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公开(公告)号：US5602203A
公开(公告)日：1997-02-11
申请号：US396580
申请日：1995-03-01
IPC分类号： C08L23/02 , C08L23/16 , C08F255/02
CPC分类号： C08L23/16 , C08L2312/00
摘要： An olefinic resin composition which comprises 100 parts by weight of a thermoplastic olefin elastomer consisting of a polyolefin resin and an olefinic copolymer rubber and 0.5 to 30 parts by weight of a modified polyolefin obtained by reacting an unsaturated carboxylic acid (anhydride)-modified polyolefin with an aminoalcohol represented by the formula H.sub.2 N--R--OH in which R is an alkylene, arylene or aralkylene group having 18 or less carbon atoms. The olefinic resin composition can give a molded article which can be satisfactorily coated with a coating material without a primer and has excellent heat fusibility to various resin and metals.
摘要翻译： 一种烯烃树脂组合物，其包含100重量份由聚烯烃树脂和烯烃共聚物橡胶组成的热塑性烯烃弹性体和0.5-30重量份通过使不饱和羧酸（酸酐）改性的聚烯烃与 由式H2N-R-OH表示的氨基醇，其中R是具有18个或更少碳原子的亚烷基，亚芳基或亚芳基。 烯烃树脂组合物可以得到可以令人满意地涂覆没有底漆的涂料的模塑制品，并且对各种树脂和金属具有优异的热熔融性。
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2.发明授权Thermoplastic elastomer powder for powder molding, powder molding method using the same and molded article thereof 失效用于粉末成型的热塑性弹性体粉末，使用其的粉末成型方法及其模制品
公开(公告)号：US5308700A
公开(公告)日：1994-05-03
申请号：US769734
申请日：1991-10-02
申请人： Tadashi Hikasa , Hiroaki Mendori , Tatsuo Hamanaka , Toshio Igarashi , Yuu Shida
发明人： Tadashi Hikasa , Hiroaki Mendori , Tatsuo Hamanaka , Toshio Igarashi , Yuu Shida
CPC分类号： C08L23/10 , C08L23/14 , C08L23/142 , C08L23/16 , C08L2312/00 , C08L83/04 , Y10T428/2982
摘要： A thermoplastic elastomer powder for powder molding, comprising an elastomer composition of an ethylene-.alpha.-olefin copolymer rubber and a polyolefin resin, wherein said elastomer composition has a complex dynamic viscosity .eta.*(1) as measured at frequency of 1 radian/sec. in dynamic viscoelasticity measurement at 250.degree. C., of 1.5.times.10.sup.5 poise or less, a Newtonian viscosity index n calculated from the following formula by using the complex dynamic viscosity .eta.*(1) at a frequency of 1 radian/sec. and the complex dynamic viscosity .eta.*(100) at a frequency of 100 radian/sec. of 0.67 or less, and a hardness (shore D) of 45 or less:n={log.eta.*(1)-log.eta.*(100)}/2.
摘要翻译： 一种用于粉末成型的热塑性弹性体粉末，包括乙烯-α-烯烃共聚物橡胶和聚烯烃树脂的弹性体组合物，其中所述弹性体组合物具有以1弧度/秒的频率测量的复合动态粘度η（1）。 在250℃的动态粘弹性测定中为1.5×10 5泊以下，通过以1弧度/秒的频率使用复数动态粘度η（1）由下式算出的牛顿粘度指数n。 和100弧度/秒的频率下的复数动态粘度eta *（100）。 为0.67以下，硬度（Shore D）为45以下：n = {log eta *（1）-log eta *（100）} / 2。
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3.发明授权Thermoplastic elastomer composition which has a shore a hardness of less than 45 失效具有小于45的硬度的热塑性弹性体组合物
公开(公告)号：US5187224A
公开(公告)日：1993-02-16
申请号：US692456
申请日：1991-04-08
申请人： Tatsuo Hamanaka , Tadashi Hikasa , Koichiro Ibuki
发明人： Tatsuo Hamanaka , Tadashi Hikasa , Koichiro Ibuki
CPC分类号： C08L23/02 , C08L23/16 , C08L53/025 , C08L2205/035 , C08L23/14 , C08L23/142 , C08L2312/00 , C08L91/00
摘要： A blend which comprises a partially crosslinked product of a mixture of an oil-extended olefinic copolymer rubber comprising an olefinic copolymer rubber having a 100.degree. C. Mooney viscosity 150-350, a polyolefin resin, a selectively hydrogenated block copolymer, and a specific mineral oil type softening agent has excellent flexibility of less than 45 in Shore A hardness. The blend is not tacky, nor does the softening agent bleed. An anti-static agent for polyolefins and/or a higher fatty acid amide may be included in the composition.
