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1.发明授权公开(公告)号：US07053016B2
公开(公告)日：2006-05-30
申请号：US10308507
申请日：2002-12-03
IPC分类号： C03C17/22
CPC分类号： C04B41/009 , B01D39/201 , B01D39/202 , C03C8/14 , C03C14/004 , C04B41/52 , C04B41/89 , C04B2111/00793 , C04B41/4535 , C04B41/5022 , C04B41/5027 , C04B41/5089 , C04B41/0072 , C04B41/4539 , C04B41/5031 , C04B35/10
摘要： A ceramic porous body is provided which uses a binder made of a glass that has excellent acid resistance and alkali resistance and which can be used for a long period of time as a filtration filter. The ceramic porous body is formed from ceramic particles that are bonded using a glass binder comprising 5 to 20 mol % of a plurality of metal oxides, selected from the group consisting of Li2O, Na2O, K2O, MgO, CaO, SrO and BaO and containing at least two alkali metal oxides selected from the group consisting of Li2O, Na2O and K2O as an essential component, at least 3 mol % of at least one of ZrO2 and TiO2 as a total amount, and SiO2 and incidental impurities as the balance.
摘要翻译： 提供了一种陶瓷多孔体，其使用具有优异的耐酸性和耐碱性的玻璃制粘合剂，并且可以作为过滤器长时间使用。 陶瓷多孔体由使用包含5〜20摩尔％的多种金属氧化物的玻璃粘合剂结合的陶瓷颗粒形成，所述金属氧化物选自Li 2 O 2，Na 2 O， 2 O，K 2 O，MgO，CaO，SrO和BaO，并且含有至少两种选自Li 2 O， 作为必要成分的Na 2 O 2和K 2 O 2，至少3摩尔％的ZrO 2和TiO 2的至少一种， 作为总量的SiO 2和偶氮杂质作为余量。
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2.发明授权
公开(公告)号：US5897970A
公开(公告)日：1999-04-27
申请号：US961502
申请日：1997-10-30
申请人： Manabu Isomura , Takao Soma , Tomonori Takahashi
发明人： Manabu Isomura , Takao Soma , Tomonori Takahashi
IPC分类号： B01D53/22 , B01J19/24 , C01B3/32 , C01B3/34 , C01B3/38 , C01B3/50 , H01M8/00 , H01M8/06 , H01M16/00
CPC分类号： H01M8/0631 , B01J19/2475 , C01B3/32 , C01B3/323 , C01B3/34 , C01B3/38 , C01B3/382 , C01B3/386 , C01B3/501 , H01M8/0612 , B01J2219/0011 , B01J2219/00117 , B01J2219/00159 , C01B2203/0244 , C01B2203/041 , C01B2203/0465 , C01B2203/047 , C01B2203/066 , C01B2203/0811 , C01B2203/0822 , C01B2203/0827 , C01B2203/0844 , C01B2203/0866 , C01B2203/1064 , C01B2203/1076 , C01B2203/1223 , C01B2203/1288 , C01B2203/142 , C01B2203/1604 , C01B2203/82 , Y02P20/126 , Y02P20/128
摘要： There is a system for producing high-purity hydrogen by reforming a hydrocarbon and/or an oxygen atom-containing hydrocarbon to form a reformed gas containing hydrogen and separating the hydrogen from said gas. The system includes a hydrocarbon source, a water source, an oxygen source, a vaporization chamber connecting with the hydrocarbon source, the water source and the oxygen source, and a reforming chamber provided with a catalyst for steam reforming and partial oxidation and a hydrogen-separating membrane. The reforming chamber is thermally connected with the vaporization chamber. A process for producing high-purity hydrogen includes heating a reforming chamber provided with a hydrogen-separating membrane, feeding, into the reforming chamber, hydrocarbon, steam and oxygen or air to give rise to steam reforming and partial oxidation therein to produce a reaction gas, and passing the reaction gas through the hydrogen-separating membrane to recover high-purity hydrogen. The heat possessed by the portion of the reaction gas not permeable into the hydrogen-separating membrane and the heat generated by the partial oxidation are utilized for the heating and reforming of the hydrocarbon, water and oxygen or air.
