公开(公告)号：US5376772A

公开(公告)日：1994-12-27

申请号：US750245

申请日：1991-08-27

申请人： Tanehiro Nakagawa ,  Yoshiaki Ono ,  Tsutomu Tomatsu ,  Takeo Yamaguchi

发明人： Tanehiro Nakagawa ,  Yoshiaki Ono ,  Tsutomu Tomatsu ,  Takeo Yamaguchi

IPC分类号： A63H33/22 ,  H05B3/14 ,  H01C7/02 ,  H05B1/02 ,  H05B3/00

CPC分类号： H05B3/141 ,  A63H33/22 ,  A63F2250/1031

摘要： An electrothermal color-varying instrument for inducing color change in a color-varying layer includes a heat generating element composed of a sintered barium titanate thermistor in face-to face contact with a heat transmitting member having a heating end portion for transmitting heat to the thermal color-varying layer. The thermistor has:(i) a positive temperature coefficient on the electrical resistance within a temperature range from 25.degree. C. to 70.degree. C.;(ii) a volume resistivity at 25.degree. C. (.rho..sub.25) within a range of 9.8.times.10.sup.-3 to 2.97.times.10.sup.5 .OMEGA..multidot.cm; and(iii) a ratio (.rho..sub.70 /.rho..sub.25) of the volume resistivity at 70.degree. C. to that at 25.degree. C. within a range of 5.ltoreq.(.rho..sub.70 /.rho..sub.25).ltoreq.400.The electrothermal heat generating element generates heat under the application of a voltage in the range of 0.8 to 40 volts and maintains a saturated heating temperature within a range of 30 to 100 degrees C.

摘要翻译： 一种用于在变色层中引起颜色变化的电热变色仪器包括由与烧结的钛酸钡热敏电阻组成的发热元件，所述发热元件与具有用于将热传递到热的加热端部的传热部件接触地接触 变色层。 热敏电阻具有：（i）在25℃至70℃的温度范围内的电阻的正温度系数。 （ii）在25℃（rho 25）下的体积电阻率在9.8×10-3至2.97×10 5欧米伽×厘米的范围内; 和（iii）在5℃（rho 70 / rho 25）的范围内70℃下体积电阻率与25℃下的体积电阻率的比（rho 70 / rho 25）= 400。 电热发生元件在施加0.8〜40伏范围内的电压下产生热量，并将饱和加热温度维持在30〜100℃的范围内。

公开(公告)号：US5316513A

公开(公告)日：1994-05-31

申请号：US107907

申请日：1993-08-18

申请人： Tanehiro Nakagawa ,  Yoshiaki Ono ,  Tsutomu Tomatsu ,  Takeo Yamaguchi ,  Kyoji Aoyama ,  Toshiaki Tanaka

发明人： Tanehiro Nakagawa ,  Yoshiaki Ono ,  Tsutomu Tomatsu ,  Takeo Yamaguchi ,  Kyoji Aoyama ,  Toshiaki Tanaka

IPC分类号： A63H3/36 ,  A63H33/22 ,  G02F1/01 ,  A63H33/00 ,  A63H29/22

CPC分类号： G02F1/0147 ,  A63H3/36 ,  A63H33/22 ,  A63F2250/1031 ,  Y10S428/913

摘要： There is disclosed an electrothermal color-varying device inducing color change in a thermally color-varying layer by heat generation in an electrothermal heat-generating member, in which the heat-generating member is composed of a non-metallic member having a positive temperature coefficient on the electric resistance at least in a temperature range 25.degree. C. to 65.degree. C. and a particular volume resistivity, is adapted to generate heat by the application of a low voltage and is capable of self-control of the saturated heating temperature at an arbitrary temperature within a range of 25.degree. C. to 65.degree. C., whereby improved safety is achieved without the danger of overheating or current leakage. Also there are disclosed toys utilizing such color-varying device.

摘要翻译： 公开了一种电热变色装置，其通过在电热发生部件中发热而在热变色层中引起颜色变化，其中发热部件由具有正温度系数的非金属部件 至少在25℃至65℃的温度范围内的电阻和特定体积电阻率适于通过施加低电压产生热量，并且能够自我控制饱和加热温度 任意温度在25℃至65℃的范围内，从而实现了改进的安全性，而没有过热或电流泄漏的危险。 还公开了利用这种变色装置的玩具。

公开(公告)号：US20150152591A1

公开(公告)日：2015-06-04

申请号：US14556693

申请日：2014-12-01

申请人： Tsuyoshi Asami ,  Tsuneo Kurotori ,  Takeo Yamaguchi ,  Noriaki Okada

发明人： Tsuyoshi Asami ,  Tsuneo Kurotori ,  Takeo Yamaguchi ,  Noriaki Okada

IPC分类号： D06P1/04 ,  D06P5/30

CPC分类号： D06P1/04 ,  D06P5/006 ,  D06P5/30 ,  G03G7/0093 ,  G03G9/091

摘要： A textile printing method that includes printing to a textile with a material including a dye expressed by the following general formula 1. In general formula 1, R1 to R16 is H, CH3, OH, NHC2H5, COOH, SO3H, SO3Na, NO2, or NH2.

