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公开(公告)号：US06927275B2
公开(公告)日：2005-08-09
申请号：US10659397
申请日：2003-09-11
IPC分类号： C08G63/18 , C08G63/672 , C08G63/66
CPC分类号： C08G63/672
摘要： The process of the present invention for producing a polyester resin comprising a dicarboxylic acid constitutional unit and a diol constitutional unit having a cyclic acetal skeleton comprises a step (1) of subjecting a diol (A) having a cyclic acetal skeleton and an ester (D) to transesterification reaction and a step (2) of mainly converting the resultant oligomer into a high polymer. The step (1) simultaneously satisfies the requirements (i) to (iv) as described in the specification. In the process of the present invention, the polyester resins having excellent moldability and mechanical properties are stably produced by a transesterification method which is less detrimental to environments.
摘要翻译： 本发明的制备包含二羧酸结构单元的聚酯树脂和具有环状缩醛骨架的二醇结构单元的本发明的方法包括：对具有环状缩醛骨架的二醇（A）和酯（D ）和酯交换反应的步骤（2）和主要将所得低聚物转化为高聚物的步骤（2）。 步骤（1）同时满足说明书中所述的要求（i）至（iv）。 在本发明的方法中，具有优异的成型性和机械性能的聚酯树脂通过对环境不利的酯交换法稳定地生产。
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公开(公告)号：US07183362B2
公开(公告)日：2007-02-27
申请号：US10998058
申请日：2004-11-29
CPC分类号： C08G63/82 , C08G63/672 , C08G63/85
摘要： In the invention, a polyester resin comprising dicarboxylic acid constitutional units and diol constitutional units wherein 5 to 60 mol % of the diol constitutional units has a cyclic acetal skeleton is produced by a process comprising an oligomerization step and a polymerization step. In the oligomerization step, an ester having a limited acid value is transesterified with a diol having a cyclic acetal skeleton in the presence of a basic compound to obtain an oligomer. The oligomer is then polymerized in the subsequent polymerization step to increase the molecular weight.
摘要翻译： 在本发明中，通过包括低聚步骤和聚合步骤的方法制备包含二羧酸结构单元的聚酯树脂和其中5至60mol％的二醇结构单元具有环状缩醛骨架的二醇结构单元。 在低聚步骤中，在碱性化合物的存在下，将具有有限酸值的酯与具有环状缩醛骨架的二醇酯交换，得到低聚物。 然后在随后的聚合步骤中聚合低聚物以增加分子量。
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公开(公告)号：US20050176914A1
公开(公告)日：2005-08-11
申请号：US10998058
申请日：2004-11-29
CPC分类号： C08G63/82 , C08G63/672 , C08G63/85
摘要： In the invention, a polyester resin comprising dicarboxylic acid constitutional units and diol constitutional units wherein 5 to 60 mol % of the diol constitutional units has a cyclic acetal skeleton is produced by a process comprising an oligomerization step and a polymerization step. In the oligomerization step, an ester having a limited acid value is transesterified with a diol having a cyclic acetal skeleton in the presence of a basic compound to obtain an oligomer. The oligomer is then polymerized in the subsequent polymerization step to increase the molecular weight.
摘要翻译： 在本发明中，通过包括低聚步骤和聚合步骤的方法制备包含二羧酸结构单元的聚酯树脂和其中5至60mol％的二醇结构单元具有环状缩醛骨架的二醇结构单元。 在低聚步骤中，在碱性化合物的存在下，将具有有限酸值的酯与具有环状缩醛骨架的二醇酯交换，得到低聚物。 然后在随后的聚合步骤中聚合低聚物以增加分子量。
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公开(公告)号：US07179869B2
公开(公告)日：2007-02-20
申请号：US11076964
申请日：2005-03-11
CPC分类号： C08G63/85 , C08G63/672
摘要： In the invention, a polyester resin having dicarboxylic acid constitutional units and diol constitutional units wherein 5 to 60 mol % of the diol constitutional units has a cyclic acetal skeleton is produced by a process including an oligomerization step and a polymerization step. In the oligomerization step, an ester having a limited acid value is transesterified with a diol having a cyclic acetal skeleton in the presence of a titanium compound to obtain an oligomer. The oligomer is then polymerized in the subsequent polymerization step to increase the molecular weight.
