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公开(公告)号：US5132157A
公开(公告)日：1992-07-21
申请号：US525726
申请日：1990-05-21
CPC分类号： C08J5/18 , B29C55/005 , B29C59/022 , B29K2023/12 , B29K2995/0026 , B29K2995/0072 , C08J2323/10 , Y10S428/91 , Y10T156/1002 , Y10T156/1023 , Y10T428/24355 , Y10T428/24479 , Y10T428/26 , Y10T428/269 , Y10T428/31 , Y10T428/31938
摘要： A stretched film of polypropylene which is excellent in transparency, substantially free of an antiblocking agent and at least uniaxially stretched and which is characterized in that it has uniformly distributed projections having a height ranging from 0.05 to 0.50 .mu. and a width ranging from 10 to 100 .mu. at least on the surface thereof as well as a method for preparing the foregoing stretched film of polypropylene which comprises the steps of forming, into a sheet, polypropylene which comprises a nucleating agent in an amount selected so that the crystallization temperature of polypropylene is increased by 1.degree.to 10.degree. C. by the addition thereof and then stretching the sheet at a temperature ranging from 140.degree. to 165.degree. C. are herein disclosed.
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公开(公告)号：US5200131A
公开(公告)日：1993-04-06
申请号：US679522
申请日：1991-04-02
申请人： Tadashi Asanuma , Tateyo Sasaki , Mitsuru Ito , Shigeru Kimura , Takeo Inoue
发明人： Tadashi Asanuma , Tateyo Sasaki , Mitsuru Ito , Shigeru Kimura , Takeo Inoue
CPC分类号： D01F6/06 , C08J5/18 , C08J7/02 , C08J2323/10 , C08L2207/12 , C08L23/10 , Y10S526/943
摘要： A method for molding a polypropylene or a propylene copolymer having a syndiotactic structure which comprises the steps of melting, molding, if desired, quenching and then stretching a propylene homopolymer or a copolymer of propylene and a small amount of ethylene or another .alpha.-olefin which has a substantially syndiotactic structure, or a mixture of the same and a small amount of a polypropylene having a substantially isotactic structure. The molded and stretched article can be heated at a temperature of a molding temperature or more, while a load is applied to the article. Furthermore, the molded and stretched article, if desired, can be treated with a hydrocarbon vapor, while a load is applied to the article. The molded article obtained by the method of the present invention has a novel crystalline structure.
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3.发明授权公开(公告)号：US06255425B1
公开(公告)日：2001-07-03
申请号：US08182348
申请日：1994-01-18
申请人： Tadashi Asanuma , Tetsunosuke Shiomura , Nobutaka Uchikawa , Tateyo Sasaki , Osamu Uchida , Tutomu Iwatani , Shigeru Kimura , Takeo Inoue
发明人： Tadashi Asanuma , Tetsunosuke Shiomura , Nobutaka Uchikawa , Tateyo Sasaki , Osamu Uchida , Tutomu Iwatani , Shigeru Kimura , Takeo Inoue
IPC分类号： C08F21006
CPC分类号： C08J5/18 , C08F210/06 , C08J2323/10 , C08L23/10 , Y10S526/916 , Y10T428/1345 , Y10T428/1352 , Y10T428/1397 , C08F210/16 , C08F2500/16 , C08F2500/03 , C08F210/14 , C08F210/08
摘要： A syndiotactic polypropylene copolymer is disclosed which comprises 70 to 99.9 mole % of propylene and 0.1 to 30 mole % of an olefin other than propylene; in the 13C-NMR spectrum of the syndiotactic polypropylene copolymer, a ratio of the intensity of a peak at about 20.2 ppm to the sum of the intensities of the total peaks attributable to methyl groups in propylene units at about 19-22 ppm being 0.3 or more. Also disclosed are extrusion-molded high-transparency articles, especially films and sheets and blown films, obtained by the extrusion of a polypropylene substantially having a syndiotactic structure.