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公开(公告)号：US5180769A
公开(公告)日：1993-01-19
申请号：US854405
申请日：1992-03-19
摘要： An olefinic thermoplastic elastomer composition which is excellent in mechanical properties and is substitutable for vulcanized rubbers is provided, which comprises a mixture comprising (A) 40-95% by weight of an oil-extended olefinic copolymer rubber comprising 100 parts by weight of an olefinic copolymer rubber having a Mooney viscosity (ML.sub.1+4 100.degree. C.) of 150-350 and 20-150 parts byw eight of a mineral oil and (B) 5-60% by weight of an olefinic plastic, said mixture being partially crosslinked by dynamic heat treatment in the presence of an organic peroxide. This composition gives superior molded articles free from bleeding of oil on the surface.
摘要翻译： 提供机械性能优异且可替代硫化橡胶的烯烃热塑性弹性体组合物，其包含（A）40-95重量％的油 - 烯烃共聚物橡胶的混合物，其包含100重量份的烯烃 具有150-350的门尼粘度（ML1 + 4 100℃）和20-150份（重量）八份矿物油和（B）5-60％重量的烯烃塑料的共聚物橡胶，所述混合物部分交联 通过在有机过氧化物存在下进行动态热处理。 该组合物提供优异的模制品，其表面上没有油渗出。
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5.发明授权Thermoplastic elastomer powder for powder slush molding powder slush molding method using the same and molded article thereof 失效用于粉末搪塑粉末的热塑性弹性体粉末使用该粉末搪塑成型方法及其模塑制品
公开(公告)号：US5308699A
公开(公告)日：1994-05-03
申请号：US769733
申请日：1991-10-02
申请人： Tadashi Hikasa , Hiroaki Mendori , Tatsuo Hamanaka , Toshio Igarashi , Yuu Shida
发明人： Tadashi Hikasa , Hiroaki Mendori , Tatsuo Hamanaka , Toshio Igarashi , Yuu Shida
IPC分类号： B29C41/00 , B29C41/18 , C08L23/10 , C08L23/14 , C08L23/16 , C08L83/04 , C08L23/26 , C08J3/12 , C08J3/24
CPC分类号： C08L23/10 , B29C41/003 , C08L23/142 , C08L23/16 , B29C41/18 , B29K2023/16 , B29K2105/251 , C08L2312/00 , C08L83/04 , Y10T428/2982
摘要： A thermoplastic elastomer powder for powder slush molding, comprising an elastomer composition of an ethylene-.alpha.-olefin copolymer rubber and a polyolefin resin, wherein said elastomer composition has a complex dynamic viscosity .eta.*(1) as measured at a frequency of 1 radian/sec. in a dynamic viscoelasticity measurement at 250.degree. C., of 1.5.times.10.sup.5 poise or less, a Newtonian viscosity index n calculated from the following formula by using the complex dynamic viscosity .eta.*(1) at a frequency of 1 radian/sec. and the complex dynamic viscosity .eta.*(100) at a frequency of 100 radian/sec. of 0.67 or less:n=[log.eta.*(1)-log.eta.*(100)]/2.
