公开(公告)号：US20080226909A1

公开(公告)日：2008-09-18

申请号：US11955541

申请日：2007-12-13

申请人： Steven R. Schmid ,  Petrus Jacobus Hubertus Niels ,  Paulus Antonius Maria Steeman ,  Xiaosong Wu ,  Wendell Wayne Cattron ,  Tyson Dean Norlin ,  Edward J. Murphy ,  John M. Zimmerman ,  Anthony Joseph Tortorello

发明人： Steven R. Schmid ,  Petrus Jacobus Hubertus Niels ,  Paulus Antonius Maria Steeman ,  Xiaosong Wu ,  Wendell Wayne Cattron ,  Tyson Dean Norlin ,  Edward J. Murphy ,  John M. Zimmerman ,  Anthony Joseph Tortorello

IPC分类号： B32B1/08 ,  B05D3/06

CPC分类号： G02B1/14 ,  C03C25/1065 ,  C08G18/672 ,  C08G18/724 ,  C09D5/002 ,  C09D175/16 ,  G02B1/10 ,  G02B6/02395 ,  Y10T428/24942 ,  Y10T428/2933 ,  Y10T428/2942 ,  Y10T428/2947 ,  C08G18/48

摘要： The invention provides an optical fiber coated with a Supercoating, wherein the Supercoating comprises at least two layers, wherein the first layer is a Primary Coating that is in contact with the outer surface of the optical fiber and the second layer is a Secondary Coating in contact with the outer surface of the Primary Coating, wherein the cured Primary Coating on the optical fiber has the following properties after initial cure and after one month aging at 85° C. and 85% relative humidity: A) a % RAU of from about 84% to about 99%;B) an in-situ modulus of between about 0.15 MPa and about 0.60 MPa; and C) a Tube Tg, of from about −25° C. to about −55° C.; wherein the cured Secondary Coating on the optical fiber has the following properties after initial cure and after one month aging at 85° C. and 85% relative humidity: A) a % RAU of from about 80% to about 98%; B) an in-situ modulus of between about 0.60 GPa and about 1.90 GPa; and C) a Tube Tg, of from about 50° C. to about 80° C.

摘要翻译： 本发明提供涂覆有超涂层的光纤，其中超涂层包括至少两层，其中第一层是与光纤的外表面接触的主涂层，第二层是接触的第二涂层 其中主要涂层的外表面，其中光纤上的固化的一次涂层在初始固化后和在85℃和85％相对湿度下老化一个月后具有以下性质：A）约84％的％RAU， 至约99％; B）约0.15MPa至约0.60MPa的原位模量; 和C）管Tg，约-25℃至约-55℃; 其中光纤上的固化的二次涂层在初始固化之后和在85℃和85％相对湿度下老化一个月后具有以下性能：A）约80％至约98％的％RAU; B）原位模量在约0.60GPa和约1.90GPa之间; 和C）管Tg，为约50℃至约80℃

公开(公告)号：US08426020B2

公开(公告)日：2013-04-23

申请号：US11955541

申请日：2007-12-13

申请人： Steven R. Schmid ,  Petrus Jacobus Hubertus Niels ,  Paulus Antonius Maria Steeman ,  Xiaosong Wu ,  Wendell Wayne Cattron ,  Tyson Dean Norlin ,  Edward J. Murphy ,  John M. Zimmerman ,  Anthony Joseph Tortorello

发明人： Steven R. Schmid ,  Petrus Jacobus Hubertus Niels ,  Paulus Antonius Maria Steeman ,  Xiaosong Wu ,  Wendell Wayne Cattron ,  Tyson Dean Norlin ,  Edward J. Murphy ,  John M. Zimmerman ,  Anthony Joseph Tortorello

IPC分类号： C08F2/50 ,  B05D5/06 ,  D02G3/00 ,  G02B6/00

CPC分类号： G02B1/14 ,  C03C25/1065 ,  C08G18/672 ,  C08G18/724 ,  C09D5/002 ,  C09D175/16 ,  G02B1/10 ,  G02B6/02395 ,  Y10T428/24942 ,  Y10T428/2933 ,  Y10T428/2942 ,  Y10T428/2947 ,  C08G18/48

