Process for the Oxidative Coupling of Hydrocarbons
    2.
    发明申请
    Process for the Oxidative Coupling of Hydrocarbons 有权
    碳氢化合物的氧化偶合过程

    公开(公告)号:US20130231513A1

    公开(公告)日:2013-09-05

    申请号:US13867295

    申请日:2013-04-22

    IPC分类号: C07C2/84

    摘要: A method for the oxidative coupling of hydrocarbons, such as the oxidative coupling of methane to toluene, includes providing an oxidative catalyst inside a reactor, and carrying out the oxidative coupling reaction under a set of reaction conditions. The oxidative catalyst includes (A) at least one element selected from the group consisting of the Lanthanoid group, Mg, Ca, and the elements of Group 4 of the periodic table (Ti, Zr, and Hf); (B) at least one element selected from the group consisting of the Group 1 elements of Li, Na, K, Rb, Cs, and the elements of Group 3 (including La and Ac) and Groups 5-15 of the periodic table; (C) at least one element selected from the group consisting of the Group 1 elements of Li, Na, K, Rb, Cs, and the elements Ca, Sr, and Ba; and (D) oxygen.

    摘要翻译: 烃的氧化偶合的方法,例如甲烷氧化偶联甲苯,包括在反应器内提供氧化催化剂,并在一组反应条件下进行氧化偶联反应。 氧化催化剂包括(A)选自镧系元素,Mg,Ca和元素周期表第4族元素(Ti,Zr和Hf)中的至少一种元素; (B)选自Li,Na,K,Rb,Cs的第1族元素和第3族元素(包括La和Ac)和元素周期表第5-15族中的至少一种元素; (C)选自Li,Na,K,Rb,Cs族元素和元素Ca,Sr和Ba中的至少一种元素; 和(D)氧气。

    Process for the oxidative coupling of hydrocarbons
    3.
    发明授权
    Process for the oxidative coupling of hydrocarbons 失效
    碳氢化合物的氧化偶合方法

    公开(公告)号:US08450546B2

    公开(公告)日:2013-05-28

    申请号:US12494138

    申请日:2009-06-29

    IPC分类号: C07C2/66

    摘要: A method for the oxidative coupling of hydrocarbons, such as the oxidative coupling of methane to toluene, includes providing an oxidative catalyst inside a reactor, and carrying out the oxidative coupling reaction under a set of reaction conditions. The oxidative catalyst includes (A) at least one element selected from the group consisting of the Lanthanoid group, Mg, Ca, and the elements of Group 4 of the periodic table (Ti, Zr, and Hf); (B) at least one element selected from the group consisting of the Group 1 elements of Li, Na, K, Rb, Cs, and the elements of Group 3 (including La and Ac) and Groups 5-15 of the periodic table; (C) at least one element selected from the group consisting of the Group 1 elements of Li, Na, K, Rb, Cs, and the elements Ca, Sr, and Ba; and (D) oxygen.

    摘要翻译: 烃的氧化偶合的方法,例如甲烷氧化偶联甲苯,包括在反应器内提供氧化催化剂,并在一组反应条件下进行氧化偶联反应。 氧化催化剂包括(A)选自镧系元素,Mg,Ca和元素周期表第4族元素(Ti,Zr和Hf)中的至少一种元素; (B)选自Li,Na,K,Rb,Cs的第1族元素和第3族元素(包括La和Ac)和元素周期表第5-15族中的至少一种元素; (C)选自Li,Na,K,Rb,Cs族元素和元素Ca,Sr和Ba中的至少一种元素; 和(D)氧气。

    Process for the oxidative coupling of methane
    6.
    发明授权
    Process for the oxidative coupling of methane 有权
    甲烷氧化偶联的方法

    公开(公告)号:US08912381B2

    公开(公告)日:2014-12-16

    申请号:US12494117

    申请日:2009-06-29

    摘要: A method for the oxidative coupling of hydrocarbons, such as the oxidative coupling of methane, includes providing an oxidative catalyst inside a reactor, and carrying out the oxidative coupling reaction under a set of reaction conditions. The oxidative catalyst includes (A) at least one element selected from the group consisting of the Lanthanoid group, Mg, Ca, and the elements of Group 4 of the periodic table (Ti, Zr, and Hf); (B) at least one element selected from the group consisting of the Group 1 elements of Li, Na, K, Rb, Cs, and the elements of Group 3 (including La and Ac) and Groups 5-15 of the periodic table; (C) at least one element selected from the group consisting of the Group 1 elements of Li, Na, K, Rb, Cs, and the elements Ca, Sr, and Ba; and (D) oxygen.

