. Moldings which have been produced from the ethylene/.alpha.-olefin copolymers obtained in the novel procedure have a particularly high environmental stress cracking resistance and an excellent creep rupture strength.

    摘要翻译： 用于乙烯与α-烯烃共聚的新颖的菲利普斯催化剂包含作为催化活性组分的细碎的含硅酸铝载体的含磷的铬催化剂。 这可以通过在所用的反应条件下施用至少一种不与所述磷化合物反应的有机磷（III），（IV）和/或（V）化合物和至少一种铬（III）化合物来制备， 以任何顺序或同时的方式，在形成催化剂中间体的细分的硅酸铝水凝胶或干凝胶中，并在氧化气氛中在高温下活化催化剂中间体，结果形成铬催化剂。 新型菲利普斯催化剂提供了乙烯/α-烯烃共聚物，其中共聚单体比共聚物链更均匀地分布在使用常规菲利普斯催化剂制备的乙烯/α-烯烃共聚物的情况下。 由新方法得到的乙烯/α-烯烃共聚物制成的成型品具有特别高的耐环境应力开裂性和优异的抗蠕变断裂强度。

    Phillips catalyst and its use for the preparation of ethylene/alpha-olefin copolymers
    5.
    发明授权
    Phillips catalyst and its use for the preparation of ethylene/alpha-olefin copolymers 失效
    菲利普斯催化剂及其用于制备乙烯/α-烯烃共聚物的用途

    公开(公告)号：US5480852A

    公开(公告)日：1996-01-02

    申请号：US247479

    申请日：1994-05-23

    申请人： Hans-Joachim Mueller ,  Kaspar Evertz ,  Siegfried Weber ,  Guido Funk ,  Rainer Konrad ,  Roland Saive

    发明人： Hans-Joachim Mueller ,  Kaspar Evertz ,  Siegfried Weber ,  Guido Funk ,  Rainer Konrad ,  Roland Saive

    IPC分类号： C08F2/42 ,  C08F4/00 ,  C08F4/02 ,  C08F4/06 ,  C08F4/22 ,  C08F4/24 ,  C08F10/00 ,  C08F10/02 ,  B01J27/182

    CPC分类号： C08F10/00

    摘要： A novel Phillips catalyst for the copolymerization of ethylene with .alpha.-olefins, contains, as a catalytically active component, a finely divided, aluminum silicate-supported, phosphorus-containing chromium catalyst. This can be prepared by applying at least one organic phosphorus(III), (IV) and/or (V) compound and at least one chromium(III) compound which does not react with said phosphorus compounds under the reaction conditions used, in succcession in any order or simultaneously, to a finely divided aluminum silicate hydrogel or xerogel with formation of a catalyst intermediate and activating the catalyst intermediate at elevated temperatures in an oxidizing atmosphere, with the result that the chromium catalyst is formed. The novel Phillips catalyst gives ethylene/.alpha.-olefin copolymers in which the comonomers are more uniformly distributed over the copolymer chains than is the case with ethylene/.alpha.-olefin copolymers which have been prepared with the aid of conventional Phillips catalysts. Moldings which have been produced from the ethylene/.alpha.-olefin copolymers obtained in the novel procedure have a particularly high environmental stress cracking resistance and an excellent creep rupture strength.

    摘要翻译： 用于乙烯与α-烯烃共聚的新颖的菲利普斯催化剂包含作为催化活性组分的细碎的含硅酸铝载体的含磷的铬催化剂。 这可以通过在所用的反应条件下施用至少一种不与所述磷化合物反应的有机磷（III），（IV）和/或（V）化合物和至少一种铬（III）化合物来制备， 以任何顺序或同时的方式，在形成催化剂中间体的细分的硅酸铝水凝胶或干凝胶中，并在氧化气氛中在高温下活化催化剂中间体，结果形成铬催化剂。 新型菲利普斯催化剂提供了乙烯/α-烯烃共聚物，其中共聚单体比共聚物链更均匀地分布在使用常规菲利普斯催化剂制备的乙烯/α-烯烃共聚物的情况下。 由新方法得到的乙烯/α-烯烃共聚物制成的成型品具有特别高的耐环境应力开裂性和优异的抗蠕变断裂强度。

    Preparation of homopolymers of ethene and copolymers of ethene with higher a-monoolefins using a Ziegler catalyst system
    7.
    发明授权
    Preparation of homopolymers of ethene and copolymers of ethene with higher a-monoolefins using a Ziegler catalyst system 失效
    使用齐格勒催化剂体系制备乙烯与乙烯共聚物与高级单环戊二烯的共聚物