摘要： The invention provides an optical fiber coated with a Supercoating, wherein the Supercoating comprises at least two layers, wherein the first layer is a Primary Coating that is in contact with the outer surface of the optical fiber and the second layer is a Secondary Coating in contact with the outer surface of the Primary Coating, wherein the cured Primary Coating on the optical fiber has the following properties after initial cure and after one month aging at 85° C. and 85% relative humidity: A) a % RAU of from about 84% to about 99%;B) an in-situ modulus of between about 0.15 MPa and about 0.60 MPa; andC) a Tube Tg, of from about −25° C. to about −55° C.; wherein the cured Secondary Coating on the optical fiber has the following properties after initial cure and after one month aging at 85° C. and 85% relative humidity: A) a % RAU of from about 80% to about 98%; B) an in-situ modulus of between about 0.60 GPa and about 1.90 GPa; and C) a Tube Tg, of from about 50° C. to about 80° C.

摘要翻译： 本发明提供涂覆有超涂层的光纤，其中超涂层包括至少两层，其中第一层是与光纤的外表面接触的主涂层，第二层是接触的第二涂层 其中主要涂层的外表面，其中光纤上的固化的一次涂层在初始固化后和在85℃和85％相对湿度下老化一个月后具有以下性质：A）约84％的％RAU， 至约99％; B）约0.15MPa至约0.60MPa的原位模量; 和C）管Tg，约-25℃至约-55℃; 其中光纤上的固化的二次涂层在初始固化之后和在85℃和85％相对湿度下老化一个月后具有以下性能：A）约80％至约98％的％RAU; B）原位模量在约0.60GPa和约1.90GPa之间; 和C）管Tg，为约50℃至约80℃

公开(公告)号：US20120003474A1

公开(公告)日：2012-01-05

申请号：US13233670

申请日：2011-09-15

申请人： Wendell Wayne Cattron ,  Steven R. Schmid ,  Edward J. Murphy ,  John M. Zimmerman ,  Anthony Joseph Tortorello

发明人： Wendell Wayne Cattron ,  Steven R. Schmid ,  Edward J. Murphy ,  John M. Zimmerman ,  Anthony Joseph Tortorello

IPC分类号： B32B9/00 ,  C09D175/16 ,  G02B6/00 ,  C03C25/48 ,  C03B37/02 ,  C09D163/00 ,  C03C25/26

CPC分类号： G02B1/12 ,  C03C25/1065 ,  C08G18/672 ,  C08G18/724 ,  C09D163/00 ,  C09D175/14 ,  C09D175/16 ,  Y10T428/2938 ,  Y10T428/2964 ,  C08G18/48

摘要： The invention relates to a Radiation Curable Secondary Coating composition for use on an Optical Fiber. The Radiation Curable Secondary Coating composition is a urethane-free Alpha Oligomer prepared by reaction of the following: (a) an acrylate compound selected from an alcohol-containing acrylate or alcohol-containing methacrylate compound, (b) an anhydride compound, (c) an epoxy-containing compound, (d) optionally an extender compound, and (e) optionally a catalyst. The invention also relates to a coated wire and to a coated optical fiber.

摘要翻译： 本发明涉及一种用于光纤的辐射固化二次涂料组合物。 辐射固化二次涂料组合物是通过以下反应制备的不含氨基甲酸酯的α-低聚物：（a）选自含醇丙烯酸酯或含醇甲基丙烯酸酯化合物的丙烯酸酯化合物，（b）酸酐化合物，（c） 含环氧基的化合物，（d）任选的增量化合物，和（e）任选的催化剂。 本发明还涉及涂覆线和涂覆光纤。

公开(公告)号：US20080233397A1

公开(公告)日：2008-09-25

申请号：US11955721

申请日：2007-12-13

申请人： Wendell Wayne Cattron ,  Steven R. Schmid ,  Edward J. Murphy ,  John M. Zimmerman ,  Anthony Joseph Tortorello

发明人： Wendell Wayne Cattron ,  Steven R. Schmid ,  Edward J. Murphy ,  John M. Zimmerman ,  Anthony Joseph Tortorello

IPC分类号： B32B17/02 ,  C08L75/04 ,  B32B17/10 ,  C03C25/34

CPC分类号： G02B6/02395 ,  C03C25/106 ,  C03C25/1065 ,  C08G18/672 ,  C09D163/00 ,  C09D175/16 ,  Y10T428/2964 ,  C08G18/48

摘要： A Radiation Curable Secondary Coating comprising A) a Secondary Coating Oligomer Blend, which is mixed with B) a first diluent; C) a second diluent; D) an antioxidant; E) a first photoinitiator; F) a second photoinitiator; and G) optionally a slip additive or a blend of slip additives; wherein said Secondary Coating Oligomer Blend comprises: α) an Alpha Oligomer, which is non-urethane; β) a Beta Oligomer; which is a urethane or non-urethane. γ) a Gamma Oligomer; wherein said Gamma Oligomer is an epoxy diacrylate.

