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公开(公告)号：US4946880A
公开(公告)日：1990-08-07
申请号：US103961
申请日：1987-10-05
申请人： Silvestro Costanzi , Damiano Gussoni , Omero Zavattini, deceased , by Clara Pungiluppi, heir , by Renato Zavattini, heir , Luciano Pallini
发明人： Silvestro Costanzi , Damiano Gussoni , Omero Zavattini, deceased , by Clara Pungiluppi, heir , by Renato Zavattini, heir , Luciano Pallini
IPC分类号： C07D207/08 , C07D211/46 , C07F7/08 , C07F7/18 , C08K5/544 , C08L23/02 , C09D7/12 , C09D183/04 , C09K15/32
CPC分类号： C07D207/08 , C07D211/46 , C07F7/0896 , C07F7/182 , C08K5/5442 , Y10T428/31645 , Y10T428/31667 , Y10T428/31938
摘要： Reactive stabilizer compounds, to be used in the stabilization of organic polymers, contain a sterically hindered, N-substituted piperidinic, morpholinic or pyrrolidinic group, and at least a hydrolysable silicic function.Such compounds give rise, by hydrolysis of the silicic function, to complex resinous structures endowed with stabilizing properties.The reactive stabilizer compounds can spontaneously hydrolyse inside the polymer, or they can be stably supported on a solid support, or they can be chemically linked to the polymeric chain to be stabilized.
摘要翻译： 用于稳定有机聚合物的反应性稳定剂化合物含有空间位阻的N-取代的哌啶基，吗啉代或吡咯烷基，以及至少可水解的硅的功能。 这种化合物通过硅酸功能的水解产生复合的具有稳定性质的树脂结构。 反应性稳定剂化合物可以在聚合物内部自发水解，或者它们可以稳定地负载在固体载体上，或者它们可以化学连接到待稳定的聚合物链上。
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2.发明授权
公开(公告)号：US4935063A
公开(公告)日：1990-06-19
申请号：US242956
申请日：1988-09-09
CPC分类号： C09C1/3684 , C09C3/12 , C01P2004/61 , C01P2004/84 , C01P2006/80
摘要： Stabilizing inorganic fillers or pigments having simultaneous reinforcing effect and stabilizing effect on organic polymers are obtained by a process comprising the following stages:(a) bringing the inorganic filler or pigment into contact with a solution, in an inert organic solvent, of a sterically hindered amine comprising one or more alkoxysilane groups in its molecule;(b) maintaining the obtained mixture at higher than ambient temperature (20.degree.-25.degree. C.) for a period of at least 0.5 hours;(c) removing the solvent, treating at a temperature of 120.degree.-200.degree. C. and recovering the stabilizing filler or pigment obtained.
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3.发明授权Process of (co)polymerization of .alpha.-olefins in the presence of stabilizers 失效在稳定剂存在下，α-烯烃（共）聚合的方法
公开(公告)号：US5350786A
公开(公告)日：1994-09-27
申请号：US26097
申请日：1993-03-04
IPC分类号： C08F2/44 , C08F10/00 , C08K5/3435
CPC分类号： C08F10/00 , C08F110/06
摘要： Stabilizers for organic polymers, consisting of one or more compounds of the classis of the sterically hindered amines (HALS) are directly added to the reaction mixture during the (co)polymerization of the .alpha.-olefins or of their mixtures with other unsaturated monomers.The so-obtained polymeric compositions result perfectly stabilized and show a thermo- and photo-oxidative resistance higher than that of the same polymeric compositions to which the same stabilizers are added by a traditional route.
