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1.发明授权Aqueous dispersions of polymers which comprise a fluorescent dye, process for their production and their use for marking materials 有权包含荧光染料的聚合物的水性分散体，其制备方法及其用于标记材料的用途公开(公告)号：US08735518B2
公开(公告)日：2014-05-27
申请号：US12097559
申请日：2006-12-11
申请人： Sven Holger Behrens , Simon Champ , Ulrike Geissler , Hans-Peter Hentze , Marc Rudolf Jung , Hans-Peter Kaub , Simon Nord
发明人： Sven Holger Behrens , Simon Champ , Ulrike Geissler , Hans-Peter Hentze , Marc Rudolf Jung , Hans-Peter Kaub , Simon Nord
CPC分类号： C09K11/06 , C08F2/18 , C08F2/22 , C08F2/44 , C08F212/08 , C08F220/06 , C08F220/14 , C08F220/40 , C08F222/1006 , C08K5/0008 , C08K5/0041 , C09D133/02
摘要： Aqueous dispersions of polymers which obtained by free radical suspension polymerization or free radical miniemulsion polymerization of ethylenically unsaturated monomers in an oil-in-water emulsion whose disperse phase comprises at least one fluorescent dye dissolved in at least one ethylenically unsaturated monomer and has an average particle diameter of at least 1μm, in the presence of at least one surface-active compound and at least 0.5% by weight, based on the monomers, of at least one hydrophobic, nonpolymerizable, organic compound, of a hydrophobic polymer of at least one C2- to C6-olefin having a molar mass Mw of up to 10000, of a siloxane having a molar mass Mw of up to 5000 and/or polystyrene having a molar mass Mw of up to 10000, and of the powders obtainable from these polymer dispersions in each case by drying and comprising at least one fluorescent dye for marking of materials.
摘要翻译： 通过自由基悬浮聚合或烯键式不饱和单体在水包油乳液中的自由基细乳液聚合获得的聚合物的水分散体，其分散相包含溶解在至少一种烯属不饱和单体中的至少一种荧光染料并具有平均颗粒 在至少一种表面活性化合物存在下至少为1μm的至少一种表面活性化合物和至少0.5重量％的至少一种疏水性聚合物的至少一种C2的至少一种C2 - 摩尔质量Mw高达10000的C 6 - 烯烃，摩尔质量Mw高达5000的硅氧烷和/或摩尔质量Mw高达10000的聚苯乙烯和可从这些聚合物分散体获得的粉末 在每种情况下通过干燥并包含至少一种用于标记材料的荧光染料。
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公开(公告)号：US20080262154A1
公开(公告)日：2008-10-23
申请号：US12097559
申请日：2006-12-11
申请人： Sven Holger Behrens , Simom Champ , Ulrike Geissler , Hans-Peter Hentze , Marc Rudolf Jung , Hans-Peter Kaub , Simon Nord
发明人： Sven Holger Behrens , Simom Champ , Ulrike Geissler , Hans-Peter Hentze , Marc Rudolf Jung , Hans-Peter Kaub , Simon Nord
IPC分类号： C08F2/32
CPC分类号： C09K11/06 , C08F2/18 , C08F2/22 , C08F2/44 , C08F212/08 , C08F220/06 , C08F220/14 , C08F220/40 , C08F222/1006 , C08K5/0008 , C08K5/0041 , C09D133/02
摘要： Aqueous dispersions of polymers which are obtainable by free radical suspension polymerization of ethylenically unsaturated monomers in an oil-in-water emulsion whose disperse phase comprises at least one fluorescent dye dissolved in at least one ethylenically unsaturated monomer and has an average particle diameter of at least 1 μm, in the presence of at least one surface-active compound and at least 0.5% per weight, based on the monomers, of at least one hydrophobic, nonpolymerizable organic compound, of a hydrophobic polymer of at least one C2- to C6-olefin having a molar mass Mw of up to 10 000, of a siloxane having a molar mass Mw of up to 5000 and/or polystyrene having a molar mass Mw of up to 10 000, processes for the preparation of these dispersions and use of aqueous dispersions of polymers which are obtainable by free radical suspension polymerization or by free radical miniemulsion polymerization of ethylenically unsaturated monomers in an oil-in-water emulsion whose disperse phase comprises at least one fluorescent dye in at least one ethylenically unsaturated monomer and has an average particle diameter of at least 100 nm, in the presence of at least one surface-active compound and at least 0.5% by weight, based on the monomers, of at least one hydrophobic, nonpolymerizable, organic compound, of a hydrophobic polymer of at least one C2- to C6-olefin having a molar mass Mw of up to 10 000, of a siloxane having a molar mass Mw of up to 5000 and/or polystyrene having a molar mass Mw of up to 10 000 and of the powders obtainable from these polymer dispersions in each case by drying and comprising at least one fluorescent dye for the marking of materials.