摘要翻译： 存在通过重整烃和/或含氧原子的烃来形成含氢的重整气体并从所述气体中分离出氢气的方法来生产高纯度氢气。 该系统包括烃源，水源，氧源，与烃源连接的蒸发室，水源和氧源，以及设置有用于蒸汽重整和部分氧化的催化剂的重整室， 分离膜。 重整室与蒸发室热连接。 一种生产高纯度氢的方法包括加热设置有氢分离膜的重整室，向重整室供给碳氢化合物，蒸气和氧气或空气，引起蒸汽重整和部分氧化，产生反应气体 ，并使反应气体通过氢分离膜以回收高纯度氢。 反应气体不能透过氢分离膜的部分所产生的热量以及由部分氧化产生的热量用于烃，水和氧气或空气的加热和重整。
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公开(公告)号：US07585347B2
公开(公告)日：2009-09-08
申请号：US11375089
申请日：2006-03-14
CPC分类号： B01D63/061 , B01D63/066 , B01D65/003 , B01D65/02 , B01D71/02 , B01D71/024 , B01D71/025 , B01D2321/162 , B01D2321/168 , C02F1/44 , C03C8/24 , C04B38/0012 , C04B38/0051 , C04B2111/00793 , C04B35/00 , C04B41/5022
摘要： A ceramic filter is provided, including a base body having partition walls made of a ceramic porous body and defining cells, filter membranes provided on the partition walls which are made of a ceramic porous body having an average pore diameter smaller than that of the surface of each partition wall, and a glass seal provided to cover at least the end face of the base body. The glass seal includes an alkali-free glass containing silica (SiO2) in an amount of 55 to 65 mol %, zirconia (ZrO2) in an amount of 1 to 10 mol % and at least one kind of alkaline earth metal oxide selected from calcia, baria and strontia, but which does not substantially contain zinc oxide.
摘要翻译： 提供一种陶瓷过滤器，包括具有由陶瓷多孔体制成的分隔壁并限定单元的基体，设置在隔壁上的过滤膜，其由具有平均孔径小于表面的平均孔径的陶瓷多孔体制成 每个分隔壁和设置成至少覆盖基体的端面的玻璃密封件。 玻璃密封件包括含有55〜65摩尔％的二氧化硅（SiO 2），1〜10摩尔％的氧化锆（ZrO 2）和选自氧化钙中的至少一种碱土金属氧化物的无碱玻璃 ，baria和strontia，但其实质上不含氧化锌。
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公开(公告)号：US5238882A
公开(公告)日：1993-08-24
申请号：US894640
申请日：1992-06-05
IPC分类号： C04B35/584 , C04B35/593
CPC分类号： C04B35/5935 , C04B35/584
摘要： Silicon nitride sintered bodies are disclosed which contain silicon carbide therein and in which intergranular phases between silicon nitride particles are substantially crystallized. Further, a manufacturing method of the sintered bodies is disclosed, in which a silicon carbide powdery raw material is used as an additive when preparing raw powders and the intergranular phases are crystallized during a temperature descending stage following a firing. Silicone carbide effectivley promotes densification of the structure of the sintered body and crystallization of the intergranular phases, thereby making it possible to provide the sintered bodies having intergranular phases with little glass phases uncrystallized and excellent high-temperature strengths.