摘要翻译： 在α-烯烃或其混合物与其它不饱和单体的（共）聚合过程中，直接将有机聚合物的稳定剂（由空间位阻胺类的一种或多种化合物（HALS）组成）直接加入到反应混合物中。 如此获得的聚合物组合物完全稳定，并且显示比通过传统路线添加相同稳定剂的相同聚合物组合物的热和光氧化抗性更高。
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4.发明授权Process for the synthesis of allylated derivatives of 2,2,6,6-tetraalkylpiperidinols 失效合成2,2,6,6-四烷基哌啶醇的烯丙基化衍生物的方法
公开(公告)号：US5270470A
公开(公告)日：1993-12-14
申请号：US481725
申请日：1990-02-16
IPC分类号： C07D211/46 , C07D211/36
CPC分类号： C07D211/46
摘要： A process is disclosed for the synthesis of 4-allyloxy-2,2,6,6-tetraalkylpiperidinic derivatives by starting from the corresponding 2,2,6,6-tetraaLkyLpiperidinols and from an allyl halide, characterized in that the reaction is made to take place in the absence of water, and in the presence of a finely subdivided allyl-metal hydroxide and of small amounts of a phase-transfer catalyst. The products, which are thus obtained with yields higher than 90%, are useful a stabilizers for polymers or as intermediates for such products.
摘要翻译： 公开了用于合成4-烯丙氧基-2,2,6,6-四烷基哌啶衍生物的方法，由相应的2,2,6,6-四氢基哌啶醇和烯丙基卤开始，其特征在于使反应生成 在不存在水的情况下进行，并且在细分的烯丙基 - 金属氢氧化物和少量的相转移催化剂的存在下进行。 因此获得的产率高于90％的产品可用作聚合物的稳定剂或作为这种产品的中间体。
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公开(公告)号：US4898946A
公开(公告)日：1990-02-06
申请号：US56880
申请日：1987-06-03
IPC分类号： C07D211/44 , C07B61/00 , C07D211/46 , C08K5/3435
CPC分类号： C08K5/3435 , C07D211/46
摘要： A process is described for the preparation of N-allyl-2,2,6,6-tetraalkyl-piperidine derivatives which involves reaction of the corresponding 2,2,6,6-tetraalkyl-piperidine with an allylic carbonate in the presence of palladium catalysts. The products which are thus obtained are useful as polymer stabilizers and chemical intermediates.
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公开(公告)号：US5051458A
公开(公告)日：1991-09-24
申请号：US353097
申请日：1989-05-17
申请人： Silvestro Costanzi , Luigi Cassar , Carlo Bosetto , Carlo Neri , Damiano Gussoni
发明人： Silvestro Costanzi , Luigi Cassar , Carlo Bosetto , Carlo Neri , Damiano Gussoni
IPC分类号： C09K3/00 , C08G77/388 , C08G77/42 , C08K5/544 , C08K9/06 , C08L9/00 , C08L23/02 , C08L23/12 , C08L75/00 , C08L75/04 , C08L83/08 , C08L101/00 , C09K15/32
CPC分类号： C08K5/5442 , C08G77/388 , C08L101/00
摘要： Polymeric stabilizer compounds with a polyorganosiloxane structure suitable for stabilizing organic polymers against UV radiation and heat, containing sterically hindered piperidino groups in their molecule and easily prepared in well defined, predetermined structures.
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7.发明授权Stabilized polyolefinic compositions and stabilizer compounds suitable to that purpose 失效稳定的聚烯烃组合物和适用于该目的的稳定剂化合物
公开(公告)号：US4617333A
公开(公告)日：1986-10-14
申请号：US709546
申请日：1985-03-08
IPC分类号： C08K5/357 , C08K5/5373 , C08K5/34
CPC分类号： C08K5/357 , C08K5/5373
摘要： Stabilized polyolefinic compositions comprise a polyolefin, such as polyethylene and polypropylene and a stabilizing amount of an organic compound comprising at least one 3,3,5,5-tetramethylmorpholine or one 2,3,3,5,5-pentamethylene morpholine: ##STR1## wherein R is hydrogen or the methyl group; bearing a substituent on the carbon atom in the position 2 and/or on the nitrogen atom in the position 4 of the ring.