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公开(公告)号：US08575240B2
公开(公告)日：2013-11-05
申请号：US13515974
申请日：2010-12-16
申请人： Torsten Freund , Simon Nord , Marc Rudolf Jung , Hans-Peter Kaub , Tina Schröder-Grimonpont , Dirk Schmitt
发明人： Torsten Freund , Simon Nord , Marc Rudolf Jung , Hans-Peter Kaub , Tina Schröder-Grimonpont , Dirk Schmitt
CPC分类号： C04B40/0096 , C04B40/0039 , C04B2111/807 , C04B24/26 , C04B28/02 , C04B2103/54 , C04B24/2641 , C04B24/2664 , C04B2103/52
摘要： Identification and quantification of mass-produced goods in articles, a dye-containing polymer dispersion having been added to the mass-produced goods. The polymer dispersions contain particles which are coded by a mixture of dyes, and the polymer dispersion particles are quantitatively determined.
摘要翻译： 物品中批量生产物品的鉴定和定量，已经添加到大量生产的商品中的含染料的聚合物分散体。 聚合物分散体包含由染料混合物编码的颗粒，并且定量测定聚合物分散体颗粒。
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公开(公告)号：US20130035422A1
公开(公告)日：2013-02-07
申请号：US13515974
申请日：2010-12-16
申请人： Torsten Freund , Simon Nord , Marc Rudolf Jung , Hans-Peter Kaub , Tina Schröder-Grimonpont , Dirk Schmitt
发明人： Torsten Freund , Simon Nord , Marc Rudolf Jung , Hans-Peter Kaub , Tina Schröder-Grimonpont , Dirk Schmitt
CPC分类号： C04B40/0096 , C04B40/0039 , C04B2111/807 , C04B24/26 , C04B28/02 , C04B2103/54 , C04B24/2641 , C04B24/2664 , C04B2103/52
摘要： Identification and quantification of mass-produced goods in articles, a dye-containing polymer dispersion having been added to the mass-produced goods. The polymer dispersions contain particles which are coded by a mixture of dyes, and the polymer dispersion particles are quantitatively determined.
摘要翻译： 物品中批量生产物品的鉴定和定量，已经添加到批量生产的商品中的含染料的聚合物分散体。 聚合物分散体包含由染料混合物编码的颗粒，并且定量测定聚合物分散体颗粒。
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公开(公告)号：US08449981B2
公开(公告)日：2013-05-28
申请号：US12517360
申请日：2007-12-10
申请人： Marc Rudolf Jung , Hans-Peter Hentze , Rainer Dyllick-Brenzinger , Dieter Niederberger , Hans Willax
发明人： Marc Rudolf Jung , Hans-Peter Hentze , Rainer Dyllick-Brenzinger , Dieter Niederberger , Hans Willax
CPC分类号： C08L33/14 , B01J13/18 , B01J13/185 , C09K5/063 , C09K5/10 , D06M23/12 , F28D20/023 , Y10T428/2984 , Y10T428/2985 , Y10T428/2987 , Y10T428/2998
摘要： The present invention concerns microcapsules comprising a capsule core and a capsule wall, the capsule wall being constructed from 30% to 90% by weight of one or more C1-C24-alkyl esters of acrylic and/or methacrylic acid, acrylic acid, methacrylic acid and/or maleic acid (monomers I), 10% to 70% by weight of a mixture of divinyl and polyvinyl monomers (monomers II), the fraction of polyvinyl monomers being in the range from 2% to 90% by weight based on the monomers II, and also 0% to 30% by weight of one or more miscellaneous monomers (monomer III), all based on the total weight of the monomers, a process for their production and their use in textiles, bindered building materials and heat transfer fluids.