摘要翻译： 在本发明中，通过包括低聚步骤和聚合步骤的方法制备具有二羧酸结构单元的聚酯树脂和其中5至60mol％的二醇结构单元具有环状缩醛骨架的二醇结构单元。 在低聚步骤中，在钛化合物的存在下，将具有有限酸值的酯与具有环状缩醛骨架的二醇酯交换，得到低聚物。 然后在随后的聚合步骤中聚合低聚物以增加分子量。
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公开(公告)号：US20050209435A1
公开(公告)日：2005-09-22
申请号：US11076964
申请日：2005-03-11
IPC分类号： C08G63/02 , C08G63/181 , C08G63/183 , C08G63/199 , C08G63/66 , C08G63/672 , C08G63/78 , C08G63/85
CPC分类号： C08G63/85 , C08G63/672
摘要： In the invention, a polyester resin having dicarboxylic acid constitutional units and diol constitutional units wherein 5 to 60 mol % of the diol constitutional units has a cyclic acetal skeleton is produced by a process including an oligomerization step and a polymerization step. In the oligomerization step, an ester having a limited acid value is transesterified with a diol having a cyclic acetal skeleton in the presence of a titanium compound to obtain an oligomer. The oligomer is then polymerized in the subsequent polymerization step to increase the molecular weight.
摘要翻译： 在本发明中，通过包括低聚步骤和聚合步骤的方法制备具有二羧酸结构单元的聚酯树脂和其中5至60mol％的二醇结构单元具有环状缩醛骨架的二醇结构单元。 在低聚步骤中，在钛化合物的存在下，将具有有限酸值的酯与具有环状缩醛骨架的二醇酯交换，得到低聚物。 然后在随后的聚合步骤中聚合低聚物以增加分子量。
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公开(公告)号：US06653440B2
公开(公告)日：2003-11-25
申请号：US10288308
申请日：2002-11-06
IPC分类号： C08G6500
CPC分类号： C08G63/16 , C08G63/672 , C08G63/78
摘要： In the production method of the present invention, a copolyester of intended sublimable diol proportion is produced by the reaction of a dicarboxylic acid and/or an ester-forming derivative thereof with a sublimable diol and a non-sublimable diol with an increased conversion of the sublimable diol. Since the escape of the sublimable diol is effectively prevented, the process solves the problem of clogging pressure-reduced pipes, etc. of an apparatus for polyester resin production.
摘要翻译： 在本发明的制造方法中，通过二羧酸和/或其成酯衍生物与可升华的二醇和不可升华的二醇的转化率的增加来制备所需的可升华的二醇比例的共聚酯， 可升华的二醇。 由于有效地防止了可升华二醇的逸出，所以该方法解决了聚酯树脂生产装置的减压管等堵塞的问题。
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公开(公告)号：US08030434B2
公开(公告)日：2011-10-04
申请号：US11815361
申请日：2006-01-31
申请人： Tsuyoshi Ikeda , Koshi Koide , Nobuyuki Koike , Tadashi Kawabata , Takeshi Hirokane , Shojiro Kuwahara
发明人： Tsuyoshi Ikeda , Koshi Koide , Nobuyuki Koike , Tadashi Kawabata , Takeshi Hirokane , Shojiro Kuwahara
CPC分类号： C08J5/18 , C08G63/672 , C08J2367/02 , Y10T428/24479 , Y10T428/24595 , Y10T428/24612 , Y10T428/24802
摘要： The present invention relates to a polyester film produced by melt-extruding a polyester composed of a dicarboxylic acid unit and a diol unit, wherein 1 to 80 mol % of the diol unit is a unit containing a cyclic acetal skeleton, and the polyester film has an in-plane retardation of 20 nm or less at a wavelength of 550 nm. The polyester film is an optically isotropic polyester film which is easily produced by an extrusion-molding method and has an economical advantage. The polyester film is useful for production of optical members or optical products such as phase difference films, protective films for polarizing plates, light diffusion films, lens sheets, anti-reflection films and optical information recording media.
