公开(公告)号：US06882517B2

公开(公告)日：2005-04-19

申请号：US10724229

申请日：2003-12-01

申请人： Tamotsu Tano ,  Takashi Oyama ,  Akinori Mogami ,  Makoto Takeuchi ,  Hiroshi Kobayashi ,  Yukinori Kude

发明人： Tamotsu Tano ,  Takashi Oyama ,  Akinori Mogami ,  Makoto Takeuchi ,  Hiroshi Kobayashi ,  Yukinori Kude

IPC分类号： C01B31/02 ,  C10B55/02 ,  H01G9/00 ,  H01G11/22 ,  H01G11/24 ,  H01G11/32 ,  H01G11/34 ,  H01G11/38 ,  H01G11/42 ,  H01G11/44 ,  H01G11/84 ,  H01G11/86 ,  H01M4/96

CPC分类号： H01G9/155 ,  H01M4/583 ,  H01M4/96 ,  Y02E60/13 ,  Y10T428/30

摘要： A raw material composite 10 for a carbon material used in an electric double layer capacitor contains microcrystalline carbon having a layered crystal structure similar to graphite, and is formed a carbon material for an electric double layer capacitor by undergoing an activation treatment. Here, the raw material composite is characterized in that a Hardgrove grindability index HGI defined by ASTMD-409-71 is 50 or above, an interlayer distance d002 of the microcrystalline carbon determined by an X-ray diffraction method is 0.343 NM or below, and a crystallite size Lc002 of the microcrystalline carbon determined by the X-ray diffraction method is 3.0 nm or below.

摘要翻译： 用于双电层电容器中的碳材料的原料复合材料10包含具有与石墨类似的层状晶体结构的微晶碳，并且通过进行活化处理形成双电层电容器的碳材料。 这里，原料复合体的特征在于，由ASTMD-409-71定义的Hardgrove研磨性指数HGI为50以上，通过X射线衍射测定的微晶碳的层间距离d 002 方法为0.343NM以下，通过X射线衍射法测定的微晶碳的微晶尺寸Lc 002℃为3.0nm以下。

公开(公告)号：US08741125B2

公开(公告)日：2014-06-03

申请号：US13140057

申请日：2009-12-25

申请人： Tamotsu Tano ,  Takashi Oyama ,  Ippei Fujinaga ,  Masayuki Tasaki ,  Akio Sakamoto

发明人： Tamotsu Tano ,  Takashi Oyama ,  Ippei Fujinaga ,  Masayuki Tasaki ,  Akio Sakamoto

IPC分类号： C10B57/04 ,  C10M101/00

CPC分类号： H01M4/587 ,  C01B32/05 ,  C10B57/045 ,  H01M10/0525

摘要： The invention provides a stock oil composition for a carbon material for a negative electrode for a lithium ion secondary battery, having a 10 vol % distillation temperature of 280° C. or higher as the distillation property, a density of at least 0.90 g/cm3 at a temperature of 15° C. and a normal paraffin content of at least 3 parts by weight with respect to 100 parts by weight as the total weight of the stock oil composition; and having an aromatic component content of 30-85 parts by weight with respect to 100 parts by weight as the total weight of the stock oil composition and an aromatic component molecular weight of 250-1600 when the aromatic components and non-aromatic components are separated by elution chromatography.

摘要翻译： 本发明提供一种用于锂离子二次电池用负极用碳材料的原料油组合物，其蒸馏性能为10体积％，蒸馏温度为280℃以上，密度为0.90g / cm 3以上 相对于原料油组合物的总重量为100重量份，在15℃的温度下，正链烷烃含量为至少3重量份; 相对于原料油组合物的总重量为100重量份，芳香族成分含量为30〜85重量份，芳香族成分和非芳香族成分分离时的芳香族成分分子量为250〜1600 通过洗脱色谱法。

公开(公告)号：US07754178B2

公开(公告)日：2010-07-13

申请号：US11573875

申请日：2005-08-12

申请人： Tamotsu Tano ,  Takashi Oyama ,  Hideki Ono ,  Keizo Ikai ,  Kiwamu Takeshita

发明人： Tamotsu Tano ,  Takashi Oyama ,  Hideki Ono ,  Keizo Ikai ,  Kiwamu Takeshita

IPC分类号： D01F9/12 ,  C01B31/00 ,  C01B31/02 ,  H01G4/008

CPC分类号： H01G11/44 ,  C01B32/05 ,  C01B32/348 ,  H01G11/32 ,  H01G11/34 ,  Y02E60/13 ,  Y02T10/7022

摘要： The capacitance per volume of an electric double-layer capacitor can be increased by using a raw-material carbon composition for use in a carbon material for an electrode of the electric double-layer capacitor by applying an activation process, characterized in that the raw-material carbon composition has a volatile content of 1.3% by mass to 15% by mass (both inclusive), and microstrength of 5 to 30% when the volatile content is less than 6% by mass while microstrength of 5 to 20% when the volatile content is 6% or more.