摘要翻译： 一种纺织印花方法，其包括用包含由以下通式1表示的染料的材料印刷到织物上。通式1中，R 1至R 16为H，CH 3，OH，NHC 2 H 5，COOH，SO 3 H，SO 3 Na，NO 2或 NH2。

公开(公告)号：US08632701B2

公开(公告)日：2014-01-21

申请号：US12064224

申请日：2005-10-03

申请人： Takeo Yamaguchi ,  Ju Myeung Lee ,  Gopinathan Madhavikutty Anilkumar

发明人： Takeo Yamaguchi ,  Ju Myeung Lee ,  Gopinathan Madhavikutty Anilkumar

IPC分类号： H01L31/0264 ,  H01M4/86 ,  H01M4/96 ,  H01M8/02

CPC分类号： H01B1/122 ,  H01M4/86 ,  H01M8/0289 ,  H01M8/1023 ,  H01M8/1048 ,  H01M8/1051 ,  H01M2300/0091

摘要： This invention provides an organic-inorganic hybrid material, which can exhibit high proton conductivity in a wide temperature range of a low temperature to a high temperature, a proton conductive material, which has a small particle diameter, that is, has a particle diameter capable of reaching pores of primary particles of carbon powder or the like, and has controlled particle diameters, a catalyst layer containing these materials for a fuel cell and an electrolyte film containing these materials for a fuel cell, and a fuel cell. The proton conductive hybrid material comprises proton conductive inorganic nanoparticles and a proton conductive polymer, wherein the Stokes particle diameter of the proton conductive hybrid material by dynamic light scattering is not more than 20 nm.

摘要翻译： 本发明提供一种有机 - 无机杂化材料，其在低温到高温的宽温度范围内可以表现出高质子传导性，具有小粒径的质子传导材料，即具有能够 达到碳粉末等的一次粒子的孔隙，并且具有受控的粒径，包含这些用于燃料电池的材料的催化剂层和含有这些燃料电池用材料的电解质膜和燃料电池。 质子传导性杂化材料包括质子传导性无机纳米粒子和质子传导性聚合物，其中通过动态光散射的质子传导混合材料的斯托克斯粒径不大于20nm。

公开(公告)号：US5644010A

公开(公告)日：1997-07-01

申请号：US503723

申请日：1995-07-18

申请人： Toru Kurihashi ,  Miki Kawashima ,  Takeo Yamaguchi

发明人： Toru Kurihashi ,  Miki Kawashima ,  Takeo Yamaguchi

IPC分类号： C08F220/18 ,  C08F220/28 ,  C08F224/00 ,  C07C11/12 ,  C07C69/54 ,  C07C233/16 ,  C08F220/04 ,  C08F220/10 ,  C08F220/58 ,  C08F230/00

CPC分类号： C08F220/18 ,  C08F220/28 ,  Y10S106/901

摘要： A curable liquid resin which can give a coating composition capable of forming a film, the curable liquid resin being a copolymer obtained from(A) a monomer of the formula (1) or (2),CH.sub.2 .dbd.C(R.sup.1)COO--R.sup.2 (1)CH.sub.2 .dbd.C(R.sup.3)COO(C.sub.n H.sub.2n O).sub.m--R.sup.4(2)and(B) at least one monomer selected from the group consisting of(B1) a monomer prepared by reacting an ethylenically unsaturated epoxide (a) with a fatty acid (b) of the formula (3)R.sup.5 COOH (3)(B2) a monomer of the formula (4),CH.sub.2 .dbd.C(R.sup.6)CONR.sup.7 R.sup.8 (4)and(B3) a monomer whose molecule has at least two ethylenically unsaturated double bonds.

