公开(公告)号：US20140241982A1

公开(公告)日：2014-08-28

申请号：US14185115

申请日：2014-02-20

申请人： Stacey I. Zones ,  Alexander S. Katz ,  Isao Ogino ,  Xiaoying Ouyong

发明人： Stacey I. Zones ,  Alexander S. Katz ,  Isao Ogino ,  Xiaoying Ouyong

IPC分类号： B01J29/86

CPC分类号： B01J29/86 ,  B01J29/061 ,  B01J29/072 ,  B01J29/70 ,  B01J29/76 ,  B01J35/1014 ,  C01B39/026 ,  C01B39/48

摘要： A zeolite material is provided having non-boron heteroatoms on the external surface of the zeolitic material lattice framework and B heteroatoms, or silanols created from boron hydrolysis, throughout the remainder of the lattice framework. The lattice framework of the zeolite material comprises large pore 12 member ring or larger openings at the external surface of the framework, and 10 member ring or smaller openings beneath the external surface large pore openings. Also provided is a process for preparing the zeolitic material.

摘要翻译： 提供沸石材料，其在沸石材料晶格框架的外表面上具有非硼杂原子，并且在整个晶格框架的其余部分中提供B杂原子或由硼水解生成的硅烷醇。 沸石材料的晶格框架在框架的外表面包括大孔12构件环或更大的开口，以及在外表面下方的10个孔或更小的开口较大孔隙。 还提供了制备沸石材料的方法。

公开(公告)号：US09636669B2

公开(公告)日：2017-05-02

申请号：US14185115

申请日：2014-02-20

申请人： Stacey I. Zones ,  Alexander S. Katz ,  Isao Ogino ,  Xiaoying Ouyong

发明人： Stacey I. Zones ,  Alexander S. Katz ,  Isao Ogino ,  Xiaoying Ouyong

IPC分类号： C01B39/02 ,  C01B39/48 ,  B01J29/06 ,  B01J29/072 ,  B01J29/86 ,  B01J29/70 ,  B01J29/76 ,  B01J35/10

CPC分类号： B01J29/86 ,  B01J29/061 ,  B01J29/072 ,  B01J29/70 ,  B01J29/76 ,  B01J35/1014 ,  C01B39/026 ,  C01B39/48

摘要： A zeolite material is provided having non-boron heteroatoms on the external surface of the zeolitic material lattice framework and B heteroatoms, or silanols created from boron hydrolysis, throughout the remainder of the lattice framework. The lattice framework of the zeolite material comprises large pore 12 member ring or larger openings at the external surface of the framework, and 10 member ring or smaller openings beneath the external surface large pore openings. Also provided is a process for preparing the zeolitic material.

公开(公告)号：US09522390B2

公开(公告)日：2016-12-20

申请号：US13161091

申请日：2011-06-15

申请人： Alexander Katz ,  Isao Ogino ,  Stacey I. Zones

发明人： Alexander Katz ,  Isao Ogino ,  Stacey I. Zones

IPC分类号： C01B39/02 ,  B01J29/70 ,  C01B39/48 ,  C01B39/46 ,  B01J37/00

CPC分类号： B01J29/7038 ,  B01J29/041 ,  B01J29/65 ,  B01J29/70 ,  B01J29/7088 ,  B01J29/86 ,  B01J35/002 ,  B01J35/1057 ,  B01J35/1061 ,  B01J37/0072 ,  B01J37/343 ,  B01J2229/34 ,  B01J2229/37 ,  B01J2229/38 ,  C01B39/026 ,  C01B39/38 ,  C01B39/40 ,  C01B39/46 ,  C01B39/48

摘要： The present invention is directed to the synthesis of novel delaminated layered zeolite precursor materials prepared by fluoride/chloride anion-promoted exfoliation. The method comprises, for example, using a combination of fluoride and chloride anions at a mild pH in aqueous solution to affect delamination of a layered zeolite precursor. The method can also comprise using a combination of fluoride and chloride anions in a non-aqueous solution comprising an organic solvent. The method may be used in conjunction with either acidification or sonication, or both. The resulting delaminated zeolite precursors are then isolated. Precursors that are then isolated lack amorphous silica content. The UCB-1 product is an example of such a novel oxide material and is obtained in yields in excess of 90% without the need for sonication.

