Olefin separations employing CTS molecular sieves
    5.
    发明授权
    Olefin separations employing CTS molecular sieves 有权
    使用CTS分子筛的烯烃分离

    公开(公告)号:US06517611B1

    公开(公告)日:2003-02-11

    申请号:US09911031

    申请日:2001-07-23

    IPC分类号: B01D53047

    摘要: Separation of ethylene from ethane is achieved by feeding a mixture of the C2 hydrocarbons in contact with a CTS-1 crystalline titanium silicate molecular sieve which has a controlled pore size to selectively adsorb ethylene and size exclude ethane. The feed stream can also contain acetylene which can be selectively adsorbed from both ethane and ethylene by further controlling the pore size of the CTS-1 molecular sieve. Propane/propylene separation is also disclosed.

    摘要翻译: 乙烯与乙烷的分离是通过将与可控孔径的CTS-1结晶硅酸钛分子筛接触的C 2烃混合物进行进料,以选择性地吸附乙烯并排除乙烷的大小来实现的。 进料流还可以包含可以通过进一步控制CTS-1分子筛的孔径从乙烷和乙烯中选择性吸附的乙炔。 还公开了丙烷/丙烯分离。

    Method of forming aluminosilicate zeolites
    9.
    发明授权
    Method of forming aluminosilicate zeolites 有权
    形成硅铝酸盐沸石的方法

    公开(公告)号:US06416732B1

    公开(公告)日:2002-07-09

    申请号:US09533707

    申请日:2000-03-23

    IPC分类号: C01B3902

    摘要: Aluminosilicate zeolites are formed in a novel reaction medium which contains a silicate source and an aluminum source in an aqueous alkaline solution and which reaction medium further includes an additional electrolyte salt. The addition of the electrolyte salt provides nucleation sites for the zeolite so as to form very small crystals. In high silica reaction environments, it is possible to form high aluminum zeolites which contain occluded silicate and wherein the morphology of the zeolites comprise macroscopic aggregates of microcrystalline zeolites. The addition of the electrolyte salt can also decrease the reaction time or temperature needed for crystallization.

    摘要翻译: 铝硅酸盐沸石在新型反应介质中形成,该反应介质在碱性水溶液中含有硅酸盐源和铝源,该反应介质还包含另外的电解质盐。 电解质盐的添加为沸石提供了成核位点,从而形成非常小的晶体。 在高二氧化硅反应环境中,可形成含有封闭硅酸盐的高铝沸石,其中沸石的形态包括微晶沸石的宏观聚集体。 电解质盐的添加也可以降低结晶所需的反应时间或温度。