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公开(公告)号：US5178802A
公开(公告)日：1993-01-12
申请号：US601007
申请日：1990-10-22
摘要： The adhesion of polyolefin objects, in particular highly oriented polyethylene filaments, to, for instance, polar matrices is improved by oxidizing the surface of the objects and then treating it with a solution of a silane compound, a titanate or a chromium complex.
摘要翻译： 通过氧化物体的表面，然后用硅烷化合物，钛酸盐或铬络合物的溶液处理聚烯烃物体，特别是高度取向的聚乙烯长丝，例如极性基质的粘附性得到改善。
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2.发明授权Elongated object made of a copolymer of carbon monoxide and an olefinically unsaturated monomer 失效由一氧化碳和烯属不饱和单体的共聚物制成的细长物体
公开(公告)号：US5281692A
公开(公告)日：1994-01-25
申请号：US775978
申请日：1991-10-31
CPC分类号： C08J5/18 , C08G67/02 , D01F6/30 , C08J2323/02
摘要： Elongated object, made of an orientated alternating copolymer of carbon monoxide and an olefinically unsaturated monomer, which has a modulus of elasticity of at least 16 GPa, and a method for the production of objects from an alternating copolymer, orientated by stretching, of carbon monoxide and an olefinically unsaturated monomer, by dissolving the copolymer in a suitable solvent, converting the solution obtained, at a temperature above the dissolving point of the solution, to an object consisting of the solution, converting the object consisting of the solution to a solvent-containing object consisting of the copolymer, completely or partially removing the solvent from the solvent-containing object consisting of the copolymer and stretching at least the object thus obtained, or the solvent-containing object consisting of the copolymer, at elevated tempera-ture, it being possible for the stretching of tapes and films also to take place in two directions.
摘要翻译： PCT No.PCT / NL90 / 00072 Sec。 371日期1991年3月31日 102（e）日期1991年10月31日PCT提交1990年5月16日PCT公布。 WO90 / 14453 PCT出版物 日期：1990年11月29日，由具有至少16GPa的弹性模量的一氧化碳和烯属不饱和单体的取向交替共聚物制成的长型物体，以及由交替共聚物制造物体的方法， 通过将共聚物溶解在合适的溶剂中，通过拉伸一氧化碳和烯属不饱和单体取向，将所得溶液在溶液的溶解点以上的温度下转化成由溶液组成的物体， 由共聚物组成的含溶剂物体的溶液，从由共聚物组成的含溶剂物质中完全或部分地除去溶剂，并至少拉伸所得到的物体，或由共聚物组成的含溶剂物质， 在升高的温度下，带和胶片的拉伸也可以在两个方向进行。
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公开(公告)号：US5248461A
公开(公告)日：1993-09-28
申请号：US754158
申请日：1991-09-03
CPC分类号： C08J9/18 , B29C55/005 , C08J3/092 , C08J5/18 , C08J9/28 , B29K2023/0683 , B29K2105/04 , C08J2201/0502 , C08J2323/06
摘要： The invention relates to microporous films of ultrahigh molecular weight polyethylene and to a process for the preparation thereof by forming a solution of UHMWPE in an evaporable solvent into a film and evaporating the solvent from the film at a temperature below the dissolution temperature, the shrinking tendency occurring in the film being prevented in at least one direction in the plane of the film.
摘要翻译： 本发明涉及超高分子量聚乙烯微孔薄膜及其制备方法，通过将UHMWPE在蒸发溶剂中的溶液形成薄膜，并在低于溶解温度的温度下从薄膜中蒸发溶剂，其收缩趋势 在膜的平面中至少一个方向上防止了膜的发生。
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公开(公告)号：US5310866A
公开(公告)日：1994-05-10
申请号：US937185
申请日：1992-08-31
IPC分类号： B29C55/00 , C08F293/00 , C08F297/00 , C08J5/18 , C08J7/02 , D01D10/00 , D01F11/04 , D02J1/22 , C08F6/00
CPC分类号： C08J5/18 , B29C55/005 , D01D10/00 , D01F11/04 , D02J1/22 , B29K2105/0085
摘要： Process for stretching an article substantially consisting of a flexible-chain polymer, which is swollen in a solvent for that polymer, in which process an article substantially consisting of a copolymer of the polymer with a second polymer is swollen in a selective solvent for the flexible-chain polymer, and stretched, and an article containing an oriented flexible-chain polymer with a dichroic ratio of at least 1.1.
