D1369 D RADIATION CURABLE SECONDARY COATING FOR OPTICAL FIBER
    5.
    发明申请
    D1369 D RADIATION CURABLE SECONDARY COATING FOR OPTICAL FIBER 审中-公开
    D1369 D光纤固化二次涂层

    公开(公告)号:US20080226913A1

    公开(公告)日:2008-09-18

    申请号:US11955604

    申请日:2007-12-13

    摘要: A new radiation curable Secondary Coating for optical fibers is described and claimed wherein said composition comprises a Secondary Coating Oligomer Blend, which is mixed with a first diluent monomer; a second diluent monomer; optionally, a third diluent monomer; an antioxidant; a first photoinitiator; a second photoinitiator; and optionally a slip additive or a blend of slip additives; wherein said Secondary Coating Oligomer Blend comprises: α) an Omega Oligomer; and β) an Upsilon Oligomer; wherein said Omega Oligomer is synthesized by the reaction of α1) a hydroxyl-containing (meth)acrylate; α2) an isocyanate; α3) a polyether polyol; and α4) tripropylene glycol; in the presence of α5) a polymerization inhibitor; and α6) a catalyst; to yield the Omega Oligomer; wherein said catalyst is selected from the group consisting of dibutyl tin dilaurate; metal carboxylates, including, but not limited to: organobismuth catalysts such as bismuth neodecanoate; zinc neodecanoate; zirconium neodecanoate; zinc 2-ethylhexanoate; sulfonic acids, including but not limited to dodecylbenzene sulfonic acid, methane sulfonic acid; amino or organo-base catalysts, including, but not limited to: 1,2-dimethylimidazole and diazabicyclooctane; triphenyl phosphine; alkoxides of zirconium and titanium, including, but not limited to Zirconium butoxide and Titanium butoxide; and Ionic liquid phosphonium salts; and tetradecyl(trihexyl)phosphonium chloride; and wherein said Upsilon Oligomer is an epoxy diacrylate.

    摘要翻译: 描述和要求保护的用于光纤的新的可辐射固化的二次涂层,其中所述组合物包含与第一稀释剂单体混合的第二涂料低聚物混合物; 第二稀释剂单体; 任选地,第三稀释剂单体; 抗氧化剂 第一种光引发剂; 第二光引发剂; 和任选的滑爽添加剂或滑爽添加剂的混合物; 其中所述第二涂料低聚物共混物包含:α)ω-低聚物; 和β)Upsilon低聚物; 其中所述欧米加低聚物通过α1)含羟基的(甲基)丙烯酸酯的反应合成; α2)异氰酸酯; α3)聚醚多元醇; 和α4)三丙二醇; 在α5的存在下)聚合抑制剂; 和α6)催化剂; 产生欧米茄低聚物; 其中所述催化剂选自二月桂酸二丁基锡; 金属羧酸盐,包括但不限于:有机铋催化剂如新戊酸铋; 新癸酸锌; 新癸酸锆; 2-乙基己酸锌; 磺酸,包括但不限于十二烷基苯磺酸,甲磺酸; 氨基或有机碱催化剂,包括但不限于:1,2-二甲基咪唑和二氮杂双环辛烷; 三苯基膦 锆和钛的醇盐包括但不限于丁氧基锆和丁醇钛; 和离子液体鏻盐; 和十四烷基(三己基)鏻氯化物; 并且其中所述Upsilon低聚物是环氧二丙烯酸酯。

    D1365 BJ RADIATION CURABLE PRIMARY COATING FOR OPTICAL FIBER
    8.
    发明申请
    D1365 BJ RADIATION CURABLE PRIMARY COATING FOR OPTICAL FIBER 审中-公开
    D1365 BJ辐射可固化主要用于光纤的涂层

