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公开(公告)号:US06852773B2
公开(公告)日:2005-02-08
申请号:US10193683
申请日:2002-07-12
申请人: Takayoshi Tanabe , Jiro Ueda , Tetsuya Yamamura , Takashi Ukachi
发明人: Takayoshi Tanabe , Jiro Ueda , Tetsuya Yamamura , Takashi Ukachi
IPC分类号: C08F2/46 , C08F220/16 , C08F283/00 , C08F290/00 , C08F290/06 , C08G18/32 , C08G18/48 , C08G18/62 , C08G18/67 , C08G18/81 , C08K5/521 , C08L55/00 , G02B1/04 , G02B3/00 , C08F3/28 , C08C2/46
CPC分类号: C08K5/521 , C08F283/006 , C08F290/06 , C08F290/067 , C08G18/3215 , C08G18/4854 , C08G18/672 , C08G18/8175 , G02B1/04 , C08L51/08 , C08G18/48 , C08L33/06 , C08L75/04
摘要: The invention relates to a photocurable resin composition comprising: (A) a di or more functional urethane (meth)acrylate compound; (B) a monofunctional (meth)acrylate; (C) a photoinitiator; and (D) a polyoxyalkylene alkyl ether phosphate represented by the following formula (2): and to cured products obtained from the resins composition.
摘要翻译: 本发明涉及一种光固化树脂组合物,其包含:(A)二官能或多官能氨基甲酸酯(甲基)丙烯酸酯化合物; (B)单官能(甲基)丙烯酸酯; (C)光引发剂; 和(D)由下式(2)表示的聚氧化烯烷基醚磷酸酯和由树脂组合物获得的固化产物。
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公开(公告)号:US06685869B2
公开(公告)日:2004-02-03
申请号:US10157034
申请日:2002-05-30
IPC分类号: G03C908
CPC分类号: G03F7/0037 , B33Y10/00 , B33Y70/00 , G03F7/038
摘要: A photocurable resin composition suitable for use in three-dimensional photofabrication comprising (A) a cationically polymerizable organic compound, (B) a cationic photoinitiator, and (C) a (co)polymer obtainable by (co)polymerization of monomers comprising at least one (meth)acrylate-group comprising monomer. A process for producing a three-dimensional object which comprises the use of a washing agent having a Hansen-solubility between 27-35 (Mpa)½.
摘要翻译: 适用于三维光固化的光固化树脂组合物,其包含(A)阳离子可聚合有机化合物,(B)阳离子光引发剂和(C)可通过(共)聚合单体得到的(C)共聚物,所述单体包含至少一种 (甲基)丙烯酸酯基。3.一种制备三维物体的方法,其包括使用Hansen-溶解度在27-35(Mpa)1/2之间的洗涤剂。
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3.
公开(公告)号:US20050171255A1
公开(公告)日:2005-08-04
申请号:US10898560
申请日:2004-07-26
IPC分类号: C08L71/00 , C08F2/46 , C08G59/00 , C08G59/24 , C08G59/68 , C08G65/10 , C08G65/18 , G03F7/00 , G03F7/038 , C08L1/00
CPC分类号: C08F255/00 , C08F257/02 , C08F279/02 , C08F287/00 , C08G59/00 , C08G59/24 , C08G59/68 , C08G65/10 , C08G65/18 , C08L51/006 , C08L51/04 , C08L51/06 , C08L71/02 , G03F7/0037 , G03F7/027 , G03F7/038 , C08L2666/02
摘要: Photocurable resin composition for photofabrication of three-dimensional objects comprising (A) 5-80 parts by weight of an exetane compound, (B) 5-80 parts by weight of an epoxy compound, (C) 0.1 10 parts by weight of a photoacid generator, (D) 1-35 parts by weight of elastomer particles with an average particle diameter of 10-700 nm, (E) 0-35 parts by weight of a polyol compound, (F) 0-45 parts by weight of an ethylenically unsaturated monomer, end (G) 0-10 parts by weight of a radical photopolymerization initiator.
