Lithium iron phosphate having olivine structure and method for preparing the same
    5.
    发明授权
    Lithium iron phosphate having olivine structure and method for preparing the same 有权
    具有橄榄石结构的磷酸铁锂及其制备方法

    公开(公告)号:US09458016B2

    公开(公告)日:2016-10-04

    申请号:US12709200

    申请日:2010-02-19

    摘要: Provided is an olivine-type lithium iron phosphate composed of secondary particles having a mean particle diameter (D50) of 5 to 100 μm, formed by aggregation of primary particles having a mean particle diameter (D50) of 50 to 550 nm, wherein the primary and secondary particles have a composition represented by Formula I below and the secondary particles have a porosity of 15 to 40%: Li1+aFe1−xMx(PO4−b)Xb (I) wherein M is selected from Al, Mg, Ni, Co, Mn, Ti, Ga, Cu, V, Nb, Zr, Ce, In, Zn, Y and combinations thereof; X is selected from F, S, N and combinations thereof; −0.5≦a≦+0.5; 0≦x≦0.5; and 0≦b≦0.1.

    摘要翻译: 本发明提供一种由平均粒径(D50)为5〜100μm的二次粒子组成的橄榄石型磷酸铁锂,其特征在于,其平均粒径(D50)为50〜550nm的一次粒子的聚集形成, 二次粒子具有下述式I所示的组成,二次粒子的孔隙率为15〜40%:Li1 + aFe1-xMx(PO4-b)Xb(I)其中M选自Al,Mg,Ni,Co ,Mn,Ti,Ga,Cu,V,Nb,Zr,Ce,In,Zn,Y及其组合; X选自F,S,N及其组合; -0.5≤a≤+ 0.5; 0≤x≤0.5; 0≤b≤0.1。

    CATHODE ACTIVE MATERIAL PROVIDING IMPROVED EFFICIENCY AND ENERGY DENSITY OF ELECTRODE
    6.
    发明申请
    CATHODE ACTIVE MATERIAL PROVIDING IMPROVED EFFICIENCY AND ENERGY DENSITY OF ELECTRODE 有权
    阴极活性材料提高电极效率和能量密度

    公开(公告)号:US20110287315A1

    公开(公告)日:2011-11-24

    申请号:US13124421

    申请日:2009-10-22

    摘要: Provided is a cathode active material having a composition represented by the following Formula I: LiFe(P1-XO4) (I) wherein a molar fraction (1-x) of phosphorus (P) is in the range of 0.910 to 0.999, to allow operational efficiency of the cathode active material to be leveled to a lower operational efficiency of an anode active material and improve energy density of the cathode active material. Furthermore, a cathode active material, wherein a molar fraction (1-x) of phosphorus (P) is lower than 1, contains both Fe2+ and Fe3+, thus advantageously preventing structural deformation, improving ionic conductivity, exhibiting superior rate properties and inhibiting IR drop upon charge/discharge, thereby imparting high energy density to batteries.

    摘要翻译: 本发明提供具有以下式I表示的组成的正极活性物质:磷(P)的摩尔分数(1-x)为0.910〜0.999的LiFe(P1-XO4)(I),以允许 阴极活性材料的操作效率被平衡到负极活性材料的较低的操作效率并且改善阴极活性材料的能量密度。 此外,其中磷(P)的摩尔分数(1-x)低于1的正极活性材料含有Fe 2+和Fe 3+,从而有利地防止结构变形,改善离子电导率,表现出优异的速率性质和抑制IR降低 充电/放电,从而赋予电池高的能量密度。

    LITHIUM IRON PHOSPHATE HAVING OLIVINE STRUCTURE AND METHOD FOR PREPARING THE SAME
    7.
    发明申请
    LITHIUM IRON PHOSPHATE HAVING OLIVINE STRUCTURE AND METHOD FOR PREPARING THE SAME 有权
    具有OLIVINE结构的锂铁磷酸盐及其制备方法

    公开(公告)号:US20100233540A1

    公开(公告)日:2010-09-16

    申请号:US12709200

    申请日:2010-02-19

    IPC分类号: H01M4/525

    摘要: Provided is an olivine-type lithium iron phosphate composed of secondary particles having a mean particle diameter (D50) of 5 to 100 μm, formed by aggregation of primary particles having a mean particle diameter (D50) of 50 to 550 nm, wherein the primary and secondary particles have a composition represented by Formula I below and the secondary particles have a porosity of 15 to 40%: Li1+aFe1-xMx(PO4-b)Xb (I) wherein M, X, a, x and b are as defined above.The olivine-type lithium iron phosphate is in the form of secondary particles, thus imparting a high bulk density to lithium secondary batteries and exhibiting superior process efficiency due to shortened mixing time, when used to fabricate the lithium secondary batteries. Furthermore, the olivine-type lithium iron phosphate has the high porosity, thus allowing at least a portion of the secondary particles to be deformed and converted into primary particles in the process of pressing to fabricate electrodes and preventing deterioration in ionic conductivity due to the large particle diameter.

    摘要翻译: 本发明提供一种由平均粒径(D50)为5〜100μm的二次粒子构成的橄榄石型磷酸铁锂,其通过聚集平均粒径(D50)为50〜550nm的一次粒子而形成,其中, 二次粒子具有下述式I所示的组成,二次粒子的孔隙率为15〜40%:Li1 + aFe1-xMx(PO4-b)Xb(I)其中M,X,a,x和b分别为 以上定义。 橄榄石型磷酸铁锂是二次粒子的形式,因此当锂二次电池用于制造锂二次电池时,由于缩短了混合时间,因此赋予锂二次电池高的堆积密度,并表现出优异的工艺效率。 此外,橄榄石型磷酸铁锂具有高孔隙率,从而允许至少一部分二次粒子在压制过程中变形并转化为一次粒子,以制造电极,并防止由于大的离子导电性导致的劣化 粒径。

    Bar type clay member for craft
    10.
    发明授权
    Bar type clay member for craft 有权
    酒吧型粘土成员工艺

    公开(公告)号:US09074068B2

    公开(公告)日:2015-07-07

    申请号:US12983942

    申请日:2011-01-04

    摘要: A bar type clay member for craft includes a body formed by heating and melting 50 wt % to 80 wt % of wax, adding 10 wt % to 40 wt % of body pigment and 1 wt % to 10 wt % of a colorant to the melted wax, and then melting and dispersing the body pigment and colorant in the wax, wherein the body has a thickness ranging from 0.3 mm to 10 mm and has a bar-like shape.

    摘要翻译: 用于工艺的条形粘土构件包括通过加热和熔化蜡的50重量%至80重量%而形成的主体,将熔体中加入10重量%至40重量%的主体颜料和1重量%至10重量%的着色剂 蜡,然后将体颜料和着色剂熔化并分散在蜡中,其中本体具有0.3mm至10mm的厚度并具有棒状形状。