摘要翻译： 本发明涉及通过熔融挤出由二羧酸单元和二醇单元组成的聚酯制成的聚酯薄膜，其中1〜80摩尔％的二醇单元为含有环状缩醛骨架的单元，聚酯薄膜 波长550nm处的面内延迟为20nm以下。 聚酯膜是通过挤出成型法容易地制造的光学各向同性的聚酯膜，具有经济的优点。 聚酯膜可用于制造相位差膜，偏振片用保护膜，光扩散膜，透镜片，防反射膜，光信息记录介质等光学部件或光学产品。
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公开(公告)号：US07064169B2
公开(公告)日：2006-06-20
申请号：US10322485
申请日：2002-12-19
IPC分类号： C08L67/02 , C08G63/123
CPC分类号： C08J5/18 , C08J2367/02 , C08L67/02 , C08L67/025 , C08L2666/18
摘要： Polyester resin composition (C) comprises polyester resin (A), which comprises polyester resin (l) comprising a diol unit having a cyclic acetal structure (CA) and a dicarboxylic acid unit having no CA, polyester resin (m) comprising a dicarboxylic acid unit having CA and a diol unit having no CA and/or polyester resin (n) comprising a diol unit having CA and a dicarboxylic acid unit having CA, and polyester resin (B) having no CA. The sum of the fraction of the dicarboxylic acid unit having CA in the entire dicarboxylic acid unit and the fraction of the diol unit having CA in the entire diol unit in composition (C) is 0.05% by mole or greater. The polyester resin compositions are excellent in transparency, melt viscoelasticity, heat resistance and moldability, and exhibit a samll crystallization rate.
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公开(公告)号：US07192994B2
公开(公告)日：2007-03-20
申请号：US10960925
申请日：2004-10-12
申请人： Nobuyuki Koike , Shojiro Kuwahara
发明人： Nobuyuki Koike , Shojiro Kuwahara
IPC分类号： C08J3/12
CPC分类号： C09D133/14 , C08L2666/28
摘要： Disclosed is a method of producing a powdery coating material by using: a curable polyester resin (A) having a hydroxyl group and/or a carboxyl group at the terminals thereof, and further having a number average molecular weight of from 1,000 to 30,000, a glass transition temperature of from 30 to 100° C.; a curing agent (B) which is solid at normal temperature and is capable of being reacted with the hydroxyl group or the carboxyl group of the curable polyester resin (A); and a solvent (C) having a boiling point under normal pressure of from 50 to 130° C.; and comprising a step of kneading the curable polyester resin (A), the curing agent (B) and the solvent (C) under condition in which at 50 to 130° C., not less than 20% by weight of the curing agent (B) is dissolved in the solvent and, then, vapor-removing the solvent (C) under a reduced pressure.
摘要翻译： 本发明公开了一种粉末涂料的制造方法，其特征在于，使用下述方法：在其末端具有羟基和/或羧基的固化性聚酯树脂（A），数均分子量为1,000〜30,000， 玻璃化转变温度为30〜100℃。 在常温下为固体并且能够与可固化聚酯树脂（A）的羟基或羧基反应的固化剂（B）; 和在常压下沸点为50-130℃的溶剂（C）。 在固化剂（A），固化剂（B）和溶剂（C）的混合条件下，在50〜130℃，不低于固化剂的20重量％的条件下， B）溶解在溶剂中，然后在减压下蒸发去除溶剂（C）。
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公开(公告)号：US5980790A
公开(公告)日：1999-11-09
申请号：US27970
申请日：1998-02-23
IPC分类号： C08F2/06 , C08F212/08 , C08F220/14 , B29C47/76
CPC分类号： C08F220/14 , C08F212/08
摘要： A high quality copolymer of styrene and methyl methacrylate is economically produced by polymerizing styrene and methyl methacrylate in a homogeneous solution of raw materials comprising methyl methacrylate, styrene, and an antioxidant, while the solution of raw materials is continuously supplied to a polymerization reactor including at least one complete-mixing type reaction tank, continuously removing the polymerization product from the polymerization reactor, supplying the polymerization product removed from the polymerization reactor directly to an extruder having a plurality of vents, and extruding a copolymer from the extruder, while volatile matter are removed through the plurality of vents.
摘要翻译： 苯乙烯和甲基丙烯酸甲酯的高品质共聚物通过在包含甲基丙烯酸甲酯，苯乙烯和抗氧化剂的原料的均匀溶液中聚合苯乙烯和甲基丙烯酸甲酯而经济地制备，同时将原料溶液连续供给到包括 至少一个完全混合型反应槽，从聚合反应器中连续除去聚合产物，将从聚合反应器中除去的聚合产物直接供给到具有多个通风口的挤出机中，并从挤出机挤出共聚物，而挥发物为 通过多个通风口去除。
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