摘要翻译: 包含(A)5-80重量份的丙烯腈化合物,(B)5-80重量份的环氧化合物,(C)0.1重量份的光致酸性的三维物体的光固化性树脂组合物 发泡剂,(D)1-35重量份平均粒径为10-700nm的弹性体颗粒,(E)0-35重量份的多元醇化合物,(F)0-45重量份的 烯键式不饱和单体,末端(G)0-10重量份自由基光聚合引发剂。
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4.
公开(公告)号:US20070043138A1
公开(公告)日:2007-02-22
申请号:US11357420
申请日:2006-02-21
IPC分类号: C08G65/18
CPC分类号: C08F255/00 , C08F257/02 , C08F279/02 , C08F287/00 , C08G59/00 , C08G59/24 , C08G59/68 , C08G65/10 , C08G65/18 , C08L51/006 , C08L51/04 , C08L51/06 , C08L71/02 , G03F7/0037 , G03F7/027 , G03F7/038 , C08L2666/02
摘要: Photocurable resin composition for photofabrication of three-dimensional objects comprising (A) 5-80 parts by weight of an oxetane compound, (B) 5-80 parts by weight of an epoxy compound, (C) 0, 1 10 parts by weight of a photoacid generator, (D) 1-35 parts by weight of elastomer particles with an average particle diameter of 10-700 nm, (E) 0-35 parts by weight of a polyol compound, (F) 0-45 parts by weight of an ethylenically unsaturated monomer, and (G) 0-10 parts by weight of a radical photopolymerization initiator.
摘要翻译: 包含(A)5-80重量份的氧杂环丁烷化合物的(B)5-80重量份的环氧化合物,(C)0-110重量份的环氧化合物, (D)1-35重量份平均粒径为10-700nm的弹性体颗粒,(E)0-35重量份多元醇化合物,(F)0-45重量份 的烯键式不饱和单体,和(G)0-10重量份的基团光聚合引发剂。
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公开(公告)号:US06967224B2
公开(公告)日:2005-11-22
申请号:US10677253
申请日:2003-10-03
CPC分类号: G03F7/0037 , B33Y10/00 , B33Y70/00 , G03F7/038
摘要: A photocurable resin composition suitable for use in three-dimensional photofabrication comprising (A) a cationically polymerizable organic compound, (B) a cationic photoinitiator, and (C) a (co)polymer obtainable by (co)polymerization of monomers comprising at least one (meth)acrylate-group comprising monomer.A process for producing a three-dimensional object which comprises the use of a washing agent having a Hansen-solubility between 27-35 (Mpa)1/2.
摘要翻译: 适用于三维光固化的光固化树脂组合物,其包含(A)阳离子可聚合有机化合物,(B)阳离子光引发剂和(C)可通过(共)聚合单体得到的(C)共聚物,所述单体包含至少一种 (甲基)丙烯酸酯基。 一种制造三维物体的方法,其包括使用Hansen溶解度为27-35(Mpa)1/2的洗涤剂。
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公开(公告)号:US06710097B2
公开(公告)日:2004-03-23
申请号:US09998929
申请日:2001-12-03
申请人: Hideaki Takase , Jirou Ueda , Takayoshi Tanabe , Takashi Ukachi
发明人: Hideaki Takase , Jirou Ueda , Takayoshi Tanabe , Takashi Ukachi
IPC分类号: C08F246
CPC分类号: C08F283/006 , C08F283/00 , C08G18/672 , C08G18/48
摘要: A photocurable resin composition comprising: (A) a urethane (meth)acrylate produced by reacting at least a polyether polyol with a number average molecular weight of 500 or more having an alkyleneoxy structure in the molecule, an organic polyisocyanate compound, and a (meth)acrylate containing a hydroxyl group; (B) a monofunctional (meth)acrylate shown by the following formula (1), wherein R1 represents a hydrogen atom or a methyl group, R2 represents —(CH2CH2O)p—, —(CH(CH3)CH2O)q—, or —CH2CH(OH)CH2O—, Y1, Y2, and Y3 individually represent a hydrogen atom, bromine atom, alkyl group having 1-10 carbon atoms, phenyl group, or —C(CH3)2C6H5—, and p and q represent integers from 0 to 10; and (C) a photoinitiator; its use and optical parts prepared from the photocurable resin composition.
