Abstract:
The present development is a catalyst for use in the water-gas-shift reaction. The catalyst includes a Group VIII or Group IB metal, a transition metal promoter selected from the group consisting of rhenium, niobium, silver, manganese, vanadium, molybdenum, titanium, tungsten and a combination thereof, and a ceria-based support. The support may further include gadolinium, samarium, zirconium, lithium, cesium, lanthanum, praseodymium, manganese, titanium, tungsten or a combination thereof. A process for preparing the catalyst is also presented. In a preferred embodiment, the process involves providing nullcleannull precursors as starting materials in the catalyst preparation.
Abstract:
A catalyst adsorbent for the desulfurization of a feed stream, preferably in a fuel cell, wherein the catalyst includes from about 30 percent to about 80 percent nickel or a nickel compound, from about 5 percent to about 45 percent silica as a carrier, from about 1 percent to about 10 percent alumina as a promoter and from about 0.01 percent to about 15 percent magnesia as a promoter. The invention also includes processes of manufacture of the catalyst adsorbent.