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公开(公告)号:US09061270B2
公开(公告)日:2015-06-23
申请号:US13520467
申请日:2010-12-17
申请人: Teng Xu , Terry E. Helton , Jihad M. Dakka , Tan-Jen Chen , Sabato Miseo , Lorenzo C. Decaul , Edward A. Lemon, Jr.
发明人: Teng Xu , Terry E. Helton , Jihad M. Dakka , Tan-Jen Chen , Sabato Miseo , Lorenzo C. Decaul , Edward A. Lemon, Jr.
IPC分类号: C07C37/08 , C07C37/00 , B01J29/04 , B01J21/00 , B01J23/58 , B01J21/08 , B01J37/02 , B01J37/12 , C07C2/74 , C07C37/06 , C07C45/53 , C07C407/00 , C07C37/07
CPC分类号: B01J23/58 , B01J21/08 , B01J37/0205 , B01J37/12 , C07C2/74 , C07C37/06 , C07C37/07 , C07C37/08 , C07C45/53 , C07C407/00 , C07C2529/70 , C07C2601/14 , Y02P20/52 , C07C13/28 , C07C39/04 , C07C49/403 , C07C409/14
摘要: A catalyst composition comprising: (i) a support; (ii) a first component comprising at least one metal component selected from Group 1 and Group 2 of the Periodic Table of Elements; and (iii) a second component comprising at least one metal component selected from Groups 6 to 10 of the Periodic Table of Elements, wherein the catalyst composition exhibits an oxygen chemisorption of greater than 50%.
摘要翻译: 一种催化剂组合物,其包含:(i)载体; (ii)包含选自元素周期表第1族和第2族的至少一种金属成分的第一成分; 和(iii)包含选自元素周期表第6至10族的至少一种金属组分的第二组分,其中催化剂组合物显示出大于50%的氧化学吸附。
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公开(公告)号:US09024078B2
公开(公告)日:2015-05-05
申请号:US13515104
申请日:2010-12-17
申请人: Jihad M. Dakka , Lorenzo C. Decaul , Sabato Miseo , James R. Lattner , Tan-Jen Chen , Terry E. Helton , Teng Xu
发明人: Jihad M. Dakka , Lorenzo C. Decaul , Sabato Miseo , James R. Lattner , Tan-Jen Chen , Terry E. Helton , Teng Xu
IPC分类号: C07C37/08 , C07C5/32 , C07C37/07 , C07C45/53 , C07C407/00
CPC分类号: C07C37/08 , B01J23/58 , B01J35/1019 , B01J35/1061 , B01J37/0009 , B01J37/0203 , C07C5/367 , C07C37/07 , C07C45/53 , C07C407/00 , C07C2521/08 , C07C2523/42 , C07C2523/58 , C07C2601/14 , Y02P20/52 , C07C39/04 , C07C49/403 , C07C409/14 , C07C15/04
摘要: A dehydrogenation process for the dehydrogenation of at least one dehydrogenatable hydrocarbon, the process comprising contacting a feed comprising the at least one dehydrogenatable hydrocarbon under dehydrogenation conditions with a catalyst composition comprising a support and at least one dehydrogenation component wherein said conditions include a temperature of from 400° C. to 750° C. and a pressure of at least 50 psig (345 kPag).
摘要翻译: 用于脱氢至少一种可脱氢烃的脱氢方法,该方法包括在脱氢条件下使包含至少一种可脱氢烃的进料与包含载体和至少一种脱氢组分的催化剂组合物接触,其中所述条件包括 400℃至750℃,压力至少为50psig(345kPag)。
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公开(公告)号:US20120302798A1
公开(公告)日:2012-11-29
申请号:US13515104
申请日:2010-12-17
申请人: Jihad M. Dakka , Lorenzo C. Decaul , Sabato Miseo , James R. Lattner , Tan-Jen Chen , Terry E. Helton , Teng Xu
发明人: Jihad M. Dakka , Lorenzo C. Decaul , Sabato Miseo , James R. Lattner , Tan-Jen Chen , Terry E. Helton , Teng Xu
CPC分类号: C07C37/08 , B01J23/58 , B01J35/1019 , B01J35/1061 , B01J37/0009 , B01J37/0203 , C07C5/367 , C07C37/07 , C07C45/53 , C07C407/00 , C07C2521/08 , C07C2523/42 , C07C2523/58 , C07C2601/14 , Y02P20/52 , C07C39/04 , C07C49/403 , C07C409/14 , C07C15/04
摘要: A dehydrogenation process for the dehydrogenation of at least one dehydrogenatable hydrocarbon, the process comprising contacting a feed comprising the at least one dehydrogenatable hydrocarbon under dehydrogenation conditions with a catalyst composition comprising a support and at least one dehydrogenation component wherein said conditions include a temperature of from 400° C. to 750° C. and a pressure of at least 50 psig (345 kPag).
