Optical disk of polycarbonate
    1.
    发明授权
    Optical disk of polycarbonate 失效
    聚碳酸酯的光盘

    公开(公告)号:US4978578A

    公开(公告)日:1990-12-18

    申请号:US225052

    申请日:1988-07-27

    IPC分类号: C08G64/06 G11B7/253

    摘要: An optical disk of the invention comprises a substrate of an aromatic polycarbonate obtained by polymerizing one or two monomers polymerized through carbonate linkages and a recording layer coated thereon, said recording layer being recordable and readable by a laser beam,the monomer being selected from the group consisting of:(a-1) 1,1'-bis-(4-hydroxyphenyl)-p-diisopropylbenzene(a-2) 1,1'-bis-(4-hydroxyphenyl)-m-diisopropylbenzene,(b-1) 2,2-bis-(4-hydroxyphenyl)propane,(b-2) 2,2-bis-(4-hydroxyphenyl)butane,(b-3) 2,2-bis-(4-hydroxyphenyl)-4-methylpentane,(b-4) 2,2-bis-(4-hydroxyphenyl)octane,(b-5) 1,1-bis-(4-hydroxyphenyl)cyclohexane,(b-6) 4,4'-dihydroxy-2,2,2-triphenylethane,(b-7) 2,2-bis-(4-hydroxy-3-methylphenyl)propane,(b-8) 2,2-bis-(4-hydroxy-3-isopropylphenyl)propane,(b-9) 2,2-bis-(4-hydroxy-3-sec.-butylphenyl)propane,(b-10) 2,2-bis-(3,5-dimethyl-4-hydroxyphenyl)propane,the polycarbonate being selected from the group consisting of:(I) a copolymer of 3 to 97 mole percent of (a-1) and 97 to 3 mole percent of one of (b-1) to (b-10),(II) a homopolymer of (a-1) and(III) a copolymer of 3 to 97 mole percent of (a-2) and 97 to 3 mole percent of one of (b-1), (b-5), (b-6), (b-10) and (a-1).

    摘要翻译: 本发明的光盘包括通过聚合通过碳酸酯键聚合的一种或两种单体和其上涂覆有记录层而获得的芳族聚碳酸酯的基材,所述记录层可由激光束记录和读取,所述单体选自组 由(a-1)1,1'-双 - (4-羟基苯基) - 对二异丙基苯(a-2)1,1'-双 - (4-羟基苯基) - 间二异丙苯,(b-1 )2,2-双 - (4-羟基苯基)丙烷,(b-2)2,2-双 - (4-羟基苯基)丁烷,(b-3)2,2-双 - (4-羟基苯基)-4 (b-4)2,2-双 - (4-羟基苯基)辛烷,(b-5)1,1-双 - (4-羟基苯基)环己烷,(b-6)4,4'-二羟基 -2,2,2-三苯基乙烷,(b-7)2,2-双 - (4-羟基-3-甲基苯基)丙烷,(b-8)2,2-双 - (4-羟基-3-异丙基苯基 )丙烷,(b-9)2,2-双 - (4-羟基-3-仲丁基苯基)丙烷,(b-10)2,2-双 - (3,5-二甲基-4-羟基苯基) 丙烷,所述聚碳酸酯选自:(I)3至97摩尔%的共聚物 (a-1)和(III)的均聚物(a-1)和97〜3摩尔%的(b-1)〜(b-10),(II) (a-2)和(b-1),(b-5),(b-6),(b-10)和(a-1)之一的(a-2)和97〜3摩尔%的百分比。

    Plastic optical fiber
    3.
    发明授权
    Plastic optical fiber 失效
    塑料光纤

    公开(公告)号:US5002362A

    公开(公告)日:1991-03-26

    申请号:US423345

    申请日:1989-10-18

    IPC分类号: G02B1/04

    CPC分类号: G02B6/02033 G02B1/046

    摘要: A plastic optical fiber comprising an aromatic polycarbonate copolymer having a photoelastic constant of 60 Brewsters (10.sup.-12 m.sup.2 /N) or less as a core component resin exhibits small birefringence.