摘要翻译： 公开了间同立构聚丙烯共聚物，其包含70-99.9摩尔％的丙烯和0.1-30摩尔％的除丙烯以外的烯烃; 在间同立构聚丙烯共聚物的13 C-NMR光谱中，约20.2ppm处的峰强度与归属于丙烯单元的甲基的总峰的强度的总和的比例为约为19-22ppm，为0.3或 更多。 还公开了挤出成型的高透明度制品，特别是通过挤出基本上具有间同立构结构的聚丙烯获得的薄膜和片材和吹塑薄膜。
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公开(公告)号：US5637367A
公开(公告)日：1997-06-10
申请号：US124531
申请日：1993-09-22
申请人： Tadashi Asanuma , Tateyo Sasaki , Shosuke Nakanishi , Takeo Inoue
发明人： Tadashi Asanuma , Tateyo Sasaki , Shosuke Nakanishi , Takeo Inoue
CPC分类号： C08L23/12 , B29C49/0005 , C08L23/10 , C08L23/142 , C08L23/16 , B29B2911/1402 , B29B2911/14026 , B29B2911/14033 , B29B2911/1404 , B29B2911/14106 , B29B2911/14133 , B29C49/00 , B29K2023/12 , B29K2995/0026 , B29K2995/0089 , B29L2031/7158 , C08L2203/10 , C08L2207/12 , C08L23/0815 , C08L23/14 , Y10T428/1352 , Y10T428/139 , Y10T428/1393 , Y10T428/1397
摘要： A molded article obtained by blow molding a propylene having a substantially syndiotactic structure or a resin composition comprising a polypropylene having a substantially syndiotactic structure and a copolymer of ethylene and propylene, and a multi-layer molded article obtained from this resin composition in which at least one surface of the molded article is a polypropylene layer having the substantially syndiotactic structure.
摘要翻译： 通过吹塑具有基本上间同立构结构的丙烯或包含具有基本上间同立构结构的聚丙烯和乙烯和丙烯的共聚物的树脂组合物和由该树脂组合物获得的多层模塑制品而获得的模制品，其中至少 模制品的一个表面是具有基本上间同立构结构的聚丙烯层。
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5.发明授权
公开(公告)号：US5232992A
公开(公告)日：1993-08-03
申请号：US593734
申请日：1990-10-05
CPC分类号： C08J5/00 , B29C67/24 , C08K3/0008 , C08K5/0008 , C08K5/0083 , C08L23/10 , B29C71/02 , B29K2023/12 , C08J2323/10 , C08L2205/02 , C08L2207/12
摘要： According to the present invention, molded articles can be provided in which a melting point attributed to a syndiotactic polypropylene and measured at a temperature rise rate of 10.degree. C./minute by differential scanning thermal analysis is indicated by a substantially single peak, the aforesaid molded articles being obtained by heating, melting and molding a substantially syndiotactic homopolymer of propylene, a substantially syndiotactic copolymer of propylene and a small amount of another olefin, or a mixture of these polymers and a small amount of a substantially isotactic polypropylene, and then subjecting the molded products to a heat treatment. Furthermore, a method for preparing the above-mentioned molded articles is also provided. The molded articles have high stiffness and impact resistance.
摘要翻译： 根据本发明，可以提供通过差示扫描热分析以10℃/分钟的升温速度测定归因于间同立构聚丙烯的熔点的成型体，其基本上由单峰表示，上述 通过加热，熔融和模制丙烯基本上间同立构的均聚物，丙烯和少量另一种烯烃的基本上间同立构共聚物，或这些聚合物和少量的基本上为全同立构的聚丙烯的混合物而获得的模塑制品， 成型产品进行热处理。 此外，还提供了制备上述模制品的方法。 模制品具有高刚度和抗冲击性。
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公开(公告)号：US5278216A
公开(公告)日：1994-01-11
申请号：US899141
申请日：1992-06-17
IPC分类号： B29C67/24 , B29C71/02 , C08J5/00 , C08K3/00 , C08K5/00 , C08L23/10 , C08K5/09 , C08K3/32 , C08K3/34 , C08K5/16
CPC分类号： C08J5/00 , B29C67/24 , C08K3/0008 , C08K5/0008 , C08K5/0083 , C08L23/10 , B29C71/02 , B29K2023/12 , C08J2323/10 , C08L2205/02 , C08L2207/12 , Y10S526/943
摘要： A syndiotactic polypropylene resin composition comprising a polypropylene having a substantially syndiotactic structure and a nucleating agent. The syndiotactic polypropylene may be a homopolymer of the propylene, a copolymer of the propylene and a smaller amount of another olefin or a mixture of the above-mentioned (co)polymer and an isotactic polypropylene. The resin composition preferably has a higher crystallization temperature than a polypropylene containing no nucleating agent by 5.degree. C. or more, as measurement is made by a differential scanning thermal analysis.