    公开(公告)号：US5210160A

    公开(公告)日：1993-05-11

    申请号：US410047

    申请日：1989-09-19

    申请人： Roland Saive ,  Guido Funk ,  Rainer Hemmerich

    发明人： Roland Saive ,  Guido Funk ,  Rainer Hemmerich

    IPC分类号： C08F4/607 ,  C08F4/642 ,  C08F4/647 ,  C08F4/65 ,  C08F4/685 ,  C08F10/02

    CPC分类号： C08F10/02

    摘要： Homopolymerization and copolymerization of ethene is carried out using a Ziegler catalyst system consisting of (1) a transition metal catalyst component, (2) an organoaluminum catalyst component and (3) an organohalogen catalyst component. The component (1) used is the solid-phase product (VI) which has been obtained by a method in which (1.1) first (1.1.1) an inorganic oxidic substance (I) as a carrier and (1.1.2) a solution (II) of (IIa) a certain oxahydrocarbon and (IIb) a mixture of (IIb1) a vanadium trichloride/alcohol complex and (IIb2) a titanium trihalide or titanium trihalide/alcohol complex and (IIc) a silicon or boron compound are combined with formation of a suspension (III) and the latter is evaporated to form a solid-phase intermediate (IV) and (1.2) then (1.2.1) the intermediate (IV) obtained in (1.1) and (1.2.2) a dissolved organoaluminum compound (V) are combined with formation of a suspension, the solid-phase product (VI) formed as the suspended substance being the transition metal catalyst component (1).

    摘要翻译： 使用由（1）过渡金属催化剂组分，（2）有机铝催化剂组分和（3）有机卤化物催化剂组分组成的齐格勒催化剂体系进行乙烯的均聚和共聚。 所使用的组分（1）是通过以下方法获得的固相产物（VI）：（1.1）第一（1.1.1）作为载体的无机氧化物质（I）和（1.1.2）a （IIa）的某些氧杂烃的溶液（II）和（IIb）（IIb1）三氯化钒/醇络合物和（IIb2）三卤化钛或三卤化钛/醇络合物和（IIc）硅或硼化合物的混合物 （IV）和（1.2）然后（1.2.1）（1.1）和（1.2.2）中得到的中间体（Ⅳ），然后蒸发形成悬浮液（III） 将溶解的有机铝化合物（V）与形成悬浮液组合，形成为作为过渡金属催化剂组分（1）的悬浮物质的固相产物（VI）。

    Preparation of finely divided homopolymers and copolymers of ethene using a liquid alkane as reaction medium
    8.
    发明授权
    Preparation of finely divided homopolymers and copolymers of ethene using a liquid alkane as reaction medium 失效
    使用液体烷烃作为反应介质制备细碎的乙烯均聚物和共聚物

    公开(公告)号：US4794151A

    公开(公告)日：1988-12-27

    申请号：US035919

    申请日：1987-04-08

    申请人： Rudolf Mueller-Mall ,  Guido Funk ,  Robert Bachl ,  Peter Hennenberger ,  Erich Kolk

    发明人： Rudolf Mueller-Mall ,  Guido Funk ,  Robert Bachl ,  Peter Hennenberger ,  Erich Kolk

    IPC分类号： C08F2/06 ,  C08F2/14 ,  C08F2/18 ,  C08F10/02 ,  C08F210/16 ,  C08F10/08

    CPC分类号： C08F10/02 ,  C08F210/16 ,  Y10S526/909 ,  Y10S526/922

    摘要： A process for the continuous preparation of finely divided homopolymers and copolymers of ethene by catalytic polymerization in a circular tube reactor using a liquid alkane as reaction medium in which the ethene or ethene/comonomer mixture to be polymerized is present in dissolved form and the polymer formed is present in suspended form and running the reaction mixture as a cycle stream to which the feed materials are added by bleeding in and from which the polymer formed is withdrawn by bleeding out reaction mixture, comprising (a) maintaining the mean concentration C.sub.m of polymer in the cycle stream at a value within a certain range and (b) effecting the bleeding out of reaction mixture at a point of the cycle stream at which the concentration of polymer has a value which is lower than the mean concentration C.sub.m by a distinct and definite amount.

    摘要翻译： 通过催化聚合在圆管反应器中连续制备乙烯的均匀聚合物和共聚物的方法，其中使用液体烷烃作为反应介质，其中待聚合的乙烯或乙烯/共聚单体混合物以溶解形式存在并形成聚合物 以悬浮形式存在，并以作为循环流的方式运行反应混合物，通过渗出反应混合物，通过渗出所形成的聚合物而将原料加入到该循环流中，通过渗出反应混合物排出，其包括（a）将聚合物的平均浓度Cm保持在 循环流在一定范围内的值，和（b）在聚合物浓度具有低于平均浓度C m的值的循环流的点处，通过不同的和明确的方式实现反应混合物的渗出 量。

    Process for feeding a catalyst in a polymerization reactor
    9.
    发明授权
    Process for feeding a catalyst in a polymerization reactor 有权
    在聚合反应器中进料催化剂的方法