    摘要翻译: 作为核心成分树脂,包含光弹性常数为60〜18m2 / N的光弹性常数的芳香族聚碳酸酯共聚物的塑料光纤显示小的双折射。

    Process for the preparation of (co)polycarbonate
    5.
    发明授权
    Process for the preparation of (co)polycarbonate 失效
    (共)聚碳酸酯的制备方法

    公开(公告)号:US5434235A

    公开(公告)日:1995-07-18

    申请号:US227548

    申请日:1994-04-14

    IPC分类号: C08G64/30 C08G64/00

    CPC分类号: C08G64/307

    摘要: A process for the preparation of a substantially chlorine-free, high-molecular-weight, colorless and transparent (co)polycarbonate by melt-polycondensing a dihydroxy compound with a carbonic diester, which comprises using a carbonic diester which satisfies at lease one factor selected from the group consisting of:(factor-1) the carbonic diester is substantially free from phenyl salicylate, o-phenoxybenzoic acid and phenyl o-phenoxybenzoate,(factor-2) the carbonic diester is substantially free from tin ion, and(factor-3) the carbonic diester is substantially free from methyl phenyl carbonate.

    摘要翻译: 通过使二羟基化合物与碳酸二酯熔融缩聚制备基本上无氯,高分子量,无色和透明(共)聚碳酸酯的方法,该方法包括使用至少满足一个因素选择的碳酸二酯 来自由(因子-1)组成的组,碳酸二酯基本上不含水杨酸苯酯,邻苯氧基苯甲酸和邻苯氧基苯甲酸苯酯(因子-2),碳酸二酯基本上不含锡离子,(因子 - 3)碳酸二酯基本上不含碳酸甲基苯酯。

    Process for producing (co)polycarbonate
    6.
    发明授权
    Process for producing (co)polycarbonate 失效
    (共)聚碳酸酯的制造方法

    公开(公告)号:US5405934A

    公开(公告)日:1995-04-11

    申请号:US159840

    申请日:1993-11-30

    IPC分类号: C08G64/20 C08G64/30 C08G64/00

    CPC分类号: C08G64/307

    摘要: A process for producing a (co)polycarbonate having excellent thermal resistance, hue and impact resistance and a high molecular weight, which comprises conducting a melt-polycondensation of a dihydroxy compound and a carbonic diester as monomers in the presence of a transesterification catalyst in a tank reactor, while removing a monohydroxy-compound formed by the melt-polycondensation, thereby obtaining a reaction mixture comprising a prepolymer in a molten state (the first step), cooling the molten reaction mixture obtained in the first step to solidify it (the second step), and conducting a melt-polycondensation of the reaction mixture comprising the prepolymer in a horizontal polycondensation reactor, thereby obtaining a reaction mixture comprising a high-molecular-weight (co)polycarbonate (the third step).

    摘要翻译: 一种制备具有优异的耐热性,色相和耐冲击性以及高分子量的(共)聚碳酸酯的方法,其包括在酯交换催化剂存在下,将二羟基化合物和碳酸二酯作为单体进行熔融缩聚反应 同时除去通过熔融缩聚形成的单羟基化合物,从而获得包含熔融状态的预聚物(第一步)的反应混合物,冷却在第一步骤中获得的熔融反应混合物使其固化(第二步 步骤),并将包含预聚物的反应混合物在水性缩聚反应器中进行熔融缩聚,从而得到包含高分子量(共)聚碳酸酯(第三步)的反应混合物。

    Styrene-based resin compositions and molded articles thereof
    8.
    发明授权
    Styrene-based resin compositions and molded articles thereof 失效
    苯乙烯类树脂组合物及其成型体