摘要翻译： 本发明涉及通过氟化物/氯化物阴离子促进剥离制备的新型脱层分层沸石前体材料的合成。 该方法包括例如在温和的pH在水溶液中使用氟化物和氯化物阴离子的组合以影响层状沸石前体的分层。 该方法还可以包括在包含有机溶剂的非水溶液中使用氟化物和氯化物阴离子的组合。 该方法可以与酸化或超声处理或二者结合使用。 然后分离得到的分层沸石前体。 然后分离的前体缺乏无定形二氧化硅含量。 UCB-1产品是这种新型氧化物材料的一个例子，其产率超过90％而不需要超声处理。

公开(公告)号：US20120148487A1

公开(公告)日：2012-06-14

申请号：US13161091

申请日：2011-06-15

申请人： Alexander Katz ,  Isao Ogino ,  Stacey I. Zones

发明人： Alexander Katz ,  Isao Ogino ,  Stacey I. Zones

IPC分类号： C01B39/00 ,  C01B39/54 ,  C01B39/02

CPC分类号： B01J29/7038 ,  B01J29/041 ,  B01J29/65 ,  B01J29/70 ,  B01J29/7088 ,  B01J29/86 ,  B01J35/002 ,  B01J35/1057 ,  B01J35/1061 ,  B01J37/0072 ,  B01J37/343 ,  B01J2229/34 ,  B01J2229/37 ,  B01J2229/38 ,  C01B39/026 ,  C01B39/38 ,  C01B39/40 ,  C01B39/46 ,  C01B39/48

摘要： The present invention is directed to the synthesis of novel delaminated layered zeolite precursor materials prepared by fluoride/chloride anion-promoted exfoliation. The method comprises, for example, using a combination of fluoride and chloride anions at a mild pH in aqueous solution to affect delamination of a layered zeolite precursor. The method can also comprise using a combination of fluoride and chloride anions in a non-aqueous solution comprising an organic solvent. The method may be used in conjunction with either acidification or sonication, or both. The resulting delaminated zeolite precursors are then isolated. Precursors that are then isolated lack amorphous silica content. The UCB-1 product is an example of such a novel oxide material and is obtained in yields in excess of 90% without the need for sonication.

摘要翻译： 本发明涉及通过氟化物/氯化物阴离子促进剥离制备的新型脱层分层沸石前体材料的合成。 该方法包括例如在温和的pH在水溶液中使用氟化物和氯化物阴离子的组合以影响层状沸石前体的分层。 该方法还可以包括在包含有机溶剂的非水溶液中使用氟化物和氯化物阴离子的组合。 该方法可以与酸化或超声处理或二者结合使用。 然后分离得到的分层沸石前体。 然后分离的前体缺乏无定形二氧化硅含量。 UCB-1产品是这种新型氧化物材料的一个例子，其产率超过90％而不需要超声处理。

公开(公告)号：US09718048B2

公开(公告)日：2017-08-01

申请号：US14587527

申请日：2014-12-31

申请人： Alexander Katz ,  Isao Ogino ,  Stacey Ian Zones

发明人： Alexander Katz ,  Isao Ogino ,  Stacey Ian Zones

IPC分类号： C01B39/02 ,  C01B39/38 ,  C01B39/40 ,  C01B39/46 ,  C01B39/48 ,  B01J29/70 ,  B01J29/65 ,  B01J29/04 ,  B01J37/00 ,  B01J37/34 ,  B01J29/86 ,  B01J35/00 ,  B01J35/10