摘要翻译： 公开了在其中含有碳化硅并且其中氮化硅颗粒之间的晶间相基本上结晶的氮化硅烧结体。 此外，公开了烧结体的制造方法，其中在制备原料粉末时使用碳化硅粉末原料作为添加剂，并且在烧制之后的温度下降阶段期间晶间相结晶。 有机碳化物有利于促进烧结体的结构的致密化和晶间相的结晶化，从而可以提供具有很少的玻璃相的晶间相的烧结体，并且具有优异的高温强度。
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公开(公告)号：US5177038A
公开(公告)日：1993-01-05
申请号：US521567
申请日：1990-05-10
IPC分类号： C04B35/584 , C04B35/593
CPC分类号： C04B35/5935 , C04B35/584
摘要： Silicon nitride sintered bodies are disclosed which contain silicon carbide therein and in which intergranular phases between silicon nitride particles are substantially crystallized. Further, a manufacturing method of the sintered bodies is disclosed, in which a silicon carbide powdery raw material is used as an additive when preparing raw powders and the intergranular phases are crystallized during a temperature descending stage following a firing. Silicon carbide effectively promotes densification of the structure of the sintered body and crystallization of the intergranular phases, thereby making it possible to provide the sintered bodies having intergranular phases with little glass phases uncrystallized and excellent high-temperature strengths.
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公开(公告)号：US07288199B2
公开(公告)日：2007-10-30
申请号：US10309321
申请日：2002-12-02
申请人： Manabu Isomura , Tomonori Takahashi , Kenji Mutoh , Minoru Ohta , Makoto Itoh
发明人： Manabu Isomura , Tomonori Takahashi , Kenji Mutoh , Minoru Ohta , Makoto Itoh
CPC分类号： B01D67/0046 , B01D39/2068 , B01D69/12 , B01D71/024 , B01D2325/04 , B01D2325/28 , C02F1/444 , C04B38/0054 , C04B41/009 , C04B41/52 , C04B41/89 , C04B2111/00801 , C04B2111/2092 , C04B35/46 , C04B41/0072 , C04B41/4539 , C04B41/5022 , C04B41/5031 , C04B41/5041 , C04B35/10 , C04B38/00
摘要： A ceramic filter is provided including a substrate, a separation layer comprising titania and having an average pore size in a range of 0.08 to 1 μm and a thickness in a range of 5 to 20 μm, and an intermediate layer formed between the substrate and the separation layer. The intermediate layer includes aggregate particles that are bonded together with glass frits, and aggregate particles of the intermediate layer are smaller than aggregate particles of the substrate and larger than aggregate particles of the separation layer.
摘要翻译： 提供一种陶瓷过滤器，其包括基材，包含二氧化钛并且平均孔径在0.08-1μm的范围内，厚度在5-20μm范围内的分离层，以及形成在基材和 分离层。 中间层包括用玻璃料粘合在一起的聚集体颗粒，中间层的聚集颗粒小于基体的聚集颗粒并且大于分离层的聚集颗粒。
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公开(公告)号：US20060213165A1
公开(公告)日：2006-09-28
申请号：US11375089
申请日：2006-03-14
IPC分类号： B01D46/00
CPC分类号： B01D63/061 , B01D63/066 , B01D65/003 , B01D65/02 , B01D71/02 , B01D71/024 , B01D71/025 , B01D2321/162 , B01D2321/168 , C02F1/44 , C03C8/24 , C04B38/0012 , C04B38/0051 , C04B2111/00793 , C04B35/00 , C04B41/5022
摘要： A ceramic filter has (A) a base body having partition walls made of a ceramic porous body, wherein cells 18 are defined by the partition walls, (B) filer membranes provided on the partition walls, made of a ceramic porous body having an average pore diameter smaller than that of the surface of each partition wall, and (C) a glass seal provided so as to cover at least the end face of the base body, wherein the glass seal is constituted by an alkali-free glass containing silica (SiO2) in an amount of 55 to 65 mol %, zirconia (ZrO2) in an amount of 1 to 10 mol % and at least one kind of alkaline earth metal oxide selected from calcia, baria and strontia but substantially not containing zinc oxide.