摘要翻译： 用于拉伸基本上由柔性链聚合物组成的制品的方法，该柔性链聚合物在用于该聚合物的溶剂中溶胀，其中基本上由聚合物与第二聚合物的共聚物组成的制品在选择性溶剂中溶胀，用于柔性 并且拉伸，以及含有二色性比至少为1.1的取向的柔性链聚合物的制品。
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5.发明授权
公开(公告)号：US5183701A
公开(公告)日：1993-02-02
申请号：US747490
申请日：1991-08-19
IPC分类号： D06M10/02
CPC分类号： D06M10/025 , D06M2101/18 , D06M2200/50 , Y10S428/902 , Y10T428/2907 , Y10T428/2938 , Y10T428/2942 , Y10T428/2967 , Y10T428/31 , Y10T442/2484 , Y10T442/2738 , Y10T442/291
摘要： The invention relates to articles consisting of highly oriented polyolefins having an ultrahigh molecular weight of more than 600,000 g/mol (weight-average molecular weight), especially filaments, fibers, yarns, fabrics and films, having good wetting and adhesive properties, especially on conventional matrix materials, which have been subjected to a plasma treatment of their surface, and also to a process for producing these articles and to their use for the manufacture of composites with the use of conventional matrix materials. In these composites, yarns according to the invention, for example, show a substantially higher adhesive strength than corresponding yarns which have not been plasma-treated, their tensile strength not being impaired by the plasma treatment.
摘要翻译： 本发明涉及具有超高分子量超过600,000g / mol（重均分子量）的高取向聚烯烃，特别是长丝，纤维，纱线，织物和薄膜，具有良好的润湿和粘合性能，特别是在 已经对其表面进行等离子体处理的常规基体材料，以及制造这些制品的方法及其用于使用常规基质材料制造复合材料的用途。 在这些复合材料中，根据本发明的纱线例如显示出比未经等离子体处理的相应纱线显着更高的粘合强度，其拉伸强度不受等离子体处理的影响。
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6.发明授权
公开(公告)号：US4966803A
公开(公告)日：1990-10-30
申请号：US223594
申请日：1988-07-25
CPC分类号： C08J5/18 , B29C55/005 , B29K2105/20 , C08J2323/02 , Y10S428/91 , Y10T428/24777 , Y10T428/31507 , Y10T428/31533 , Y10T428/3154 , Y10T428/31544 , Y10T428/31721 , Y10T428/31786 , Y10T428/31797 , Y10T428/31935
摘要： The invention relates to films of polymers of high molecular weight, which have been obtained by casting polymers dissolved or swollen in solvents and partially contain stiffened segments, which films serve either for decorative, handling or fixing purposes or allow, especially when formed on the film edges, a particularly ultrahigh stretching of the films without excessive formation of lips.
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7.发明授权Process for the preparation of polyvinyl alcohol articles of high strength and modulus 失效制备高强度和模量的聚乙烯醇制品的方法
公开(公告)号：US4810450A
公开(公告)日：1989-03-07
申请号：US105543
申请日：1987-10-08
CPC分类号： C08J5/18 , B29C55/005 , D01F6/14 , B29K2029/00 , B29K2105/0061 , C08J2329/04
摘要： High modulus and high strength articles of polyvinylalcohol are obtained by thermoreversible gelation of a 5-50 wt. % solution of a polyvinylalcohol with an M.sub.W of 2.5.times.10.sup.4 to 5.times.10.sup.5 in water, followed by solvent removal and high stretching.Pref. gelation is obtained by cooling to a temperature of at least 40.degree. C. below the gelation temperature.With this process low costs of solvent removal and regeneration are obtained.