摘要翻译： 通过施加激活过程，可以通过使用用于双电层电容器的电极的碳材料的原料碳组合物来增加电双层电容器的体积电容，其特征在于， 当挥发物含量小于6质量％时，挥发物含量为1.3质量％〜15质量％（微小），当微量强度为5〜20％时，挥发性 内容为6％以上。

公开(公告)号：US20080144255A1

公开(公告)日：2008-06-19

申请号：US11722397

申请日：2005-12-21

申请人： Tamotsu Tano ,  Shiro Nakamo ,  Takashi Oyama ,  Hideki Ono ,  Keizou Ikai ,  Kiwamu Takeshita

发明人： Tamotsu Tano ,  Shiro Nakamo ,  Takashi Oyama ,  Hideki Ono ,  Keizou Ikai ,  Kiwamu Takeshita

IPC分类号： H01G4/008 ,  C01B31/00

CPC分类号： H01G9/155 ,  C01B32/348 ,  H01G9/058 ,  H01G11/34 ,  Y02E60/13

摘要： The present invention provides a raw material carbon composition that is converted to a carbon material for an electrode in an electric double layer capacitor that can develop a high level of electrostatic capacity with good reproducibility without producing any synthetic pitch. The raw material carbon composition is converted to a carbon material for an electrode in an electric double layer capacitor upon activation treatment and is characterized in that, when the raw material carbon composition is carbonized in an inert gas atmosphere at a temperature of 1000 to 1500° C., the true relative density (RD) and the total hydrogen content (TH %) in the carbonized material obtained after the burning satisfy the following formula (1): RD=−0.75TH %+intercept   (1) wherein the intercept is 2.160 or greater.

摘要翻译： 本发明提供一种原料碳组合物，其可以转化为双电层电容器中的电极用碳材料，其可以以高再现性产生高水平的静电容量，而不产生任何合成间距。 原料碳组合物在活化处理后转变为双电层电容器中的电极用碳材料，其特征在于，当原料碳组成在惰性气体气氛中在1000〜1500℃的温度下碳化时 在燃烧后获得的碳化材料中的真实相对密度（RD）和总氢含量（TH％）满足下式（1）：<？在线公式描述=“在线公式” end =“lead”？> RD = -0.75TH％+ intercept（1）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中截距为2.160或更大。

公开(公告)号：US20110186478A1

公开(公告)日：2011-08-04

申请号：US13062106

申请日：2009-09-04

申请人： Tamotsu Tano ,  Takashi Oyama ,  Toshiyuki Oda ,  Ippei Fujinaga ,  Hiromitsu Hashisaka

发明人： Tamotsu Tano ,  Takashi Oyama ,  Toshiyuki Oda ,  Ippei Fujinaga ,  Hiromitsu Hashisaka

IPC分类号： C10G99/00

CPC分类号： C10B57/005 ,  C04B35/522 ,  C10B55/00 ,  C10B57/045 ,  C10L9/08

摘要： The invention provides a stock oil composition for needle coke for a graphite electrode, the stock oil composition having a 10 vol % distillation temperature of 280° C. or higher as the distillation property, and when separated into the aromatic component and non-aromatic component by elution chromatography, having an aromatic component content of 30-80 wt % with respect to the total weight of the stock oil composition and an aromatic component molecular weight of 255-1300, as well as a non-aromatic component normal paraffin content of at least 5 parts by weight with respect to 100 parts by weight of the aromatic component.

摘要翻译： 本发明提供一种用于石墨电极的针状焦炭用原料油组合物，所述原料油组合物的蒸馏温度为10℃以上，蒸馏温度为280℃以上，分离成芳香族成分和非芳香族成分 通过洗脱色谱法，相对于原料油组合物的总重量和芳族组分分子量为255-1300的芳族组分含量为30-80重量％，以及非芳族组分正链烷烃含量为 相对于100重量份的芳族成分为至少5重量份。

公开(公告)号：US07964173B2

公开(公告)日：2011-06-21

申请号：US12094222

申请日：2006-12-27

申请人： Takashi Oyama ,  Kazuhisa Nakanishi ,  Tamotsu Tano ,  Keiji Higashi ,  Ippei Fujinaga ,  Hiromitsu Hashisaka ,  Kiwamu Takeshita ,  Masaki Fujii ,  Hideki Ono