摘要翻译： 一种用于粉末搪塑的热塑性弹性体粉末，包括乙烯-α-烯烃共聚物橡胶和聚烯烃树脂的弹性体组合物，其中所述弹性体组合物具有以1弧度/秒的频率测量的复数动态粘度η（1） 秒 在250℃下的动态粘弹性测量值为1.5×10 5泊或更小时，通过以1弧度/秒的频率使用复数动态粘度eta *（1）由下式计算的牛顿粘度指数n。 和100弧度/秒的频率下的复数动态粘度eta *（100）。 为0.67以下：n = [log eta *（1）-log eta *（100）] / 2。
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公开(公告)号：US5118753A
公开(公告)日：1992-06-02
申请号：US548207
申请日：1990-07-05
摘要： An olefinic thermoplastic elastomer composition which is excellent in mechanical properties and is substitutable for vulcanized rubbers is provided, which comprises a mixture comprising (A) 40-95 % by weight of an oil-extended olefinic copolymer rubber comprising 100 parts by weight of an olefinic copolymer rubber having a Mooney viscosity (ML.sub.1+4 100.degree. C.) of 150-350 and 20-150 parts by weight of a mineral oil and (B) 5-60% by weight of an olefinic plastic, said mixture being partially crosslinked by dynamic heat treatment in the presence of an organic peroxide. This composition gives superior molded articles free from bleeding of oil on the surface.
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公开(公告)号：US5298211A
公开(公告)日：1994-03-29
申请号：US985269
申请日：1992-12-03
申请人： Tatsuo Hamanaka , Noboru Komine , Tadashi Hikasa , Yuji Gotoh , Keitaro Kojima
发明人： Tatsuo Hamanaka , Noboru Komine , Tadashi Hikasa , Yuji Gotoh , Keitaro Kojima
CPC分类号： C08L23/16 , C08L2312/00
摘要： Provided is a method for producing a thermoplastic elastomer composition excellent in flexibility, mechanical properties and extrusion moldability which comprises directly feeding a particulate olefinic copolymer rubber (A) having a particle shape index .alpha. defined below of 0.1-0.9 and an olefinic plastic (B) to a continuous kneading extruder to carry out melt kneading and then, feeding an organic peroxide to downstream side of said extruder to carry out dynamic crosslinking:.alpha.=D.sub.A /D.sub.Bwherein D.sub.A denotes bulk density of the particulate olefinic copolymer rubber (A) and D.sub.B denotes bulk density of the olefinic plastic (B).
摘要翻译： 本发明提供一种柔软性，机械性能和挤出成型性优异的热塑性弹性体组合物的制造方法，其特征在于，直接进料具有下述0.1-0.9以下的粒子形状指数（α）的烯烃系共聚物橡胶（A）和烯烃类塑料（ B）到连续捏合挤出机进行熔融捏合，然后将有机过氧化物供入所述挤出机的下游侧进行动态交联：（α）= DA / DB其中DA表示颗粒状烯属共聚物橡胶的堆积密度 A），DB表示烯烃塑料（B）的堆积密度。
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公开(公告)号：US4933389A
公开(公告)日：1990-06-12
申请号：US304223
申请日：1989-01-31
IPC分类号： C08L23/00 , C08L23/02 , C08L23/08 , C08L23/12 , C08L23/16 , C08L31/04 , C08L33/04 , C08L33/06 , C08L91/00
CPC分类号： C08L23/0869 , C08L23/16 , C08L2205/03 , C08L23/12 , C08L2312/00 , C08L91/00
摘要： The present invention provides a thermoplastic elastomer composition excellent in oil resistance. This composition comprises a partially crosslinked mixture of (A) an ethylene copolymer rubber comprising ethylene and an acrylate ester or a methacrylate ester and (B) an olefin polymer and, if necessary, (C) an olefin copolymer rubber.