    公开(公告)号:US20080226912A1

    公开(公告)日:2008-09-18

    申请号:US11955547

    申请日:2007-12-13

    摘要: Radiation curable coatings for use as a Primary Coating for optical fibers, optical fibers coated with said coatings and methods for the preparation of coated optical fibers. The present invention provides a radiation curable Primary Coating composition comprising: an oligomer; first diluent monomer; a second diluent monomer; a third diluent monomer; a first light stabilizer; a first photoinitiator; a second photoinitiator; an antioxidant; a second light stabilizer; and an adhesion promoter; wherein said oligomer is the reaction product of hydroxyl-containing acrylate; an isocyanate; a polyether polyol; a polymerization inhibitor; a catalyst; and a diluent; wherein said oligomer has a number average molecular weight of from at least about 4000 g/mol to less than or equal to about 15,000 g/mol; and wherein said catalyst is selected from the group consisting of copper naphthenate; cobalt naphthenate; zinc naphthenate; triethylamine; triethylenediamine; 2-methyltriethyleneamine; dibutyl tin dilaurate; metal carboxylates, including, but not limited to: organobismuth catalysts such as bismuth neodecanoate; zinc neodecanoate; zirconium neodecanoate; zinc 2-ethylhexanoate; sulfonic acids, including but not limited to dodecylbenzene sulfonic acid, methane sulfonic acid; amino or organo-base catalysts, including, but not limited to, 1,2-dimethylimidazole and diazabicyclooctane; triphenyl phosphine; alkoxides of zirconium and titanium, including, but not limited to Zirconium butoxide and Titanium butoxide; and Ionic liquid phosphonium salts; and tetradecyl(trihexyl) phosphonium chloride; and wherein a cured film of said radiation curable Primary Coating composition has a peak tan □ Tg of from about −25° C. to about −55° C.; and a modulus of from about 0.85 MPa to about 1.10 MPa.

    摘要翻译: 用作光纤的主要涂层的辐射固化涂层,涂覆有所述涂层的光纤以及用于制备涂覆的光纤的方法。 本发明提供了一种可辐射固化的初级涂料组合物,其包含:低聚物; 第一稀释剂单体; 第二稀释剂单体; 第三稀释剂单体; 第一光稳定剂; 第一种光引发剂; 第二光引发剂; 抗氧化剂 第二种光稳定剂; 和粘合促进剂; 其中所述低聚物是含羟基的丙烯酸酯的反应产物; 异氰酸酯; 聚醚多元醇; 阻聚剂; 催化剂 和稀释剂; 其中所述低聚物的数均分子量为至少约4000g / mol至小于或等于约15,000g / mol; 并且其中所述催化剂选自环烷酸铜; 环烷酸钴; 环烷酸锌; 三乙胺 三亚乙基二胺 2-甲基三亚乙基胺; 二月桂酸二丁基锡; 金属羧酸盐,包括但不限于:有机铋催化剂如新戊酸铋; 新癸酸锌; 新癸酸锆; 2-乙基己酸锌; 磺酸,包括但不限于十二烷基苯磺酸,甲磺酸; 氨基或有机碱催化剂,包括但不限于1,2-二甲基咪唑和二氮杂双环辛烷; 三苯基膦 锆和钛的醇盐包括但不限于丁氧基锆和丁醇钛; 和离子液体鏻盐; 和十四烷基(三己基)鏻氯化物; 并且其中所述可辐射固化的初级涂层组合物的固化膜具有约-25℃至约-55℃的峰值tanδTg。 和约0.85MPa至约1.10MPa的模量。

    D1368 CR RADIATION CURABLE PRIMARY COATING FOR OPTICAL FIBER
    9.
    发明申请
    D1368 CR RADIATION CURABLE PRIMARY COATING FOR OPTICAL FIBER 审中-公开
    D1368 CR辐射可固化主要用于光纤的涂层

    公开(公告)号:US20080226914A1

    公开(公告)日:2008-09-18

    申请号:US11955614

    申请日:2007-12-13

    摘要: Radiation curable coatings for use as a Primary Coating for optical fibers, optical fibers coated with said coatings and processes for coating optical fibers. The radiation curable Primary Coating composition of the instant claimed invention includes an oligomer, a diluent monomer; a photoinitiator; an antioxidant; and an adhesion promoter; wherein said oligomer is the reaction product of: a hydroxyethyl acrylate; an aromatic isocyanate; an aliphatic isocyanate; a polyol; a catalyst; and an inhibitor, wherein said oligomer has a number average molecular weight of from at least about 4000 g/mol to less than or equal to about 15,000 g/μmol; and wherein said catalyst is selected from the group consisting of dibutyl tin dilaurate; metal carboxylates, including, but not limited to: organobismuth catalysts such as bismuth neodecanoate; zinc neodecanoate; zirconium neodecanoate; zinc 2-ethylhexanoate; sulfonic acids, including but not limited to dodecylbenzene sulfonic acid, methane sulfonic acid; amino or organo-base catalysts, including, but not limited to: 1,2-dimethylimidazole and diazabicyclooctane; triphenyl phosphine; alkoxides of zirconium and titanium, including, but not limited to Zirconium butoxide and Titanium butoxide; and Ionic liquid phosphonium salts; and tetradecyl(trihexyl)phosphonium chloride; and wherein a cured film of said radiation curable Primary Coating composition has a peak tan delta Tg of from about −25° C. to about −45° C. and a modulus of from about 0.50 MPa to about 1.2 MPa.

