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公开(公告)号:US20230273521A1
公开(公告)日:2023-08-31
申请号:US18006987
申请日:2021-07-07
发明人: Daisuke OJIMA , Yuta YAMAMOTO , Akiya KAWAUE
IPC分类号: G03F7/039
CPC分类号: G03F7/0392
摘要: A chemically amplified positive-type photosensitive composition capable of forming a patterned resist film having a square cross-section of a nonresist portion and good plating liquid resistance, even when forming a thick patterned resist film; a photosensitive dry film including a photosensitive layer consisting of the photosensitive composition; a production method of a substrate having a template for plating using the photosensitive composition; and a production method of a plated article using the substrate having the template formed by the aforementioned method. An acrylic resin having a constituent unit derived from a crosslinkable monomer which meets predetermined requirements as a resin is added to a chemically amplified positive-type photosensitive composition containing an acid generator which generates an acid by irradiation of active rays or radioactive rays and the resin, and a calculated value of glass transition temperature of hypothetical non-crosslinked acrylic resin which the constituent unit is excluded from the acrylic resin is set to 90° C. or higher and 120° C. or lower.
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公开(公告)号:US20170362460A1
公开(公告)日:2017-12-21
申请号:US15185899
申请日:2016-06-17
发明人: Akiya KAWAUE , Takehiro SESHIMO , Takaya MAEHASHI , Tasuku MATSUMIYA , Ken MIYAGI , Hitoshi YAMANO , Xuanxuan CHEN , Paul Franklin NEALEY
IPC分类号: C09D153/00 , C09D5/00 , B05D3/10 , C09D7/12 , B05D1/00
CPC分类号: C09D153/00 , B05D3/107 , C08K5/17 , C08K5/3415 , C08K5/3435 , C09D5/00 , C09D7/63 , G03F3/00 , G03F7/00
摘要: A resin composition for forming a phase-separated structure, including: a block copolymer, and an ion liquid containing a compound (IL) having a cation moiety and an anion moiety, the energy of the LUMO of the cation moiety being −4.5 eV or more, and the energy difference between the LUMO and the HOMO of the cation moiety being 10.0 ev or more, or the Log P value of the anion moiety being 1 to 3.
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公开(公告)号:US20170240766A1
公开(公告)日:2017-08-24
申请号:US15047468
申请日:2016-02-18
发明人: Akiya KAWAUE , Takehiro SESHIMO , Takaya MAEHASHI , Tasuku MATSUMIYA , Ken MIYAGI , Hitoshi YAMANO , Xuanxuan CHEN , Paul Franklin NEALEY
IPC分类号: C09D153/00
CPC分类号: C09D153/00 , B82Y40/00 , G03F7/0002
摘要: A resin composition for forming a phase-separated structure, including: a block copolymer, and an ion liquid containing a compound (IL) having a cation moiety and an anion moiety, the cation moiety of the compound (IL) having a dipole moment of 3 debye or more.
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公开(公告)号:US20230102353A1
公开(公告)日:2023-03-30
申请号:US17757502
申请日:2020-12-01
发明人: Yusuke KISHIMOTO , Akiya KAWAUE
IPC分类号: G03F7/039
摘要: A chemically amplified positive-type photosensitive resin composition with which a resist pattern having a rectangular cross-sectional shape is easily formed, which has satisfactory sensitivity, and which can suppress decomposition of the acid generating agent; a photosensitive dry film having a photosensitive layer including the photosensitive resin composition; a method for producing the photosensitive dry film; a method for producing a patterned resist film using the positive-type photosensitive resin composition; a method for producing a substrate provided with a template using the positive-type photosensitive resin composition; and a method for producing a plated article using the positive-type photosensitive resin composition. The photosensitive resin composition includes an acid generating agent to generate an acid by irradiation with an active ray or radiation, a resin having alkali solubility that increases under action of an acid, and an acid diffusion suppressing agent, wherein the acid generating agent includes a non-ionic acid generating agent that generates sulfonic acid upon the irradiation, and the acid diffusion suppressing agent includes a compound having a specific structure that is decomposed by the irradiation.
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公开(公告)号:US20190276698A1
公开(公告)日:2019-09-12
申请号:US16335129
申请日:2017-09-26
发明人: Takahiro DAZAI , Hitoshi YAMANO , Akiya KAWAUE , Ken MIYAGI
IPC分类号: C09D153/00
摘要: A method of producing a structure containing a phase-separated structure, including: a step of using a resin composition for forming a phase-separated structure including a block copolymer and an ion liquid containing a compound (IL) having a cation moiety and an anion moiety to form a BCP layer (3) containing a block copolymer on a substrate (1); and a step of vaporizing at least a part of the compound (IL), and phase-separating the BCP layer (3) to obtain a structure (3′) containing a phase-separated structure.
