摘要:
Disclosed is an anode active material, comprising: (a) a carbonaceous material; and (b) a carbide coating layer partially or totally formed on a surface of the carbonaceous material, the carbide coating layer comprising at least one element selected from the group consisting of metals and metalloids. An anode obtained by using the anode active material and an electrochemical device comprising the anode are also disclosed. The carbonaceous material comprises a coating layer of metal-/metalloid-carbide obtained by treating it at high temperature under inert atmosphere, wherein the coating layer has increased interfacial boding force to the carbonaceous material and thus shows minimized reactivity to lithium. The carbonaceous material as anode active material can minimize the irreversible anode capacity needed for the formation of an SEI film during the first charge/discharge cycle, thereby providing high capacity, high efficiency and significantly improved anode qualities.
摘要:
Disclosed is an anode active material, comprising: (a) a carbonaceous material; and (b) a carbide coating layer partially or totally formed on a surface of the carbonaceous material, the carbide coating layer comprising at least one element selected from the group consisting of metals and metalloids. An anode obtained by using the anode active material and an electrochemical device comprising the anode are also disclosed. The carbonaceous material comprises a coating layer of metal-/metalloid-carbide obtained by treating it at high temperature under inert atmosphere, wherein the coating layer has increased interfacial boding force to the carbonaceous material and thus shows minimized reactivity to lithium. The carbonaceous material as anode active material can minimize the irreversible anode capacity needed for the formation of an SEI film during the first charge/discharge cycle, thereby providing high capacity, high efficiency and significantly improved anode qualities.
摘要:
The present invention is an apparatus for protecting a secondary battery, in which, when the secondary battery such as a lithium-ion secondary battery is exposed to high temperature exceeding a working range due to a change in external environment, external impacts, and so on, or heated due to spontaneous generation of heat caused by internal defects, the secondary battery is discharged. The apparatus includes a thyristor or transistor having an anode and a cathode connected both terminals of the secondary battery respectively, and shorting both terminals of the secondary battery when gate current is supplied, and a temperature sensor detecting temperature of the secondary battery and supplying the gate current to the thyristor or transistor when the detected temperature is higher than predetermined temperature.
摘要:
The present invention relates to an apparatus for protecting a secondary battery by preventing overcharge of the secondary battery.The apparatus for protecting a secondary battery includes: a secondary battery; a power supply, connected with both electrode terminals of the secondary battery, for providing a charging voltage and a charging current to the secondary battery to charge the secondary battery; and a secondary battery protection unit for shorting the power supply thereby to stop charging the secondary battery if a charging voltage of the secondary battery is above a predetermined voltage.
摘要:
Disclosed are a safety device and a secondary battery using the same. The safety device includes a voltage sensitive heating device generating heat when a voltage difference between both ends thereof exceeds a predetermined voltage level and a temperature sensitive device having a reversible current ON/OFF function according to a temperature. The temperature sensitive device is coupled with the voltage sensitive heating device such that the temperature sensitive device detects the heat generated from the voltage sensitive heating device.
摘要:
An object of the present invention is to provide the device for protecting a secondary battery safely from overvoltage and overheating caused by the overcharge by using simple safety device, which provides a contacted safety device which connects between a constant voltage element showing a discharge characteristic in the state of overvoltage and a MIT (metal insulator transition) element showing a discharge characteristic in the state of overheating. Each of the constant voltage element and the MIT element are connected in parallel between a cathode lead and an anode lead of the secondary battery. The contacted safety device has a characteristic combining a discharge/heat dissipation characteristic of the constant voltage element and a discharge characteristic of the MIT element which immediately responds to the heat dissipation of the constant voltage element, resulting in effect of preventing overcharge advantageously since the contacted safety device makes discharge in terms of 2 factors of voltage and temperature in case of overcharge.
摘要:
Disclosed is a secondary battery having a constant-voltage device for preventing the secondary battery from being excessively overcharged. The breakdown voltage of the constant-voltage device is lower than the explosion or ignition voltage of the secondary battery, so the discharge operation may occur before the secondary battery is exploded or ignited even if the voltage of the secondary battery rises above the overcharge voltage, thereby protecting the secondary battery from explosion or ignition. The leakage current value of the constant-voltage device is less than 0.05% of the capacity value of the secondary battery under the maximum charge voltage of the secondary battery, or the breakdown voltage of the constant-voltage device is higher than the maximum charge voltage of the secondary battery. Thus, the constant-voltage device rarely generates the leakage current even if the secondary battery has been charged with the maximum charge voltage.
摘要:
Disclosed is a battery safety device having a first metal plate, a second metal plate, and a pressure-sensitive conducting film interposed between both metal plates and adapted to exhibit electrical conductivity when a predetermined pressure or higher is applied. The first and second metal plates are electrically connected to the positive and negative electrodes of the battery, respectively. The safety device connected to a battery prevents the battery from being damaged or at least from igniting or exploding, even when an external impact caused by pressure, a nail, or a nipper or an external pressure is applied to the battery, by conducting the current of the battery to the safety device and discharging the battery before the battery is damaged by the external impact or external pressure.
摘要:
Disclosed is a compound represented by the following formula 1. A lithium secondary battery using the same compound as electrode active material, preferably as cathode active material, is also disclosed. LiMP1-xAxO4 [Formula 1] wherein M is a transition metal, A is an element having an oxidation number of +4 or less and 0
摘要:
Disclosed are a safety element for a battery, which is provided with material having a Metal-Insulator Transition (MIT) characteristic where resistance abruptly drops at or above a certain temperature, and a battery with such a safety element. This battery with an MIT safety element is turned into a stable discharged state when it is exposed to an elevated temperature or a battery temperature rises due to external impact, so that it can ensure its safety.