摘要:
An optical disk of the invention comprises a substrate of an aromatic polycarbonate obtained by polymerizing one or two monomers polymerized through carbonate linkages and a recording layer coated thereon, said recording layer being recordable and readable by a laser beam,the monomer being selected from the group consisting of:(a-1) 1,1'-bis-(4-hydroxyphenyl)-p-diisopropylbenzene(a-2) 1,1'-bis-(4-hydroxyphenyl)-m-diisopropylbenzene,(b-1) 2,2-bis-(4-hydroxyphenyl)propane,(b-2) 2,2-bis-(4-hydroxyphenyl)butane,(b-3) 2,2-bis-(4-hydroxyphenyl)-4-methylpentane,(b-4) 2,2-bis-(4-hydroxyphenyl)octane,(b-5) 1,1-bis-(4-hydroxyphenyl)cyclohexane,(b-6) 4,4'-dihydroxy-2,2,2-triphenylethane,(b-7) 2,2-bis-(4-hydroxy-3-methylphenyl)propane,(b-8) 2,2-bis-(4-hydroxy-3-isopropylphenyl)propane,(b-9) 2,2-bis-(4-hydroxy-3-sec.-butylphenyl)propane,(b-10) 2,2-bis-(3,5-dimethyl-4-hydroxyphenyl)propane,the polycarbonate being selected from the group consisting of:(I) a copolymer of 3 to 97 mole percent of (a-1) and 97 to 3 mole percent of one of (b-1) to (b-10),(II) a homopolymer of (a-1) and(III) a copolymer of 3 to 97 mole percent of (a-2) and 97 to 3 mole percent of one of (b-1), (b-5), (b-6), (b-10) and (a-1).
摘要:
A new aromatic polycarbonate is obtained from (1) 2,2-bis(4-hydroxy-3-isopropylphenyl)propane, (2) 2,2-bis(4-hydroxyphenyl)propane and 2,2-bis(4-hydroxy-3-isopropylphenyl) propane or (3) 4,4'-dihydroxy-2,2,2-triphenylethane and 2,2-bis(4-hydroxy-3-isopropylphenyl)propane through a carbonate linkage and is useful as a starting material for an optical disk.
摘要:
A plastic optical fiber comprising an aromatic polycarbonate copolymer having a photoelastic constant of 60 Brewsters (10.sup.-12 m.sup.2 /N) or less as a core component resin exhibits small birefringence.
摘要:
An aromatic polycarbonate copolymer is useful for a substrate of an optical disk and is composed of 1 to 99 mole percent of the unit of 2,2-bis(4-hydroxy-3-tertiary-butyl-phenyl)propane, 99 to 1 mole percent of the unit of a comonomer selected from the group consisting of(1) 2,2-bis(4-hydroxyphenyl)propane,(2) 4,4'-dihydroxy-2,2,2-triphenylethane,(3) 2,2-bis(4-hydroxy-3-methylphenyl)-propane,(4) 1,1'-bis(4-hydroxyphenyl)-p-diisopropylbenzene,(5) 1,1'-bis(4-hydroxyphenyl)-m-diisopropyl-benzene,(6) 2,2-bis(4-hydroxyphenyl)butane,(7) 2,2-bis(4-hydroxyphenyl)-4-methylpentane,(8) 2,2-bis(4-hydroxyphenyl)octane,(9) 1,1-bis(4-hydroxyphenyl)cyclohexane and(10) 2,2-bis(3,5-dimethyl-4-hydroxyphenyl)propaneand a carbonate group located between the two units.
摘要:
A process for the preparation of a substantially chlorine-free, high-molecular-weight, colorless and transparent (co)polycarbonate by melt-polycondensing a dihydroxy compound with a carbonic diester, which comprises using a carbonic diester which satisfies at lease one factor selected from the group consisting of:(factor-1) the carbonic diester is substantially free from phenyl salicylate, o-phenoxybenzoic acid and phenyl o-phenoxybenzoate,(factor-2) the carbonic diester is substantially free from tin ion, and(factor-3) the carbonic diester is substantially free from methyl phenyl carbonate.
摘要:
A process for producing a (co)polycarbonate having excellent thermal resistance, hue and impact resistance and a high molecular weight, which comprises conducting a melt-polycondensation of a dihydroxy compound and a carbonic diester as monomers in the presence of a transesterification catalyst in a tank reactor, while removing a monohydroxy-compound formed by the melt-polycondensation, thereby obtaining a reaction mixture comprising a prepolymer in a molten state (the first step), cooling the molten reaction mixture obtained in the first step to solidify it (the second step), and conducting a melt-polycondensation of the reaction mixture comprising the prepolymer in a horizontal polycondensation reactor, thereby obtaining a reaction mixture comprising a high-molecular-weight (co)polycarbonate (the third step).
摘要:
Mono(meth)acrylate or di(meth)acrylate of 2-methylpropylene glycol. The diacrylate, or a low molecular weight oligomer thereof, with polymeric filler and sensitizer is useful as a photosensitive component.
摘要:
A modified styrene-based resin composition in which silicone powder is added to styrene-based resin.One can obtain styrene-based resin compositions remarkably improved in impact resistance and sliding properties, particularly in permanence during sliding. In particular, when the base material is transparent polystyrene-based resin, it was found that the present invention can provide styrene-based resin compositions having excellent impact strength, sliding properties, and transparency without spoiling their fluidity and thermostability. In addition, use of rubber modified polystyrene as styrene-based resin permits styrene-based resin compositions exhibiting well-balanced impact resistance, sliding properties, heat distortion resistance, molding properties, workability, and surface appearance of molded articles. Thus, the present invention enables general-purpose styrene-based rigid thermoplastics to be used for various applications, that is, it allows improvement of such thermoplastics particularly in adaptability to injection molding, extrusion molding and the like, and thereby will contributes to extension of the range of their application.
摘要:
A processes for producing a (co)polycarbonate having a low terminal hydroxyl group concentration and being excellent in heat resistance and hue, which comprises melt-polycondensing a dihydroxy compound with a carbonic diester in the presence of a catalyst for transesterification selected from the group consisting of a nitrogen-containing basic compound, an alkali metal borate and an alkaline earth metal borate and in the presence of a specific ester compound.
摘要:
A process for the preparation of a (co)polycarbonate having an excellent hue, heat resistance, residence to hydrolysis and impact resistance by transesterification with the use of an aparatuses of a low price. In the first step, a dihydroxy compound is reacted with a carbonic diester in a reactor having a surface area contacting the dihydroxy compound and the carbonic diester made of a material containing iron in an amount of 20% by weight or less, to give a prepolymer and, in the second step, melt-polycondensing the prepolymer in a reactor other than the reactor used in the first step.