CPC分类号： B01J29/7038 ,  B01J29/041 ,  B01J29/65 ,  B01J29/70 ,  B01J29/7088 ,  B01J29/86 ,  B01J35/002 ,  B01J35/1057 ,  B01J35/1061 ,  B01J37/0072 ,  B01J37/343 ,  B01J2229/34 ,  B01J2229/37 ,  B01J2229/38 ,  C01B39/026 ,  C01B39/38 ,  C01B39/40 ,  C01B39/46 ,  C01B39/48

摘要： The present invention is directed to the synthesis of novel delaminated layered zeolite precursor materials prepared by fluoride/chloride anion-promoted exfoliation. The method comprises, for example, using a combination of fluoride and chloride anions at a mild pH in a non-aqueous solution to affect delamination of a layered zeolite precursor, generally comprising an organic solvent. The method may be used in conjunction with either acidification or sonication, or both. The resulting delaminated zeolite precursors are then isolated. Precursors that are then isolated lack amorphous silica content. The UCB-1 product is an example of such a novel oxide material and is obtained in yields in excess of 90% without the need for sonication.

公开(公告)号：US09718049B2

公开(公告)日：2017-08-01

申请号：US14587608

申请日：2014-12-31

申请人： Alexander Katz ,  Isao Ogino ,  Stacey Ian Zones

发明人： Alexander Katz ,  Isao Ogino ,  Stacey Ian Zones

IPC分类号： C01B39/02 ,  C01B39/38 ,  C01B39/40 ,  C01B39/46 ,  C01B39/48 ,  B01J29/70 ,  B01J29/65 ,  B01J29/04 ,  B01J37/00 ,  B01J37/34 ,  B01J29/86 ,  B01J35/00 ,  B01J35/10

CPC分类号： B01J29/7038 ,  B01J29/041 ,  B01J29/65 ,  B01J29/70 ,  B01J29/7088 ,  B01J29/86 ,  B01J35/002 ,  B01J35/1057 ,  B01J35/1061 ,  B01J37/0072 ,  B01J37/343 ,  B01J2229/34 ,  B01J2229/37 ,  B01J2229/38 ,  C01B39/026 ,  C01B39/38 ,  C01B39/40 ,  C01B39/46 ,  C01B39/48

摘要： The present invention is directed to the synthesis of novel delaminated layered zeolite precursor materials prepared by fluoride/chloride anion-promoted exfoliation. The method comprises, for example, using a combination of fluoride and chloride anions at a mild pH in aqueous solution to affect delamination of a layered zeolite precursor. The method can also comprise using a combination of fluoride and chloride anions in a non-aqueous solution comprising an organic solvent. The method may be used in conjunction with either acidification or sonication, or both. The resulting delaminated zeolite precursors are then isolated. Precursors that are then isolated lack amorphous silica content. The UCB-1 product is an example of such a novel oxide material and is obtained in yields in excess of 90% without the need for sonication.

公开(公告)号：US06375740B1

公开(公告)日：2002-04-23

申请号：US09678321

申请日：2000-10-03

申请人： Isao Ogino ,  Yukikazu Aoki

发明人： Isao Ogino ,  Yukikazu Aoki

IPC分类号： B05C1300

CPC分类号： C23C2/02

摘要： A heating furnace (2) heats a workpiece to be plated. An ingot preheating furnace (8) encloses an ingot carrying device (7) that carries ingots (6) to a place near a melting furnace (3) that melts the ingots (6) of a plating material, contains the molten plating material in which a workpiece to be plated is immersed. The ingot preheating furnace (8) preheats the ingots (6) supported by the ingot carrying device (7) at a temperature below the melting point of the ingots (6) by an exhaust gas (G) discharged from the heating furnace (2).

