摘要:
A resin composition for forming a phase-separated structure includes a block copolymer having a block (b1) formed of a repeating structure of styrene units, the block (b1) being partially substituted with a constituent unit represented by the following General Formula (c1) and a block (b2) having a repeating structure of methyl methacrylate units. In the formula, R is a hydrogen atom or a methyl group and Rc0 is a hydrophobic functional group
摘要:
A method of producing a structure containing a phase-separated structure, including: a step of using a resin composition for forming a phase-separated structure including a block copolymer and an ion liquid containing a compound (IL) having a cation moiety and an anion moiety to form a BCP layer (3) containing a block copolymer on a substrate (1); and a step of vaporizing at least a part of the compound (IL), and phase-separating the BCP layer (3) to obtain a structure (3′) containing a phase-separated structure.
摘要:
A method of producing a purified product of a resin composition for forming a phase-separated structure, the method including subjecting a resin composition for forming a phase-separated structure to filtration using a filter having a porous structure in which adjacent spherical cells are mutually communicating, the filter being provided with a porous membrane containing at least one resin selected from the group consisting of polyimide and polyamideimide, and the resin composition for forming a phase-separated structure including a block copolymer and an organic solvent component.
摘要:
A method of producing a structure containing a phase-separated structure, including using a resin composition for forming a phase-separated structure including a block copolymer having a period L0 and an ion liquid containing a compound (IL) having a cation moiety and an anion moiety to form a BCP layer containing a block copolymer and having a thickness of d (nm) on a substrate; and vaporizing at least a part of the compound (IL), and phase-separating the BCP layer to obtain a structure containing a phase-separated structure, wherein, in step (i), the BCP layer is formed such that the period L0 (nm) of the block copolymer and the thickness d (nm) of the BCP layer satisfies the following formula (1): Thickness d/Period L0=n+a (1) wherein n represents an integer of 0 or more; and a is a number which satisfies 0
摘要:
A resin composition for forming a phase-separated structure includes a block copolymer having a block (b1) having a repeating structure of styrene units; a block (b2) having a repeating structure of methyl methacrylate units partially substituted with a constituent unit represented by general formula (h1); and a number average molecular weight of less than 28,000. In general formula (h1), Rh0 is a hydrophilic functional group.
摘要:
A resin composition for forming a phase-separated structure, including a block copolymer, and an ion liquid containing a compound having a cation moiety and an anion moiety, the anion moiety being represented by general formula (a1), (a2) or (a3), in which X″ represents an alkylene group of 2 to 6 carbon atoms in which at least one hydrogen atom is substituted with a fluorine atom; Y″ and Z″ each independently represents an alkyl group of 1 to 10 carbon atoms in which at least one hydrogen atom is substituted with a fluorine atom; R″ represents an alkyl group of 1 to 5 carbon atoms in which at least one hydrogen atom is optionally substituted with a fluorine atom, m represents an integer of 1 to 6, and n represents an integer of 0 to 5, provided that m+n=6.
摘要:
A resin composition for forming a phase-separated structure, the resin composition including a block copolymer, an ion liquid and an organic solvent component, the ion liquid containing a compound (IL) having a cation moiety and an anion moiety, and the organic solvent component containing an organic solvent (S1) having a boiling point of lower than 150° C., and an organic solvent (S2) having a boiling point of 150° C. or higher.
摘要:
A brush composition used for phase-separation of a layer containing a block copolymer on a substrate, the brush composition including a resin component (N), the resin component (N) containing a hydrophobic structural unit (Nx) and a hydrophilic structural unit (Ny), the amount of the structural unit (Ny) within the resin component (N) being 5 mol % or less.
摘要:
[Problem] To easily and accurately perform authentication at low cost. [Means to Solve Problem] Provided is an authentication object C1 that serves as a target of authentication performed by an authentication system, comprising an authentication medium M1 having authentication information that includes a feature related to a pattern of a part of a phase separation structure formed on a substrate from a resin composition for phase separation structure formation and is to be acquired by an acquisition device provided in the authentication system.
摘要:
A resin composition for forming a phase-separated structure containing a block copolymer having a first block and a second block, in which the first block is formed of a constituent unit represented by Formula (b1), the second block is formed of a constituent unit represented by Formula (b2m) and a random copolymer having a constituent unit represented by Formula (b2g), and a ratio of a volume of the first block is 20% to 80% by volume. In the formulas, R1 is a hydrogen atom or an alkyl group, Rb1 is a hydrogen atom or a methyl group, R2 is an alkyl group which may have a silicon atom, a fluorine atom, a carboxy group, an amino group, a hydroxy group, or a phosphoric acid group, R3 is a linear or branched alkylene group having 1 to 10 carbon atoms, which may have a hydroxy group, and Rb2 is a hydrogen atom, an alkyl group having 1 to 5 carbon atoms, or a halogenated alkyl group having 1 to 5 carbon atoms