摘要翻译： 包含具有基本间同立构结构的聚丙烯和成核剂的间同立构聚丙烯树脂组合物。 间同立构聚丙烯可以是丙烯的均聚物，丙烯与较少量的另一种烯烃的共聚物或上述（共）聚合物和全同立构聚丙烯的混合物。 当通过差示扫描热分析进行测量时，树脂组合物优选具有比不含成核剂的聚丙烯高5℃或更高的结晶温度。
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公开(公告)号：US5260395A
公开(公告)日：1993-11-09
申请号：US928062
申请日：1992-08-11
申请人： Tadashi Asanuma , Tateyo Sasaki , Mitsuru Ito , Shigeru Kimura , Takeo Inoue
发明人： Tadashi Asanuma , Tateyo Sasaki , Mitsuru Ito , Shigeru Kimura , Takeo Inoue
IPC分类号： C08J5/18 , C08J7/02 , C08L23/10 , D01F6/06 , C08F10/06 , C08F110/06 , C08F210/06
CPC分类号： D01F6/06 , C08J5/18 , C08J7/02 , C08L23/12 , C08J2323/10 , C08L2203/12 , C08L2205/02 , C08L2205/025 , C08L2207/12 , C08L23/142
摘要： A method for molding a polypropylene or a propylene copolymer having a syndiotactic structure which comprises the steps of melting, molding, if desired, quenching and then stretching a propylene homopolymer or a copolymer of propylene and a small amount of ethylene or another .alpha.-olefin which has a substantially syndiotactic structure, or a mixture of the same and a small amount of a polypropylene having a substantially isotactic structure. The molded and stretched article can be heated at a temperature of a molding temperature or more, while a load is applied to the article. Furthermore, the molded and stretched article, if desired, can be treated with a hydrocarbon vapor, while a load is applied to the article. The molded article obtained by the method of the present invention has a novel crystalline structure.
摘要翻译： 用于模制具有间同立构结构的聚丙烯或丙烯共聚物的方法包括以下步骤：熔融，模塑，如果需要，淬火然后拉伸丙烯均聚物或丙烯与少量乙烯或另一种α-烯烃的共聚物 具有基本间同立构结构，或相同和少量具有基本上全同立构结构的聚丙烯的混合物。 模制和拉伸的制品可以在成型温度或更高的温度下加热，同时将负载施加到制品上。 此外，如果需要，模制和拉伸的制品可以用烃蒸气处理，同时将负载施加到制品上。 通过本发明的方法获得的模制品具有新颖的晶体结构。
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公开(公告)号：US4439567A
公开(公告)日：1984-03-27
申请号：US396202
申请日：1982-07-08
申请人： Takeo Inoue , Jun Otsu , Tateyo Sasaki , Hiroyuki Doi , Keigo Suehiro
发明人： Takeo Inoue , Jun Otsu , Tateyo Sasaki , Hiroyuki Doi , Keigo Suehiro
IPC分类号： C08K5/1575 , C08K5/15
CPC分类号： C08K5/1575
摘要： There is provided a polyolefin resin composition for injection molding which comprises adding to polyolefin a condensate of sorbitol with an aldehyde compound and a lubricant of 1/20 to 1/2 parts by weight based on 1.0 part by weight of said condensate. Thereby polyolefin injection moldings with good transparency are obtained without bringing a foaming phenomenon.