摘要翻译： 一种可辐射固化二次涂层，其包含A）第二涂料低聚物混合物，其与B）第一稀释剂混合; C）第二稀释剂; D）抗氧化剂; E）第一光引发剂; F）第二光引发剂; 和G）任选的滑爽添加剂或滑爽添加剂的混合物; 其中所述第二涂料低聚物共混物包含：α）非聚氨酯的α低聚物; β）β低聚物; 其是聚氨酯或非聚氨酯。 γ）伽马低聚物; 其中所述Gamma低聚物是环氧二丙烯酸酯。

公开(公告)号：US08426021B2

公开(公告)日：2013-04-23

申请号：US13233670

申请日：2011-09-15

申请人： Wendell Wayne Cattron ,  Steven R. Schmid ,  Edward J. Murphy ,  John M. Zimmerman ,  Anthony Joseph Tortorello

发明人： Wendell Wayne Cattron ,  Steven R. Schmid ,  Edward J. Murphy ,  John M. Zimmerman ,  Anthony Joseph Tortorello

IPC分类号： B32B9/00 ,  D02G3/00 ,  C08F283/10 ,  C08F20/22

CPC分类号： G02B1/12 ,  C03C25/1065 ,  C08G18/672 ,  C08G18/724 ,  C09D163/00 ,  C09D175/14 ,  C09D175/16 ,  Y10T428/2938 ,  Y10T428/2964 ,  C08G18/48

摘要： The invention relates to a Radiation Curable Secondary Coating composition for use on an Optical Fiber. The Radiation Curable Secondary Coating composition is a urethane-free Alpha Oligomer prepared by reaction of the following: (a) an acrylate compound selected from an alcohol-containing acrylate or alcohol-containing methacrylate compound, (b) an anhydride compound, (c) an epoxy-containing compound, (d) optionally an extender compound, and (e) optionally a catalyst. The invention also relates to a coated wire and to a coated optical fiber.

摘要翻译： 本发明涉及一种用于光纤的辐射固化二次涂料组合物。 辐射固化二次涂料组合物是通过以下反应制备的不含氨基甲酸酯的α-低聚物：（a）选自含醇丙烯酸酯或含醇甲基丙烯酸酯化合物的丙烯酸酯化合物，（b）酸酐化合物，（c） 含环氧基的化合物，（d）任选的增量化合物，和（e）任选的催化剂。 本发明还涉及涂覆线和涂覆光纤。

公开(公告)号：US20080226913A1

公开(公告)日：2008-09-18

申请号：US11955604

申请日：2007-12-13

申请人： Wendell Wayne Cattron ,  Steven R. Schmid ,  Edward J. Murphy ,  John M. Zimmerman ,  Anthony Joseph Tortorello

发明人： Wendell Wayne Cattron ,  Steven R. Schmid ,  Edward J. Murphy ,  John M. Zimmerman ,  Anthony Joseph Tortorello