摘要翻译: 用于脱氢至少一种可脱氢烃的脱氢方法,该方法包括在脱氢条件下使包含至少一种可脱氢烃的进料与包含载体和至少一种脱氢组分的催化剂组合物接触,其中所述条件包括 400℃至750℃,压力至少为50psig(345kPag)。
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公开(公告)号:US20130090499A1
公开(公告)日:2013-04-11
申请号:US13520467
申请日:2010-12-17
申请人: Teng Xu , Terry E. Helton , Jihad M. Bakka , Tan-Jen Chen , Sabato Miseo , Lorenzo C. Decaul , Edward A. Lemon, JR.
发明人: Teng Xu , Terry E. Helton , Jihad M. Bakka , Tan-Jen Chen , Sabato Miseo , Lorenzo C. Decaul , Edward A. Lemon, JR.
CPC分类号: B01J23/58 , B01J21/08 , B01J37/0205 , B01J37/12 , C07C2/74 , C07C37/06 , C07C37/07 , C07C37/08 , C07C45/53 , C07C407/00 , C07C2529/70 , C07C2601/14 , Y02P20/52 , C07C13/28 , C07C39/04 , C07C49/403 , C07C409/14
摘要: A catalyst composition comprising: (i) a support; (ii) a first component comprising at least one metal component selected from Group 1 and Group 2 of the Periodic Table of Elements; and (iii) a second component comprising at least one metal component selected from Groups 6 to 10 of the Periodic Table of Elements, wherein the catalyst composition exhibits an oxygen chemisorption of greater than 50%.
摘要翻译: 一种催化剂组合物,其包含:(i)载体; (ii)包含选自元素周期表第1族和第2族的至少一种金属成分的第一成分; 和(iii)包含选自元素周期表第6至10族的至少一种金属组分的第二组分,其中催化剂组合物显示出大于50%的氧化学吸附。
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公开(公告)号:US09242227B2
公开(公告)日:2016-01-26
申请号:US13515142
申请日:2010-12-17
IPC分类号: C07C37/08 , B01J23/58 , B01J21/08 , B01J37/02 , B01J37/12 , C07C2/74 , C07C37/06 , C07C45/53 , C07C407/00
CPC分类号: B01J23/58 , B01J21/08 , B01J37/0205 , B01J37/12 , C07C2/74 , C07C37/06 , C07C37/08 , C07C45/53 , C07C407/00 , C07C2529/70 , C07C2601/14 , Y02P20/52 , C07C13/28 , C07C39/04 , C07C49/403 , C07C409/14
摘要: A catalyst composition comprises (i) a support; (ii) a dehydrogenation component comprising at least one metal or compound thereof selected from Groups 6 to 10 of the Periodic Table of Elements; and (iii) potassium or a potassium compound present in an amount of about 0.15 to about 0.6 wt % of potassium based upon the total weight of the catalyst composition, wherein the catalyst composition has an oxygen chemisorption of greater than 50%.