摘要翻译： 陶瓷过滤器具有（A）具有由陶瓷多孔体制成的隔壁的基体，其中单元18由隔壁限定，（B）设置在隔壁上的由具有平均值的陶瓷多孔体制成的隔膜 孔径小于每个分隔壁的表面，以及（C）玻璃密封件，其设置成至少覆盖基体的端面，其中玻璃密封件由含有二氧化硅的无碱玻璃（ SiO 2）为55〜65摩尔％，氧化锆（ZrO 2）为1〜10摩尔％，以及至少一种碱土金属氧化物，其选自钙，钡和锶，但基本上不含氧化锌。
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8.发明授权Ceramic porous membrane, ceramic filter using the same, and method of manufacturing the same 失效陶瓷多孔膜，使用其的陶瓷过滤器及其制造方法
公开(公告)号：US6077800A
公开(公告)日：2000-06-20
申请号：US996188
申请日：1997-12-22
申请人： Tomonori Takahashi , Manabu Isomura
发明人： Tomonori Takahashi , Manabu Isomura
CPC分类号： B01D67/0046 , B01D71/024 , B01D71/025 , C04B38/00 , C04B38/0045 , C04B41/009 , C04B41/4582 , C04B41/81 , B01D2323/08 , C04B2111/00801
摘要： A ceramic porous membrane in which aggregate particles are bound by binding portions composed of a titania, is provided. The binding portions composed of a titania are contained in an amount of 1-30% by weight based on the aggregate particles, and the aggregate particles comprise an .alpha.-alumina. The porous membrane is formed on a porous substrate to form a ceramic filter. A slurry comprising aggregate particles and 1-70% by weight of binding portions composed of a titania based on the aggregate particles are prepared, and thermally treating the slurry at a temperature of 300-700.degree. C. under ambient atmosphere to form the porous membrane.
摘要翻译： 提供了一种陶瓷多孔膜，其中聚集体颗粒通过由二氧化钛组成的结合部分结合。 由二氧化钛构成的结合部分的含量相对于聚集体颗粒为1-30重量％，聚集体颗粒包含α-氧化铝。 多孔膜形成在多孔基材上以形成陶瓷过滤器。 制备包含聚集体颗粒的浆料和基于聚集体颗粒的由二氧化钛组成的结合部分的1-70重量％的浆料，并在室温下在300-700℃下热处理浆料以形成多孔膜 。
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公开(公告)号：US5741474A
公开(公告)日：1998-04-21
申请号：US443551
申请日：1995-05-18
申请人： Manabu Isomura , Takao Soma , Tomonori Takahashi
发明人： Manabu Isomura , Takao Soma , Tomonori Takahashi
IPC分类号： B01D53/22 , B01J19/24 , C01B3/32 , C01B3/34 , C01B3/38 , C01B3/50 , H01M8/00 , H01M8/06 , C01B3/02 , C01B3/24 , C01B3/26
CPC分类号： H01M8/0631 , B01J19/2475 , C01B3/32 , C01B3/323 , C01B3/34 , C01B3/38 , C01B3/382 , C01B3/386 , C01B3/501 , H01M8/0612 , B01J2219/0011 , B01J2219/00117 , B01J2219/00159 , C01B2203/0244 , C01B2203/041 , C01B2203/0465 , C01B2203/047 , C01B2203/066 , C01B2203/0811 , C01B2203/0822 , C01B2203/0827 , C01B2203/0844 , C01B2203/0866 , C01B2203/1064 , C01B2203/1076 , C01B2203/1223 , C01B2203/1288 , C01B2203/142 , C01B2203/1604 , C01B2203/82 , Y02P20/126 , Y02P20/128
摘要： There is a system for producing high-purity hydrogen by reforming a hydrocarbon and/or an oxygen atom-containing hydrocarbon to form a reformed gas containing hydrogen and separating the hydrogen from said gas. The system includes a hydrocarbon source, a water source, an oxygen source, a vaporization chamber connecting with the hydrocarbon source, the water source and the oxygen source, and a reforming chamber provided with a catalyst for steam reforming and partial oxidation and a hydrogen-separating membrane. The reforming chamber is thermally connected with the vaporization chamber. A process for producing high-purity hydrogen includes heating a reforming chamber provided with a hydrogen-separating membrane, feeding, into the reforming chamber, hydrocarbon, steam and oxygen or air to give rise to steam reforming and partial oxidation therein to produce a reaction gas, and passing the reaction gas through the hydrogen-separating membrane to recover high-purity hydrogen. The heat possessed by the portion of the reaction gas not permeable into the hydrogen-separating membrane and the heat generated by the partial oxidation are utilized for the heating and reforming of the hydrocarbon, water and oxygen or air.