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公开(公告)号：US5516582A
公开(公告)日：1996-05-14
申请号：US729196
申请日：1991-07-12
申请人： Tadashi Hikasa , Hiroaki Mendori , Takahisa Hara , Nobuhiro Usui
发明人： Tadashi Hikasa , Hiroaki Mendori , Takahisa Hara , Nobuhiro Usui
IPC分类号： B32B5/18 , B29C43/18 , B29C43/20 , B29C51/08 , B29C70/78 , B29K23/00 , B29L9/00 , B29L31/58 , B32B27/00 , B28B5/00
CPC分类号： B29C70/78 , B29C43/184 , B29C51/082 , B29K2995/00 , B29K2995/0077 , Y10T428/249993
摘要： A multilayer molded article having a body of a thermoplastic resin and a skin material which is laminated on a surface of said body and made of an olefin thermoplastic elastomer having 100% modulus (M100) at 23.degree. C. of from 20 to 60 kg/cm.sup.2 and a frictional resistance (tan .delta.) against a metal surface of 1.0 or lower which is backed with a foam layer, which has good appearance and also good weather resistance.
摘要翻译： 一种多层模制品，其具有热塑性树脂体和表层材料，其层压在所述主体的表面上并由在23℃下的100％模量（M100）为20至60kg / m 2的烯烃热塑性弹性体制成， cm2，相对于1.0以下的金属表面的摩擦阻力（tanδ），其背面具有良好的外观和耐候性。
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10.发明授权Thermoplastic elastomer composition, covering materials for industrial parts comprising the composition and laminates comprising the covering materials 失效热塑性弹性体组合物，用于包含该组合物的工业部件的覆盖材料和包括覆盖材料的层压材料
公开(公告)号：US5407991A
公开(公告)日：1995-04-18
申请号：US141668
申请日：1993-10-26
申请人： Tadashi Hikasa , Koji Yamashita , Satoru Hosoda , Kiyoshi Mitsui , Yuji Kanda
发明人： Tadashi Hikasa , Koji Yamashita , Satoru Hosoda , Kiyoshi Mitsui , Yuji Kanda
IPC分类号： B29C51/10 , B32B5/18 , B32B27/08 , B32B27/32 , B60R13/02 , C08J3/24 , C08K5/01 , C08L23/00 , C08L23/16 , C08L91/00
摘要： The invention provides an olefinic thermoplastic elastomer composition which is excellent in flexibility, processability into sheet and appearance of the resulting sheet and which is able to substitute for flexible polyvinyl chloride. The invention further provides a covering material for industrial parts comprising said composition and a laminate comprising said covering material.The composition comprises a partially crosslinked thermoplastic elastomer I containing an oil-extended olefinic copolymer rubber comprising an olefinic copolymer rubber having a Mooney viscosity of 200-350 or the thermoplastic elastomer I and a partially crosslinked thermoplastic elastomer II containing an oil-extended olefinic copolymer rubber comprising an olefinic copolymer rubber having a Mooney viscosity of 120 or higher and lower than 200 and the composition has a specific viscoelastic characteristics.
摘要翻译： 本发明提供了一种烯烃类热塑性弹性体组合物，该组合物的柔软性，加工性能优于片材，并且得到的片材外观可以替代柔性聚氯乙烯。 本发明还提供了一种用于包含所述组合物的工业部件的覆盖材料和包括所述覆盖材料的层压体。 组合物包含部分交联的热塑性弹性体I，其含有油扩展的烯烃共聚物橡胶，其包含门尼粘度为200-350的烯烃共聚物橡胶或热塑性弹性体I和部分交联的热塑性弹性体II，其含有油延伸的烯烃共聚物橡胶 包含门尼粘度为120以上且低于200的烯烃共聚物橡胶，该组合物具有特定的粘弹性特性。
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