摘要翻译： 高模量和高强度的聚乙烯醇制品通过5-50重量％的热可逆凝胶化获得。 ％水溶液中的MW为2.5×10 4至5×10 5的聚乙烯醇溶液，然后除去溶剂并进行高拉伸。 Pref。 通过在凝胶化温度以下冷却至少40℃的温度获得凝胶化。 通过该方法，可以获得低成本的溶剂去除和再生。
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8.发明授权Elongated object made of a copolymer of carbon monoxide and an olefinically unsaturated monomer, and method for the production thereof 失效由一氧化碳和烯属不饱和单体的共聚物制成的伸长物体及其制造方法
公开(公告)号：US5403531A
公开(公告)日：1995-04-04
申请号：US150242
申请日：1993-11-09
CPC分类号： C08J5/18 , C08G67/02 , D01F6/30 , C08J2323/02
摘要： A process for producing an elongated object of an alternating copolymer of carbon monoxide and an olefinically unsaturated monomer wherein the copolymer has an intrinsic viscosity measured in m-cresol at 100.degree. C. of at least 1 dl/g, involve converting a solution of the copolymer into a solvent-containing object, removing between 90 and 99.9% of the solvent from the solvent-containing object, and stretching the thus obtained object at a temperature below the melting point of the copolymer.
摘要翻译： 用于生产一氧化碳和烯属不饱和单体的交替共聚物的细长物体的方法，其中该共聚物在100℃下在间甲酚中测得的特性粘度为至少11dl / g，涉及将 共聚物转变成含溶剂的物体，从含溶剂的物体中除去90-99.9％的溶剂，并在低于共聚物熔点的温度下拉伸由此获得的物体。
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公开(公告)号：US4963299A
公开(公告)日：1990-10-16
申请号：US210905
申请日：1988-06-24
CPC分类号： C08J7/12 , B29C59/00 , C08J5/06 , B29C59/16 , B29C71/02 , B29K2023/00 , B29K2223/00 , C08J2323/02
摘要： The invention relates to a process for the treatment of surfaces of highly oriented polyolefin objects, obtained by converting a solution or melt of a linear polyolefin with a weight average molecular weight of at least 400.000 g/mol, at a temperature above the dissolution temperature, respectively above the melting temperature, into a shaped object, converting this object into a gel-object by cooling, and stretching the gel-object at elevated temperature optionally after full or partial removal of the solvent, in which the surface of the object is contacted with a solution of a radical-forming compound and that the object is then exposed to a temperature of at least 30.degree. C. for at least 1 minute.
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10.发明授权Polyolefin foams having open and/or closed pores and consisting of polyolefins of ultrahigh molecular weight, process for their production, and their use 失效具有开孔和/或闭孔的聚烯烃泡沫，由超高分子量的聚烯烃，其生产方法及其使用组成
公开(公告)号：US4810570A
公开(公告)日：1989-03-07
申请号：US223660
申请日：1988-07-25
IPC分类号： C08J9/04 , C08J9/06 , C08J9/14 , C08J9/26 , C08J9/28 , B29D9/00 , B32B3/26 , B32B5/20 , C08F110/00
CPC分类号： C08J9/26 , C08J9/06 , C08J9/141 , C08J9/28 , C08J2201/0482 , C08J2201/0484 , C08J2201/05 , C08J2201/0502 , C08J2323/04 , Y10T428/249988 , Y10T428/249989 , Y10T428/249992
摘要： The invention relates to polyolefin foams consisting of polyolefins of ultrahigh molecular weight, i.e. weight-average molecular weight from about 4.times.10.sup.5 to 6.times.10.sup.6 g/mol and higher, and to a novel process for producing these foams by foaming a solution of a polyolefin of ultrahigh molecular weight in a solvent with the use of a physical or chemical blowing agent or of an inert gas blown into the solution, and cooling of the resulting foam to a temperature below the gelling temperature of the polyolefin. If appropriate, these foams can be provided wholly or partially with a smooth skin on their surface by superficial cooling, if appropriate under the action of pressure. These foams are distinguished by high tensile strength and impact strength values, shock-absorbing properties, low glass transition temperatures, low embrittlement at low temperatures and high chemical resistance, and they are used especially as mechanical and acoustic insulating materials, materials of construction, filter agents and implantation materials.
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