    公开(公告)号:US6153698A

    公开(公告)日:2000-11-28

    申请号:US100498

    申请日:1998-06-19

    CPC分类号: C08L25/06 C08L83/04

    摘要: A modified styrene-based resin composition in which silicone powder is added to styrene-based resin.One can obtain styrene-based resin compositions remarkably improved in impact resistance and sliding properties, particularly in permanence during sliding. In particular, when the base material is transparent polystyrene-based resin, it was found that the present invention can provide styrene-based resin compositions having excellent impact strength, sliding properties, and transparency without spoiling their fluidity and thermostability. In addition, use of rubber modified polystyrene as styrene-based resin permits styrene-based resin compositions exhibiting well-balanced impact resistance, sliding properties, heat distortion resistance, molding properties, workability, and surface appearance of molded articles. Thus, the present invention enables general-purpose styrene-based rigid thermoplastics to be used for various applications, that is, it allows improvement of such thermoplastics particularly in adaptability to injection molding, extrusion molding and the like, and thereby will contributes to extension of the range of their application.

    摘要翻译: 将苯乙烯类树脂中加入硅酮粉末的改性苯乙烯类树脂组合物。 可以获得显着提高抗冲击性和滑动性的苯乙烯类树脂组合物,特别是在滑动时的耐久性。 特别地,当基材为透明聚苯乙烯类树脂时,发现本发明可以提供具有优异冲击强度,滑动性能和透明性的苯乙烯类树脂组合物,而不会破坏它们的流动性和热稳定性。 此外,使用橡胶改性聚苯乙烯作为苯乙烯类树脂,可以使成型品的耐冲击性,滑动性,耐热变形性,成型性,加工性,表面外观均匀的苯乙烯类树脂组合物。 因此,本发明使通用的基于苯乙烯的刚性热塑性塑料能够用于各种应用,即,可以改进这种热塑性塑料,特别是在注射成型,挤出成型等的适应性方面,从而有助于延长 其应用范围。

    (Co)polycarbonate and borate composition
    9.
    发明授权
    (Co)polycarbonate and borate composition 失效
    (Co)聚碳酸酯和硼酸盐组合物

    公开(公告)号:US5658978A

    公开(公告)日:1997-08-19

    申请号:US456560

    申请日:1995-06-01

    摘要: A processes for producing a (co)polycarbonate having a low terminal hydroxyl group concentration and being excellent in heat resistance and hue, which comprises melt-polycondensing a dihydroxy compound with a carbonic diester in the presence of a catalyst for transesterification selected from the group consisting of a nitrogen-containing basic compound, an alkali metal borate and an alkaline earth metal borate and in the presence of a specific ester compound.

    摘要翻译: 一种制备具有低端羟基浓度并具有优异的耐热性和色调的(共)聚碳酸酯的方法,其包括在用于酯交换的催化剂的存在下,使二羟基化合物与碳酸二酯熔融缩聚,所述催化剂选自 的含氮碱性化合物,碱金属硼酸盐和碱土金属硼酸盐,并在特定的酯化合物存在下进行。

    Process for the preparation of (co)polycarbonate
    10.
    发明授权
    Process for the preparation of (co)polycarbonate 失效
    (共)聚碳酸酯的制备方法

    公开(公告)号:US5416186A

    公开(公告)日:1995-05-16

    申请号:US229292

    申请日:1994-04-18

    摘要: A process for the preparation of a (co)polycarbonate having an excellent hue, heat resistance, residence to hydrolysis and impact resistance by transesterification with the use of an aparatuses of a low price. In the first step, a dihydroxy compound is reacted with a carbonic diester in a reactor having a surface area contacting the dihydroxy compound and the carbonic diester made of a material containing iron in an amount of 20% by weight or less, to give a prepolymer and, in the second step, melt-polycondensing the prepolymer in a reactor other than the reactor used in the first step.

    摘要翻译: 通过使用低价格的装置,制备具有优异色调,耐热性,耐水解和耐冲击性的(共)聚碳酸酯的方法。 在第一步中,将二羟基化合物与碳二酯在反应器中反应,该反应器具有与二羟基化合物的表面积和由含铁量为20重量%以下的材料制成的碳酸二酯,得到预聚物 并且在第二步骤中,使预聚物在第一步骤中使用的反应器以外的反应器中熔融缩聚。