摘要翻译： 本发明涉及包含胶囊核心和胶囊壁的微胶囊，胶囊壁由30％至90％重量的一种或多种丙烯酸和/或甲基丙烯酸的C 1 -C 24烷基酯，丙烯酸，甲基丙烯酸 和/或马来酸（单体I），10重量％至70重量％的二乙烯基和聚乙烯基单体（单体II）的混合物，聚乙烯基单体的分数为2重量％至90重量％，基于 单体II，以及0％至30％重量的一种或多种其它单体（单体III），均基于单体的总重量，其生产方法及其在纺织品中的应用，结合建筑材料和热传递 流体。
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公开(公告)号：US20100323892A1
公开(公告)日：2010-12-23
申请号：US12865756
申请日：2009-02-04
申请人： Tatjana Levy , Marc Rudolf Jung , Rainer Berghaus , Hans-Peter Hentze , Tobias Joachim Koplin , Jurith Montag , Anke Reinold , Christian Sowa
发明人： Tatjana Levy , Marc Rudolf Jung , Rainer Berghaus , Hans-Peter Hentze , Tobias Joachim Koplin , Jurith Montag , Anke Reinold , Christian Sowa
CPC分类号： B01J13/14
摘要： The invention relates to an aqueous dispersion comprising microcapsules, the capsule wall of which is formed from radically polymerized monomers and the capsule core of which comprises at least one oil, in which the capsule core comprises at least one lipophilic surfactant and the continuous phase of the dispersion comprises at least one agrochemical. In addition, the invention relates to a process for the preparation of an aqueous dispersion by (i) providing an aqueous dispersion comprising microcapsules, the capsule wall of which is formed from radically polymerized monomers and the capsule core of which comprises at least one oil and at least one lipophilic surfactant (microcapsule crude dispersion), and (ii) mixing with at least one agrochemical. Furthermore, the invention relates to the use of the microcapsule crude dispersion for the preparation of an aqueous dispersion, and also to a product comprising, as separate components, a microcapsule crude dispersion and at least one agrochemical for combined use in combating undesirable plant growth and/or in combating undesirable insect or acarid infestation on plants and/or in combating phytopathogenic fungi.
摘要翻译： 本发明涉及包含微胶囊的水分散体，其胶囊壁由自由基聚合的单体形成，其胶囊核心包含至少一种油，其中胶囊核心包含至少一种亲脂性表面活性剂和连续相 分散体包含至少一种农用化学品。 另外，本发明涉及通过（i）提供包含微胶囊的水分散体制备水性分散体的方法，所述微胶囊的胶囊壁由自由基聚合的单体形成，其胶囊核心包含至少一种油和 至少一种亲脂性表面活性剂（微胶囊粗分散体），和（ii）与至少一种农药混合。 此外，本发明涉及微胶囊粗分散体用于制备水性分散体的用途，还涉及包含作为单独组分的微胶囊粗分散体和至少一种用于组合用于防治不需要的植物生长的农药的产品 /或防治植物上不希望的昆虫或螨虫侵袭和/或防治植物病原真菌。
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公开(公告)号：US08163207B2
公开(公告)日：2012-04-24
申请号：US12444051
申请日：2007-10-17
CPC分类号： B01J13/22 , B01J13/14 , Y10T428/2985 , Y10T428/2987 , Y10T428/2989
摘要： The invention described herein relates to a method of preparing microcapsules comprising a capsule core, a polymeric capsule wall and also, disposed on the outer surface of the capsule wall, a polyelectrolyte having an average molecular weight in the range from 500 g/mol to 10 million g/mol, the polymeric capsule wall being formed from specified monomers, where the microcapsules have an average particle size of 1.5-2.5 μm and 90% of the particles have a particle size ≦4 μm, by microencapsulating a capsule core with a polymeric capsule wall and then contacting the polymeric capsule wall with one or more polyelectrolytes in water or an aqueous medium.