摘要翻译： 一种可以得到能够形成膜的涂料组合物的可固化液体树脂，该可固化液体树脂是由（A）式（1）或（2）的单体获得的共聚物，CH 2 = C（R 1）COO-R 2 （1）CH 2 = C（R 3）COO（C n H 2n O）m -R 4（2）和（B）至少一种选自（B1）通过烯属不饱和环氧化物（a）与 式（3）的脂肪酸（b）R5COOH（3）（B2）式（4）的单体，CH2 = C（R6）CONR7R8（4）和（B3）分子具有至少两个烯属 不饱和双键。

公开(公告)号：US10767071B2

公开(公告)日：2020-09-08

申请号：US15041761

申请日：2016-02-11

申请人： Keiko Osaka ,  Takeo Yamaguchi

发明人： Keiko Osaka ,  Takeo Yamaguchi

IPC分类号： C09D139/06 ,  C09D129/04 ,  B22F3/10 ,  C09D171/02 ,  C08K5/17 ,  B33Y70/00 ,  C08L71/02 ,  C09J171/02 ,  C09J139/06 ,  B22F1/00 ,  B22F3/00 ,  C08L39/06 ,  C04B35/64 ,  C08K3/08 ,  B29C64/165 ,  C08L29/04 ,  B29C64/00 ,  C04B35/486 ,  C08K5/053 ,  C08K5/51 ,  C08K5/5317 ,  B33Y10/00 ,  B33Y30/00

摘要： Provided is a liquid material for forming a three-dimensional object used for forming a three-dimensional object made of a powder material for forming a three-dimensional object containing an organic material and a base material, wherein the liquid material contains a cross-linking agent cross-linkable with the organic material and a water-soluble resin having a weight average molecular weight of greater than or equal to 50,000.

公开(公告)号：US20160040025A1

公开(公告)日：2016-02-11

申请号：US14816370

申请日：2015-08-03

申请人： Yoshihiro NORIKANE ,  Yasutada Shitara ,  Teruki Kusahara ,  Takuya Saito ,  Takeo Yamaguchi

发明人： Yoshihiro NORIKANE ,  Yasutada Shitara ,  Teruki Kusahara ,  Takuya Saito ,  Takeo Yamaguchi

IPC分类号： C09D129/04 ,  C09D133/02 ,  C09D171/02 ,  C09D101/28 ,  C09D189/00 ,  B29C67/00 ,  C09D103/02

CPC分类号： B33Y80/00 ,  B29C64/165 ,  B29L2009/00 ,  B33Y10/00 ,  B33Y70/00 ,  C08K3/10 ,  C08K3/20 ,  C08K3/34 ,  C08K3/36 ,  C08K3/38 ,  C08K2003/2206 ,  C08K2003/2227 ,  C08K2003/2237 ,  C08K2003/387 ,  C09D101/286 ,  C09D103/02 ,  C09D171/02 ,  C09D189/00

摘要： Provided is a three-dimensional object formation powder material used for three-dimensional object formation of forming a three-dimensional object by stacking up a plurality of powder material layers each bound by a resin and having a predetermined shape. The three-dimensional object formation powder material contains particles in which a plurality of cores are fixed by a water-soluble resin.

摘要翻译： 本发明提供一种三维物体形成用粉末材料，其通过层叠多个由树脂结合并具有规定形状的粉末材料层而用于形成三维物体的三维物体形成。 三维物体形成粉末材料含有多个芯通过水溶性树脂固定的颗粒。

公开(公告)号：US20090220840A1

公开(公告)日：2009-09-03

申请号：US12064224

申请日：2005-10-03

申请人： Takeo Yamaguchi ,  Ju Myeung Lee ,  Gopinathan Madhavikutty Anilkumar

发明人： Takeo Yamaguchi ,  Ju Myeung Lee ,  Gopinathan Madhavikutty Anilkumar

IPC分类号： H01M8/10 ,  H01M8/08

CPC分类号： H01B1/122 ,  H01M4/86 ,  H01M8/0289 ,  H01M8/1023 ,  H01M8/1048 ,  H01M8/1051 ,  H01M2300/0091

摘要： This invention provides an organic-inorganic hybrid material, which can exhibit high proton conductivity in a wide temperature range of a low temperature to a high temperature, a proton conductive material, which has a small particle diameter, that is, has a particle diameter capable of reaching pores of primary particles of carbon powder or the like, and has controlled particle diameters, a catalyst layer containing these materials for a fuel cell and an electrolyte film containing these materials for a fuel cell, and a fuel cell. The proton conductive hybrid material comprises proton conductive inorganic nanoparticles and a proton conductive polymer, wherein the Stokes particle diameter of the proton conductive hybrid material by dynamic light scattering is not more than 20 nm.

摘要翻译： 本发明提供一种有机 - 无机杂化材料，其在低温到高温的宽温度范围内可以表现出高质子传导性，具有小粒径的质子传导材料，即具有能够 达到碳粉末等的一次粒子的孔隙，并且具有受控的粒径，包含这些用于燃料电池的材料的催化剂层和含有这些燃料电池用材料的电解质膜和燃料电池。 质子传导性杂化材料包括质子传导性无机纳米粒子和质子传导性聚合物，其中通过动态光散射的质子传导混合材料的斯托克斯粒径不大于20nm。