发明人： Takashi Oyama ,  Kazuhisa Nakanishi ,  Tamotsu Tano ,  Keiji Higashi ,  Ippei Fujinaga ,  Hiromitsu Hashisaka ,  Kiwamu Takeshita ,  Masaki Fujii ,  Hideki Ono

IPC分类号： C01B31/00 ,  C01B31/04 ,  C01B31/02 ,  C01D3/00 ,  C09C1/56 ,  H01G9/00 ,  C10L1/00 ,  C10C3/00 ,  C10G11/00 ,  C10G9/14 ,  H01B1/04 ,  H01B1/24 ,  C10B53/00 ,  C10B51/00

CPC分类号： H01G11/44 ,  C01B32/05 ,  C01B32/342 ,  C10B57/045 ,  H01G11/34 ,  Y02E60/13

摘要： The present invention provides feedstock compositions for use of the production of an activated carbon for electric double layer capacitor electrodes or the production of needle coke, comprising a first heavy oil with an initial boiling point of 300° C. or higher, an asphalten content of 12 percent by mass or less, a saturate content of 50 percent by mass or more and a sulfur content of 0.3 percent by mass or less, produced as a residue resulting from vacuum-distillation of a petroleum-based oil and a second heavy oil with an initial boiling point of 150° C. or higher and a sulfur content of 0.5 percent by mass or less, produced by subjecting a hydrocarbon oil to fluidized catalytic cracking.

摘要翻译： 本发明提供了用于生产双电层电容器电极的活性炭或生产针状焦的原料组合物，其包括初沸点为300℃或更高的第一重油，沥青含量为 12质量％以下，饱和物含量为50质量％以上，硫含量为0.3质量％以下，作为由石油系油和第二重油的真空蒸馏得到的残留物 初始沸点为150℃以上，硫含量为0.5质量％以下，通过使烃油进行流化催化裂化而得到。

公开(公告)号：US07959888B2

公开(公告)日：2011-06-14

申请号：US12158165

申请日：2006-12-27

申请人： Takashi Oyama ,  Kazuhisa Nakanishi ,  Tamotsu Tano ,  Keiji Higashi ,  Ippei Fujinaga ,  Hiromitsu Hashisaka ,  Toshitaka Fujii ,  Takashi Noro ,  Akio Sakamoto ,  Kiwamu Takeshita ,  Keizou Ikai ,  Masaki Fujii ,  Hideki Ono

发明人： Takashi Oyama ,  Kazuhisa Nakanishi ,  Tamotsu Tano ,  Keiji Higashi ,  Ippei Fujinaga ,  Hiromitsu Hashisaka ,  Toshitaka Fujii ,  Takashi Noro ,  Akio Sakamoto ,  Kiwamu Takeshita ,  Keizou Ikai ,  Masaki Fujii ,  Hideki Ono

IPC分类号： C01B31/00 ,  C01B31/04 ,  C01B31/02 ,  C01D3/00 ,  C09C1/56 ,  H01G9/00 ,  C10L1/00 ,  C10C3/00 ,  C10G11/00 ,  C10G9/14 ,  H01B1/04 ,  H01B1/24

CPC分类号： H01G11/44 ,  C01B32/05 ,  C01B32/30 ,  C10B57/045 ,  H01G11/34 ,  Y02E60/13

摘要： The present invention provides a raw coke having such a structure that the graphitized product resulting from graphitization of the raw coke at a temperature of 2800° C. under an inactive gas atmosphere will have ratios of the crystallite size to the lattice constant of 360 or less in the (002) plane and 1500 or less in the (110) plane, as a raw coke providing active carbon produced by alkali-activating the raw coke, which is reduced in remaining alkali content and can simplify washing operation because washing liquid can easily pass through the activated carbon, or as a raw coke for the production of needle coke.

摘要翻译： 本发明提供一种具有这样一种结构的原焦炭，即在惰性气体气氛下，在2800℃的温度下由原焦炭石墨化产生的石墨化产物将使微晶尺寸与晶格常数之比为360以下 在（002）面中，在（110）面中为1500以下的原料焦炭，作为提供通过碱活化生焦炭生成的活性炭的原焦炭，其还原了剩余的碱含量，并且可以简化洗涤操作，因为洗涤液容易 通过活性炭，或作为用于生产针状焦的原焦炭。

公开(公告)号：US20100298116A1

公开(公告)日：2010-11-25

申请号：US12669055

申请日：2007-07-27

申请人： Tamotsu Tano ,  Masayuki Tasaki ,  Takashi Oyama ,  Kazuo Mukai ,  Norio Yano ,  Susumu Nakano ,  Akio Sakamoto ,  Masaki Fujii

发明人： Tamotsu Tano ,  Masayuki Tasaki ,  Takashi Oyama ,  Kazuo Mukai ,  Norio Yano ,  Susumu Nakano ,  Akio Sakamoto ,  Masaki Fujii