摘要翻译: 一种光固化性树脂组合物,其含有:(A)通过至少使分子中具有亚烷基氧基结构的数均分子量为500以上的聚醚多元醇,有机多异氰酸酯化合物和(甲基)丙烯酸酯, )丙烯酸酯;(B)由下式(1)表示的单官能(甲基)丙烯酸酯,其中R 1表示氢原子或甲基,R 2表示 - (CH 2 CH 2 O) , - (CH(CH 3)CH 2 O)q-或-CH 2 CH(OH)CH 2 O-,Y 1,Y 2和Y 3各自表示氢原子,溴原子, 10个碳原子,苯基或-C(CH 3)2 C 6 H 5 - ,p和q表示0至10的整数; 和(C)光引发剂;其用途和由光固化树脂组合物制备的光学部件。
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7.
公开(公告)号:US20060128836A1
公开(公告)日:2006-06-15
申请号:US10533252
申请日:2003-10-29
申请人: Miwa Honda , Hiroomi Shimomura , Tetsuya Yamamura , Naoki Sugiyama , Yuichi Eriyama , Takayoshi Tanabe
发明人: Miwa Honda , Hiroomi Shimomura , Tetsuya Yamamura , Naoki Sugiyama , Yuichi Eriyama , Takayoshi Tanabe
CPC分类号: G02B1/115 , Y10T428/256 , Y10T428/3154
摘要: A curing composition including: 100 parts by weight of (1) titanium oxide particles coated with oxide of one or more metal elements selected from the group consisting of silicon, aluminum, titanium, zirconium, tin, antimony and zinc, 1 to 150 parts by weight of (2) a curing compound, and 0.1 to 100 parts by weight of (3) acuring catalyst. An antireflective multilayer body (16) which successively includes, on a substrate layer (12), a high-refractive-index film (10) which is formed by curing this curing composition and has a refractive index of 1.60 or more and a low-refractive-index film (14) having a lower refractive index than that thereof exhibits excellent antireflection effect in the field in which an antireflection film is used.
摘要翻译: 一种固化组合物,其包含:(1)包含选自硅,铝,钛,锆,锡,锑和锌中的一种或多种金属元素的氧化物的氧化钛颗粒100重量份,1至150重量份 (2)固化化合物的重量和0.1至100重量份的(3)固化催化剂。 一种抗反射多层体(16),其在衬底层(12)上依次包括通过固化该固化组合物而形成的折射率为1.60以上的高折射率膜(10) 具有比其折射率低的折射率膜(14)在使用抗反射膜的领域中表现出优异的抗反射效果。
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公开(公告)号:US20070172646A1
公开(公告)日:2007-07-26
申请号:US10556602
申请日:2004-05-07
申请人: Takayoshi Tanabe , Yuichi Eriyama , Tetsuya Yamamura , Yasunobu Suzuki , Hiroomi Shimomura , Mitsunobu Doimoto
发明人: Takayoshi Tanabe , Yuichi Eriyama , Tetsuya Yamamura , Yasunobu Suzuki , Hiroomi Shimomura , Mitsunobu Doimoto
CPC分类号: B32B27/18 , B32B7/02 , B32B23/08 , B32B27/08 , B32B27/26 , B32B27/28 , B32B27/322 , B32B2250/24 , B32B2264/102 , B32B2307/408 , B32B2307/418 , B32B2457/20 , B32B2551/00 , B32B2559/00 , C08K3/22 , G02B1/105 , G02B1/111 , G02B1/14 , G02B1/16 , Y10T428/256 , Y10T428/3154 , C08L27/12
摘要: A liquid resin composition containing (A) fluorine-containing polymer, (B) curable compound, (C) metal oxide particles having a number average particle size of 100 nm or less and (D) a solvent. When the composition is cured, the metal oxide particles (C) are distributed unevenly, the refractive index changes in the thickness direction by 0.05 to 0.8, so that there can be produced a cured film having a bilayer structure substantially consisting of a low-refractivity layer and a high-refractivity layer.