摘要翻译: 催化剂组合物包含(i)载体; (ii)包含选自元素周期表第6至10族的至少一种金属或其化合物的脱氢组分; 和(iii)基于催化剂组合物的总重量,钾或钾化合物的存在量为约0.15至约0.6重量%的钾,其中催化剂组合物的氧化学吸附率大于50%。
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公开(公告)号:US20120302799A1
公开(公告)日:2012-11-29
申请号:US13515142
申请日:2010-12-17
CPC分类号: B01J23/58 , B01J21/08 , B01J37/0205 , B01J37/12 , C07C2/74 , C07C37/06 , C07C37/08 , C07C45/53 , C07C407/00 , C07C2529/70 , C07C2601/14 , Y02P20/52 , C07C13/28 , C07C39/04 , C07C49/403 , C07C409/14
摘要: A catalyst composition comprises (i) a support; (ii) a dehydrogenation component comprising at least one metal or compound thereof selected from Groups 6 to 10 of the Periodic Table of Elements; and (iii) potassium or a potassium compound present in an amount of about 0.15 to about 0.6 wt % of potassium based upon the total weight of the catalyst composition, wherein the catalyst composition has an oxygen chemisorption of greater than 50%.
摘要翻译: 催化剂组合物包含(i)载体; (ii)包含选自元素周期表第6至10族的至少一种金属或其化合物的脱氢组分; 和(iii)基于催化剂组合物的总重量,钾或钾化合物的存在量为约0.15至约0.6重量%的钾,其中催化剂组合物的氧化学吸附率大于50%。
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公开(公告)号:US20120271077A1
公开(公告)日:2012-10-25
申请号:US13512625
申请日:2010-12-17
申请人: Teng Xu , Stuart L. Soled , Edward A. Lemon, JR. , Christine E. Kliewer , Tan-Jen Chen , Joseph E. Baumgartner , Sabato Miseo
发明人: Teng Xu , Stuart L. Soled , Edward A. Lemon, JR. , Christine E. Kliewer , Tan-Jen Chen , Joseph E. Baumgartner , Sabato Miseo
IPC分类号: C07C5/367
CPC分类号: B01J37/0203 , B01J23/40 , C07C5/367 , C07C5/373 , C07C13/19 , C07C2523/42 , Y02P20/52 , C07C15/04 , C07C9/14
摘要: In a dehydrogenation process a hydrocarbon stream comprising at least one non-aromatic six-membered ring compound and at least one five-membered ring compound is contacted with a dehydrogenation catalyst produced by a method comprising treating the support with a liquid composition comprising the dehydrogenation component or a precursor thereof and at least one organic dispersant selected from an amino alcohol and an amino acid. The contacting is conducted under conditions effective to convert at least a portion of the at least one non-aromatic six-membered ring compound in the hydrocarbon stream to benzene and to convert at least a portion of the at least one five-membered ring compound in the hydrocarbon stream to paraffins.
摘要翻译: 在脱氢方法中,包含至少一种非芳族六元环化合物和至少一种五元环化合物的烃流与脱氢催化剂接触,所述脱氢催化剂通过包括用包含脱氢组分的液体组合物处理载体的方法制备 或其前体和至少一种选自氨基醇和氨基酸的有机分散剂。 该接触在有效将烃流中的至少一种非芳香族六元环化合物的至少一部分转化为苯并将至少一部分至少一种五元环化合物转化为 烃流至石蜡。
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公开(公告)号:US08969639B2
公开(公告)日:2015-03-03
申请号:US13512625
申请日:2010-12-17
申请人: Teng Xu , Stuart L. Soled , Edward A. Lemon, Jr. , Christine E. Kliewer , Tan-Jen Chen , Joseph E. Baumgartner , Sabato Miseo
发明人: Teng Xu , Stuart L. Soled , Edward A. Lemon, Jr. , Christine E. Kliewer , Tan-Jen Chen , Joseph E. Baumgartner , Sabato Miseo
CPC分类号: B01J37/0203 , B01J23/40 , C07C5/367 , C07C5/373 , C07C13/19 , C07C2523/42 , Y02P20/52 , C07C15/04 , C07C9/14
摘要: In a dehydrogenation process a hydrocarbon stream comprising at least one non-aromatic six-membered ring compound and at least one five-membered ring compound is contacted with a dehydrogenation catalyst produced by a method comprising treating the support with a liquid composition comprising the dehydrogenation component or a precursor thereof and at least one organic dispersant selected from an amino alcohol and an amino acid. The contacting is conducted under conditions effective to convert at least a portion of the at least one non-aromatic six-membered ring compound in the hydrocarbon stream to benzene and to convert at least a portion of the at least one five-membered ring compound in the hydrocarbon stream to paraffins.