摘要翻译： 稳定的聚烯烃组合物包括聚烯烃，例如聚乙烯和聚丙烯，以及稳定量的包含至少一种3,3,5,5-四甲基吗啉或一种2,3,3,5,5-五亚甲基吗啉的有机化合物：
其中R是氢或甲基; 在环的位置2和/或位置4上的氮原子上的碳原子上具有取代基。 -
公开(公告)号：US6056897A
公开(公告)日：2000-05-02
申请号：US25244
申请日：1998-02-18
CPC分类号： C08K5/5442 , C08J3/226 , C08K5/1545 , C08J2423/00
摘要： Solid form of a stabilizer for organic polymers consisting of one or more tocopherols, as such or in formulation, absorbed on porous polypropylene with a high crystallinity, in a quantity ranging from 30% to 85% by weight. The above tocopherols, as such or in formulation, can also be used in a mixture with other stabilizers such as, for example, secondary antioxidants containing phosphorous or sulfur, sterically hindered phenols and sterically hindered amines.
摘要翻译： 一种由一种或多种生育酚组成的有机聚合物的固体形式，如此或在制剂中，吸收在具有高结晶度的多孔聚丙烯上，其量为30重量％至85重量％。 上述生育酚本身或在制剂中也可以与其它稳定剂的混合物使用，例如含有磷或硫的二级抗氧化剂，空间位阻酚和空间位阻胺。
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公开(公告)号：US20080033079A1
公开(公告)日：2008-02-07
申请号：US10585421
申请日：2004-01-07
IPC分类号： C08L77/00 , C08K3/32 , C08K5/3492
摘要： The present invention relates to a thermoplastic composition comprising at least aluminium hypophosphite (aluminium phosphinate), corresponding to the chemical formula Al(H2PO2)3 as halogen-free flame retardant agent, and at least a polymer based on polyamide. The flame retarded halogen-free thermoplastic moulding compositions according to the invention is used to produce articles based on polyamide polymers with or without glass fiber reinforcement, which are flame retarded.
摘要翻译： 本发明涉及一种热塑性组合物，其包含至少次磷酸铝（次膦酸铝），其对应于化学式Al（H 2 PO 3）3 SUB>作为无卤阻燃剂，和至少一种基于聚酰胺的聚合物。 根据本发明的阻燃无卤素热塑性模塑组合物用于生产基于具有或不具有阻燃性的玻璃纤维增强剂的聚酰胺聚合物的制品。
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10.发明授权Polyolefin compositions stabilized against UV light radiations with open-chain hindered amines 失效使用开链受阻胺稳定抗紫外线辐射的聚烯烃组合物
公开(公告)号：US4321190A
公开(公告)日：1982-03-23
申请号：US213656
申请日：1980-12-05
IPC分类号： C08L23/00 , C08K5/17 , C08L101/00
CPC分类号： C08K5/17
摘要： This invention relates to particular polyolefin compositions which contain, as stabilizers against UV-light radiations, open-chain amine compounds which are hindered in the alpha-position by alkyl radicals, said amine compounds corresponding to the following general formula: ##STR1## wherein R', R", R"', R.sup.IV, R.sup.V and R.sup.VI which can be equal or different, are radicals of aliphatic hydrocarbons with a number of C-atoms variable from 1 to 20, or can be hydrogen atoms, n is an integer variable from 2 to 12, and n' is an integer comprised between 1 and 15.
摘要翻译： 本发明涉及特定的聚烯烃组合物，其包含作为UV光辐射的稳定剂的通过烷基阻碍在α-位上的开链胺化合物，所述胺化合物对应于以下通式：其中R 可以相同或不同的R'，R“'，RIV，RV和RVI是C原子数可以为1至20的脂肪族烃基，或者可以是氢原子，n是 整数变量从2到12，n'是1到15之间的整数。
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