摘要翻译: 含有(A)含氟聚合物,(B)固化性化合物,(C)数均粒径为100nm以下的金属氧化物粒子和(D)溶剂的液态树脂组合物。 当组合物固化时,金属氧化物颗粒(C)分布不均匀,折射率在厚度方向上改变0.05至0.8,从而可以制备具有基本上由低折射率组成的双层结构的固化膜 层和高折射率层。
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9.
公开(公告)号:US20070155882A1
公开(公告)日:2007-07-05
申请号:US10552510
申请日:2004-04-05
CPC分类号: C09D5/006 , C08F290/068 , C08K3/22 , C08K9/06 , C09D5/24 , C09D7/62 , C09D11/101
摘要: To provide a curable liquid composition excelling in storage stability and curability and capable of forming a coat (film) which excels in antistatic properties, hardness, scratch resistance, and transparency on the surface of various substrates, a cured film of the composition, and an antistatic laminate. A curable liquid composition comprising (A) particles including an oxide of at least one element selected from the group consisting of indium, antimony, zinc, and tin as a major component, (B) a compound having at least two polymerizable unsaturated groups in the molecule, (C) a solvent in which solubility of the component (B) is less than 10 wt %, and (D) a solvent in which solubility of the component (B) is 10 wt % or more, the components (A) and (B) being uniformly dispersed or dissolved in the composition.
摘要翻译: 为了提供优异的储存稳定性和固化性的可固化液体组合物,并且能够形成在各种基材的表面上的抗静电性,硬度,耐刮擦性和透明性优异的涂层(膜),该组合物的固化膜和 抗静电层压板 一种可固化液体组合物,其包含(A)包含选自由铟,锑,锌和锡组成的组中的至少一种元素的氧化物的主要成分的颗粒,(B)具有至少两个可聚合不饱和基团的化合物 分子,(C)成分(B)的溶解度小于10重量%的溶剂,(D)成分(B)的溶解度为10重量%以上的成分(A) 和(B)均匀地分散或溶解在组合物中。
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公开(公告)号:US20080096033A1
公开(公告)日:2008-04-24
申请号:US11576166
申请日:2005-10-14
IPC分类号: C08L33/02
CPC分类号: C09D175/16 , C08G18/289 , C08G18/673 , C08K9/04 , Y10T428/31855 , C08L75/16
摘要: To provide a curable a composition exhibiting excellent applicability and capable of forming a coating having high hardness, low curling properties, and excellent flexibility on the surface of a substrate, and a cured film including a cured product of the composition. A curable composition comprising: (A) 30 to 80 wt % of metal oxide particles to which an organic compound containing a polymerizable unsaturated group is bonded, and (B) 5 to 50 wt % of a urethane (meth)acrylate having an aromatic cyclic structure in the molecule and including three or more (meth)acryloyl groups, provided that the total amount of the composition excluding an organic solvent is 100 wt %; and a cured layer formed by curing the composition, and a laminate.
摘要翻译: 为了提供一种表现出优异适用性并且能够形成具有高硬度,低卷曲性和在基材表面上的优异柔软性的涂层的固化性组合物,以及包含该组合物的固化产物的固化膜。 一种可固化组合物,其包含:(A)30〜80重量%的含有可聚合不饱和基团的有机化合物的金属氧化物粒子,和(B)5〜50重量%的具有芳香族环状的氨基甲酸酯(甲基)丙烯酸酯 并且包括三个以上(甲基)丙烯酰基,但不包括有机溶剂的组合物的总量为100重量% 以及通过固化该组合物形成的固化层和层压体。
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