摘要翻译: 在脱氢方法中,包含至少一种非芳族六元环化合物和至少一种五元环化合物的烃流与脱氢催化剂接触,所述脱氢催化剂通过包括用包含脱氢组分的液体组合物处理载体的方法制备 或其前体和至少一种选自氨基醇和氨基酸的有机分散剂。 该接触在有效将烃流中的至少一种非芳香族六元环化合物的至少一部分转化为苯并将至少一部分至少一种五元环化合物转化为 烃流至石蜡。
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公开(公告)号:US08802907B2
公开(公告)日:2014-08-12
申请号:US13516401
申请日:2010-12-17
申请人: Teng Xu , Edward A. Lemon, Jr. , Tan-Jen Chen , Terry E. Helton
发明人: Teng Xu , Edward A. Lemon, Jr. , Tan-Jen Chen , Terry E. Helton
CPC分类号: C07C5/31 , C07C2/74 , C07C5/367 , C07C2529/12 , C07C2529/14 , C07C2529/44 , C07C2529/46 , C07C2529/74 , C07C2529/76 , C07C2601/14 , C07C13/28 , C07C9/15 , C07C9/16 , C07C15/04
摘要: A processes for producing a dehydrogenation reaction product stream comprising the step of contacting a hydrocarbon stream comprising cyclohexane and methyl cyclopentane with a dehydrogenation catalyst comprising at least one metal or compound thereof and at least one molecular sieve and under conditions effective to convert at least a portion of the cyclohexane to benzene and to convert at least a portion of the methyl cyclopentane to at least one paraffin. The hydrocarbon stream is produced by hydroalkylating benzene and hydrogen to form a hydroalkylation reaction product stream which is separated to yield the hydrocarbon stream.
摘要翻译: 一种用于生产脱氢反应产物流的方法,包括使包含环己烷和甲基环戊烷的烃物流与包含至少一种金属或其化合物的脱氢催化剂和至少一种分子筛接触的步骤,并且在有效地将至少一部分 的环己烷至苯并将至少一部分甲基环戊烷转化为至少一种石蜡。 烃流是通过加氢烷基化苯和氢来形成加氢烷基化反应产物流,其被分离以产生烃流。
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公开(公告)号:US20120271079A1
公开(公告)日:2012-10-25
申请号:US13516401
申请日:2010-12-17
申请人: Teng Xu , Edward A. Lemon, JR. , Tan-Jen Chen , Terry E. Helton
发明人: Teng Xu , Edward A. Lemon, JR. , Tan-Jen Chen , Terry E. Helton
CPC分类号: C07C5/31 , C07C2/74 , C07C5/367 , C07C2529/12 , C07C2529/14 , C07C2529/44 , C07C2529/46 , C07C2529/74 , C07C2529/76 , C07C2601/14 , C07C13/28 , C07C9/15 , C07C9/16 , C07C15/04
摘要: A processes for producing a dehydrogenation reaction product stream comprising the step of contacting a hydrocarbon stream comprising cyclohexane and methyl cyclopentane with a dehydrogenation catalyst comprising at least one metal or compound thereof and at least one molecular sieve and under conditions effective to convert at least a portion of the cyclohexane to benzene and to convert at least a portion of the methyl cyclopentane to at least one paraffin. The hydrocarbon stream is produced by hydroalkylating benzene and hydrogen to form a hydroalkylation reaction product stream which is separated to yield the hydrocarbon stream.
摘要翻译: 一种用于生产脱氢反应产物流的方法,包括使包含环己烷和甲基环戊烷的烃物流与包含至少一种金属或其化合物的脱氢催化剂和至少一种分子筛接触的步骤,并且在有效地将至少一部分 的环己烷至苯并将至少一部分甲基环戊烷转化为至少一种石蜡。 烃流是通过加氢烷基化苯和氢来形成加氢烷基化反应产物流,其被分离以产生烃流。
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