IPC分类号： B01J38/48

CPC分类号： B01J20/3416 ,  B01J20/20 ,  B01J20/28059 ,  B01J20/3078 ,  B01J20/3475 ,  C02F1/283 ,  C02F1/40 ,  C02F2209/02 ,  C02F2303/16

摘要： The present invention provides a method of regenerating an oil adsorbent, wherein an oil adsorbent even if containing a large amount of oil can be regenerated without taking it out from the facility. The method of regenerating an oil adsorbent comprises washing a carbonaceous oil adsorbent made from calcined coke, with oil adsorbed thereon, with warm water of 40° C. or higher or gas-bubbled warm water of 40° C. or higher.

摘要翻译： 本发明提供一种再生油吸附剂的方法，其中即使含有大量油的油吸附剂也可以再生而不从设备中取出。 再生油吸附剂的方法包括用温度为40℃或更高的温水或40℃或更高的气体鼓泡的温水洗涤由煅烧焦炭制成的含油吸附剂，吸附有油的油。

公开(公告)号：US08784644B2

公开(公告)日：2014-07-22

申请号：US13727815

申请日：2012-12-27

申请人： Tamotsu Tano ,  Takashi Oyama ,  Hiroshi Ozawa ,  Jun Ougiya ,  Akio Sakamoto

发明人： Tamotsu Tano ,  Takashi Oyama ,  Hiroshi Ozawa ,  Jun Ougiya ,  Akio Sakamoto

IPC分类号： C10G11/00 ,  H01M4/133

CPC分类号： H01M4/133 ,  B02C23/00 ,  C01B32/20 ,  H01M4/587 ,  H01M10/052

摘要： Provided is a stock oil composition for a carbonaceous material for a negative electrode of a lithium-ion secondary battery which composition is useful for achieving excellent high-speed charge and discharge characteristics. The stock oil composition for a carbonaceous material for a negative electrode of a lithium-ion secondary battery uses a bottom oil of residue fluid catalytic cracking apparatus as a raw material. The stock oil composition comprises, of a saturated component, an aromatic component, a resin component and an asphaltene component detectable by development of the stock oil composition using thin-layer chromatography, the saturated component ranging from 30 to 50% by weight and the aromatic component ranging from 50 to 70% by weight; and has an average molecular weight of from 400 to 600.

摘要翻译： 提供一种用于锂离子二次电池负极碳质材料的原料油组合物，其组合物可用于获得优异的高速充放电特性。 作为锂离子二次电池的负极用碳质材料的原料油组合物，以渣油流化催化裂化装置的底油为原料。 所述原料油组合物包含通过使用薄层色谱法开发所述原料油组合物可检测的芳族组分，树脂组分和沥青质组分的饱和组分，饱和组分为30至50重量％，芳族化合物 组分范围为50至70重量％; 平均分子量为400〜600。

公开(公告)号：US08226921B2

公开(公告)日：2012-07-24

申请号：US13158008

申请日：2011-06-10

申请人： Takashi Oyama ,  Kazuhisa Nakanishi ,  Tamotsu Tano ,  Keiji Higashi ,  Ippei Fujinaga ,  Hiromitsu Hashisaka ,  Toshitaka Fujii ,  Takashi Noro ,  Akio Sakamoto ,  Kiwamu Takeshita ,  Keizou Ikai ,  Masaki Fujii ,  Hideki Ono

发明人： Takashi Oyama ,  Kazuhisa Nakanishi ,  Tamotsu Tano ,  Keiji Higashi ,  Ippei Fujinaga ,  Hiromitsu Hashisaka ,  Toshitaka Fujii ,  Takashi Noro ,  Akio Sakamoto ,  Kiwamu Takeshita ,  Keizou Ikai ,  Masaki Fujii ,  Hideki Ono

IPC分类号： C01B31/00 ,  C01B31/04 ,  C01B57/04 ,  C01B53/00 ,  H01G4/00 ,  H01G9/00 ,  C01G1/00 ,  C01G17/00 ,  C01C3/00

CPC分类号： H01G11/44 ,  C01B32/05 ,  C01B32/30 ,  C10B57/045 ,  H01G11/34 ,  Y02E60/13

摘要： The present invention provides a raw coke having such a structure that the graphitized product resulting from graphitization of the raw coke at a temperature of 2800° C. under an inactive gas atmosphere will have ratios of the crystallite size to the lattice constant of 360 or less in the (002) plane and 1500 or less in the (110) plane, as a raw coke providing active carbon produced by alkali-activating the raw coke, which is reduced in remaining alkali content and can simplify washing operation because washing liquid can easily pass through the activated carbon, or as a raw coke for the production of needle coke.