    公开(公告)号：US08431658B2

    公开(公告)日：2013-04-30

    申请号：US13142444

    申请日：2009-12-23

    申请人： Pietro Baita ,  Rainer Karer ,  Gerhardus Meier ,  Guido Funk ,  Gabriele Mei

    发明人： Pietro Baita ,  Rainer Karer ,  Gerhardus Meier ,  Guido Funk ,  Gabriele Mei

    IPC分类号： C08F4/44 ,  B01J31/02

    CPC分类号： B01J8/0015 ,  B01J8/1827 ,  B01J2208/00752 ,  B01J2208/00769 ,  C08F10/00 ,  C08F210/16 ,  C08F2/34 ,  C08F210/08 ,  C08F2500/12

    摘要： A process for introducing a catalyst powder based on a titanium compound supported on magnesium halide into a gas-phase olefin polymerization reactor, characterized in that it comprises: (a) storing the catalyst powder under an atmosphere of a liquid C3-C12 alkane; (b) withdrawing from step (a) a measured amount of said catalyst powder by means of a rotary valve; (c) transferring said metered amount of catalyst powder to a catalyst activation section by a continuous pick-up flow of a liquid C3-C12 alkane; (d) contacting the catalyst powder with a liquid phase comprising an organo-aluminum compound and optionally an external donor compound, at a temperature ranging from −20° C. to 60° C.; (e) introducing the activated catalyst powder in one or more gas-phase olefin polymerization reactors, where a gaseous mixture comprising at least one alpha-olefin is subjected to polymerization.

    摘要翻译： 将基于负载在卤化镁上的钛化合物的催化剂粉末引入气相烯烃聚合反应器的方法，其特征在于，其包括：（a）将催化剂粉末在液体C 3 -C 12烷烃的气氛下储存; （b）通过旋转阀从步骤（a）中取出测量量的所述催化剂粉末; （c）通过液体C 3 -C 12烷烃的连续提取流将所述计量的催化剂粉末转移到催化剂活化部分; （d）在-20℃至60℃的温度下使催化剂粉末与包含有机铝化合物和任选的外部供体化合物的液相接触; （e）将活化的催化剂粉末引入一个或多个气相烯烃聚合反应器中，其中包含至少一种α-烯烃的气体混合物进行聚合。

    Process for Feeding a Catalyst in a Polymerization Reactor
    10.
    发明申请
    Process for Feeding a Catalyst in a Polymerization Reactor 有权
    在聚合反应器中加入催化剂的方法

    公开(公告)号：US20110282013A1

    公开(公告)日：2011-11-17

    申请号：US13142444

    申请日：2009-12-23

    申请人： Pietro Baita ,  Rainer Karer ,  Gerhardus Meier ,  Guido Funk ,  Gabriele Mei

    发明人： Pietro Baita ,  Rainer Karer ,  Gerhardus Meier ,  Guido Funk ,  Gabriele Mei

    IPC分类号： C08F4/16

    CPC分类号： B01J8/0015 ,  B01J8/1827 ,  B01J2208/00752 ,  B01J2208/00769 ,  C08F10/00 ,  C08F210/16 ,  C08F2/34 ,  C08F210/08 ,  C08F2500/12

    摘要： A process for introducing a catalyst powder based on a titanium compound supported on magnesium halide into a gas-phase olefin polymerization reactor, characterized in that it comprises: (a) storing the catalyst powder under an atmosphere of a liquid C3-C12 alkane; (b) withdrawing from step (a) a measured amount of said catalyst powder by means of a rotary valve; (c) transferring said metered amount of catalyst powder to a catalyst activation section by a continuous pick-up flow of a liquid C3-C12 alkane; (d) contacting the catalyst powder with a liquid phase comprising an organo-aluminum compound and optionally an external donor compound, at a temperature ranging from −20° C. to 60° C.; (e) introducing the activated catalyst powder in one or more gas-phase olefin polymerization reactors, where a gaseous mixture comprising at least one alpha-olefin is subjected to polymerization.

    摘要翻译： 将基于负载在卤化镁上的钛化合物的催化剂粉末引入气相烯烃聚合反应器的方法，其特征在于，其包括：（a）将催化剂粉末在液体C 3 -C 12烷烃的气氛下储存; （b）通过旋转阀从步骤（a）中取出测量量的所述催化剂粉末; （c）通过液体C 3 -C 12烷烃的连续提取流将所述计量的催化剂粉末转移到催化剂活化部分; （d）在-20℃至60℃的温度下使催化剂粉末与包含有机铝化合物和任选的外部供体化合物的液相接触; （e）将活化的催化剂粉末引入一个或多个气相烯烃聚合反应器中，其中包含至少一种α-烯烃的气体混合物进行聚合。