    摘要翻译: 用作光纤的主要涂层的可辐射固化涂层,涂覆有所述涂层的光纤和用于涂覆光纤的工艺。 本发明的可辐射固化的初级涂料组合物包括低聚物,稀释剂单体; 光引发剂; 抗氧化剂 和粘合促进剂; 其中所述低聚物是以下物质的反应产物:丙烯酸羟乙酯; 芳香族异氰酸酯; 脂族异氰酸酯; 多元醇 催化剂 和抑制剂,其中所述低聚物的数均分子量为至少约4000g / mol至小于或等于约15,000g / mumol; 并且其中所述催化剂选自二月桂酸二丁基锡; 金属羧酸盐,包括但不限于:有机铋催化剂如新戊酸铋; 新癸酸锌; 新癸酸锆; 2-乙基己酸锌; 磺酸,包括但不限于十二烷基苯磺酸,甲磺酸; 氨基或有机碱催化剂,包括但不限于:1,2-二甲基咪唑和二氮杂双环辛烷; 三苯基膦 锆和钛的醇盐包括但不限于丁氧基锆和丁醇钛; 和离子液体鏻盐; 和十四烷基(三己基)鏻氯化物; 并且其中所述可辐射固化的初级涂料组合物的固化膜的峰值tanδTg为约-25℃至约-45℃,模量为约0.50MPa至约1.2MPa。

    D1363 BT RADIATION CURABLE PRIMARY COATINGS ON OPTICAL FIBER
    10.
    发明申请
    D1363 BT RADIATION CURABLE PRIMARY COATINGS ON OPTICAL FIBER 审中-公开
    D1363 BT辐射可固化主要涂料在光纤上

    公开(公告)号:US20080226916A1

    公开(公告)日:2008-09-18

    申请号:US11955935

    申请日:2007-12-13

    摘要: Radiation curable coatings for use as a Primary Coating for optical fibers, optical fibers coated with said coatings and methods for the preparation of coated optical fibers. The radiation curable coating comprises at least one (meth)acrylate functional oligomer and a photoinitiator, wherein the urethane-(meth)acrylate oligomer CA/CR comprises (meth)acrylate groups, at least one polyol backbone and urethane groups, wherein about 15% or more of the urethane groups are derived from one or both of 2,4- and 2,6-toluene diisocyanate, wherein at least 15% of the urethane groups are derived from a cyclic or branched aliphatic isocyanate, and wherein said (meth)acrylate functional oligomer has a number average molecular weight of from at least about 4000 g/mol to less than or equal to about 15,000 g/mol; and wherein a cured film of the radiation curable Primary Coating composition has a modulus of less than or equal to about 1.2 MPa.

    摘要翻译: 用作光纤的主要涂层的辐射固化涂层,涂覆有所述涂层的光纤以及用于制备涂覆的光纤的方法。 可辐射固化涂层包含至少一种(甲基)丙烯酸酯官能低聚物和光引发剂,其中氨基甲酸酯 - (甲基)丙烯酸酯低聚物CA / CR包含(甲基)丙烯酸酯基团,至少一个多元醇主链和氨基甲酸酯基团,其中约15% 或更多的氨基甲酸酯基衍生自2,4-和2,6-甲苯二异氰酸酯中的一种或两种,其中至少15%的氨基甲酸酯基团衍生自环状或支链脂族异氰酸酯,并且其中所述(甲基) 丙烯酸酯官能低聚物的数均分子量为至少约4000g / mol至小于或等于约15,000g / mol; 并且其中所述可辐射固化的初级涂层组合物的固化膜的模量小于或等于约1.2MPa。