摘要:
An electroconductive roller including an electroconductive cellular material layer, comprised of a polyurethane composition, which has an average foamed cell diameter not more than 100 μm and a variation ΔD of the foamed cell diameter not more than 50 μm. The electroconductive roller has a hardness variation ΔHs not more than 8 degrees and a circumferential non-uniformity index RMAX/RMIN in an electric resistance thereof not more than 1.3. The electroconductive cellular material layer is made of a thermosetting one-part polyurethane composition. And the polyurethane composition is cured instantly at a temperature not less than a thermosetting critical temperature for curing thereof, after it is foamed by a mechanical foaming method.
摘要翻译:一种包含导电细胞材料层的导电辊,其由聚氨酯组合物组成,其具有不大于100μm的平均泡沫泡孔直径和不大于50μm的泡沫泡孔直径的变化DeltaD。 导电辊的电阻不大于1.3的硬度变化ΔHs不大于8度,周向非均匀性指数R MAX MAX / R MIN MIN SUB>。 导电多孔材料层由热固性单组分聚氨酯组合物制成。 在通过机械发泡法发泡后,聚氨酯组合物在不低于其固化的热固化临界温度的温度下立即固化。
摘要:
An electroconductive roller including an electroconductive cellular material layer, comprised of a polyurethane composition, which has an average foamed cell diameter not more than 100 μm and a variation ΔD of the foamed cell diameter not more than 50 μm. The electroconductive roller has a hardness variation ΔHs not more than 8 degrees and a circumferential non-uniformity index RMAX/RMIN in an electric resistance thereof not more than 1.3. The electroconductive cellular material layer is made of a thermosetting one-part polyurethane composition. And the polyurethane composition is cured instantly at a temperature not less than a thermosetting critical temperature for curing thereof, after it is foamed by a mechanical foaming method.
摘要翻译:一种包含导电细胞材料层的导电辊,其由聚氨酯组合物组成,其具有不大于100μm的平均泡沫泡孔直径和不大于50μm的泡沫泡孔直径的变化DeltaD。 导电辊的电阻不大于1.3的硬度变化ΔHs不大于8度,周向非均匀性指数R MAX MAX / R MIN MIN SUB>。 导电多孔材料层由热固性单组分聚氨酯组合物制成。 在通过机械发泡法发泡后,聚氨酯组合物在不低于其固化的热固化临界温度的温度下立即固化。
摘要:
The invention provides a reactive polymer-supporting porous film for use as a battery separator which comprises a porous substrate film and a partially crosslinked reactive polymer supported on the porous substrate film, the partially crosslinked reactive polymer being obtained by the reaction of a crosslinkable polymer having at least one reactive group selected from the group consisting of 3-oxetanyl group and epoxy group in the molecule with a monocarboxylic acid.The invention further provides a method of manufacturing a battery which comprises layering electrodes on the reactive polymer-supporting porous film to obtain an electrode/reactive polymer-supporting porous film layered body; placing the electrode/reactive polymer-supporting porous film layered body in a battery container; introducing an electrolytic solution containing a cationic polymerization catalyst into the battery container so that at least a portion of the reactive polymer is swollen or dissolved in the electrolytic solution at least in the vicinity of the interface of the porous film and the electrodes and cationically polymerized so that the electrodes are bonded to the porous film.
摘要:
Provided is a reactive polymer-supporting porous film for use as a battery separator which comprises a porous substrate film and a partially crosslinked reactive polymer supported on the porous substrate film, the partially crosslinked reactive polymer being obtained by the reaction of a crosslinkable polymer having at least one reactive group selected from the group consisting of 3-oxetanyl group and epoxy group in the molecule with a monocarboxylic acid. Further, provided is a method of manufacturing a battery which comprises layering electrodes on the reactive polymer-supporting porous film.
摘要:
A polymer for bonding the positive electrode and negative electrode of a lithium secondary battery, which includes a positive electrode, a negative electrode and an electrolyte solution, with a separator arranged between the positive electrode and the negative electrode. The polymer contains a cationically polymerizable monomer unit (A), a monomer unit (B) providing affinity to the electrolyte solution, a monomer unit (C) providing poor solubility to the electrolyte solution, and a monomer unit (D) containing an anionic or nonionic hydrophilic group. This polymer can be obtained through radical polymerization such as emulsion polymerization or suspension polymerization, and is characterized by having a dissolution rate into a mixed solvent of ethylene carbonate (EC) and diethyl carbonate (DEC) [EC:DEC=5:5 (weight ratio)] of not more than 10% by weight.
摘要:
A polymer for bonding the positive electrode and negative electrode of a lithium secondary battery, which includes a positive electrode, a negative electrode and an electrolyte solution, with a separator arranged between the positive electrode and the negative electrode. The polymer contains a cationically polymerizable monomer unit (A), a monomer unit (B) providing affinity to the electrolyte solution, a monomer unit (C) providing poor solubility to the electrolyte solution, and a monomer unit (D) containing an anionic or nonionic hydrophilic group. This polymer can be obtained through radical polymerization such as emulsion polymerization or suspension polymerization, and is characterized by having a dissolution rate into a mixed solvent of ethylene carbonate (EC) and diethyl carbonate (DEC)[EC:DEC=5:5 (weight ratio)] of not more than 10% by weight.