摘要翻译： 存在通过重整烃和/或含氧原子的烃来形成含氢的重整气体并从所述气体中分离出氢气的方法来生产高纯度氢气。 该系统包括烃源，水源，氧源，与烃源连接的蒸发室，水源和氧源，以及设置有用于蒸汽重整和部分氧化的催化剂的重整室， 分离膜。 重整室与蒸发室热连接。 一种生产高纯度氢的方法包括加热设置有氢分离膜的重整室，向重整室供给碳氢化合物，蒸气和氧气或空气，引起蒸汽重整和部分氧化，产生反应气体 ，并使反应气体通过氢分离膜以回收高纯度氢。 反应气体不能透过氢分离膜的部分所产生的热量以及由部分氧化产生的热量用于烃，水和氧气或空气的加热和重整。
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公开(公告)号：US5366941A
公开(公告)日：1994-11-22
申请号：US960333
申请日：1992-10-13
申请人： Tomonori Takahashi , Manabu Isomura
发明人： Tomonori Takahashi , Manabu Isomura
IPC分类号： C04B35/584 , C04B35/575 , C04B35/593 , C04B35/645 , C04B35/78 , C04B35/54 , C04B35/56
CPC分类号： C04B35/575 , C04B35/593
摘要： A composite ceramic material that is stable and shows a high strength in the temperature range of room temperature to 1600.degree. C. as well as has a toughness high-enough to be used as structural material and a process for producing it are provided. This composite ceramic material is composed of a matrix substantially made up of Si.sub.3 N.sub.4 and Si.sub.2 N.sub.2 O and a dispersion phase substantially made up of SiC where the matrix contains 0.05% by weight or less of metal element impurities such as Al, Ca and Fe. SiC grains or fibers are dispersed in the dense matrix made up of Si.sub.3 N.sub.4 and Si.sub.2 N.sub.2 O fine grains, which are substantially free from element impurities except Si, C and O. According to one aspect of this invention, this ceramic material is produced by Si.sub.3 N.sub.4 with SiO.sub.2 to form matrix powders that contain 0.05% by weight or less of metal element impurities such as Al, Ca and Fe, mixing and compacting the powders with a SiC dispersion phase to form a compact and firing or sintering the compact under pressure for densification.
摘要翻译： 一种复合陶瓷材料，其在室温至1600℃的温度范围内稳定且显示出高强度，并且具有足够高的韧度以用作结构材料的韧性及其制造方法。 该复合陶瓷材料由基本上由Si 3 N 4和Si 2 N 2 O构成的基体和基本上由SiC组成的分散相构成，其中基体含有0.05重量％以下的金属元素杂质如Al，Ca和Fe。 SiC颗粒或纤维分散在由Si 3 N 4和Si 2 N 2 O细颗粒组成的致密基质中，其基本上不含除Si，C和O之外的元素杂质。根据本发明的一个方面，该陶瓷材料由Si 3 N 4与SiO 2 形成含有0.05重量％以下的金属元素杂质如Al，Ca和Fe的基质粉末，用SiC分散相混合和压实粉末以形成压块并在压力下烧结或烧结压块以进行致密化。
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