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公开(公告)号:US20180273794A1
公开(公告)日:2018-09-27
申请号:US15924772
申请日:2018-03-19
发明人: Akiya KAWAUE
IPC分类号: C09D165/00 , C08G61/04 , B05D1/00 , B05D3/02 , B05D3/10
摘要: A brush composition usable for phase-separation of a layer containing a block copolymer formed on a substrate, the brush composition including a resin component (A), the resin component (A) containing a polymeric compound (A1) in which a first polymer block and a second polymer block are bonded to each other through a linking group containing a substrate adhering group.
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公开(公告)号:US20170166664A1
公开(公告)日:2017-06-15
申请号:US15369471
申请日:2016-12-05
发明人: Masatoshi ARAI , Yoshitaka KOMURO , Akiya KAWAUE
IPC分类号: C08F8/00
CPC分类号: C08F8/00 , C08F220/18 , C08F224/00 , C08F228/00 , C08F2230/085
摘要: A method for manufacturing a polymer compound which has a constituent unit (a10) which includes a hydroxy group and a constituent unit (a1) which includes an acid decomposable group of which a polarity increases due to an effect of an acid, the method including copolymerizing a monomer for deriving a constituent unit (a0) which includes a group which protects a phenolic hydroxyl group or a hydroxy group of a carboxy group with an organic silicon compound and a monomer for deriving the constituent unit (a1) and obtaining a prepolymer which has the constituent unit (a0) and the constituent unit (a1), and selectively deprotecting the constituent unit (a0) by reacting a compound which has a fluoride anion with the prepolymer and obtaining a polymer compound which has the constituent unit (a10) and the constituent unit (a1).
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公开(公告)号:US20200209739A1
公开(公告)日:2020-07-02
申请号:US16715685
申请日:2019-12-16
发明人: Akiya KAWAUE , Yasushi KUROIWA
IPC分类号: G03F7/004 , G03F7/039 , C07C229/60 , G03F7/09
摘要: A chemically amplified photosensitive composition which forms a resist pattern whose cross-sectional shape is rectangular, and which has a wide depth of focus margin; a photosensitive dry film having a photosensitive layer made from the composition; a method of manufacturing a patterned-resist film using the composition; a method of manufacturing a substrate with a template using the composition; a method of manufacturing a plated article using the substrate with a template; and a novel compound. An acid diffusion suppressing agent having a specific structure is blended into the composition including an acid generator which generates acid upon exposure to an irradiated active ray or radiation.
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公开(公告)号:US20190121233A1
公开(公告)日:2019-04-25
申请号:US16160297
申请日:2018-10-15
发明人: Akiya KAWAUE , Yuta YAMAMOTO , Kazuaki EBISAWA , Yasushi KUROIWA
IPC分类号: G03F7/004 , G03F7/039 , G03F7/16 , G03F7/20 , G03F7/38 , G03F7/32 , C07D493/08 , C07C323/61
摘要: A chemically amplified positive-type photosensitive resin composition capable of suppressing the occurrence of “footing” in which the width of the bottom (the side proximal to the surface of a support) becomes narrower than that of the top (the side proximal to the surface of a resist layer) in the nonresist portion; and the generation of development residue when a resist pattern serving as a template for a plated article is formed on a metal surface of a substrate using the photosensitive resin composition. A mercapto compound having a specific structure is included in the photosensitive resin composition, and includes an acid generator which generates acid upon exposure to an irradiated active ray or radiation, and a resin whose solubility in alkali increases under the action of acid.
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公开(公告)号:US20190101825A1
公开(公告)日:2019-04-04
申请号:US16136786
申请日:2018-09-20
发明人: Akiya KAWAUE , Yasushi KUROIWA , Shota KATAYAMA , Kazuaki EBISAWA
摘要: A chemically amplified positive-type photosensitive resin composition capable of suppressing the occurrence of “footing” in which the width of the bottom (the side proximal to the surface of a support) becomes narrower than the top (the side proximal to the surface of a resist layer) in the nonresist portion when a resist pattern serving as a template for a plated article is formed on a metal surface of a substrate having a metal surface using the composition. A mercapto compound with a specific structure is added to the composition and includes an acid generator which generates acid upon exposure to an irradiated active ray or radiation and a resin the solubility of which in alkali increases under the action of acid.
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