IPC分类号： B32B17/02 ,  C08L75/04 ,  B32B17/10 ,  C03C25/34

CPC分类号： C03C25/1065 ,  C08G18/6674 ,  C08G18/672 ,  C09D175/16 ,  G02B6/02395 ,  Y10T428/2964

摘要： A new radiation curable Secondary Coating for optical fibers is described and claimed wherein said composition comprises a Secondary Coating Oligomer Blend, which is mixed with a first diluent monomer; a second diluent monomer; optionally, a third diluent monomer; an antioxidant; a first photoinitiator; a second photoinitiator; and optionally a slip additive or a blend of slip additives; wherein said Secondary Coating Oligomer Blend comprises: α) an Omega Oligomer; and β) an Upsilon Oligomer; wherein said Omega Oligomer is synthesized by the reaction of α1) a hydroxyl-containing (meth)acrylate; α2) an isocyanate; α3) a polyether polyol; and α4) tripropylene glycol; in the presence of α5) a polymerization inhibitor; and α6) a catalyst; to yield the Omega Oligomer; wherein said catalyst is selected from the group consisting of dibutyl tin dilaurate; metal carboxylates, including, but not limited to: organobismuth catalysts such as bismuth neodecanoate; zinc neodecanoate; zirconium neodecanoate; zinc 2-ethylhexanoate; sulfonic acids, including but not limited to dodecylbenzene sulfonic acid, methane sulfonic acid; amino or organo-base catalysts, including, but not limited to: 1,2-dimethylimidazole and diazabicyclooctane; triphenyl phosphine; alkoxides of zirconium and titanium, including, but not limited to Zirconium butoxide and Titanium butoxide; and Ionic liquid phosphonium salts; and tetradecyl(trihexyl)phosphonium chloride; and wherein said Upsilon Oligomer is an epoxy diacrylate.

摘要翻译： 描述和要求保护的用于光纤的新的可辐射固化的二次涂层，其中所述组合物包含与第一稀释剂单体混合的第二涂料低聚物混合物; 第二稀释剂单体; 任选地，第三稀释剂单体; 抗氧化剂 第一种光引发剂; 第二光引发剂; 和任选的滑爽添加剂或滑爽添加剂的混合物; 其中所述第二涂料低聚物共混物包含：α）ω-低聚物; 和β）Upsilon低聚物; 其中所述欧米加低聚物通过α1）含羟基的（甲基）丙烯酸酯的反应合成; α2）异氰酸酯; α3）聚醚多元醇; 和α4）三丙二醇; 在α5的存在下）聚合抑制剂; 和α6）催化剂; 产生欧米茄低聚物; 其中所述催化剂选自二月桂酸二丁基锡; 金属羧酸盐，包括但不限于：有机铋催化剂如新戊酸铋; 新癸酸锌; 新癸酸锆; 2-乙基己酸锌; 磺酸，包括但不限于十二烷基苯磺酸，甲磺酸; 氨基或有机碱催化剂，包括但不限于：1,2-二甲基咪唑和二氮杂双环辛烷; 三苯基膦 锆和钛的醇盐包括但不限于丁氧基锆和丁醇钛; 和离子液体鏻盐; 和十四烷基（三己基）鏻氯化物; 并且其中所述Upsilon低聚物是环氧二丙烯酸酯。

公开(公告)号：US20120128314A1

公开(公告)日：2012-05-24

申请号：US13388726

申请日：2010-10-08

申请人： Xiaosong Wu ,  Steven Robert Schmid ,  Timothy Edward Bishop ,  John Monroe Zimmerman ,  Wendell Wayne Cattron ,  Edward Joseph Murphy ,  Pratik Shah ,  Margaret Brumm

发明人： Xiaosong Wu ,  Steven Robert Schmid ,  Timothy Edward Bishop ,  John Monroe Zimmerman ,  Wendell Wayne Cattron ,  Edward Joseph Murphy ,  Pratik Shah ,  Margaret Brumm

IPC分类号： G02B6/00 ,  B29C35/08 ,  B29C41/52 ,  B05D5/06 ,  C03C17/00

CPC分类号： G02B1/10 ,  B05D1/42 ,  C03C25/1065 ,  C03C25/12 ,  C08G18/4866 ,  C08G18/672 ,  C09D175/16 ,  G02B1/046 ,  G02B6/02395 ,  Y10T428/2933 ,  C08G18/48

摘要： The first aspect of the instant claimed invention is a method of formulating radiation curable Supercoatings for application to an optical fiber used in a telecommunications network. A Multi-layer Film Drawdown Method useful in the Method of formulating radiation curable Supercoatings is also described and claimed. Single mode Optical fibers coated with specific radiation curable Supercoatings are also described and claimed.

摘要翻译： 本发明的第一方面是一种配制可辐射固化的超涂层以应用于在电信网络中使用的光纤的方法。 还描述并要求保护用于配制可辐射固化的超涂层的方法中的多层薄膜缩小方法。 单模式也描述和要求保护涂覆有特定可辐射固化的超涂层的光纤。