公开(公告)号：US07344791B1

公开(公告)日：2008-03-18

申请号：US09936148

申请日：2000-03-07

申请人： Takeo Yamaguchi ,  Shinichi Nakao

发明人： Takeo Yamaguchi ,  Shinichi Nakao

IPC分类号： H01M8/10

CPC分类号： H01M8/1011 ,  C08J5/2275 ,  C08J2327/18 ,  C08J2351/00 ,  C08J2379/08 ,  H01M8/1004 ,  H01M8/1009 ,  H01M8/1023 ,  H01M8/1039 ,  H01M8/106 ,  H01M8/1072 ,  H01M8/1088 ,  H01M2300/0088 ,  Y02E60/523 ,  Y02P70/56

摘要： A conventional direct methanol solid polymer fuel cell comprises a solid polymer electrolyte as an electrolyte. This type of cell involves some problems; methanol permeates the membrane; the electromotive force lowers because of direct oxidation; and the membrane melts at about 130° C. when the temperature is increased to enhance the catalyst activity. According to the invention, an electrolyte membrane made of a porous substrate (1) that does not swell substantially with methanol and water and has pores (2) filled with a polymer (3) having proton conductivity is produced and used to suppress the permeation of methanol as much as possible, providing an electrolyte membrane for fuel cells endurable in a high-temperature environment, a fuel cell comprising such a membrane, a method of manufacturing such a fuel cell, and a method of manufacturing an electrolyte membrane comprising irradiation a porous substrate having swell-resistance against organic solvent and water with energy and contacting the substrate with a monomer to cause polymerization.

摘要翻译： 常规的直接甲醇固体聚合物燃料电池包括作为电解质的固体聚合物电解质。 这种类型的电池涉及一些问题; 甲醇渗透膜; 电动势由于直接氧化而降低; 当温度升高时，膜在约130℃下熔融以提高催化剂活性。 根据本发明，制造由多孔基材（1）制成的电解质膜，其不会用甲醇和水基本上膨胀并且具有填充有质子传导性的聚合物（3）的孔（2），并用于抑制渗透 甲醇，提供在高温环境下耐用的燃料电池的电解质膜，包含这种膜的燃料电池，制造这种燃料电池的方法，以及制造电解质膜的方法，其包括将多孔 基材具有对有机溶剂的抗溶胀性和能量的水，并使基材与单体接触以引起聚合。

公开(公告)号：US20080038614A1

公开(公告)日：2008-02-14

申请号：US11706364

申请日：2007-02-15

申请人： Satoshi Nakazawa ,  Takeo Yamaguchi ,  Nobuo Hara

发明人： Satoshi Nakazawa ,  Takeo Yamaguchi ,  Nobuo Hara

IPC分类号： H01M8/10

CPC分类号： H01M4/926 ,  H01M4/921 ,  H01M8/0289 ,  H01M8/1025 ,  H01M8/1027 ,  H01M8/103 ,  H01M8/1032 ,  H01M8/106 ,  H01M8/1062 ,  H01M8/1067 ,  H01M8/1072 ,  Y02P70/56

摘要： The present invention provides an electrolyte membrane capable of inhibiting permeation of water, methanol or other electrolyte solutions, permeation of hydrogen and oxygen gas, and swelling caused by electrolyte solution, and having superior mechanical strength, a production process thereof and a membrane-electrode assembly and fuel cell using that electrolyte membrane. The electrolyte membrane has a porous base material having a plurality of pores, and a proton-conducting polymer composition retained in said pores, wherein the proton-conducting polymer composition contains an aromatic hydrocarbon resin having protonic acid groups, free water contained in the electrolyte membrane at 25° C. is present at 0.5 molecules or less per each of the protonic acid groups, bound water contained in the electrolyte membrane at 25° C. is present at 1 molecule or less for each of the protonic acid groups, proton conductivity of the electrolyte membrane in water at 25° C. is 0.001 S/cm or more, and methanol permeability of the electrolyte membrane in 30% by weight methanol at 25° C. is 50 (kg·μm/m2·h) or less.

摘要翻译： 本发明提供能够抑制水，甲醇或其他电解质溶液渗透的电解质膜，氢气和氧气的渗透以及由电解质溶液引起的溶胀，并且具有优异的机械强度，其制造方法和膜 - 电极组件 和使用该电解质膜的燃料电池。 所述电解质膜具有多孔的多孔基材和保留在所述孔中的质子传导聚合物组合物，其中所述质子传导性聚合物组合物含有具有质子酸基的芳香族烃树脂，所述电解质膜中含有游离水 在25℃下，每个质子酸基团以0.5分子或更少的比例存在，在25℃下包含在电解质膜中的结合水对于每个质子酸基团存在1分子以下，质子传导率 在25℃的水中的电解质膜为0.001S / cm以上，25℃下30重量％甲醇中的电解质膜的甲醇透过率为50（kg.mum / m 2） SUP> .h）以下。