摘要翻译： 本文描述的本发明涉及一种制备微胶囊的方法，所述微胶囊包括胶囊芯，聚合物胶囊壁，并且还设置在所述胶囊壁的外表面上，所述聚电解质的平均分子量为500g / mol至10 聚合物胶囊壁由特定单体形成，其中微胶囊具有1.5-2.5μm的平均粒度，并且90％的颗粒具有粒径＆nlE;4μm，通过将胶囊芯与 聚合物胶囊壁，然后使聚合物胶囊壁与一种或多种聚电解质在水或水性介质中接触。
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公开(公告)号：US20100286018A1
公开(公告)日：2010-11-11
申请号：US12812325
申请日：2009-01-13
CPC分类号： B01J13/14 , C11D3/3757 , C11D3/505
摘要： The present invention relates to microcapsules, microcapsule preparations, and detergents and cleaners comprising these, where the microcapsules comprise, in their core, one or more scents or fragrance(s) whose release behavior from the core of the microcapsules is considerably slowed through the use of more than one crosslinker.
摘要翻译： 本发明涉及微胶囊，微胶囊制剂，以及包含这些的微胶囊制剂，以及洗涤剂和清洁剂，其中微胶囊在其核心中包含一种或多种香料或香料，其通过使用使微胶囊核心的释放行为显着减慢 的多个交联剂。
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公开(公告)号：US20100068525A1
公开(公告)日：2010-03-18
申请号：US12517360
申请日：2007-12-10
申请人： Marc Rudolf Jung , Hans-Peter Hentze , Rainer Dyllick-Brenzinger , Dieter Niederberger , Hans Willax
发明人： Marc Rudolf Jung , Hans-Peter Hentze , Rainer Dyllick-Brenzinger , Dieter Niederberger , Hans Willax
CPC分类号： C08L33/14 , B01J13/18 , B01J13/185 , C09K5/063 , C09K5/10 , D06M23/12 , F28D20/023 , Y10T428/2984 , Y10T428/2985 , Y10T428/2987 , Y10T428/2998
摘要： The present invention concerns microcapsules comprising a capsule core and a capsule wall, the capsule wall being constructed from 30% to 90% by weight of one or more C1-C24-alkyl esters of acrylic and/or methacrylic acid, acrylic acid, methacrylic acid and/or maleic acid (monomers I), 10% to 70% by weight of a mixture of divinyl and polyvinyl monomers (monomers II), the fraction of polyvinyl monomers being in the range from 2% to 90% by weight based on the monomers II, and also 0% to 30% by weight of one or more miscellaneous monomers (monomer III), all based on the total weight of the monomers, a process for their production and their use in textiles, bindered building materials and heat transfer fluids.
摘要翻译： 本发明涉及包含胶囊核心和胶囊壁的微胶囊，胶囊壁由30％至90％重量的一种或多种丙烯酸和/或甲基丙烯酸的C 1 -C 24烷基酯，丙烯酸，甲基丙烯酸 和/或马来酸（单体I），10重量％至70重量％的二乙烯基和聚乙烯基单体（单体II）的混合物，聚乙烯基单体的分数为2重量％至90重量％，基于 单体II，以及0％至30％重量的一种或多种其它单体（单体III），均基于单体的总重量，其生产方法及其在纺织品中的应用，结合建筑材料和热传递 流体。
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公开(公告)号：US20100065209A1
公开(公告)日：2010-03-18
申请号：US12517481
申请日：2007-12-11
申请人： Andre Burghardt , Maria Teresa Hechavarria Fonseca , Karl Haeberle , Oliver Hartz , Marc Rudolf Jung , Karl-Heinz Schumacher , Denise von Preysing , Hans-Peter Hentze
发明人： Andre Burghardt , Maria Teresa Hechavarria Fonseca , Karl Haeberle , Oliver Hartz , Marc Rudolf Jung , Karl-Heinz Schumacher , Denise von Preysing , Hans-Peter Hentze
IPC分类号： B32B37/12 , B32B27/00 , C09J175/04
CPC分类号： C08G18/797 , C08G18/025 , C08G18/0823 , C08G18/2825 , C08G18/4854 , C08G18/6692 , C08G2170/80 , D21H21/54 , Y10T428/2985
摘要： Microcapsules wherein the capsule wall is formed from an organic polymer (capsule wall polymer for short) and the core of the microcapsules comprises compounds containing carbodiimide groups (carbodiimide compound for short).
摘要翻译： 其中胶囊壁由有机聚合物形成（微胶囊壁聚合物）和微胶囊核心的微胶囊包含含有碳二亚胺基团的化合物（简称为碳二亚胺化合物）。
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