摘要翻译： 提供了一种用于注射成型的聚烯烃树脂组合物，其包括向聚烯烃中加入山梨糖醇与醛化合物的缩合物和基于1.0重量份所述缩合物的1/20至1/2重量份的润滑剂。 从而获得具有良好透明度的聚烯烃注射成型品而不产生起泡现象。
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9.发明授权
公开(公告)号：US5573840A
公开(公告)日：1996-11-12
申请号：US451394
申请日：1995-05-26
申请人： Takeo Inoue , Shigeru Kimura , Tutomu Iwatani , Takayuki Yamada , Yukio Ishii , Ryuichi Sugimoto
发明人： Takeo Inoue , Shigeru Kimura , Tutomu Iwatani , Takayuki Yamada , Yukio Ishii , Ryuichi Sugimoto
CPC分类号： C08L23/10 , C08L23/12 , H01B3/441 , C08L51/06 , C08L83/04 , C08L83/12 , Y10S428/91 , Y10T428/24975 , Y10T428/25
摘要： The invention provides a polymeric insulating material having a high dielectric breakdown voltage. The material comprises polypropylene which has been obtained in a yield of at least 300,000 g/g-Ti based on titanium in a catalyst upon polymerization, contains ash in an amount not greater than 40 ppm by weight when analyzed by completely burning the polypropylene in air, said ash containing titanium in an amount not greater than 1 ppm by weight based on the weight of the polypropylene, and also contains chlorine in an amount not greater than 2 ppm by weight and boiling n-heptane soluble matter in an amount not smaller than 1 wt. % but not greater than 10 wt. %. To further improve the dielectric breakdown voltage an inorganic oxide or hydroxide free of particles of 10 .mu.m and greater in diameter and having an average particle size not greater than 1 .mu.m, an organopolysilane, a maleic-anhydride-grafted polypropylene, or a silane compound containing at least one organic polyether group can be added to the polypropylene.
摘要翻译： 本发明提供了具有高绝缘击穿电压的聚合物绝缘材料。 该材料包括在聚合时以催化剂中钛为基准的至少300,000g / g-Ti的产率获得的聚丙烯，当通过在空气中完全燃烧聚丙烯进行分析时，含有不大于40ppm重量的灰分 所述灰分含量以聚丙烯重量计不超过1重量ppm，并且还含有不大于2重量ppm的氯和沸点正庚烷可溶物质量不小于 1重量％ ％但不大于10wt。 ％。 为了进一步提高介电击穿电压，无机氧化物或氢氧化物不含直径10μm以上且平均粒径不大于1μm的颗粒，有机聚硅烷，马来酸酐接枝的聚丙烯或硅烷 可以将含有至少一个有机聚醚基团的化合物加入到聚丙烯中。
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10.发明授权
公开(公告)号：US5476709A
公开(公告)日：1995-12-19
申请号：US73676
申请日：1993-06-08
申请人： Takeo Inoue , Shigeru Kimura , Tutomu Iwatani , Takayuki Yamada , Yukio Ishii , Ryuichi Sugimoto
发明人： Takeo Inoue , Shigeru Kimura , Tutomu Iwatani , Takayuki Yamada , Yukio Ishii , Ryuichi Sugimoto
CPC分类号： C08L23/10 , C08L23/12 , H01B3/441 , C08L51/06 , C08L83/04 , C08L83/12 , Y10S428/91 , Y10T428/24975 , Y10T428/25
摘要： The invention provides a polymeric insulating material having a high dielectric breakdown voltage. The material comprises polypropylene which has been obtained in a yield of at least 300,000 g/g-Ti based on titanium in a catalyst upon polymerization, contains ash in an amount not greater than 40 ppm by weight when analyzed by completely burning the polypropylene in air, said ash containing titanium in an amount not greater than 1 ppm by weight based on the weight of the polypropylene, and also contains chlorine in an amount not greater than 2 ppm by weight and boiling n-heptane soluble matter in an amount not smaller than 1 wt. % but not greater than 10 wt. %. According to the invention, it is possible to further improve the dielectric breakdown voltage by adding to the polypropylene an inorganic oxide or hydroxide free of particles of 10 .mu.m and greater in diameter and having an average particle size not greater than 1 .mu.m, an organopolysilane, a maleic-anhydride-grafted polypropylene, or a silane compound containing at least one organic polyether group.
摘要翻译： 本发明提供了具有高绝缘击穿电压的聚合物绝缘材料。 该材料包括在聚合时以催化剂中钛为基准的至少300,000g / g-Ti的产率获得的聚丙烯，当通过在空气中完全燃烧聚丙烯进行分析时，含有不大于40ppm重量的灰分 所述灰分含量以聚丙烯重量计不超过1重量ppm，并且还含有不大于2重量ppm的氯和沸点正庚烷可溶物质量不小于 1重量％ ％但不大于10wt。 ％。 根据本发明，通过向聚丙烯中添加不含直径10μm以上的平均粒径为1μm以下的无机氧化物或氢氧化物，可以进一步提高介电击穿电压， 有机聚硅烷，马来酸酐接枝的聚丙烯或含有至少一个有机聚醚基团的硅烷化合物。
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