    摘要翻译: 烃的氧化偶合的方法,例如甲烷的氧化偶联,包括在反应器内提供氧化催化剂,并在一组反应条件下进行氧化偶联反应。 氧化催化剂包括(A)选自镧系元素,Mg,Ca和元素周期表第4族元素(Ti,Zr和Hf)中的至少一种元素; (B)选自Li,Na,K,Rb,Cs的第1族元素和第3族元素(包括La和Ac)和元素周期表第5-15族中的至少一种元素; (C)选自Li,Na,K,Rb,Cs族元素和元素Ca,Sr和Ba中的至少一种元素; 和(D)氧气。

    Addition of a base to enhance product yield in alkylation reactions
    7.
    发明授权
    Addition of a base to enhance product yield in alkylation reactions 有权
    添加碱以提高烷基化反应中的产物收率

    公开(公告)号:US08785706B2

    公开(公告)日:2014-07-22

    申请号:US13457508

    申请日:2012-04-27

    IPC分类号: C07C15/073 C07C15/46

    摘要: A process for making styrene including providing toluene, a co-feed, and a C1 source to a reactor containing a catalyst having acid sites and reacting toluene with the C1 source in the presence of the catalyst and the co-feed to form a product stream containing ethylbenzene and styrene, wherein the C1 source is selected from methanol, formaldehyde, formalin, trioxane, methylformcel, paraformaldehyde, methylal, dimethyl ether, and wherein the co-feed removes at least a portion of the acid sites on the catalyst. The co-feed can be selected from the group of aniline, amines, cresol, anisol, and combinations thereof.

    摘要翻译: 一种制备苯乙烯的方法,包括在含有具有酸性位点的催化剂的反应器中提供甲苯,共进料和C1源,并在催化剂和共进料存在下使甲苯与C1源反应形成产物流 含有乙苯和苯乙烯,其中C1源选自甲醇,甲醛,福尔马林,三恶烷,甲基甲缩醛,多聚甲醛,甲缩醛,二甲醚,并且其中所述共进料除去催化剂上至少一部分酸性位点。 共进料可以选自苯胺,胺,甲酚,茴香醚及其组合。

    METHOD FOR ALKYLATION OF TOLUENE IN A PRE-EXISTING DEHYDROGENATION PLANT
    9.
    发明申请
    METHOD FOR ALKYLATION OF TOLUENE IN A PRE-EXISTING DEHYDROGENATION PLANT 审中-公开
    在先前脱氢植物中氧化钛的方法

    公开(公告)号:US20120296131A1

    公开(公告)日:2012-11-22

    申请号:US13457507

    申请日:2012-04-27

    IPC分类号: C07C2/88

    摘要: A process for making styrene in a pre-existing facility including an infrastructure capable of producing styrene, wherein the infrastructure includes at least one dehydrogenation unit. The process includes coupling an alkylation unit including an alkylation reactor to the infrastructure and contacting toluene with a C1 source in the presence of a first catalyst and a co-feed in the alkylation reactor to form a first product stream comprising styrene and ethylbenzene. The styrene and ethylbenzene from the first product stream are routed for further processing to a portion of the pre-existing facility.

    摘要翻译: 一种在预先存在的设施中制备苯乙烯的方法,包括能够生产苯乙烯的基础设施,其中基础设施包括至少一个脱氢单元。 该方法包括将包括烷基化反应器的烷基化单元与基础设施偶联,并在烷基化反应器中在第一催化剂和共进料存在下将甲苯与C1源接触以形成包含苯乙烯和乙苯的第一产物流。 来自第一产物流的苯乙烯和乙苯被路由以进一步处理到一部分预先存在的设施。