摘要翻译： 加热炉（2）加热要被镀的工件。 铸锭预热炉（8）包围铸锭运送装置（7），该铸块运送装置（7）将铸锭（6）运送到熔化炉料（6）附近的熔融炉（3）的地方，熔化炉（6）包含镀层材料， 待镀的工件被浸没。 锭预热炉（8）通过从加热炉（2）排出的废气（G）在低于锭料（6）的熔点的温度下预热由锭料运送装置（7）支撑的锭料（6） 。

公开(公告)号：US4946614A

公开(公告)日：1990-08-07

申请号：US366066

申请日：1989-06-14

申请人： Yuria Saito ,  Isao Ogino ,  Osamu Nakamura ,  Yoshifumi Yamamoto

发明人： Yuria Saito ,  Isao Ogino ,  Osamu Nakamura ,  Yoshifumi Yamamoto

IPC分类号： C04B35/00 ,  C01B33/20 ,  C01B37/00 ,  C03C4/14 ,  C04B35/48 ,  H01B1/08 ,  H01M6/18 ,  H01M10/39

CPC分类号： H01M10/3918 ,  C04B35/481 ,  H01M6/185

摘要： An ionic conductor comprising an oxide Na.sup.+ ionic conductor represented by the formula Na.sub.4 Zr.sub.2 Si.sub.3 O.sub.12 and a solid superacid represented by the formula SO.sub.4.sup.2- /ZrO.sub.2 incorporated therein as a dispersoid.

摘要翻译： 一种离子导体，其包含由式Na 4 Zr 2 Si 3 O 12表示的氧化物Na +离子导体和由其分子结构的式SO42- / ZrO2表示的固体超强酸。

公开(公告)号：US4380575A

公开(公告)日：1983-04-19

申请号：US320429

申请日：1981-11-12

申请人： Osamu Nakamura ,  Isao Ogino ,  Teruo Kodama

发明人： Osamu Nakamura ,  Isao Ogino ,  Teruo Kodama

IPC分类号： H01M8/04 ,  H01M8/10 ,  H01M8/00

CPC分类号： H01M8/1016 ,  H01M8/04119 ,  H01M8/1007

摘要： In the conversion of chemical energy into electric energy by the electrochemical reaction of a gaseous anodic reactant and a gaseous cathodic reactant through the medium of a heteropoly acid solid electrolyte, the life of the solid electrolyte is notably increased by passing each reactant through pools of a saturated aqueous solution of a specific salt bordering on closed empty spaces thereby allowing the reactants to acquire prescribed humidities prior to the contact thereof with the anode and cathode.

摘要翻译： 在通过气态阳极反应物和气态阴极反应物通过杂多酸固体电解质的介质的电化学反应将化学能转化为电能时，通过使每个反应物通过一个 饱和的与封闭的空的空间接近的特定盐的水溶液，从而允许反应物在与阳极和阴极接触之前获得规定的湿度。

公开(公告)号：US4024036A

公开(公告)日：1977-05-17

申请号：US653219

申请日：1976-01-28

申请人： Osamu Nakamura ,  Teruo Kodama ,  Isao Ogino ,  Yoshizo Miyake

发明人： Osamu Nakamura ,  Teruo Kodama ,  Isao Ogino ,  Yoshizo Miyake

IPC分类号： C25B13/04 ,  H01M8/10 ,  H01M10/36 ,  C25B1/02 ,  H01M6/18

CPC分类号： H01M10/0562 ,  C25B13/04 ,  H01M8/10 ,  H01M8/1004

摘要： Disclosed is a proton permselective solid-state member which is formed of a heteropoly acid represented by the generic formula, H.sub.m [X.sub.x.sup.. Y.sub.y.sup.. O.sub.z ].sup.. nH.sub.2 O, or a salt thereof. Said permselective member can be used as an electrolyte in the fuel cell and as a permselective membrane in the hydrogen gas refining system.

摘要翻译： 公开了由通式Hm [Xx.Yy.Oz]·nH2O或其盐表示的杂多酸形成的质子选择性固体成分。 所述选择选择性部件可以用作燃料电池中的电解质，也可用作氢气精炼系统中的选择性选择性膜。